Scholar’s Science College

TEST CHEMISTRY 1 st year Test # 12

Name:_____________ Roll # ________ Dated.________
Multiple Choice Questions

i. Which one of the following process is an exothermic

a) sublimation b) Respiration c) Fusion d) Evaporation
ii. At constant volume, qv is equal to
a) H b) E c) P d) V
iii. Standard enthalpies are measured measured at
a) 273 K b) 298 K c) 373 K d) All
iv. A state function which describes together internal energy and product of pressure and volume is called
a) enthalpy b) internal energy c) work d) free energy
v. In a bomb calorimeter, the reactions are carried out at constant
a) pressure b) temperature c) volume d) none
vi. one calorie is equivalent to
a) 0.4184 J b) 41.841 J c) 4.1841 J d) 418.4 J
vii. In endothermic reactions, the heat content of the
a) Products is more than that of reactants b) reactants is more than that of products
b) Both a & b d) reactant and products are equal
viii. The change in heat energy of a chemical reaction at constant temperature and pressure is called
a) enthalpy change b) heat of sublimation
c) bond energy d) internal energy change
Which of the folowing is not a drying agent in desicator
a) CaCl2 b)P2O5 c) Silica gell d) 10% NaCl
The comparative rates at which the solute move in paper chromatography depend on
a) The size of paper b) Rf value of solutes c)temperature of the experiment
d) size of the chromatomatographic tank

SHORT QUESTIONS 9×2=18

i. Temperature is a state function but heat is not. Why?
ii. Differentiate between exothermic and endothermic reactions.
iii. What is a spontaneous process?
iv. Differentiate between state of the system and state function.
v. What is meant by standard enthalpy of atomization?
vi. Non – spontaneous process never happens in the universe”. Justify.
vii. Spontaneous reaction always proceeds in the forward direction. Give reason.
viii. What is enthalpy of neutralization?
ix. What is the physical significance of equation, H = qp?
x. What is Rf value? Why it has no unit?
xi. What is the principle of chromatography?
 Extensive
1. Define Hesses’s Law, calculate the lattice of NaCl. ---4

2. Discuss first law of thermodynamic and prove that E = qv --4

3. explain the measurement of enthalpy by using Bomb calorimeter 4