2 Agustus Baru

Outlet Natural Gas (S3)
Lean Benfield (S2)
Tabel Lamp
Inlet Natural Gas ( S1 )
Rich Benfield (S4)

Tabel Lampira
Tabel 5.1. Data Operasi Inlet Natural Gas (S1)
Temperatur Tekanan Flow
Tanggal
(0C) (kg/cm2) (m3/hr)
2/8/2018 108 24.98 25,495
6/8/2018 105 25.00 25,888
9/8/2018 109.9 25.89 26,180
13/08/2018 115 25.56 25,343
16/8/2018 119 25.44 25,740
(sumber : Log sheet Absorber 201-E, 2018)
Tabel 5.2. Komposisi Inlet Natural Gas ( S1 ) Tabel Lam
Tanggal
Komponen
2/8/2018 6/8/2018 9/8/2018 13/8/2018 16/8/2018
CO2 5.35 5.82 5.63 5.65 4.72
N2 1.23 1.16 0.65 1.07 1.12
CH4 84.72 84.74 85.21 84.81 85.67
C2 H 6 6.33 6.07 6.27 6.26 6.22
C3 H 8 1.41 1.3 1.4 1.29 1.41
i-C4H10 0.26 0.24 0.26 0.29 0.25
n-C4H10 0.32 0.3 0.32 0.28 0.29
i-C5H12 0.14 0.13 0.13 0.12 0.12
n-C5H13 0.09 0.09 0.08 0.07 0.08 Tabel Lam
C6H14 0.15 0.15 0.05 0.16 0.12
(sumber: Laporan Hasil Analisa kinerja Pabrik Amoniak Pusri IV, 2018)
Tabel 5.3. Data Operasi Inlet Lean Benfield (S2)

Tanggal
(0C) (kg/cm2) (m3/hr)
2/8/2018 78 24.98 121.5
6/8/2018 75 25.00 124.6
9/8/2018 73 25.89 116.6
13/08/2018 77 25.56 124.0
16/8/2018 85 25.44 121.5
(sumber : log sheet Absorber 201-E, 201
Tabel 5.4. Data Hasil Analisa SPGR Lean Benfield ( S2 )

Tanggal SPGR
2/8/2018 1.248
6/8/2018 1.236
9/8/2018 1.236
13/08/2018 1.238
16/8/2018 1.23
Sumber : Laboratorium PT PUSRI IV , 2018)
Tabel 5.5. Data Hasil Analisa Lean Benfield ( S2 )

Komponen (%)
Tanggal
K2CO3 V2O5 DEA H2O
2/8/2018 20.56 1.63 1.96 75.85
6/8/2018 20.54 1.47 2.07 75.92
9/8/2018 19.1 1.53 3.04 76.33
13/08/2018 20.04 1.51 1.46 76.99
16/8/2018 18.11 1.47 3.61 76.81
(Sumber : Laboratorium PUSRI IV, 2018)
Tabel 5.6. Data Operasi Outlet Natural Gas (S3)

Temperatur Tekanan
Tanggal
(0C) (kg/cm2)
2/8/2018 97 24.88
6/8/2018 97 24.90
9/8/2018 97 25.79
13/8/2018 97 25.46
16/8/2018 97 25.34
(sumber : Log sheet Absorber 201-E, 2018)
Tabel 5.7. Data Komponen Outlet Natural Gas (S3)

Komponen Tanggal
2/8/2018 6/8/2018 9/8/2018 13/8/2018 16/8/2018
CO2 0.27 0.27 0.27 0.28 0.27
N2 1.30 1.23 0.69 1.13 1.17
CH4 89.27 89.73 90.05 89.64 89.67
C2 H 6 6.67 6.43 6.63 6.62 6.51
C3 H 8 1.49 1.38 1.48 1.36 1.48
i-C4H10 0.27 0.25 0.27 0.31 0.26
n-C4H10 0.34 0.32 0.34 0.3 0.3
i-C5H12 0.15 0.14 0.14 0.13 0.13
n-C5H13 0.09 0.1 0.08 0.07 0.08
C6H14 0.16 0.16 0.05 0.17 0.13
(sumber: Laporan Hasil Analisa kinerja Pabrik Amoniak Pusri IV, 2018) r
Tabel 5.8. Data Operasi Outlet Rich Benfield (S4)

Temperatur Tekanan
Tanggal
(0C) (kg/cm2)
2/8/2018 119 24.88
6/8/2018 119 24.9
9/8/2018 120 25.79
13/8/2018 121 25.46
16/8/2018 121 25.34
(sumber : log sheet Absorber 201-E, 2018)
Tabel. Rich benfield masuk Stripper
Regenerator (202-E)
Temperatur Tekanan
Tanggal
(˚C) (kg/cm2)
2-Aug-18 119 0.99
6-Aug-18 119 0.90
9-Aug-18 120 0.92
13-Aug-18 121 0.93
16-Aug-18 121 0.95
Tabel Lampiran 2.29. Data Operasi Acid Gas Keluar

Stripper (202-E)
Temperatur Tekanan
Tanggal
(˚C) (Kg/Cm2)
2-Aug-18 126 0.79
6-Aug-18 125 0.70
9-Aug-18 124.5 0.72
13-Aug-18 124 0.73
16-Aug-18 124 0.75
Tabel Lampiran 2.30. Data Operasi Lean Beanfiled Keluar

Regenerator (202-E) Tanggal
Temperatur Tekanan
Tanggal
(˚C) (kg/cm2)) 2/8/2018
2-Aug-18 129 0.79 6/8/2018
6-Aug-18 131 0.7 9/8/2018
9-Aug-18 131.4 0.72 13/08/2018
13-Aug-18 131 0.73 16/8/2018
16-Aug-18 131 0.75
Tabel Lampiran 2.31. Data Operasi Steam Masuk
Reboiler (202-C)
Laju Alir Temperatur Tekanan
Tanggal
(Nm /H)
3
(˚C) (kg/cm2) Tanggal
6-Aug-18 15.1 150 3.5
7-Aug-18 14.98 150 3.5 2/8/2018
8-Aug-18 14.85 150 3.5 6/8/2018
9-Aug-18 15 150 3.5 9/8/2018
10-Aug-18 14.85 150 3.5 13/08/2018
(sumber : log sheet Absorber 201-E, 2018) 16/8/2018
Tabel Lampiran 2.31. Data Operasi Steam keluar

Reboiler (202-C)
Temperatur
Tanggal
(˚C)
6-Aug-18 127
7-Aug-18 127
8-Aug-18 128
9-Aug-18 129
10-Aug-18 128
Efisiensi
Tanggal
(%)
2 Agustus 2018 46.6
6 Agustus 2018 50.1
9 Agustus 2018 49.6
13 Agustus 2018 43.4
16 Agustus 2018 49.2
Parameter
Temperatur
(0C)
Tekanan
(kg/cm2)
Flow
(Nm3)
Tanggal (0C) (kg/cm2) (m3/hr)
S1 S2 S1 S2 S1 S2
2/8/2018 108 24.98 25,495 a
6/8/2018 105 25.00 25,888
9/8/2018 110 25.89 26,180
13/08/2018 115 25.56 25,343
16/8/2018 119 25.44 25,740
Tanggal (0C) (kg/cm2) (m3/hr)
S1 S2 S1 S2 S1 S2
2/8/2018 108 78 24.98 24.98 25,495 121.5
6/8/2018 105 75 25.00 25 25,888 124.6
9/8/2018 110 73 25.89 25.89 26,180 116.6
13/08/2018 115 77 25.56 25.56 25,343 124
16/8/2018 119 85 25.44 25.44 25,740 121.5
16/8/2018
2/8/2018 6/8/2018 9/8/2018 13/8/2018 S2 S1
Parameter
S1 S2 S1 S2 S1 S2 S1
77 119
Temperatur 115
108 78 105 75 109.9 73
(0C)
25.56 25.44
Tekanan 26
24.98 24.98 25 25 25.89 25.89
(kg/cm2)
124 25,740
Flow ###
25,495 121.5 25,888 124.6 26,180 116.6
(Nm3)
16/8/2018
S2
85
25.44
121.5
LAMPIRAN II
PERHITUNGAN EFISIENSI TERMAL PADA ABSORBER 201-E
DAN STRIPPER 202-E PADA UNIT AMONIA PUSRI IV
S3
S2
S5
S6
S1
201-E S7
202-E
S4
Gambar L2. 1 Blok Diagram Absorber dan Stripper
Keterangan :
1. Natural Gas
2. Lean Benfield
3. Sweet Gas
4. Rich Benfield
5. Acid Gas
6. Steam
7. Kondensat
LAMPIRAN II
PERHITUNGAN
A. Menghitung Neraca Massa pada Absorber Tanggal 2 Agustus 2016

Sweet Gas (S3)
P = 25.00 kg/cm²
Lean Benfield (S2) T = 108 ⁰C
P = 26.13 kg/cm² Komposisi sweet Gas :
T = 89 ⁰C CO2 = 0.49 %
V = 123.75 Nm³/hr N2 = 1.06 %
Komposisi Lean Benfield: CH4 = 89.84 %
K2CO3 = 14.16 % C2 H 6 = 6.88 %
V2O5 = 0.81 % C3 H 8 = 0.79 %
DEA = 0.93 % i-C4H10 = 0.13 %
H2O = 84.10 % n-C4H10 = 0.16 %
100 % i-C5H12 = 0.06 %
Natural Gas (S1) n-C5H13 = 0.08 %

P = 26.13 kg/cm² C6H14 = 0.05 %
T = 85 ⁰C 100 %
V = 24249 Nm³/hr Rich Benfield (S4)
Komposisi Natural Gas : P = 25.00 kg/cm²

CO2 = 5.49 % T = 110 ⁰C
N2 = 1.01 %
CH4 = 85.84 % Komposisi Rich Benfield :
C2 H 6 = 6.59 % K2CO3 = …?
C3 H 8 = 0.62 % V2O5 = …?
i-C4H10 = 0.12 % DEA = …?
n-C4H10 = 0.15 % H2O = …?
i-C5H12 = 0.06 % KHCO3 = …?
n-C5H13 = 0.08 %
C6H14 = 0.04 %
Total 100 %
Gambar L2. 1 Data Analisa dan Kondisi Operasi Absorber 201-E
1. Menghitung Massa Masuk Absorber
Basis : 1 jam operasi
Natural Gas (S₁)
Laju Alir = 24249 Nm³/hr
Tekanan = 26.13 kg/cm² 0.967 atm

1 kg/cm²
= 25.27 atm
Temperatur = 85 ⁰C
= 85 + 273 K
= 358 K
Aliran Natural Gas (S1) dalam keadaan standar (0oC, 1 atm)

1 mol = 22,41 liter
Sehingga mol Natural Gas, yaitu :
Mol = 24249 m³ 1000 liter 1 mol
1 Nm³ 22.4 liter
= 1082544.6 mol
= 1082.5446 kmol
Untuk menghitung mol komponen dapat dihitung melalui persamaan :

nkomponen = % (V) x nt
n CO2 = 5.49 % x 1082.5446 kmol
= 59.432 kmol
Untuk menghitung massa komponen dapat dihitung melalui persamaan :

mkomponen = nkomponen x BMkomponen
m CO2 = 59.43 Kmol x 44 kg/kmol
= 2614.99 kg
Hasil perhitungan massa komponen S1 ditunjukkan pada

Tabel L2. 1.
Tabel L2. 1 Massa Natural Gas Masuk Absorber (S1)

Mol BM Massa
Komponen % Volume
(Kmol) (kg/kmol) (kg)
CO2 5.49 59.432 44 2614.99
N2 1.01 10.934 28 306.14
CH4 85.84 929.256 16 14868.10
C2 H 6 6.59 71.340 30 2140.19
C3 H 8 0.62 6.712 44 295.32
i-C4H10 0.12 1.299 58 75.35
n-C4H10 0.15 1.624 58 94.18
i-C5H12 0.06 0.650 72 46.77
n-C5H13 0.08 0.866 72 62.35
C6H14 0.04 0.433 86 37.24
Total 100 % 1082.545 20540.64
Lean Benfield (S₂)

Laju Alir = 123.75 Nm³/hr
SPGR = 1.15
Densitas H2O (60 F)o
= 998.9 kg/m³
Densitas Lean Benfield = SPGR x Densitas H2O (60oF)
= 1148.7350 kg/m³
Massa Lean Benfield = Volume x ρ
= 123.8 m³ x 1148.7350 kg/m³
= 142155.9563 kg
Tabel L2. 2 Mol Lean Benfield Masuk Absorber

Massa BM Mol
Komponen % Massa
(kg/hr) (kg/kmol) (Kmol)
K2CO3 14.16 20129.283 138 145.864
V2 O5 0.81 1151.463 181 6.362
DEA 0.93 1322.050 109 12.129
H2O 84.10 119553.159 18 6641.842
Total 100 142155.956 6806.197
2. Menghitung Massa Keluar Absorber

Sweet Gas (S₃)
1 kg/cm²
= 24.18 atm
= 108 + 273 K
= 381 K
Neraca Carbon
C masuk :
CH4 = 1.0 x 929.26 kmol x 929.26 kmol
C2H6 = 1/2 x 71.34 kmol x 35.67 kmol
C3H8 = 1/3 x 6.71 kmol x 2.24 kmol
i-C4H10 = 1/4 x 1.30 kmol x 0.32 kmol
n-C4H10 = 1/4 x 1.62 kmol x 0.41 kmol
i-C5H12 = 1/5 x 0.65 kmol x 0.13 kmol
n-C5H12 = 1/5 x 0.87 kmol x 0.17 kmol
C6H14 = 1/6 x 0.43 kmol x 0.07 kmol
968.27 kmol
Menentukan Mol Sweet Gas (S3)

Cmasuk = Ckeluar
968.27 Kmol =
{ 89.8 % +
1
2
x 6.88 % +
1
3
x 0.79 % +
1
4
1 1 1
x 0.13 % + x 0.16 % + x 0.06 % +
4 5 5
x 0.08 % +
1
6
x 0.05 % }S 3
968.27 Kmol = 0.94 S₃
S3 = 1033.90 Kmol
Menentukan Mol Komponen Sweet Gas

Mol Komponen dapat dihitung melalui persamaan :
nk vk
=
nt vt
nk = vk x nt
vt
nk = (%v x vt) x nt
vt
nk = %v x nt
n CO2 = 0.49 % x 1033.8997 kmol
= 5.066 kmol
Untuk menghitung massa komponen dapat dihitung melalui persamaan :

mkomponen = nkomponen x BMkomponen
m CO2 = 5.07 Kmol x 44 kg/kmol
= 222.91 kg
Dengan cara yang sama, hasil perhitungan massa komponen Sweet

Gas dapat dilihat pada tabel L2.3
Tabel L2. 3 Massa Sweet Gas Keluar Absorber (S3)

Komponen % Volume Mol BM Massa
CO2 0.49 % 5.066 44 222.91
N2 1.06 % 10.959 28 306.86
CH4 89.84 % 928.855 16 14861.69
C2 H 6 6.88 % 71.132 30 2133.97
C3 H 8 0.79 % 8.168 44 359.38
i-C4H10 0.13 % 1.344 58 77.96
n-C4H10 0.16 % 1.654 58 95.95
i-C5H12 0.06 % 0.620 72 44.66
n-C5H13 0.08 % 0.827 72 59.55
C6H14 0.05 % 0.517 86 44.46
Total 100 % 1029.144 18207.39
Rich Benfield (S4)
Reaksi penyerapan yang terjadi adalah sebagai berikut :
K2CO3(l) + H2O(l) + CO2(g) 2KHCO3(l)
Pada reaksi ini yang menjadi reaktan pembatas adalah CO 2 dengan

jumlah mol yang bereaksi sebesar 57,98 mol sehingga didapatkan :
K2CO3 sisa = 145.86 - 54.37 ) kmol
= 91.50 Kmol
H2O sisa = 6641.84 54.37 ) kmol

= 6587.48 Kmol
CO2 sisa = 59.43 - 54.37 ) kmol

= 5.07 Kmol
KHCO3 terbentuk = 2 x 54.37 kmol

= 108.73 Kmol
Tabel L2. 4 Massa Outlet Rich Benfield Absorber (S4)

Komponen Mol BM Massa
% Massa
K2CO3 91.499 138 12626.832 8.74
V2 O5 6.362 181 1151.463 0.80
DEA 12.129 109 1322.050 0.91
H2O 6587.477 18 118574.579 82.03
KHCO3 108.731 100 10873.119 7.52
Total 6806.197 144548.042 100
Tabel L2. 5 Neraca Massa Komponen CO2 Absorber 201-E
Input, (kg) Output, (kg)
Komposisi
S1 S2 S3 S4
CO2 2614.99 - 222.91 -
N2 306.14 - 306.86 -
CH4 14868.10 - 14861.69 -
C2 H 6 2140.19 - 2133.97 -
C3 H 8 295.32 - 359.38 -
i-C4H10 75.35 - 77.96 -
n-C4H10 94.18 - 95.95 -
i-C5H12 46.77 - 44.66 -
n-C5H13 62.35 - 59.55 -
C6H14 37.24 - 44.46 -
K2CO3 - 20129.28 - 12626.83
V2O5 - 1151.46 - 1151.46
DEA - 1322.05 - 1322.05
H2O - 119553.16 - 118574.58
KHCO3 - - 10873.12
20540.64 142155.96 18207.39 144548.04
Total
162697 162755
59
Hasil Perhitungan neraca massa Absorber pada tanggal 6,9,13, dan 16
Agustus 2018 dapat dilihat pada Tabel 5.14 sampai Tabel 5.17 pada
bab 5.
Outlet Sweet Gas (S3)
P = 25.00 kg/cm²
T = 108 ⁰C
Lean Benfield (S2) Komposisi Natural Gas :
P = 26.13 kg/cm² CO2 = 222.909 kg
T = 89 ⁰C N2 = 306.861 kg
V = 123.75 Nm³/hr CH4 = 14861.687 kg
Komposisi Lean Benfield: C2H6 = 2133.969 kg
K2CO3 = 20129.283 kg C3H8 = 359.384 kg
V2O5 = 1151.463 kg i-C4H10 = 77.956 kg
DEA = 1322.050 kg n-C4H10 = 95.946 kg
H2O = 119553.159 kg i-C5H12 = 44.664 kg
n-C5H13 = 59.553 kg
Natural Gas (S1) C6H14 = 44.458 kg
P = 26.13 kg/cm²
T = 85 ⁰C
V = 24249 Nm³/hr
Komposisi Natural Gas : Rich Benfield (S4)

CO2 = 2614.995 kg P = 25.00 kg/cm²
N2 = 306.144 kg T = 110 ⁰C
CH4 = 14868.101 kg
C2 H 6 = 2140.191 kg Komposisi Rich Benfield :
C3 H 8 = 295.318 kg K2CO3 = 12626.832 kg
i-C4H10 = 75.345 kg V 2 O5 = 1151.463 kg
n-C4H10 = 94.181 kg DEA = 1322.050 kg
i-C5H12 = 46.766 kg H2 O = 118574.579 kg
n-C5H13 = 62.355 kg KHCO3 = 10873.119 kg
C6H14 = 37.240 kg
Gambar L2. 2 Neraca Massa Keseluruhan Absorber 201-E

11
### 10.959 306.86
2.13683676 5.06611 44 222.91

0.98778303 10.9593 28 306.86
116.546083 928.86 16 14861.69
0.1521875 71.1323 30 2133.97
1.32537976 8.16781 44 359.38
8.05423085 1.34407 58 77.96
6.54406257 1.65424 58 95.95
0.62034 72 44.66
116.546083 1261.66338 0.82712 72 59.55
0.51695 86 44.46
5.49
1.012 10.959 28 306.86
85.80 928.855 16 14861.69
6.57 71.132 30 2133.97
0.75 8.168 44 359.38
0.1242 1.344 58 77.96
0.15281027 1.654 58 95.95
0.05730385 0.620 72 44.66
0.07640514 0.827 72 59.55
0.04775321 0.517 86 44.46
100.089111
K2CO3(l) + H2O(l) + CO2(g) 2KHCO3(l)
145.86 kmol 6641.84 kmol 59 kmol
54.37 kmol 54.37 kmol 54 kmol 108.73 kmol
91.50 kmol 6587.48 kmol 5.07 kmol 108.73 kmol
t Sweet Gas (S3)
25.00 kg/cm²
108 ⁰C
222.909 kg
306.861 kg
14861.687 kg
2133.969 kg
359.384 kg
77.956 kg
95.946 kg
44.664 kg
59.553 kg
44.458 kg
Rich Benfield (S4)
25.00 kg/cm²
110 ⁰C
omposisi Rich Benfield :

12626.832 kg
1151.463 kg
1322.050 kg
118574.579 kg
10873.119 kg
uhan Absorber 201-E

Mencari Komponen gas Outlet
C02 = 0.27 %
Vt = Vt - V-CO2
%Co2
VT = Vt - 22917.73 Volume
0.0027 (Nm3)
22918 1- 0.0027 Vt 1331.270
Vt = 22979.7753 244.915
% volume 20815.342
CO2 22979.7753 0.27 1598.009
N2 22979.7753 ### 1.07 150.344
CH4 22979.7753 ### 90.58 29.099
C2 H 6 22979.7753 ### 6.95 36.374
C3 H 8 22979.7753 ### 0.65 14.549
i-C4H10 22979.7753 29.0988 0.13 19.399
n-C4H10 22979.7753 36.3735 0.16 9.700
i-C5H12 22979.7753 14.5494 0.06 24249.000
n-C5H13 22979.7753 19.3992 0.08
C6H14 22979.7753 9.6996 0.04
100
Tabel 21. Neraca panas CO2 absorber Unit 201-E
Input Output
Aliran Panas
(kJ/Jam) (kJ/Jam)
Inlet Natural Gas (QS1) 20540.635 -
Inlet Lean Benfield (QS2) 142155.956 -
Outlet Sweet gas (QS3) - 18207.386
Outlet Rich Benfield (QS4) - 144548.042
162696.591 162755.429
B. Menghitung Neraca Massa pada Stripper
Acid Gas (S5)

P = 0.8 kg/cm²
T = 126 °C
Komposisi Rich Benfield
Rich Benfield (S4) CO2 = …?
H2O = …?
Steam Masuk (S6)
T = 119 °C
P = 0.99 kg/cm²
K2CO3 = 8.74 % Kondensat Keluar (S7)
V2O5 = 0.80 %
DEA = 0.91 %
H2O = 82.03 % Lean Benfield (S2)
KHCO3 = 7.52 %
100 % P = 0.8 kg/cm²
T = 129 °C

K2CO3 = …?
V2O5 = …?
DEA = …?
H2O = …?
Gambar L2. 4 Data Analisa dan Kondisi Operasi Stripper 202-E

1. Menghitung Massa Masuk Stripper 201-E
Rich Benfield (S4)
Tabel L2. 6 Massa Rich Benfield masuk Stripper (S4)

Mol BM Massa
Komponen % Massa
K2CO3 91.499 138 12626.832 8.74
V2O5 6.362 181 1151.463 0.80
DEA 12.129 109 1322.050 0.91
H2O 6587.477 18 118574.579 82.03
KHCO3 108.731 100 10873.119 7.52
Total 6806.197 144548.042 100
2. Menghitung Massa Keluar Stripper 201-E

- Acid Gas dan Lean Benfield (S5 dan S2)
Diketahui:
Operasi 1 kg/cm²
= 0.76 atm
keluar = 119 + 273 K
= 392 K
Reaksi yang terjadi di Benfield Stripper adalah sebagai berikut :

2KHCO3(l) K2CO3(l) + CO2(g) + H2O(l)
CO2 terurai = 54.37 kmol x 44 kg/kmol

= 2392.0861 kg
K2CO3 terurai = 54.37 kmol x 138 kg/kmol
= 7502.452 kg
H2O terurai
Diketahui P H20 pada temperatur 119 °C
Psat H2O = 0.934 atm
(sumber: The M.W. Kellog Company, Operating Instructions Manual, 1976):
Psat H2O nH2O (hougen, 1943)

=
P(Total) nTotal - nH2O
0.934 atm nH2O
=
0.764 atm 54.37 kmol - nH2O
nH2O
1.2226 =
54.37 kmol - nH2O
66.469 kmol - 1.2226 nH₂O = nH2O
(1 + 1.2226 ) nH₂O = 66.469 kmol
nH2O = 29.906 kmol
Tabel L2. 7 Massa Lean Benfield keluar Stripper (S2)

% Massa
K2CO3 145.864 138 20129.283 14.21
V2O5 6.362 181 1151.463 0.81
DEA 12.129 109 1322.050 0.93
H2O 6611.937 18 119014.860 84.04
Total 6776.292 141617.657 100
Tabel L2. 8 Massa Acid Gas keluar Stripper (S5)

% Massa
H2O 29.906 18 538.299 18.37
CO2 54.366 44 2392.086 81.63
Total 84.271 2930.385 100
Tabel L2.9 Neraca Massa Komponen Stripper 202-E
Input, (kg) Output, (kg)
Komposisi
S4 S5 S2
K2CO3 12626.832 - 20129.283
V2O5 1151.463 - 1151.463
DEA 1322.050 - 1322.050
H2O 118574.579 538.299 119014.860
KHCO3 10873.119 - -
CO2 - 2392.086 -
144548.042 2930.385 141617.657
Total
144548.042 144548.042
Hasil Perhitungan neraca massa Stripper pada tanggal 6,9,13, dan 16

Agustus 2018 dapat dilihat pada Tabel 5.19 sampai Tabel 5.22 pada bab 5.
Acid Gas (S5)
P = 0.8 kg/cm²
T = 126 °C
Rich Benfield (S4) CO2 = 538.299 kg
H2O = 2392.086 kg
T = 119 °C SteamMasuk (S6)
P = 0.99 kg/cm²
K2CO3 = 12626.832 kg
V2O5 = 1151.463 kg Kondensat Keluar (S7)
DEA = 1322.050 kg
H2O = 118574.579 kg
KHCO3 = 10873.119 kg Lean Benfield (S2)
P = 0.8 kg/cm²
T = 129 °C
Komposisi Lean Benfield
K2CO3 = 20129.283 kg
V2O5 = 1151.463 kg
DEA = 1322.050 kg
H2O = 119014.860 kg
Gambar L2. 5 Neraca Massa Keseluruhan Stripper 202-E

108.73 kmol 54.37 kmol 54.37 kmol 54.37 kmol
Tabel 30. Neraca Energi Stripper 202-E
Input Output
Aliran Panas
(kJ/Jam) (kJ/Jam)
Inlet Rich Benfield(QS4) 144548.04 -
Outlet Lean Benfield (QS2) - 141617.66
Outlet Acid gas (QS5) - 2930.39
144548.04 144548.04
36
T = 381.15 K P = 24.156 atm

energi masuk
Cp0 Cp0 Pc
Komponen a b x 10-2 c x 10-5 d x 10-9
(kkal/kmol-K) (kj/kmol-K) (atm)
CO2 4.728 1.754 -1.338 4.097 9.6964 40.5971 72.9
N2 7.44 -0.324 0.640 -2.79 6.9803 29.2253 33.5
CH4 4.598 1.245 0.286 -2.703 9.6091 40.2315 45.8
C2 H 6 1.292 4.254 -1.657 2.081 15.2141 63.6986 48.2
C3 H 8 -1.009 7.315 -3.789 7.678 21.7928 91.2420 42.01
i-C4H10 -0.332 9.189 -4.409 6.915 28.6696 120.0338 36
n-C4H10 2.266 7.913 -2.647 -0.674 28.5436 119.5065 37.47
i-C5H12 -2.275 12.100 -6.519 13.67 35.1306 147.0847 32.9
n-C5H13 -0.866 11.640 -6.163 12.67 35.2481 147.5768 33.31
C6H14 -1.054 13.900 -7.449 15.51 41.9631 175.6911 29.92
381.15 K 24.156 atm 8.3145 hougen cal/gmolC energi keluar

381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 Pc
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 (atm)
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 72.9
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 33.5
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 45.8
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 48.2
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 42.01
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 36
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 37.47
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145 32.9
370.15 K 24.059 atm 8.3145 33.31
29.92
37
energi masuk
Pc Tc Cp-Cp0 Cp0 Cp
Pr Tr Komponen
(atm) (K) KJ/Kmol-K
72.9 304.2 0.33136 1.25296 5.201 39.031 44.232 CO2
33.5 126.2 0.72107 3.02021 0.648 29.185 29.833 N2
45.8 190.7 0.52742 1.99869 2.795 38.034 40.829 CH4
48.2 305.43 0.50116 1.24791 9.813 58.545 68.358 C2H6
42.01 369.9 0.57501 1.03041 24.393 83.217 107.610 C3H8
36 408.1 0.671 0.93396 98.025 109.715 207.74 i-C4H10
37.47 425.2 0.64468 0.8964 74.382 109.698 184.080 n-C4H10
32.9 461 0.73422 0.82679 66.129 134.041 200.170 i-C5H12
33.31 469.8 0.72519 0.8113 65.017 134.933 199.950 n-C5H13
29.92 507.9 0.80735 0.75044 66.867 160.673 227.540 C6H14
energi keluar 4.1868

Pc Tc Cp-Cp0 Cp0 Cp
Pr Tr
(atm) (K) KJ/Kmol-K
72.9 304.2 0.33003 0.82183 5.400 38.809 44.209 CO2
33.5 126.2 0.71818 0.34094 0.677 29.180 29.857 N2
45.8 190.7 0.52531 0.5152 2.614 37.725 40.339 CH4
48.2 305.43 0.49915 0.82515 9.726 57.816 67.542 C2 H 6
42.01 369.9 0.5727 0.99932 27.320 82.080 109.400 C3 H 8
36 408.1 0.66831 1.10253 76.227 108.253 184.48 i-C4H10
37.47 425.2 0.64209 1.14872 65.620 108.310 173.930 n-C4H10
32.9 461 0.73128 1.24544 61.907 132.193 194.100 i-C5H12
33.31 469.8 0.72228 1.26922 61.288 133.142 194.430 n-C5H13
29.92 507.9 0.80411 1.37215 63.975 158.545 222.520 C6H14
38
Cp0
Komponen a a1x10-3 a2x10-5 a3x10-8 a4x10-11
(kj/kmol-K)
CO2 3.259 1.356 1.502 -2.374 1.056 40.4602
N2 3.359 -0.026 0.007 0.157 -0.099 28.4796
CH4 4.568 -8.975 3.631 -3.407 1.091 39.6258
C2H6 4.178 -4.427 5.660 -6.651 2.487 62.8189
C3H8 3.847 5.131 6.011 -7.893 3.079 89.9173
i-C4H10 3.351 17.883 5.477 -8.099 3.243 119.0945
n-C4H10 5.547 5.536 8.057 -10.57 4.134 119.5756
i-C5H12 1.959 38.191 2.434 -5.175 2.165 146.6922
n-C5H13 7.554 -0.368 11.846 -14.94 5.753 146.0416
C6H14 8.831 -0.166 14.302 -18.31 7.124 173.8559
4.1868 0.9 3.76812 10.5964

44.2283 44.3652
1. Menghitung Panas Masuk Absorber 201-E
Natural Gas (QS₁)
masuk = 85 ⁰C + 273.15 K
= 358.15 K
Temperatur 30 ⁰C
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 55 K

1 kg/cm²
= 25.27 atm
Menentukan kapasitas panas dalam kondisi tekanan konstan 1 atm (Cp*)

dapat dihitung melalui persamaan :
Cp* = a + bT + (cT2) + (dT3)
(∫_𝑇1^𝑇2▒ 〖 a+bT+cT2+dT3 〗 " dT "
Cpm =
)/(T2+T1)
= a + b/2 (T1+T2) + c/3 (T1 + T1T2 + T2 ) + d/4 (T1 + T1 T2 +

2 2 3 2
T1T22
+T23)
Cp CO2= 4,728 + (1,754 𝑥 〖 10 〗 ^(−2))/2 x (381,15 + 303,15) +
(−1,34 𝑥 〖 10 〗 ^(−5))/3 x (381,152
+ 381,15 x 303,15 + 303,152) + (4,097 𝑥 〖 10 〗 ^(−9))/4 x

(381,153 + 381,152
x 303,15 + 381,15 x 303,152+ 303,153)

= 9.322 kkal/kmol-K
= 39.03 kj/kmol-K
Dengan cara yang sama, hasil perhitungan kapasitas panas dalam

kondisi tekanan konstan 1 atm (Cp*) dapat dilihat pada Tabel L2.10
Tabel L2. 10 Kapasitas Panas Standar Natural Gas (CP*)
Cp*
(kj/kmol-K)
CO2 4.728 1.754 -1.338 4.097 39.0311
N2 7.44 -0.324 0.640 -2.79 29.1849
CH4 4.598 1.245 0.286 -2.703 38.0344
C2H6 1.292 4.254 -1.657 2.081 58.5453
C3H8 -1.009 7.315 -3.789 7.678 83.2166
i-C4H10 -0.332 9.189 -4.409 6.915 109.7147
n-C4H10 2.266 7.913 -2.647 -0.674 109.6975
i-C5H12 -2.275 12.100 -6.519 13.67 134.0412
n-C5H13 -0.866 11.640 -6.163 12.67 134.9334
C6H14 -1.054 13.900 -7.449 15.51 160.6731
(Sumber : Sherwood)
Menentukan kapasitas panas dalam kondisi Operasi (Cp)

CO2 (1 atm) = 39.0311 kj/kmol-K
Pc CO2 = 72.9 atm
Pr CO2 = Paktual/Pc
= 25.27 atm
72.9 atm
= 0.34661
Tc CO2 = 304.2
Tr CO2 = Taktual/Tc
= 358.15 K
304.2 K
= 1.17735
Dari gambar 108 halaman 500 buku hougen,

dan dengan Pr dan Tr CO2, maka diperoleh :
Cp-Cp* = 5.2 kj/kmol-K
Cp = (5,2 + 39,03) kj/kmol-K
= 44.232 kj/kmol-K
kondisi operasi dapat dilihat pada Tabel L2.11
Tabel L2. 11 Kapasitas Panas Natural Gas pada Kondisi Operasi

Pc Tc Cp-Cp* Cp* Cp
Komponen Pr Tr
(atm) (K) KJ/Kmol-K
CO2 72.9 304.2 0.34661 1.17735 5.2 39.03 44.23
N2 33.5 126.2 0.75426 2.83796 0.6 29.18 29.83
CH4 45.8 190.7 0.5517 1.87808 2.8 38.03 40.83
C2 H 6 48.2 305.43 0.52423 1.17261 9.8 58.55 68.36
C3H8 42.01 369.9 0.60147 0.96823 24.4 83.22 107.61
i-C4H10 36 408.1 0.70188 0.8776 98.0 109.71 207.74
n-C4H10 37.47 425.2 0.67435 0.84231 74.4 109.70 184.08
i-C5H12 32.9 461 0.76802 0.7769 66.1 134.04 200.17
n-C5H13 33.31 469.8 0.75856 0.76235 65.0 134.93 199.95
C6H14 29.92 507.9 0.84451 0.70516 66.9 160.67 227.54
Menentukan panas sensibel aliran

panas sensibel dapat dihitung melalui persamaan :
Q = n x Cp x ∆T
QCO2 = 60,892 kmol x 44,23 kj/kmol-K x 78 K
= 144583.065 kJ
Dengan cara yang sama diperoleh panas sensibel untuk masing-masing

komponen natural gas dapat dilihat pada Tabel L2.12
Tabel L2. 12 Panas Sensibel Natural Gas (QS1)
Mol Komponen Cp ∆T QS1
Komponen
(Kmol) (KJ/Kmol-K) (K) KJ
CO2 59.4317 44.232 55 144583.065
N2 10.9337 29.833 55 17940.180
CH4 929.2563 40.829 55 2086733.349
C2 H 6 71.3397 68.358 55 268215.126
C3 H 8 6.7118 107.610 55 39723.986
i-C4H10 1.2991 207.740 55 14842.596
n-C4H10 1.6238 184.080 55 16440.172
i-C5H12 0.6495 200.170 55 7150.868
n-C5H13 0.8660 199.950 55 9524.011
C6H14 0.4330 227.540 55 5419.089
1082.5446 2610572.444
- Lean Benfield (QS2)

masuk = 78 ⁰C + 273.15 K
= 351.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 48 K
Tekanan Masuk = 24.98 kg/cm² 0.967 atm
1 kg/cm²
= 24.156 atm
Menentukan Kapasitas panas Komponen (Cp)

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (351,15/1000) + (-2,05) x (351,15/1000)2 Cp K2CO3 =
+ 0,71 x (351,15/1000)3 + (−0,95)/"(351,15/1000)2 "
= 122.26 kj/kmol-K
Dengan cara yang sama, hasil perhitungan kapasitas panas Lean

Benfield dapat dilihat pada Tabel L2.13
Tabel L2. 13 Kapasitas panas komponen Lean Benfield (Cp)

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 122.2576
V2 O5 7.23188 15.7514 -14.243 4.59181 -0.026 10.9947
DEA - - - - - 137.0000
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.5674
(Sumber : NIST Themochemical Tables, Fourth Edition, J. Phys. Chem. )
Menentukan panas sensibel

Panas sensibel dapat dihitung melalui persamaan :
Q = n x Cp x ∆T
QK2CO3 = 225,6612 kmol x 122,258 kj/kmol K x 48 K
= 855985.318 KJ

komponen lean benfied dapat dilihat pada Tabel L2.14
Tabel L2. 14 Panas Sensibel Lean Benfield (QS2)

Mol Komponen Cp ∆T Q(S2)
Komponen
(kmol) (KJ/Kmol-K) (K) (KJ)
K2CO3 145.8644 122.258 48 855985.318
V2O5 6.3617 10.995 48 3357.356
DEA 12.1289 137.000 48 79759.664
H2 O 6641.8422 75.567 48 24091536.136
6806.1971 25030638.475
2. Menghitung Panas Kelu
- Sweet Gas
Temperatur
masuk
Temperatur
refrensi
∆T
Tekanan
Menentukan kapasitas pana

Cp* =
(∫_𝑇1^𝑇2▒ 〖 a+bT+
Cpm =
)/(T2+T1)
= a + b/2 (T1+T2) +
T1T22
+T23)
b c d (T13+T12 T2+
a+ (T1+T2) + (T12+T1T2+T22) + Cp CO2= 4,728 + (1,754 𝑥
2 3 4 (−1,34 𝑥 〖 10 〗
T1T22+T23)
+ 370,15 x 303,15
1.754 x10⁻² -1.34x10⁻⁵ (370,153 + 370,152
4.728 + x (381,15 + 303,15) +
2 3
x 303,15 + 370,15
4.097x10⁻⁹ =
(381,15 + 381,15 x 303,15 + 303,15 )
2 2
+ x
4 =
(381,153+381,152x303,15 + 381,15 x 303,152 + 303,153)

Dengan cara yang sama
1.754 x10⁻² -1.34x10⁻⁵ kondisi tekanan konstan
4.728 + x (370,15 + 303,15) +
2 3
4.097x10⁻⁹
(370,152 + 370,15 x 303,15 + 303,152) + x
4 Tabel L2.15 Kap
(370,153+370,152x303,15 + 370,15 x 303,152 + 303,153)
Menentukan kapasitas pana

CO2 (1 atm)
Pc CO2
Pr CO2
Tc CO2
Tr CO2
Dari gambar 108 halam

dan dengan Pr dan Tr C
Cp-Cp*
Cp

kondisi operasi dapat d
Tabel L2. 16 Kapasitas
Komponen
CO2
N2
CH4
C2 H 6
C3 H 8
i-C4H10
n-C4H10
i-C5H12
n-C5H13
C6H14
Menentukan panas sens

panas sensibel dapat dih
Q
QCO2

komponen inlet natural
Tabel L2. 1
Komponen
CO2
N2
CH4
C2 H 6
C3 H 8
i-C4H10
n-C4H10
i-C5H12
n-C5H13
C6H14
- Rich benfield
Temperatur
masuk
Temperatur
refrensi
∆T
Tekanan Masuk
Menentukan Kapasitas
Persamaan Shomate :
Cp
dimana:
t
Cp K2CO3 =
Cp K2CO3 = 97,08 + 94,22 x (351,15/1000) + (-2,05) x (351,15/1000)2
+ 0,71 x (351,15/1000)3 + (−0,95)/"(351,15/1000)2 "

Dengan cara yang sama, hasil perhitungan kapasitas panas dalam Benfield dapat dilihat p
Tabel L2. 18 Kapa
Komponen
K2CO3
V2O5
DEA
H2O
KHCO3
Sumber : NIST Themochem

Panas sensibel dapat dihitun
Q
QK2CO3

komponen rich benfied
Tabel L2. 19
Komponen
K2CO3
V2 O5
DEA
H2 O
KHCO3
2. Menghitung Panas Keluar Absorber 201-E 3. Menghitung Panas Reaksi
- Sweet Gas (QS3) K2CO3(l)
Temperatur = 108 ⁰C 91.4988
masuk = 108 ⁰C + 273.15 K
= 381.15 K Tabel L2. 20 Pan
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
= 78 K
Tekanan = 25 kg/cm² 0.967 atm

1 kg/cm²
= 24.175 atm S∆H0298
Menentukan kapasitas panas dalam kondisi tekanan konstan 1 atm (Cp0)

a + bT + (cT2) + (dT3)
(∫_𝑇1^𝑇2▒ 〖 a+bT+cT2+dT3 〗 " dT "
)/(T2+T1)
a + b/2 (T1+T2) + c/3 (T12 + T1T2 + T22) + d/4 (T13 + T12T2 +

T1T22
S∆H0 Produk
+T23)
KHCO3
4,728 + (1,754 𝑥 〖 10 〗 ^(−2))/2 x (370,15 + 303,15) +
(−1,34 𝑥 〖 10 〗 ^(−5))/3 x (370,152
+ 370,15 x 303,15 + 303,152) + (4,097 𝑥 〖 10 〗 ^(−9))/4 x

(370,153 + 370,152 S∆H0Reaktan
k2CO3
x 303,15 + 370,15 x 303,152+ 303,153)
9.269 kkal/kmol-K
38.81 kj/kmol-K

Tabel L2.15 Kapasitas Panas Standar Sweet Gas (CP*) H2O
Cp*
(kj/kmol-K)
CO2 4.728 1.754 -1.338 4.097 38.8087 CO2
N2 7.440 -0.324 0.640 -2.790 29.1798
CH4 4.598 1.245 0.286 -2.703 37.7245 ∆H0 Reaktan
C2 H 6 1.292 4.254 -1.657 2.081 57.8161
C3 H 8 -1.009 7.315 -3.789 7.678 82.0798
i-C4H10 -0.332 9.189 -4.409 6.915 108.2533 ∆HR,t
n-C4H10 2.266 7.913 -2.647 -0.674 108.3096
i-C5H12 -2.275 12.100 -6.519 13.670 132.1932
n-C5H13 -0.866 11.640 -6.163 12.670 133.1422 4. Panas yang hilang ( Q loss)
C6H14 -1.054 13.900 -7.449 15.510 158.5454 Qloss
(Sumber : Sherwood)
Menentukan kapasitas panas dalam kondisi operasi (Cp)

CO2 (1 atm) = 38.809 kj/kmol-K
= 72.9 atm Tabel L2. 21 Ner
= Paktual/Pc
Aliran Panas
= 24.18 atm
72.9 atm Inlet Natural Gas (QS1)
= 0.33162 Inlet Lean Benfield (QS2)
Outlet Sweet gas (QS3)
= 304.2 Outlet Rich Benfield (QS4)
= Taktual/Tc Reaksi Absorbsi (Qr)
= 381.15 K Heat Loss (Qloss)
304.2 K
= 1.25296
Dari gambar 108 halaman 500 buku hougen,

dan dengan Pr dan Tr CO2, maka diperoleh :
Cp-Cp* = 5 kj/kmol-K
Cp = (5,4 + 38,81) kj/kmol-K
= 44.209 kj/kmol-K
kondisi operasi dapat dilihat pada Tabel L2.16
Tabel L2. 16 Kapasitas Panas Outlet Swet Gas pada Kondisi Operasi
Pc Tc Cp-Cp* Cp* Cp
Komponen Pr Tr
(atm) (K) KJ/Kmol-K
CO2 72.9 304.2 0.33162 1.25296 5.4 38.81 44.21
N2 33.5 126.2 0.72164 3.02021 0.7 29.18 29.86
CH4 45.8 190.7 0.52784 1.99869 2.6 37.72 40.34
48.2 305.43 0.50156 1.24791 9.7 57.82 67.54
C3H8 42.01 369.9 0.57546 1.03041 27.3 82.08 109.40
i-C4H10 36 408.1 0.67153 0.93396 76.2 108.25 184.48
n-C4H10 37.47 425.2 0.64518 0.8964 65.6 108.31 173.93
i-C5H12 32.9 461 0.7348 0.82679 61.9 132.19 194.10
n-C5H13 33.31 469.8 0.72576 0.8113 61.3 133.14 194.43
C6H14 29.92 507.9 0.80799 0.75044 64.0 158.55 222.52

= n x Cp x ∆T
QCO2 = 2,9165 kmol x 44,209 kj/kmol-K x 67 K
= 17469.471 kJ

komponen inlet natural gas, yaitu:
Tabel L2. 17 Panas Sensibel Sweet Gas (QS3)
Komponen
(Kmol) (KJ/Kmol-K) (K) KJ
CO2 5.0661 44.209 78 17469.471
N2 10.9593 29.857 78 25522.607
CH4 928.8554 40.339 78 2922589.794
C2H6 71.1323 67.542 78 374744.568
C3H8 8.1678 109.400 78 69697.533
i-C4H10 1.3441 184.480 78 19340.408
n-C4H10 1.6542 173.930 78 22442.306
i-C5H12 0.6203 194.100 78 9391.820
n-C5H13 0.8271 194.430 78 12543.717
C6H14 0.5169 222.520 78 8972.471
1029.1437 3482714.695
- Rich benfield (QS4)

masuk = 110 ⁰C + 273.15 K
= 383.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
= 80 K
Tekanan Masuk = 25 kg/cm² 0.967 atm
1 kg/cm²
= 24.175 atm
Persamaan Shomate :
= a+ bt + ct2 + dt3 + (e/t2)
dimana:
= T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (392,15/1000) + (-2,05) x (392,15/1000)2
+ 0,71 x (392,15/1000)3 + (−0,95)/"(392,15/1000)2 "
= 126.46 kj/kmol-K
Dengan cara yang sama, hasil perhitungan kapasitas panas Rich

Tabel L2. 18 Kapasitas panas komponen Rich Benfield (Cp)

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 126.464
V2O5 7.23188 15.7514 -14.243 4.59181 -0.026 11.257
DEA - - - - - 137.000
H2 O -203.61 1523.29 -3196 2474.46 3.8553 76.242
KHCO3 - - - - - 87.610
Sumber : NIST Themochemical Tables, Fourth Edition, J. Phys. Chem.

Q = n x Cp x ∆T
QK2CO3 = 167,6857 kmol x 127,594 kj/kmol-K x 89 K
= 925705.089 KJ

komponen rich benfied dapat dilihat pada Tabel L2.19
Tabel L2. 19 Panas Sensibel Rich Benfield (QS4)

Komponen
K2CO3 91.4988 126.464 80 925705.089
V2O5 6.3617 11.257 80 5729.232
DEA 12.1289 137.000 80 132932.773
H2O 6587.4766 76.242 80 40179303.055
KHCO3 108.7312 87.610 80 762075.131
6806.1971 42005745.280
3. Menghitung Panas Reaksi
+ CO2(g) + H2O(l) 2KHCO3(l)
91.4988 5.0661 6587.4766 108.7312 kmol Mula : 145.8644
Bereaksi 54.3656
Tabel L2. 20 Panas Pembentukan Standar (∆H f) 0
∆H0f
Komponen
(kkal/gmol) (kJ/kmol)
K2CO3 -274.01 -1146457.8
CO2 -94.05 -393505.2
H2O -68.32 -285850.9
KHCO3 -229.80 -961483.2
sumber : perry, edisi 8
= n S∆F0f Produk - S∆0f Reaktan

= 54.37 kmol x {2 x(-961483.2)} kj/kmol-
{(-1146457.84 - 393505.20 - 285850.88)} kj/kmol
= 54.37 kmol x -{ 1922966.4 kj/kmol -
-(1825813.92 kj/kmol) }
= 54.37 kmol x -97152.48 kj/kmol
= -5281752.147 kJ
S∆H0 Produk = ∑▒ 〖𝑛 〗 ∫ 24_𝑇1^𝑇2▒"Cp" dT

KHCO3 = 108.731 Kmol x 87.61 kj/kmol-K x 80 K
= 762075.131 kJ
S∆H0Reaktan = ∑_𝑅▒ 〖𝑛 〗 Cp dT
= 145.8644 kmol x {97,081 x (0,35115-0,30315) +
94,233/2 x (0,351152-0,303152) + (−2,053)/3 x 4.6599
(0,351153- 1.4796026136
0,303153) + 0,7096/4 x (0,351154-0,303154) - -0.01056580120764
0.001199020595461
"−0,948" /"351,15 − 303,15"
} 19.75
25.8801
= 855985.318 kJ 122.26 kj/kmol-K x
= 6641.8422 kmol x 75.57 kj/kmol-K x 48 K
Komponen a
= 24091536.136 kJ
CO2 4.728
= 59.4317 kmol x 44.232 kj/kmol-K x 48 K H2 O 7.701
= 126181.584 kJ ∆HoR + ∆HoProduk + ∆HoReaktan
∆H0 Reaktan = (7929224.59 + 381.192015 + 17324821.7) kJ 368.784
= 25073703.038 KJ 468.102258
-122.7045353859
= 12.9663121685933
= -29593380.055 kJ = Qr 727.148034782693
3044.42339202818
4. Panas yang hilang ( Q loss)
= SQinput - SQoutput
= (QS1 + QS2) - (QS3 + QS4 + Qr)
= 27641210.918 KJ - 15895079.921 KJ
= 11746130.997 KJ
Tabel L2. 21 Neraca panas CO2 Absorber 201-E

Input Output
Aliran Panas
(kJ/Jam) (kJ/Jam)
Inlet Lean Benfield (QS2) 25030638.475 - Efisiensi =
Outlet Rich Benfield (QS4) - 42005745.280 =
Reaksi Absorbsi (Qr) 29593380.055 -
Heat Loss (Qloss) - 11746130.997
57234590.973 57234590.973
145.8644 59.4317 6641.8422 kmol
54.3656 54.3656 54.3656 108.7312 kmol
4.6599 -9.7728
1.4796026136 23.92 kj/kmol-K
-0.01056580120764 -16.44827114448
0.001199020595461 4.18119569259733
19.75 -80.3187499999999
25.8801 -78.4379
122.26 kj/kmol-K x 48 K
Cp*
a b x 10-2 c x 10-5 d x 10-9
(kJ/kmol-K)
4.728 1.754 -1.338 4.097 3044.423 180935.260
7.701 0.046 0.252 -0.859 1626.097 10800277.7559581
∆HoR + ∆HoProduk + ∆HoReaktan 33.8770149226851
368.784
468.102258
-122.7045353859
12.9663121685933
727.148034782693
3044.42339202818
15895079.921 kJ
x 100 %
27641210.918 kJ
57.51 %
1. Menghitung Panas Masuk Absorber 201-E
Natural Gas (QS₁)
masuk = 85 ⁰C + 273.15 K
= 358.15 K
Temperatur 30 ⁰C
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 55 K

1 kg/cm²
= 25.27 atm
Kapasitas panas (Cp) Natural Gas diperoleh dari The Nist Webbook
dapat dilihat pada Tabel L2.10
Tabel L2. 10 Kapasitas Panas Natural Gas pada 381,15 K, 24,16 atm
Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 44.233 44.233
N2 29.833 29.833
CH4 40.829 40.829
C2 H 6 68.359 68.359
C3 H 8 107.620 107.620
i-C4H10 207.730 207.730
n-C4H10 184.080 184.080
i-C5H12 200.170 200.170
n-C5H13 199.950 199.950
C6H14 227.540 227.540
(Sumber : https://webbook.nist.gov)
Tabel L2. 11 Kapasitas Panas Komponen pada 303,15 K, 1 atm
Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 37.656 37.656
N2 29.173 29.173
CH4 35.987 35.987
C2 H 6 53.442 53.442
C3 H 8 75.400 75.400
i-C4H10 99.612 99.612
n-C4H10 101.780 101.780
i-C5H12 124.160 124.160
n-C5H13 168.720 168.720
C6H14 195.880 195.880
Menentukan QS1 dapat dihitung melalui persamaan :

Q = n x ((Cp1 T1) - (Cp2 T2)) (Himmelblau, 1966)
QCO2 = 60,892 kmol x ((44,233 kJ/kmol x 381,15 K) -
(37,657 kJ/kmol x 303,15 K))
= 263082.302 kJ
Hasil perhitungan QS1 setiap komponen ditunjukan pada Tabel L2.12
Tabel L2. 12 Panas Sensibel Natural Gas (QS1)
n Cp1 Cp2 T1 T2 QS1
Komponen
(Kmol) (kJ/kmol.K) (K) (kJ)
CO2 59.432 44.23 37.66 358.15 303.15 263082.302
N2 10.934 29.83 29.17 358.15 303.15 20127.784
CH4 929.256 40.83 35.99 358.15 303.15 3450744.378
C2 H 6 71.340 68.36 53.44 358.15 303.15 590823.454
C3 H 8 6.712 107.62 75.40 358.15 303.15 105284.911
i-C4H10 1.299 207.73 99.61 358.15 303.15 57419.625
n-C4H10 1.624 184.08 101.78 358.15 303.15 56953.180
i-C5H12 0.650 200.17 124.16 358.15 303.15 22117.544
n-C5H13 0.866 199.95 168.72 358.15 303.15 17723.096
C6H14 0.433 227.54 195.88 358.15 303.15 9575.077
1082.545 4593851.350
- Lean Benfield (QS2)
masuk = 89 ⁰C + 273.15 K
= 362.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 59 K
1 kg/cm²
= 25.268 atm

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (351,15/1000) + (-2,05) x (351,15/1000)2
+ 0,71 x (351,15/1000)3 + (−0,95)/"(351,15/1000)2 "
= 123.74 kj/kmol-K

Tabel L2. 13 Kapasitas panas Lean Benfield pada 351,15 K

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 123.7408
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 145.1859
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.7607

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 115.1613
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 131.9789
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.3177
Menentukan Cp DEA (C4H11NO2) menggunakan persamaaan Zabransky-

Ruzicka :
Cp = ai + bi (T/100) + di (T/100)^2
Cp C-(H)2(C)(O) = 0,52 + 1,27 x (351,15/100) -0,09 x (351,15/100)2
Cp C-(H)2(C)(O) = 3.870
Tabel L2. 15 Kapasitas panas DEA

T Cp Cp
Komponen ai bi di Jumlah
(K) J/mol.K J/mol.K
C-(H)2(C)(O) 0.52 1.27 -0.09 362.15 2 3.87 7.741
C-(H)2(C)(N) 5.66 -1.81 0.31 362.15 2 3.19 6.375
C-(H)(C)(N) 2.91 2.66 -0.60 362.15 1 4.60 4.603
O-(H)(C) 16.16 -11.94 2.85 362.15 2 10.32 20.632
C4H11O2N 39.351
C-(H)2(C)(O) 0.52 1.27 -0.09 303.15 2 3.49 6.984
C-(H)2(C)(N) 5.66 -1.81 0.31 303.15 2 3.03 6.061
C-(H)(C)(N) 2.91 2.66 -0.60 303.15 1 5.41 5.408
O-(H)(C) 16.16 -11.94 2.85 303.15 2 6.17 12.335
C4H11O2N 30.789

Q = n x ((Cp1 T1) - (Cp2 T2))
QK2CO3 = 225,661 kmol x ((122,26 kJ/kmol x 351,15 K) -
(115,16 kJ/kmol x 303,15 K))
= 1444289.941

n Cp1 Cp2 T1 T2 QS2
Komponen
K2CO3 145.864 123.74 115.16 362.15 303.15 1444289.94
V2O5 6.362 145.19 131.98 362.15 303.15 79964.22
DEA 12.129 39.35 30.79 362.15 303.15 59642.31
H2 O 6641.842 75.76 75.32 362.15 303.15 30580111.12
6806.197 32164007.60
2. Menghitung Panas Keluar Absorber 201-E

- Sweet Gas (QS3)
masuk = 108 ⁰C + 273.15 K
= 381.15 K
Temperatur 30 ⁰C
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 78 K

1 kg/cm²
= 24.18 atm
Kapasitas panas (Cp) Sweet Gas diperoleh dari The Nist Webbook
Tabel L2. 17 Kapasitas Panas Sweet Gas pada 370,15 K, 24,06 atm
Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 44.198 44.198
N2 29.857 29.857
CH4 40.339 40.339
C2 H 6 67.542 67.542
C3 H 8 109.400 109.400
i-C4H10 184.480 184.480
n-C4H10 173.930 173.930
i-C5H12 194.100 194.100
n-C5H13 194.430 194.430
C6H14 225.520 225.520

Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 37.657 37.657
N2 29.173 29.173
CH4 35.987 35.987
C2 H 6 53.442 53.442
C3 H 8 75.400 75.400
i-C4H10 99.612 99.612
n-C4H10 101.780 101.780
i-C5H12 124.160 124.160
n-C5H13 168.720 168.720
C6H14 195.880 195.880

Q = n x ((Cp1 T1) - (Cp2 T2))
(37,657 kJ/kmol x 303,15 K))
= 27510.732 kJ
Tabel L2. 19 Panas Sensibel Sweet Gas (QS3)

n Cp1 Cp2 T1 T2 QS3
Komponen
CO2 5.066 44.20 37.66 381.15 303.15 27510.732
N2 10.959 29.86 29.17 381.15 303.15 27795.075
CH4 928.855 40.34 35.99 381.15 303.15 4148036.961
C2 H 6 71.132 67.54 53.44 381.15 303.15 678793.522
C3 H 8 8.168 109.40 75.40 381.15 303.15 153883.939
i-C4H10 1.344 184.48 99.61 381.15 303.15 53920.272
n-C4H10 1.654 173.93 101.78 381.15 303.15 58624.282
i-C5H12 0.620 194.10 124.16 381.15 303.15 22544.458
n-C5H13 0.827 194.43 168.72 381.15 303.15 18990.277
C6H14 0.517 225.52 195.88 381.15 303.15 13738.420
1029.144 5203837.938
- Rich Benfield (QS4)

masuk = 110 ⁰C + 273.15 K
= 383.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 80 K
1 kg/cm²
= 24.175 atm

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (392,15/1000) + (-2,05) x (392,15/1000)2
+ 0,71 x (392,15/1000)3 + (−0,95)/"(392,15/1000)2 "
= 126.46 kj/kmol-K
Dengan cara yang sama, hasil perhitungan kapasitas panas Rich

Tabel L2. 20 Kapasitas panas Rich Benfield pada 392,15 K

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 126.4641
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 148.6352
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.2418
Tabel L2. 21 Kapasitas panas Rich Benfield pada 303,15

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 115.1613
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 131.9789
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.3177

Ruzicka :
Cp = ai + bi (T/100) + di (T/100)^2
Cp C-(H)2(C)(O) = 0,52 + 1,27 x (392,15/100) -0,09 x (392,15/100)2
Cp C-(H)2(C)(O) = 3.989

T Cp Cp
(K) J/mol.K J/mol.K
C-(H)2(C)(O) 0.52 1.27 -0.09 383.15 2 3.99 7.979
C-(H)2(C)(N) 5.66 -1.81 0.31 383.15 2 3.30 6.592
C-(H)(C)(N) 2.91 2.66 -0.60 383.15 1 4.22 4.215
O-(H)(C) 16.16 -11.94 2.85 383.15 2 12.27 24.543
C4H11O2N 43.329
C-(H)2(C)(O) 0.52 1.27 -0.09 303.15 2 3.49 6.984
C-(H)2(C)(N) 5.66 -1.81 0.31 303.15 2 3.03 6.061
C-(H)(C)(N) 2.91 2.66 -0.60 303.15 1 5.41 5.408
O-(H)(C) 16.16 -11.94 2.85 303.15 2 6.17 12.335
C4H11O2N 30.789

Q = n x ((Cp1 T1) - (Cp2 T2))
QK2CO3 = 167,686 kmol x ((127,59 kJ/kmol x 392,15 K) -
(115,16 kJ/kmol x 303,15 K))
= 1239221.760
Tabel L2. 23 Panas Sensibel Rich Benfield(QS4)

n Cp1 Cp2 T1 T2 QS4
Komponen
K2CO3 91.499 126.46 115.16 383.15 303.15 1239221.76
V2O5 6.362 148.64 131.98 383.15 303.15 107767.94
DEA 12.129 43.33 30.79 383.15 303.15 88150.08
H2 O 6587.477 76.24 75.32 383.15 303.15 42024741.38
KHCO3 108.731 87.6 87.6 383.15 303.15 761988.15
6806.197 44221869.30
3. Menghitung Panas Reaksi

K2CO3(l) + CO2(g) + H2O(l) 2KHCO3(l)
Tabel L2. 24 Panas Pembentukan Standar (∆H0f)

∆H0f
Komponen
K2CO3 -274.01 -1146457.8
CO2 -94.05 -393505.2
H2 O -68.32 -285850.9
KHCO3 -229.80 -961483.2
S∆H0298 = n S∆F0f Produk - S∆0f Reaktan

= 0.00 kmol x {2 x(-961483.2)} kj/kmol-
{(-1146457.84 - 393505.20 - 285850.88)} kj/kmol
= 0.00 kmol x -{ 1922966.4 kj/kmol -
-(1825813.92 kj/kmol) }
= 0.00 kmol x -97152.48 kj/kmol
= 0.000 kJ
Menentukan Cp CO2 pada Reaksi absorbsi dapat dihitung melalui
persamaan :
Cp = a + bT + (cT2) + (dT3)
Cp CO2 = (7,701 ) + (0,460 x 10-2) x (381,15) + (2,521 x 10-5) x
(381,15)2 - (0,859 x 10-9 x (381,15)3
= 9.294 kkal/kmol-K
= 38.91 kj/kmol-K
Menentukan Kapasitas panas Komponen K2CO3 dengan menggunakan
Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (351,15/1000) + (-2,05) x (351,15/1000) 2
+ 0,71 x (351,15/1000)3 + (−0,95)/"(351,15/1000)2 "
= #DIV/0!
Tabel L2. 25 Kapasitas panas Komponen Reaksi Absorbsi
Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 #DIV/0!
H2O -203.61 1523.29 -3196 2474.46 3.8553 #DIV/0!
Tabel L2.26 Cp Reaktan dan Produk pada Reaksi Absorbsi di Absorber

T Cp Reaktan Cp Produk
Komponen
(K) kJ/Kmol.K kJ/Kmol.K
K2CO3 0.00 #DIV/0!
H2O 0.00 #DIV/0!
CO2 358.15 19.795
KHCO3 383.15 87.600
#DIV/0! 87.600
Tabel L2.27 Cp Reaktan dan Produk pada Reaksi Absorbsi di Absorber

Komponen
K2CO3 303.15 115.16
H2O 303.15 75.318
CO2 303.15 37.656
KHCO3 303.15 87.600
228.135 87.600
Tabel L2. 28 Entalpi Reaktan dan Entalpi Produk
n Cp1 Cp2 T1 T2 ∆H
Komponen
Reaktan
K2CO3 145.864 ### 115.16 362.15 303.15 #DIV/0!
H2 O 6641.842 ### 75.32 362.15 303.15 #DIV/0!
CO2 59.432 19.80 37.66 358.15 303.15 -257087.807
Total #DIV/0!
Produk
KHCO3 0.000 87.60 87.60 383.15 303.15 0.000
Menghitung ∆Hr(T) dengan persamaan :
ΔHr(T) = ∆H0298 + ∆Hproduk - ∆Hreaktan
ΔHr(T) = ( -5632468,641 + 90400,185 - 25663731,075) kJ
= #DIV/0!
4. Panas yang hilang ( Q loss)

Qloss = SQinput - SQoutput
= (QS1 + QS2) - (QS3 + QS4 + Qr)
= 36757858.947 KJ - #DIV/0!
= #DIV/0!
Tabel L2. 29 Neraca panas CO2 Absorber 201-E

Input Output
Aliran Panas
(kJ/Jam) (kJ/Jam)
Inlet Lean Benfield (QS2) 32164007.597 -
Outlet Rich Benfield (QS4) - 44221869.303
Reaksi Absorbsi (Qr) #DIV/0! -
Heat Loss (Qloss) - #DIV/0!
#DIV/0! #DIV/0!
Hasil Perhitungan neraca massa Stripper pada tanggal 6,9,13, dan 16
Agustus 2018 dapat dilihat pada Tabel 5.23 sampai Tabel 5.27 pada bab 5.
S∆H0 Produk
KHCO3
S∆H0Reaktan
k2CO3
H2O
CO2
∆H0 Reaktan
∆HR,t
Tabel 46. Hasil Perhitungan Cp Komponen Lainnya
T Cp*
(K) (kj/kmol-K)
H2O 7.701 0.460 2.521 -0.859 32.243
CO2 4.728 17.540 -13.38 4.097 0.00 19.795
S∆H0 Produk =
KHCO3 = 108.731 Kmol x 0.00 kj/kmol-K x -2 K
= 0.000 kJ
S∆H0Reaktan = ∑_𝑅▒ 〖𝑛 〗 Cp dT
= 0.0000 kmol x {97,081 x (0,35115-0,30315) +
94,233/2 x (0,351152-0,303152) + (−2,053)/3 x
(0,351153-
0,303153) + 0,7096/4 x (0,351154-0,303154) -
"−0,948" /"351,15 − 303,15"

94,233/2 x (0,351152-0,303152) + (−2,053)/3 x
(0,351153-
0,303153) + 0,7096/4 x (0,351154-0,303154) -
"−0,948" /"351,15 − 303,15"

}
= #REF!
= 0.0000 kmol x #REF! 48 K
= #REF!
= 0.0000 kmol x #REF! 48 K

= #REF!
0
∆H Reaktan = (7929224.59 + 381.192015 + 17324821.7) kJ
= #REF!
=
= #REF! = Qr
1. Menghitung Panas Masuk Stripper 202-E E. Menghitung Efisien
Rich Benfield (QS4)
masuk = 119 ⁰C + 273.15 K
= 392.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 89 K
Masuk 1 kg/cm²
= 0.957 atm
Menentukan Kapasitas panas Komponen Rich Benfield menggunakan

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (392,15/1000) + (-2,05) x (392,15/1000)2
+ 0,71 x (392,15/1000)3 + (−0,95)/"(392,15/1000)2 "
= 127.59 kj/kmol-K
Dengan cara yang sama, hasil perhitungan kapasitas panas Rich Benfield

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 127.5937
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 149.9709
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.4965

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 115.1613
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 131.9789
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.3177

Ruzicka :
Cp = ai + bi (T/100) + di (T/100)^2
Cp C-(H)2(C)(O) = 0,52 + 1,27 x (392,15/100) -0,09 x (392,15/100)2
Cp C-(H)2(C)(O) = 8.075

T Cp Cp
(K) J/mol.K J/mol.K
C-(H)2(C)(O) 0.52 1.27 -0.09 392.15 2 4.04 8.075
C-(H)2(C)(N) 5.66 -1.81 0.31 392.15 2 3.35 6.702
C-(H)(C)(N) 2.91 2.66 -0.60 392.15 1 4.03 4.033
O-(H)(C) 16.16 -11.94 2.85 392.15 2 13.19 26.373
C4H11O2N 45.183
C-(H)2(C)(O) 0.52 1.27 -0.09 303.15 2 3.49 6.984
C-(H)2(C)(N) 5.66 -1.81 0.31 303.15 2 3.03 6.061
C-(H)(C)(N) 2.91 2.66 -0.60 303.15 1 5.41 5.408
O-(H)(C) 16.16 -11.94 2.85 303.15 2 6.17 12.335
C4H11O2N 30.789

Q = n x ((Cp1 T1) - (Cp2 T2))
(115,16 kJ/kmol x 303,15 K))
= 1383892.825
n Cp1 Cp2 T1 T2 QS4
Komponen
K2CO3 91.499 127.59 115.16 392.15 303.15 1383892.82
V2O5 6.362 149.97 131.98 392.15 303.15 119610.35
DEA 12.129 45.18 30.79 392.15 303.15 101698.90
H2 O 6587.477 76.50 75.32 392.15 303.15 47202737.41
KHCO3 108.731 87.6 392.15 303.15 3735170.64
6806.197 52543110.13
- steam reboiler (QS6)

Kondisi Operasi :
masuk = 150 ⁰C + 273.15 K
= 423.15 K
keluar = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 120 K

Masuk 1 kg/cm²
= 3.385 atm
Menghitung massa steam :

Diketahui : densitas steam pada temperatur 150 ⁰C
= 917.00 kg/m³ The M.W. Kellog Company, 1976):
mSteam = Volume steam X densitas steam
= 15.1 Nm³ x 917 kg/m³
= 13846.70 kg
n Steam = 13846.70 kg
18 kg/kmol
= 769.26 kmol
a. Menghitung panas laten Steam
λH2O = 40655.93 kJ/kmol (Hougen, 1943)
maka,
Qsteam in = nSteam x λH 2 O
= 769.26 kmol x 40655.93 kJ/kg
= 31275024.347 kJ
b. Menghitung panas sensibel steam

Menentukan Kapasitas panas H2O dengan menggunakan persamaan
Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
-203,6 + 1523,3 x (423,15/1000) + (-3196) x (423,15/

Cp H2O =
1000)2 + 2474,5 x (423,15/1000)3 + 3,8553/"(423,15/1000)2 "
= 77.65 kj/kmol-K
Tabel L2. 34 Kapasitas Panas Steam

Cp
Komponen a b c d e
KJ/Kmol-K
H2O (423,15 k) -203.61 1523.29 -3196 2474.46 3.8553 77.6530
H2O (303,15 k) -203.61 1523.29 -3196 2474.46 3.8553 75.3177
(Sumber : Sherwood)
Q = n x ((Cp1 T1) - (Cp2 T2))

= 769,3 kmol x 34,523 kJ/kmol-K x 120 K
= 7712830.70 kJ
Qsteam total = 38987855.1 kJ
2. Menghitung Panas Keluar Stripper 202-E

Lean Benfield (QS2)
masuk = 129 ⁰C + 273.15 K
= 402.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 99 K

1 kg/cm²
= 0.764 atm
Menentukan Kapasitas panas Komponen Lean Benfield menggunakan

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (402,15/1000) + (-2,05) x (402,15/1000) 2
+ 0,71 x (402,15/1000)3 + (−0,95)/"(402,15/1000)2 "
= 128.83 kj/kmol-K

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 128.8257
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 151.3677
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.8184

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 115.1613
V2 O5 161.869 33.2687 -12.934 5.12536 -3.5776 131.9789
H2O -203.61 1523.29 -3196 2474.46 3.8553 75.3177

Ruzicka :
Cp = ai + bi (T/100) + di (T/100)^2
Cp C-(H)2(C)(O) = 0,52 + 1,27 x (402,15/100) -0,09 x (402,15/100)2
Cp C-(H)2(C)(O) = 4.090
T Cp Cp
(K) J/mol.K J/mol.K
C-(H)2(C)(O) 0.52 1.27 -0.09 402.15 2 4.09 8.179
C-(H)2(C)(N) 5.66 -1.81 0.31 402.15 2 3.42 6.836
C-(H)(C)(N) 2.91 2.66 -0.60 402.15 1 3.82 3.818
O-(H)(C) 16.16 -11.94 2.85 402.15 2 14.26 28.515
C4H11O2N 47.348
C-(H)2(C)(O) 0.52 1.27 -0.09 303.15 2 3.49 6.984
C-(H)2(C)(N) 5.66 -1.81 0.31 303.15 2 3.03 6.061
C-(H)(C)(N) 2.91 2.66 -0.60 303.15 1 5.41 5.408
O-(H)(C) 16.16 -11.94 2.85 303.15 2 6.17 12.335
C4H11O2N 30.789
Q = n x ((Cp1 T1) - (Cp2 T2))
QK2CO3= 225,661 kmol x ((128,83 kJ/kmol x 402,15 K) -
(115,16 kJ/kmol x 303,15 K))
= 2464540.009
Tabel L2. 38 Panas Sensibel Lean Benfield (QS2)

n Cp1 Cp2 T1 T2 QS2
Komponen
K2CO3 145.864 128.83 115.16 402.15 303.15 2464540.01
V2O5 6.362 151.37 131.98 402.15 303.15 132724.55
DEA 12.129 47.35 30.79 402.15 303.15 117740.97
H2 O 6611.937 76.82 75.32 402.15 303.15 53291825.97
6776.292 56006831.50
- Acid Gas (QS5)

keluar = 126 ⁰C + 273.15 K
= 399.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 96 K
keluar 1 kg/cm²
= 0.764 atm
Kapasitas panas (Cp) Acid Gas diperoleh dari The Nist Webbook
dapat dilihat pada Tabel L2. 37
Tabel L2. 39 Kapasitas Panas Acid Gas pada 399,15 K, 0,764 atm
Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 41.390 41.390
H2 O 76.040 76.040

Cp Cp
Komponen
J/gmol.k kJ/kmol.K
CO2 37.657 37.657
H2O 75.301 75.301

Q = n x ((Cp1 T1) - (Cp2 T2))
(37,657 kJ/kmol x 303,15 K))
= 152670.590 kJ
Tabel L2. 41 Panas Sensibel Acid Gas (QS5)

n Cp1 Cp2 T1 T2 QS5
Komponen
CO2 29.906 41.39 37.66 399.15 303.15 152670.590
H2O 54.366 76.04 75.30 399.15 303.15 409039.534
84.271 561710.125
Kondensat Reboiler
Kondisi Operasi :
Mol kondensat = mol steam = 769.26 Nm³/hr
masuk = 127 ⁰C + 273.15 K
= 400.15 K
keluar = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 97 K
Menentukan Kapasitas panas H2O dengan menggunakan persamaan

Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp H2O = -203,6 + 1523,3 x (400,15/1000) + (-3196) x (400,15/
1000)2 + 2474,5 x (400,15/1000)3 + 3,8553/"(400,15/1000)2 "
= 76.75 kj/kmol-K
Tabel L2. 42 Kapasitas panas Kondensat

Cp
Komponen a b c d e
KJ/Kmol-K
H2O (400,15 K) -203.61 1523.29 -3196 2474.46 3.8553 76.7505
H2O (303,15 K) -203.61 1523.29 -3196 2474.46 3.8553 75.3177
(Sumber : Sherwood)
Q = n x ((Cp1 T1) - (Cp2 T2))

= 769,3 kmol x 34,523 kJ/kmol-K x 120 K
= 6061114.38 kJ
3. Panas reaksi Absorbsi (Qr)


∆H0f
Komponen
K2CO3 -274.01 -1146457.84
CO2 -94.05 -393505.2
H2O -68.32 -285850.9
KHCO3 -229.80 -961483.2
∑∆H0298 = ∑∆H0f Produk - ∑∆H0f Reaktan

= 115,951 kmol {(-1146457.84 - 393505.20 - 285850.88)
-2 x (-961483,2)} kj/kmol
= 115,951 kmol x {(-1825813,92) - (-1922966,4)} kj/kmol
= 108.731 kmol x 97152.48 kj/kmol
= 10563504.29 KJ
Menentukan Cp H2O, dan CO2 pada Reaksi absorbsi dapat dihitung melalui
persamaan :
Cp = a + bT + (cT2) + (dT3)
Komponen
Cp CO2 = (7,701 ) + (0,460 x 10-2) x (399,15) + (2,521 x 10-5) x
(399,15)2 - (0,859 x 10-9 x (399,15)3 H2O
= 9.858 kkal/kmol-K CO2
= 41.27 kj/kmol-K
Menentukan Kapasitas panas Komponen K2CO3 dengan menggunakan

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 = 97,08 + 94,22 x (402,15/1000) + (-2,05) x (402,15/1000) 2
+ 0,71 x (402,15/1000)3 + (−0,95)/"(402,15/1000)2 "
= 128.83 kj/kmol-K
Tabel L2. 44 Kapasitas panas Komponen Reaksi Absorbsi

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 128.8257
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.8184
Tabel L2. 45 Cp Reaktan dan Produk pada Reaksi Absorbsi di Absorber

Komponen
K2CO3 402.15 128.83
H2O 402.15 76.818
CO2 399.15 41.273
KHCO3 392.15 87.600
246.917 87.600
Tabel L2. 46 Cp Reaktan dan Produk pada Reaksi Absorbsi di Absorber

Komponen
K2CO3 303.15 115.16
H2O 303.15 75.32 44.6515447649824
CO2 303.15 37.66
KHCO3 303.15 87.600
228.135 87.600
Tabel L2. 47 Entalpi Produk dan Entalpi Reaktan

n Cp1 Cp2 T1 T2 ∆H
Komponen
Produk
K2CO3 54.366 128.83 115.16 402.15 303.15 918566.856
H2 O 54.366 76.82 75.32 402.15 303.15 438183.522
CO2 54.366 41.27 37.66 399.15 303.15 275022.307
Total 1631772.686
Reaktan
KHCO3 108.731 87.60 87.60 392.15 303.15 847711.812
Menghitung ∆Hr(T) dengan persamaan :

ΔHr(T) = ∆H0298 + ∆Hproduk - ∆Hreaktan
ΔHr(T) = (11264937,28 + 1740124,910 - 904001,185) kJ
= 11347565.168
4. panas yang hilang ( Q loss)

Qloss = ∑Qinput - ∑Qoutput
= (QS4 + QS6) - (QS2+ QS5 + QS7+ Qr)
= ( 91530965.2 - 73977221.17 ) kJ
= 17553744.01 kJ
Tabel L2. 48 Neraca Energi Stripper 202-E
Input Output
Aliran Panas
(kJ/Jam) (kJ/Jam)
Rich Benfield(QS4) 52543110.13 -
Steam (QS6) 38987855.05 -
Lean Benfield (QS2) - 56006831.50
Acid gas (QS5) - 561710.12 44.6515447649824
Kondensat (QS7) - 6061114.38
Reaksi Pelucutan (Qr) - 11347565.17
91530965.18 91530965.18
E. Menghitung Efisiensi
Efisiensi Reboiler :
Efisiensi = Panas reaksi pelucutan
x 100 %
Panas steam - panas kondensat
= 12101061.01
x 100 %
(38987855,05 - 6061114,38) kJ
= 34.5 %
(423,15/
/"(423,15/1000)2 "
x (400,15/
3/"(400,15/1000)2 "
T Cp*
(K) (kj/kmol-K)
H2 O 7.701 0.460 2.521 -0.859 #REF! #REF!
CO2 4.728 17.540 -13.38 4.097 392.15 41.013
44.6515447649824
44.6515447649824
P = 25.00 kg/cm²
QS3 = 5203837.94 kJ/kg
P = 26.13 kg/cm²
T = 89 ⁰C
QS2 = 32164007.60 kJ/kg P
Lean Benfield T
QS4 =
Qr #DIV/0!
Qr
Inlet Natural Gas (S1)
P = 26.13 kg/cm²
T = 85 ⁰C
QS1 = 4593851.35 kJ/kg
Rich Benfield (S4)
P = 25.00 kg/cm²
T = 110 ⁰C
QS4 = 44221869.30 kJ/kg
Gambar L2. 6 Blok Diagram Neraca Energi Absorber 201-E pada Gambar L2. 7
C. Menghitung Neraca Panas pada Absorber D. Menghitung Nerac
P = 25.00 kg/cm²
QS3 = … ?
P = 26.13 kg/cm²
T = 89 ⁰C
QS2 = … ? P
Lean Benfield T
QS4 =
Qr … ?
Qr
Inlet Natural Gas (S1)
P = 26.13 kg/cm²
T = 85 ⁰C
QS1 = … ?
Rich Benfield (S4)
P = 25.00 kg/cm²
T = 110 ⁰C
QS4 = … ?
Gambar L2. 6 Blok Diagram Neraca Energi Absorber 201-E pada Gambar L2. 7
Acid Gas (S5)
P = 0.8 kg/cm²
T = 126 °C
QS5 = 561710.12 kJ/kg
Rich Benfield (S4)
= 119.0 kg/cm² Steam Masuk (S6)

= 119 °C QS6 = 38987855.1 kJ/kg
QS4 = 52543110.1 kJ/kg
Condensat Keluar (S7)

= 11347565.17 kJ/kg
QS7 = 6061114.38 kJ/kg
Lean Benfield (S2)

P = 0.8 kg/cm²
T = 129 °C
QS2 = 56006831.50 kJ/kg
Gambar L2. 7 Blok Diagram Neraca Energi Stripper 202-E

D. Menghitung Neraca Panas pada Stripper
Acid Gas (S5)

P = 0.8 kg/cm²
T = 126 °C
QS5 = … ?
Rich Benfield (S4)
= 119.0 kg/cm² Steam Masuk (S6)

= 119 °C QS6 = … ?
QS4 = … ?
Condensat Keluar (S7)

…?
QS7 = … ?
Lean Benfield (S2)

P = 0.8 kg/cm²
T = 129 °C
QS2 = … ?
Gambar L2. 7 Blok Diagram Neraca Energi Stripper 202-E

1. Menghitung Panas Masuk Stripper 202-E E. Menghitung Efisien
Rich Benfield (QS4)
masuk = 119 ⁰C + 273.15 K
= 392.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 89 K

Masuk 1 kg/cm²
= 0.957 atm

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 =97,08 + 94,22 x (392,15/1000) + (-2,05) x (392,15/1000)2
+ 0,71 x (392,15/1000)3 + (−0,95)/"(392,15/1000)2 "
= 127.59 kj/kmol-K

Tabel L2. 22 Kapasitas panas komponen Rich Benfield (Cp)
Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 127.593669
V2 O5 7.23188 15.7514 -14.243 4.59181 -0.026 11.3263663
DEA - - - - - 137
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.4964798
KHCO3 - - - - - 87.61

Q = n x Cp x dT
= 1039045.18 kJ

komponen rich benfied dapat dilihat pada Tabel L2.23

Komponen
K2CO3 91.4988 127.59366851 89 1039045.18
V2 O5 6.3617 11.3263663071 89 6412.86526
DEA 12.1289 137 89 147887.71
H2O 6587.4766 76.4964798426 89 44848771
KHCO3 108.7312 87.61 89 847808.583
6806.1971 46889925
- steam reboiler
Kondisi Operasi :
masuk = 150 ⁰C + 273.15 K
= 423.15 K
keluar = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 120 K

Masuk 1 kg/cm²
= 3.385 atm
Menghitung massa steam :

Diketahui : densitas steam pada temperatur 150 ⁰C
= 917.00 kg/m³ The M.W. Kellog Company, 1976):
mSteam = Volume steam X densitas steam
= 15.1 Nm³ x 917 kg/m³
= 13846.70 kg
n Steam = 13846.70 kg
18 kg/kmol
= 769.26 kmol
a. Menghitung panas laten Steam

λH2O = 40655.93 kJ/kmol (Hougen, 1943)
maka,
Qsteam in = nSteam x λH 2 O
= 769.26 kmol x 40655.93 kJ/kg
= 31275024.347 kJ
b. Menghitung panas sensibel steam

Menentukan kapasitas panas (Cp)
Cpm = ∫_𝑇1^𝑇2▒(𝑎+𝑏𝑇+𝑐𝑇2+𝑑𝑇3
)/(
𝑇2−𝑇1) dT
= a + b/2 (T1+T2) + c/3 (T1 + T1T2 + T2 ) + d/4 (T1 + T1 T2 +

2 2 3 2
T1T2 2
+T23)
= a + b/2 (T1+T2) + c/3 (T1 + T1T2 + T2 ) + d/4 (T1 + T1 T2 +
2 2 3 2
T1T22
+T23)
Cp H2O= 7,701 + (0,04595 𝑥 〖 10 〗 ^(−2))/2 x (423,15 + 303,15) +

(0,2521 𝑥 〖 10 〗 ^(−5))/3 x
(423,152 + 423,15 x 303,15 + 303,152) + (0,859 𝑥

〖 10 〗 ^(−9))/4 x (423,153
+ 423,152 x 303,15 + 423,15 x 303,152+ 303,153)

= 8.246 kkal/kmol-K
= 34.523 kkal/kmol-K
Q steam in = nSteam x Cp x dT
= 769,3 kmol x 34,523 kJ/kmol-K x 120 K
= 3186841.65 kJ
Qsteam total = 34461866.0 kJ/kg
2. Menghitung Panas Keluar Stripper 202-E

Lean Benfield (QS2)
masuk = 129 ⁰C + 273.15 K
= 402.15 K
refrensi = 30 ⁰C + 273.15 K
∆T = 303.15 K
= 99 K

1 kg/cm²
= 0.764 atm

Persamaan Shomate :
Cp = a+ bt + ct2 + dt3 + (e/t2)
dimana:
t = T (K)/1000
Cp K2CO3 =97,08 + 94,22 x (402,15/1000) + (-2,05) x (402,15/1000)2
+ 0,71 x (402,15/1000)3 + (−0,95)/"(392,15/1000)2 "
= 128.83 kj/kmol-K

Tabel L2. 25 Kapasitas panas komponen Lean Benfield (Cp)

Cp
Komponen a b c d e
KJ/Kmol-K
K2CO3 97.0809 94.2233 -2.0533 0.70964 -0.9479 128.826
V2 O5 7.23188 15.7514 -14.243 4.59181 -0.026 11.401
DEA - - - - - 137.000
H2O -203.61 1523.29 -3196 2474.46 3.8553 76.818

Q = n x Cp x dT
= 1860316.736 kmol

komponen lean benfied dapat dilihat pada Tabel L2.26
Tabel L2. 26 Panas Sensibel Outlet Lean Benfield (QS2)

Komponen
K2CO3 145.864 128.825688007 99 1860316.736
V2O5 6.362 11.4007832245 99 7180.280
DEA 12.129 137 99 164504.307
H2 O 6611.937 76.8183766137 99 50283905.867
6776.292 52315907.190
- Acid Gas (QS5)

keluar = 126 ⁰C + 273.15 K
= 399.15 K
refrensi = 30 ⁰C + 273.15 K
= 303.15 K
∆T = 96 K

keluar 1 kg/cm²
= 0.764 atm
Menentukan kapasitas panas dalam kondisi tekanan konstan 1 atm (Cp*) Tabel 46. H
Cp = a + bT + (cT2) + (dT3)
)/(
𝑇2−𝑇1) dT
= a + b/2 (T1+T2) + c/3 (T1 + T1T2 + T2 ) + d/4 (T1 + T1 T2 +

2 2 3 2
T1T22
+T23)
Cp CO2= 4,728 + (1,754 𝑥 〖 10 〗 ^(−2))/2 x (399,15 + 303,15) + (−1,34 𝑥
〖 10 〗 ^(−5))/3 x (399152
+ 399,15 x 303,15 + 303,152) + (4,097 𝑥 〖 10 〗 ^(−9))/4 x

(399,153 + 399,152
x 303,15 + 399,15 x 303,152+ 303,153)

= 9.322 kkal/kmol-K
= 39.03 kj/kmol-K
Tabel L2. 27 Kapasitas Panas Standar Komponen Acid Gas (CP*)

Cp*
(kJ/kmol-K)
CO2 4.728 1.754 -1.338 4.097 39.031
H2O 7.701 0.046 0.252 -0.859 33.996
(Sumber : Sherwood)
Menentukan kapasitas panas dalam kondisi tekanan operasi (Cp)
Tabel L2. 28. Kapasitas panas Outlet Acid Gas pada Tekanan Tinggi (Cp)
Pc Tc Cp-Cp* Cp* Cp
Komponen Pr Tr
(atm) (K) kJ/Kmol-K
CO2 72.9 304.2 0.010 1.31213 2.257 39.031 41.288
H2O 33.5 126.2 0.0228 3.16284 0.610 33.996 34.606

Q = n x Cp x ∆T
QCO2 = 31,8913 Kmol x 41,288 kJ/Kmol-K x 96 K
= 180612.067 kJ

komponen Acid gas dapat dilihat pada Tabel L2.29
Tabel L2. 29 Panas Sensibel Outlet Acid Gas (QS5)

Komponen
(Kmol) (kJ/Kmol-K) (K) kJ
H2O 29.9055 41.288 96 K 118534.917
CO2 54.3656 34.606 96 K 180612.067
299146.984
Kondensat Reboiler
Kondisi Operasi :
Mol kondensat = mol steam = 769.26 Nm³/hr
masuk = 127 ⁰C + 273.15 K
= 400.15 K
keluar = 25 ⁰C + 273.15 K
= 298.15 K
∆T = 102 K
Menentukan kapasitas panas kondensat (Cp)

Cp = a + bT + (cT2) + (dT3)
)/(
𝑇2−𝑇1) dT
= a + b/2 (T1+T2) + c/3 (T1 + T1T2 + T2 ) + d/4 (T1 + T1 T2 +

2 2 3 2
T1T22
+T23)
Cp H2O= 7,701 + (0,04595 𝑥 〖 10 〗 ^(−2))/2 x (423,15 + 303,15) +

(0,2521 𝑥 〖 10 〗 ^(−5))/3 x
(423,152 + 423,15 x 303,15 + 303,152) + (0,859 𝑥

〖 10 〗 ^(−9))/4 x (423,153
+ 423,152 x 303,15 + 423,15 x 303,152+ 303,153)

= 8.358 kkal/kmol-K
= 34.99 kj/kmol-K
Q steam in = nSteam x Cp x dT
= 769.3 kmol x 34.993 kJ/kmol-K x 102 K Ta
= 2745683.46 kJ
3. Panas reaksi Absorbsi (Qr)


∆H0f
Komponen
K2CO3 -274.01 -1146457.84
CO2 -94.05 -393505.2
H2O -68.32 -285850.9
KHCO3 -229.80 -961483.2
∑∆H0298 = ∑∆H0f Produk - ∑∆H0f Reaktan

= {(-1146457.84 - 393505.20 - 285850.88)} kj/kmol
- { 2 ( -961483.2000 )}kj/kmol
= -(1825813.92 kj/kmol) - -(1922966 )kj/kmol
= 97152.48 kj/kmol
= 108.731 kmol x 97152.48 kj/kmol
= 10563504.29 KJ
∑∆H0Reaktan = ∑n x Cp x ∆T
= 108.73 kmol x 87.61 kj/kmol-K x 89 K
= 847808.58 kJ
0
∑∆H Produk = ∑n x Cp x ∆T
k2CO3 = 54.3656 kmol x 128.83 kj/kmol-K x 99 K
= 693364.80 kJ
CO2 = 54.3656 kmol x 41.288 kj/kmol-K x 99 K

= 222220.01 kJ
H2O = 54.3656 kmol x 34.61 kj/kmol-K x 99 K

= 186256.19 kJ
∆H0Produk = (784960,14 + 251337,93 + 210661,704) kJ

= 1101841.01 kJ
∆H0r = ∑∆H0Produk + ∑∆H0298 -∑∆H0Reaktan

= 10817537 KJ = Qr
4. panas yang hilang ( Q loss)

Qloss = ∑Qinput - ∑Qoutput
= (QS4 + QS6) - (QS2+ QS5 + QS7+ Qr)
= ( 81351790.9 - 66178274.35 ) kJ
= 15173516.50 kJ
Tabel L2. 32 Neraca Energi Stripper 202-E

Aliran Panas Input Output
(kJ/Jam) (kJ/Jam)
Rich Benfield(QS4) 46889924.86 -
Steam (QS6) 34461866.00 -
Lean Benfield (QS2) - 52315907.19
Acid gas (QS5) - 299146.98
Kondensat (QS7) - 2745683.46
Reaksi Absorbsi (Qr) - 10817536.72
81351790.85 81351790.85
E. Menghitung Efisiensi
Efisiensi = Panas Keluar

x 100 %
Panas Masuk 10817537 KJ
Efisiensi = 66178274.35 kJ 34461866.00
x 100 %
81351790.85 kJ 31.3898752
= 81.35 %
769.3 kmol x
Tabel 46. Hasil Perhitungan Cp Komponen Lainnya
T Cp*
(K) (kj/kmol-K)
H2 O 7.701 0.460 2.521 -0.859 #REF! #REF!
CO2 4.728 17.540 -13.38 4.097 #REF! #REF!
Tabel L2. 30 Kapasitas panas (Cp)
Cp
(kj/kmol-K)
H2O 7.701 0.046 0.252 4.097 34.9926
10817537 KJ
34461866.00
31.3898752
769.3 kmol x 34.523 kJ/kmol-K x 120 K
masuk keluar
T = 381.15 K T = 381.15 K
P = 24.156 atm P = 24.156 atm
Cp masuk Cp keluar
KJ/Kmol-K KJ/Kmol-K
CO2 44.232 44.209
N2 29.833 29.857
CH4 40.829 40.339
C2H6 68.358 67.542
C3H8 107.610 109.400
i-C4H10 207.74 184.48
n-C4H10 184.080 173.930
i-C5H12 200.170 194.100
n-C5H13 199.950 194.430
C6H14 227.540 222.520
381.15 K 24.156 atm 8.3145 hougen cal/gmolC

381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
381.15 K 24.156 atm 8.3145 370.15 K 24.059 atm 8.3145
370.15 K 24.059 atm 8.3145

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Outlet Natural Gas (S3)

Lean Benfield (S2)

Inlet Natural Gas ( S1 )

Rich Benfield (S4)

Tabel 5.3. Data Operasi Inlet Lean Benfield (S2)

Tabel 5.4. Data Hasil Analisa SPGR Lean Benfield ( S2 )

Tabel 5.5. Data Hasil Analisa Lean Benfield ( S2 )

Tabel 5.6. Data Operasi Outlet Natural Gas (S3)

Tabel 5.7. Data Komponen Outlet Natural Gas (S3)

Tabel 5.8. Data Operasi Outlet Rich Benfield (S4)

Tabel Lampiran 2.29. Data Operasi Acid Gas Keluar

Tabel Lampiran 2.30. Data Operasi Lean Beanfiled Keluar

Tabel Lampiran 2.31. Data Operasi Steam keluar

Gambar L2. 1 Blok Diagram Absorber dan Stripper

A. Menghitung Neraca Massa pada Absorber Tanggal 2 Agustus 2016

Natural Gas (S1) n-C5H13 = 0.08 %

Komposisi Natural Gas : P = 25.00 kg/cm²

Tekanan = 26.13 kg/cm² 0.967 atm

Aliran Natural Gas (S1) dalam keadaan standar (0oC, 1 atm)

Untuk menghitung mol komponen dapat dihitung melalui persamaan :

Untuk menghitung massa komponen dapat dihitung melalui persamaan :

Hasil perhitungan massa komponen S1 ditunjukkan pada

Tabel L2. 1 Massa Natural Gas Masuk Absorber (S1)

Lean Benfield (S₂)

Tabel L2. 2 Mol Lean Benfield Masuk Absorber

2. Menghitung Massa Keluar Absorber

Menentukan Mol Sweet Gas (S3)

Menentukan Mol Komponen Sweet Gas

Untuk menghitung massa komponen dapat dihitung melalui persamaan :

Dengan cara yang sama, hasil perhitungan massa komponen Sweet

Tabel L2. 3 Massa Sweet Gas Keluar Absorber (S3)

Pada reaksi ini yang menjadi reaktan pembatas adalah CO 2 dengan

H2O sisa = 6641.84 54.37 ) kmol

CO2 sisa = 59.43 - 54.37 ) kmol

KHCO3 terbentuk = 2 x 54.37 kmol

Tabel L2. 4 Massa Outlet Rich Benfield Absorber (S4)

Komposisi Natural Gas : Rich Benfield (S4)

Gambar L2. 2 Neraca Massa Keseluruhan Absorber 201-E

### 10.959 306.86

2.13683676 5.06611 44 222.91

Rich Benfield (S4)

omposisi Rich Benfield :

uhan Absorber 201-E

Acid Gas (S5)

Komposisi Rich Benfield

Gambar L2. 4 Data Analisa dan Kondisi Operasi Stripper 202-E

Tabel L2. 6 Massa Rich Benfield masuk Stripper (S4)

2. Menghitung Massa Keluar Stripper 201-E

Reaksi yang terjadi di Benfield Stripper adalah sebagai berikut :

CO2 terurai = 54.37 kmol x 44 kg/kmol

(sumber: The M.W. Kellog Company, Operating Instructions Manual, 1976):

Psat H2O nH2O (hougen, 1943)

Tabel L2. 7 Massa Lean Benfield keluar Stripper (S2)

Tabel L2. 8 Massa Acid Gas keluar Stripper (S5)

Hasil Perhitungan neraca massa Stripper pada tanggal 6,9,13, dan 16

Gambar L2. 5 Neraca Massa Keseluruhan Stripper 202-E

T = 381.15 K P = 24.156 atm

381.15 K 24.156 atm 8.3145 hougen cal/gmolC energi keluar

energi keluar 4.1868

4.1868 0.9 3.76812 10.5964

Tekanan = 26.13 kg/cm² 0.967 atm

Menentukan kapasitas panas dalam kondisi tekanan konstan 1 atm (Cp*)