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Ponchon-Savarit Method
Dignadice, Joyce Reyen B. June 6, 2020
Montesa, Shania Angel M.
1000 kg/hr of a mixture containing 42 mole percent heptane and 58 mole percent ethyl
benzene is to be fractionated to a distillate containing 97 mole percent heptane and a
residue containing 99 mole percent ethyl benzene using a total condenser and feed at
its saturated liquid condition. The enthalpy-concentration data for the heptane-ethyl
benzene at 1 atm pressure are as follows:
Given:
F=1000 kg /h
x F =0.42
x D =0.97
x W =1−0.99=0.01
saturated liquid feed
P=1 atm
R=2.5
Required:
N stages
qC
qR
Solution:
kg kg kg
(
M W F =0. 42 100
kmol ) (
+ ( 1−0.42 ) 106 )
kmol
=103.48
kmol
kg
1000
h kmol
F= =9.6637
kg h
103.48
kmol
MVC balance:
x F F=x D D+ x W W
0.42 ( 9.6637 ) =0.97 D+0.01W
Solving simultaneously,
kmol
D=4.1272
h
kmol
W =5.5365
h
Reflux ratio:
L0
R=
D
L0
2.5=
kmol
4.1272
h
kmol
L0=10.318
h
q R =473,797.99 kJ /h
Q’:
' qC
Q =H xD +
D
kJ
464,607.61
kJ h
Q ' =21,484.57 +
kmol kmol
4.1272
h
kJ
Q ' =134,056.68
kmol
Q’’:
'' qR
Q =H xW −
W
kJ
473,797.99
kJ h
Q' ' =24,327.95 −
kmol kmol
5.5365
h
kJ
Q ' ' =−61,249.22
kmol
Plotting,