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    3 views4 pages

    Фосфорная Кислота Распределительная Диаграмма

    Uploaded by

    Marshmallow

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 4

    Фосфорная кислота pH 14 13.5 13 12.5 12 11.

    5
    [H+] 1.00E-14 3.16E-14 1.00E-13 3.16E-13 1.00E-12 3.16E-12
    Z 2.25E-22 2.34E-22 2.64E-22 3.59E-22 6.60E-22 1.61E-21

    K1 7.10E-03 α(H3PO4) 4.45E-21 1.35E-19 3.79E-18 8.80E-17 1.51E-15 1.96E-14


    K2 6.20E-08 α(H2PO4-) 3.16E-09 3.03E-08 2.69E-07 1.98E-06 мольных
    Зависимость 1.08E-05 4.40E-05
    долей продуктов д
    K3 5.00E-13 α(HPO ) 4
    2-
    1.96E-02 5.95E-02 1.67E-01кислоты
    3.87E-01 от рН раствора
    6.67E-01 8.63E-01(распределит
    α(PO ) 4
    3-
    9.80E-01 9.41E-01 8.33E-01 6.13E-01 3.33E-01 1.37E-01

    0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5 5.5 6 6.5 7 7

    α(H3PO4) α(H2PO4-) α(H


    11 10.5 10 9.5 9 8.5 8 7.5 7 6.5
    1.00E-11 3.16E-11 1.00E-10 3.16E-10 1.00E-09 3.16E-09 1.00E-08 3.16E-08 1.00E-07 3.16E-07
    4.62E-21 1.41E-20 4.43E-20 1.40E-19 4.48E-19 1.46E-18 5.11E-18 2.10E-17 1.15E-16 8.49E-16

    2.16E-13 2.24E-12 2.26E-11 2.26E-10 2.23E-09 2.16E-08 1.96E-07 1.50E-06 8.69E-06 3.72E-05
    1.54E-04 5.02E-04
    ых долей продуктов 1.60E-03 фосфорной
    диссоциации 5.07E-03 1.59E-02 4.85E-02 1.39E-01 3.38E-01 6.17E-01 8.36E-01
    аствора (распределительная диаграмма)
    9.52E-01 9.84E-01 9.93E-01 9.93E-01 9.84E-01 9.51E-01 8.61E-01 6.62E-01 3.83E-01 1.64E-01

    α
    4.76E-02 1.56E-02 4.97E-03 1.57E-03 4.92E-04 1.50E-04 1.00
    4.31E-05 1.05E-05 1.91E-06 2.59E-07
    0.90

    0.80

    0.70

    0.60

    0.50

    0.40

    0.30

    0.20

    0.10

    0.00
    5 4 4.5 5 5.5 6 6.5 7 7.5 8 8.5 9 9.5 10 10.5 11 11.5 12 12.5 13 13.5 14
    pH
    4) α(H2PO4-) α(HPO42-) α(PO43-)
    6 5.5 5 4.5 4 3.5 3 2.5 2 1.5
    1.00E-06 3.16E-06 1.00E-05 3.16E-05 1.00E-04 3.16E-04 1.00E-03 3.16E-03 1.00E-02 3.16E-02
    7.54E-15 7.24E-14 7.15E-13 7.15E-12 7.20E-11 7.42E-10 8.10E-09 1.03E-07 1.71E-06 3.87E-05

    1.33E-04 4.37E-04 1.40E-03 4.43E-03 1.39E-02 4.26E-02 1.23E-01 3.08E-01 5.85E-01 8.17E-01
    9.41E-01 9.80E-01 9.92E-01 9.94E-01 9.86E-01 9.57E-01 8.76E-01 6.92E-01 4.15E-01 1.83E-01
    5.84E-02 1.92E-02 6.15E-03 1.95E-03 6.11E-04 1.88E-04 5.43E-05 1.36E-05 2.57E-06 3.59E-07
    2.92E-08 3.04E-09 3.08E-10 3.08E-11 3.06E-12 2.97E-13 2.72E-14 2.14E-15 1.29E-16 5.68E-18
    1 0.5 0
    1.00E-01 3.16E-01 1.00E+00
    1.07E-03 3.23E-02 1.01E+00

    9.34E-01 9.78E-01 9.93E-01


    6.63E-02 2.20E-02 7.05E-03
    4.11E-08 4.31E-09 4.37E-10
    2.06E-19 6.81E-21 2.19E-22

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