kw(agua) 1.

00E-14
ka(HNO2) 7.10E-04
kb(NO2-) 1.41E-11

Vol. analito(mL) 16
C. analito (M) 0.5 vol.valorante (mL) KOH(sal en p. sub)
C. valorante (M) 0.25 0 0
5 0.05952380952381
10 0.096153846153846
15 0.120967741935484
20 0.138888888888889
25 0.152439024390244
28 0.159090909090909
30 0.16304347826087
32 0.166666666666667
36 0.019230769230769
38 0.027777777777778
40 0.035714285714286
42 0.043103448275862

Titulacion HNO
14

12

10

8
PH

0
0 5 10 15 20
volume
 HNO2(sal en p. supr) OH- H30+ POH PH a
0.5 5.41E-13 1.85E-02 12.2669319 1.73306807 1
0.321428571428571 2.80E-12 3.58E-03 11.5534523 2.44654769 1
0.211538461538462 6.55E-12 1.53E-03 11.1836952 2.81630477 1
0.137096774193548 1.26E-11 7.95E-04 10.9002469 3.09975308 1
0.083333333333333 2.37E-11 4.23E-04 10.6258826 3.37411745 1
0.042682926829268 5.06E-11 1.98E-04 10.2958383 3.70416175 1
0.022727272727273 9.91E-11 1.01E-04 10.0039523 3.99604774 1
0.010869565217391 2.12E-10 4.71E-05 9.67315505 4.32684495 1
0 1.53E-06 6.52E-09 5.81446807 8.18553193 1
0.153846153846154 1.92E-02 5.20E-13 1.71600334 12.2839967 1
0.148148148148148 2.78E-02 3.60E-13 1.5563025 12.4436975 1
0.142857142857143 3.57E-02 2.80E-13 1.44715803 12.552842 1
0.137931034482759 4.31E-02 2.32E-13 1.36548798 12.634512 1

Titulacion HNO2 vs KOH

indicadores adecuados para
determinar el cambio de ph en el
punto de equivalencia:

1) o-cresolftaleina ,rango [8.1-9.8]

2) m-nitrofenol, rango [7.6-8.2]

5 10 15 20 25 30 35 40 45
volumen de KHO
 b c
7.10E-04 -3.55E-04
6.02E-02 -2.28E-04
9.69E-02 -1.50E-04
1.22E-01 -9.73E-05
1.40E-01 -5.92E-05
1.53E-01 -3.03E-05
1.60E-01 -1.61E-05
1.64E-01 -7.72E-06
1.41E-11 -2.35E-12
1.92E-02 -2.169231E-12
2.78E-02 -2.088889E-12
3.57E-02 -2.014286E-12
4.31E-02 -1.944828E-12

para
e ph en el

go [8.1-9.8]
[7.6-8.2]