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Ionic Bonding

Universidad NACIONAL de
Colombia, Sede Medellin

Chicago - Medellin, 2015


Materials Science
Electronic
Bonding State
Structure
- Ionic - Gas
- Atom structure - Covalent
- Hydrogen atom - Liquid
- Metallic - Solid
- Periodic Table - Dipole-dipole
- Schrödinger’s Equation - Van der Waals
Random - Disorder - Order
- H-bonding

Material Properties

Material Design
Last….
Electronic
Bonding State
Structure
- Ionic - Gas
- Atom structure - Covalent
- Hydrogen atom - Liquid
- Metallic - Solid
- Periodic Table - Dipole-dipole
- Schrödinger’s Equation - Van der Waals
Random - Disorder - Order
Mathematical - H-bonding
Foundation
Material Properties

Material Design
Now….
Electronic
Bonding State
Structure
- Ionic - Gas
- Atom structure - Covalent
- Hydrogen atom - Liquid
- Metallic - Solid
- Periodic Table - Dipole-dipole
- Schrödinger’s Equation - Van der Waals
Random - Disorder - Order
Mathematical - H-bonding
Foundation

Valence
Average valence electron energy (AVee)
Madelung constant
Periodic Table

http://commons.wikimedia.org
Periodic Table

n+l
2
1s 3
4 5
2s 2p 6
3s 3p 3d 7
4s 4p 4d 4f
5s 5p 5d 5f 5g
6s 6p 6p 6f 6g 6h

http://commons.wikimedia.org
Periodic Table

http://commons.wikimedia.org
Photoelectron Spectroscopy (PES)

wikipedia and chemwiki


Photoelectron Spectroscopy (PES)

population
“Intensity”

Identity of
Species

wikipedia and chemwiki


Photoelectron Spectroscopy (PES)
Inner Inner
Electrons Electrons

Outer Outer
Electrons Electrons

wikipedia and chemwiki


Valence
Inner Inner
Electrons Electrons
Chemical
reactivity

Outermost Shell

VALENCE

Outer Outer
Electrons Electrons

wikipedia and chemwiki


Average Valence electron energy

wikipedia and chemwiki


Average Valence electron energy

- Metals: <11eV Electron donor


- non-Metals: > 13eV Electron aceptor
- Semi-metals: 11eV<AVee<13eV
“depends”

wikipedia and chemwiki


Madelung Constants
Born-Haber Cycle
Born-Haber Cycle

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