1)

6
1. Single Phase Region (liquid like)
1
2. Bubble point pressure
3. Two phase region (vapor and liquid) mixture
4. Dew point pressure
5. Single phase region (vapor like)
3 a) Because the degree of freedom of the system
P 2 4 is equal to the unity which means that we only
need one single intensive property to identify
5 the system at equilibrium.
 Gibbs phase rule F=C−P+2 , having
single component and two phases then our
degree of freedom . F=1−2+2=1
Vm b) Further decreases in volume beyond the
bubble point are accompanied by a large
1) increase in pressure because the liquid is only
6 slightly compressible. This is indicated by the
1 nearly vertical isotherms on the left side. In
the undersaturated vapor region on the right
side of the diagram, a large change in volume
reduces pressure only slightly because the
vapor is highly compressible.
1 dv
P 2
3 Cg=− ( )( )
v dp
4

Vm

2)
 Critical point : ,the point at which the vapor and liquid phases can no longer be
distinguished, and their intensive properties are identical.
 Bubble point: At the bubble point, the system is 100% saturated liquid in
equilibrium with an infinitesimal amount of saturated vapor/or the point at wich
the first gas bubble comes out of the oil.
 Dew point : the system is 100% saturated the saturated vapor in equilibrium with
an infinitesimal amount of saturated liquid/or the point at which the first droplet
of oil condenses out of the gas.
  Cricondenbar : The cricondenbar is the maximum pressure above which no gas
can be formed regardless of temperature.
 Cricondentherem is the maximum temperature above which liquid cannot be
formed regardless of pressure.
3) A
1. GAS CONDENSATE
the reason is that because it has a high percentage of methane around 76% and low value
of C6+. its API is 53 sense there is an API this means that there some oil has been
condensed out of that gas.
2. BLACK OIL
High percentage of c6+ and low 1 content means that this reservoir fluid is a black oil
also looking at the API gravity of about 34 it indeed a black /or medium oil.
3. DRY GAS
High percentage of c1 and the absence of c6+ means that this reservoir fluid is a dry gas.

B.

ρw (lb/ft3) ρw (kg/m3) ρw (g/cm3)

62.4 1000 1
API SG ρo (lb/ft3) ρo(kg/m3) ρo (g/cm3)
53.1 0.767 47.83 766.52 0.7665
34 0.855 53.35 854.98 0.855
4.
a)

Vapor density =76kg/m3, Vv* = 1/76 = mv=m-ml

0.01315789m3/kg
V Vmix = ml Vl* + mv Vv*
Liquid density =313kg/m3, Vl*=1/313=0.00319489 Vmix = mlVl* + (m-ml) Vv*
m3/kg Vmix = mlVl*+mVv* - mlVv*
Total volume= 0.02m3, total mass = 4kg Vmix = mVv* + ml (Vl*-Vv*)
Specific volume =v*= 1/ρ = m3/kg ml= (vmix-mVv*)/(Vl*-Vv*)
Total mass = mass liquid + mass of vapor, m = ml+mv
Total volume = liquid vol. + vapor vol, V=Vl+Vv

m (kg) V (m3) ρl (kg/m3) ρv(kg/m3) Vl*(m3/kg) Vv*(m3/kg)

L 4 0.02 313 76 0.0032 0.0132
ml (kg) mv (kg) vl (m3) vv(m3) vl% Vv%
3.2753 0.7247 0.0105 0.0095 52.3207 47.6793
 b) F=1−2+2=1 1 degrees of freedom must be specified for the
system to exist in the two-phase region (pressure or
temperature)
5.
Componen MM mass(g mass(kg mass(lb
mole %
t (g/gmol) mole fra. Mwf g/gmol) N(g-mol) ) ) )
C1 17 16 0.17 101.54 5 507.7 0.5077 1.1193
C4 30 58 0.3
C10 31 142 0.31
C12+ 22 170 0.22
Summatio  
100
n 1