Professional Documents
Culture Documents
IMPORTANT TERMS/
FORMULAS FOR AIPMT
PHYSICS
MOTION IN A STRAIGHT LINE
gx 2
5. Equation of trajectory is y = x tan q - , which is
1. The area under the velocity-time curve and time axis gives 2u 2 cos2 q
the displacement of the object for given interval of time. parabola.
2. If a body falls freely, the distance covered by it in each 6. Equation of trajectory of an oblique projectile in terms of
subsequent second starting from first second will be in the
ratio 1 : 3 : 5 : 7, etc. æ xö
range (R) is y = x tan q ç1 - ÷
3. If a body is thrown vertically up with an initial velocity u, it è Rø
takes u/g second to reach maximum height and u/g second 7. Maximum height is equal to n times the range when the
to return, if air resistance is negligible. projectile is launched at an angle q = tan–1(4n).
4. If air resistance acting on a body is considered, the time 8. In a uniform circular motion, velocity and acceleration are
taken by the body to reach maximum height is less than the constant only in magnitude. Their directions change.
time to fall back the same height. 9. In a uniform circular motion, the kinetic energy of the body
5. For a particle having zero initial velocity if s µ t a , where r ur r
is a constant. W = 0, a ¹ 0, p ¹ constant, L = constant
a > 2 , then particle’s acceleration increases with time.
6. For a particle having zero initial velocity if s µ t a , where v2
10. ar = w2 r = = wv (Always applicable)
a < 0 , then particle’s acceleration decreases with time. r
7. Kinematic equations : 4p2
ar = 4 p2 n 2 r = 2 r (Applicable in uniform circular motion)
v = u + at ; v2 = u2 + 2as T
n = frequency of rotation, T = time period of rotation.
1 2 r r r
s = ut + at ar = w´ v
2
applicable only when particles moves with constant
LAWS OF MOTION
acceleration.
r r r r
8. If acceleration is variable use calculus approach. 1. Newton’s second law : F = ma, F = dp / dt
r r r
9. Relative velocity : vBA = vB - v A
r r ur ur t2
2. Impulse : Dp = F Dt , p 2 - p1 = ò F dt
MOTION IN A PLANE r r t1
1. If T is the time of flight, h maximum height, R horizontal 3. Newton’s third law : F12 = - F21
range of a projectile, a its angle of projection, then the 4. Frictional force f s £ ( f s )max = m s R ; f k = mk R
relations among these quantities. 5. Circular motion with variable speed. For complete circles,
gT 2 the string must be taut in the highest position, u 2 ³ 5 gl
h= ....... (1) ; gT2 = 2R tan a ....... (2);
8 where l is the length of string.
R tan a = 4h ....... (3) Circular motion ceases at the instant when the string becomes
2. For a given initial velocity, to get the same horizontal range, slack, i.e. when T = 0, range of values of u for which the
there are two angles of projection a and 90° – a. string does go slack is 2 g l < u < 5g l .
3. The equation to the parabola traced by a body projected 6. Conical pendulum : w = g / h where h is height of a point
horizontally from the top of a tower of height y, with a velocity of suspension from the centre of circular motion.
u is y = gx2/2u2, where x is the horizontal distance covered 7. The acceleration of a lift
by it from the foot of the tower. actual weight - apparent weight
4. At any instant if v is the velocity of projectile making angle a= , where the weights is
mass
b with the horizontal, then
in N. If ‘a’ is positive the lift is moving down, and if it is
vx = v cos b = u cos q and vy = v sin b = u sin q – gt
negative the lift is moving up.
2
WORK, ENERGY AND POWER 7. If a body is released from rest on rough inclined plane, then
1. If a light body and a heavy body have equal kinetic energy, n
then heavy body has greater momentum. for pure rolling m r ³ tan q (I = nmr2)
n +1 c
2. Work due to static force of friction on system as whole is
always zero. æ n ö
Rolling with sliding 0 < m s < ç ÷ tan q ;
3. If a body moves with constant power, its velocity (v) is related è n +1 ø
to distance travelled (x) by the formula v µ x3/2.
g sin q
4. Work due to kinetic force of friction between two contact < a < g sin q
surfaces is always negative. It depends on relative n +1
GRAVITATION
displacement between contact surfaces WFK = - FK ( Srel ) .
5. S W = S DK , S W Þ total work due to all kinds of forces, 1. Angular momentum conservation leads to Kepler’s second
S DK Þ total change in kinetic energy.. law. However, it is not special to the inverse square law of
gravitation. It holds for any central force.
6. SWconservative = -S DU ; SWconservative Þ Total work due 2. The acceleration due to gravity.
to all kinds of conservative forces. (a) at a height h above the Earth’s surface
S DU Þ Total change in all kinds of potential energy.. GM E GM E æ 2h ö
g ( h) = = 2 ç
1- ÷ for h << RE
velocity of separation of colliding bodies ( RE + h) 2
RE è R
e =- E ø
7.
velocity of approach of colliding bodies
8. The total momentum of a system of particles is a constant in æ 2h ö GM E
g (h) = g (0) ç1 - ÷ where g (0) =
the absence of external forces. è RE ø RE2
SYSTEM OF PARTICLES AND ROTATIONAL MOTION (b) at depth d below the Earth’s surface is
1. The centre of mass of a system of particles is defined as the GM E æ d ö æ d ö
g (d ) = 2 ç
1- ÷ = g (0) ç1 -
RE è RE ø è RE ÷ø
point whose position vector is R =
å mi riThe centre of 3. The gravitational potential energy
M
gravity of an extended body is that point where the total Gm1m2
V =- + constant
gravitational torque on the body is zero. The centre of gravity r
of a body coincides with its centre of mass only if the 4. The escape speed from the surface of the Earth is
gravitational field does not vary from one part of the body
to the other. 2GM E
ve = = 2 gRE and has a value of 11.2 km s–1.
2. The angular momentum of a system of n particles about the RE
n 5. A geostationary (geosynchronous communication) satellite
origin is L = å ri ´ pi moves in a circular orbit in the equatorial plane at a
i =1 approximate distance of 4.22 × 104 km from the Earth’s centre.
The torque or moment of force on a system of n particles GM s æ 1 + e ö GM s æ 1 - e ö
vmax = ç ÷ ; vmin =
a çè 1 + e ÷ø
6.
about the origin is t = å ri ´ Fi a è1- e ø
i 7. Whenever force responsible for orbital motion obeys inverse
3. The moment of inertia of a rigid body about an axis is defined square law, then only square of time period is directly
proportional to cube of average distance between planet
by the formula I = å mi ri 2 where ri is the perpendicular and sun.
distance of the ith point of the body from the axis. The kinetic T12 a13
T µa2 3
; =
1 2 T22 a23
energy of rotation is K = Iw
2 Applicable only when both planets revolve around same
4. The theorem of parallel axes : I z' = Iz + Ma2,. mass.Length of semi major axis is the average distance
between sun and planet during its complete orbital motion.
Theorem of perpendicular Axes - Iz = Ix + Iy
5. For rolling motion without slipping vcm = Rw, where vcm is 8. If F µ r n then T 2 µ ( r )1- n
the velocity of translation (i.e., of the centre of mass), R is
If U µ r m then T 2 µ (r )2 - m
the radius and m is the mass of the body. The kinetic energy
of such a rolling body is the sum of kinetic energies of MECHANICAL PROPERTIES OF SOLIDS
1 2 1
translation and rotation : K = mvcm + I w2 1. If S is the stress and Y is Young’s modulus, the energy
2 2 density of the wire E is equal to S2/2Y.
6. A rigid body is in mechanical equilibrium if
2. If a is the longitudinal strain and E is the energy density of
(a) It is in translational equilibrium i.e., the total external
a stretched wire, Y Young’s modulus of wire, then E is equal
force on it is zero : S Fi = 0.
(b) It is in rotational equilibrium i.e., the total external torque 1
to Y a2 .
on it is zero : S ti = Sri × Fi = 0. 2
3
MECHANICAL PROPERTIES OF FLUIDS 5. Newton’s Law of Cooling says that the rate of cooling of a
body is proportional to the excess temperature of the body
1. Pascal’s law : A change in pressure applied to an enclosed
dQ
fluid is transmitted undiminished to every point of the fluid over the surroundings : = -k (T2 - T1 ) ; where T1 is the
and the walls of the containing vessel. dt
2. Bernoulli’s principle states that as we move along a temperature of the surrounding medium and T2 is the
streamline, the sum of the pressure (P), the kinetic energy temperature of the body.
per unit volume (rv2/2) and the potential energy per unit THERMODYNAMICS
volume (rgy) remains a constant. 1. The first law of thermodynamics is the general law of
P + rv2/2 + rgy = constant conservation of energy applied to any system in which energy
3. Surface tension is a force per unit length (or surface energy transfer from or to the surroundings (through heat and work)
per unit area) acting in the plane of interface between the is taken into account. It states that DQ = DU + DW, where
liquid and the bounding surface. DQ is the heat supplied to the system, DW is the work done
4. Stokes’ law states that the viscous drag force F on a sphere by the system and DU is the change in internal energy of the
of radius a moving with velocity v through a fluid of system.
viscosity h is, F = 6phav. If Q > 0, heat is added to the system, if Q < 0, heat is removed
5. The surface tension of a liquid is zero at boiling point. The to the system, if W > 0, Work is done by the system, if
surface tension is zero at critical temperature. W < 0, Work is done on the system quantity.
2. In isothermal quasi-static processes, heat is absorbed or
6. If a drop of water of radius R is broken into n identical drops,
given out by the system even though at every stage the gas
the work done in the process is 4pR2S(n1/3 – 1). has the same temperature as that of the surrounding reservoir.
7. Two capillary tubes each of radius r are joined in parallel. This is possible because of the infinitesimal difference in
The rate of flow of liquid is Q. If they are replaced by single temperature between the system and the reservoir.
capillary tube of radius R for the same rate of flow, then In an isothermal expansion of an ideal gas from volume V1 to
R = 21/4 r. V2 at temperature T the heat absorbed (Q) equals the work
8. If radius of a drop is doubled its terminal velocity increases
æV ö
to four times. done (W) by the gas, each given by Q = W = nRT ln ç 2 ÷
è V1 ø
THERMAL PROPERTIES OF MATTER 3. g
In an adiabatic process of an ideal gas PV = constant,
1. The coefficient of linear expansion (al), superficial expansion Cp
(b) and volume expansion (av) are defined by the relations : where g = .
Cv
Dl DA DV Work done by an ideal gas in an adiabatic change of state
= a l DT ; = bDT ; = aV DT
l A V nR (T1 - T2 )
where Dl and DV denote the change in length l and volume from (P1, V1, T1) to (P2, V2, T2) is W =
g -1
V due to change of temperature DT. The relation between
4. The efficiency of a Carnot engine is given by
them is :
T
av = 3al ; b = 2a l h = 1- 2
T1
2. In conduction, heat is transferred between neighbouring No engine operating between two temperatures can have
parts of a body through molecular collisions, without any efficiency greater than that of the Carnot engine.
flow of matter. For a bar of length L and uniform cross section
A with its ends maintained at temperatures TC and TD, the KINETIC THEORY
rate of flow of heat H is : 1
1. Kinetic theory of an ideal gas gives the relation P = nmv 2 ,
TC - TD 3
H = KA , where K is the thermal conductivity of where n is number density of molecules, m the mass of the
L
the material of the bar. molecule and v 2 is the mean of squared speed. Combined
3. Convection involves flow of matter within a fluid due to with the ideal gas equation it yields a kinetic interpretation
unequal temperatures of its parts. of temperature.
4. Radiation is the transmission of heat as electromagnetic 1 3 3k BT
waves. Radiant heat travels with the speed of light. It requires nmv 2 = k BT , vrms = (v 2 )1/ 2 =
2 2 m
no medium. Stefan’s law of radiation : The energy emitted by
a black body per unit area per second is directly proportional 2. The law of equipartition of energy is stated thus: the energy
for each degree of freedom in thermal equilibrium is 1/2 (kBT)
to the fourth power of its Kelvin temperature. E = sT4, where
the constant s is known as Stefan’s constant. 3
3. The translational kinetic energy E = k B NT . This leads to
Wein’s displacement law states that lmT = constant, where 2
lm is the wavelength corresponding to maximum energy. 2
The constant is known as Wein’s constant. a relation PV = E.
3
4
inductance of coil 1 with respect to coil 2. M 12 = K L1 L2 . minimum deviation. Dispersion is the splitting of light into
its constituent colours. The deviation is maximum for violet
- Rt / L and minimum for red. Dispersive power w is the ratio of
7. LR circuit : For growth current, i = i0 [1 - e ]
angular dispersion ( dv – dr ) to the mean deviation d.
For decay of current, i = i0 e - Rt / L dv - d r
w= , where dv, dr are deviation of violet and red
d
ALTERNATING CURRENT respectively and d the deviation of mean ray (usually yellow).
4. For refraction through a spherical interface (from medium 1
1. For an alternating current i = im sin wt passing through a
to 2 of refractive index n1 and n2 respectively)
resistor R, the average power loss P (averaged over a cycle)
due to joule heating is (1/2)i2mR. To express it in the same n2 n1 n2 - n1 1 1 1
- = . Thin lens formula v - u = f , Lens
form as the dc power (P = I2R), a special value of current is v v R
used. It is called root mean square (rms) current and is
1 (n2 - n1 ) æ 1 1ö
im maker’s formula : f = n1 çè R - R ÷ø
denoted by I = = 0.707 im . 1 2
2
The power of a lens P = 1/f. The SI unit for power of a lens is
The average power loss over a complete cycle is given by P dioptre (D): 1 D = 1 m–1.
= V I cos f. The term cos f is called the power factor. If several thin lenses of focal length f1, f2, f3,.. are in contact,
When a value is given for ac voltage or current, it is ordinarily the effective focal length of their combination, is given by
the rms value. 1 1 1 1
2. An ac voltage v = vm sinwt applied to a pure inductor L, = + + + ........
f f1 f 2 f 3
drives a current in the inductor i = im sin (wt – p/2), where
The total power of a combination of several lenses is
im = vm/X L. XL = wL is called inductive reactance. The
P = P1 + P2 + P3 + …
current in the inductor lags the voltage by p/2. The average If distance between lens is d then power of combination
power supplied to an inductor over one complete cycle is = P1 + P2 – d × P1P2
zero. Chromatic aberration is the colouring of image produced by
An ac voltage v = vm sinwt applied to a capacitor drives a lenses. This can be avoided by combining a convex and a
current in the capacitor: i = im sin (wt + p/2). Here, concave lens of focal lengths f1 and f2 and dispersive powers
w1, w2 respectively satisfying the equation
vm 1
im = , XC = is called capacitive reactance. w1 w 2
XC wC + = 0 or in terms of powers w1P1 + w2 P2 = 0 .
f1 f 2
3. An interesting characteristic of a series RLC circuit is the
phenomenon of resonance. The circuit exhibits resonance, WAVE OPTICS
i.e., the amplitude of the current is maximum at the resonant
1. Young’s double slit of separation d gives equally spaced
1 fringes of angular separation l/d. The source, mid-point of
frequency, w0 = (X L = XC ) .
LC the slits, and central bright fringe lie in a straight line. An
extended source will destroy the fringes if it subtends angle
w0 L 1 more than l/d at the slits. The resultant intensity of two
The quality factor Q defined by Q = = is an waves of intensity I0/4 of phase difference f at any points is
R w 0 CR
given by
indicator of the sharpness of the resonance, the higher value
éfù
of Q indicating sharper peak in the current. I = I 0 cos 2 ê ú , where I is the maximum intensity..
ë 2û 0
RAY OPTICS
l
1. Reflection is governed by the equation Ð i = Ð r and refraction Condition for dark band : d = (2n - 1) ,
2
by the Snell’s law, sin i/sin r = n, n is refractive index where
the incident ray, reflected ray, refracted ray and normal lie in Dl
For bright band : d = nl, Fringe width b =
the same plane. d
2. A thin film of thickness t and refractive index µ appears dark
1 1 1
2. Mirror equation : + = . by reflection when viewed at an angle of refraction r if
v u f 2µt cos r = nl (n = 1, 2, 3, etc.)
8
The minimum thickness (n = 1) of a film which appears dark 6. In forward bias (n-side is connected to negative terminal of
by reflection at normal incidence (r = 0°) is 2µt = l. the battery and p-side is connected to the positive), the barrier
The minimum thickness of a film, which appears bright under is decreased while the barrier increases in reverse bias.
normal incidence of monochromatic light of wavelength l is 7. Diodes can be used for rectifying an ac voltage (restricting
l the ac voltage to one direction).
2mt = 8. Zener diode is one such special purpose diode. In reverse
2 bias, after a certain voltage, the current suddenly increases
3. A single slit of width a gives a diffraction pattern with a
(breakdown voltage) in a Zener diode. This property has
central maximum. The intensity falls to zero at angles of
been used to obtain voltage regulation.
l 2l 9. The transistors can be connected in such a manner that either
± ,± , etc. with successively weaker secondary maxima
a a C or E or B is common to both the input and output. This
in between. gives the three configurations in which a transistor is used:
MODERN PHYSICS Common Emitter (CE), Common Collector (CC) and Common
Base (CB). The plot between IC and VCE for fixed IB is called
1. Einstein’s photoelectric equation is output characteristics while the plot between IB and VBE
1 2 with fixed VCE is called input characteristics. The important
mvmax = V0 e = hn - f0 = h ( n - n0 ) transistor parameters for CE-configuration are:
2
2. The nuclear mass M is always less than the total mass, S m, æ DV ö
of its constituents. The difference in mass of a nucleus and input resistance, ri = ç BE ÷
its constituents is called the mass defect, è DI B ø V
CE
DM = (Z mp + (A – Z )mn) – M ; D Eb = DM c2.
æ DV ö
1 amu = 931 MeV output resistance, r0 = ç CE ÷
è DI C ø I
B
Z2
3. En = - ´ 13.6eV (For hydrogen like atom) æ DI C ö
n2 current amplification factor, b =
çè DI ÷ø
4. Bragg’s law : 2d sin q = nl. B V
CE
5. Law of radioactive decay : N = N0e–lt. The voltage gain of a transistor amplifier in common emitter
dN configuration is:
Activity = = -lN (unit is Becquerel)
N æv ö R
0.693 Av = ç 0 ÷ = b C , where RC and RB are respectively the
6. Half time period, T1/ 2 = èv ø
i R B
l resistances in collector and base sides of the circuit.
12400 10. The important digital circuits performing special logic
7. X-rays : l min = Å operations are called logic gates. These are: OR, AND, NOT,
V
NAND, and NOR gates.
Characteristics X-rays : l Ka < l La
COMMUNICATION SYSTEM
Moseley law : n = a (Z – b)2
1. Transmitter, transmission channel and receiver are three basic
SEMICONDUCTOR units of a communication system. In the process of
1. Pure semiconductors are called ‘intrinsic semiconductors’. transmission of message/ information signal, noise gets added
The presence of charge carriers (electrons and holes) is an to the signal anywhere between the information source and
‘intrinsic’ property of the material and these are obtained as the receiving end.
a result of thermal excitation. The number of electrons (ne ) 2. Two important forms of communication system are: Analog
is equal to the number of holes (nh) in intrinsic conductors. and Digital. The information to be transmitted is generally in
Holes are essentially electron vacancies with an effective continuous waveform for the former while for the latter it has
positive charge. only discrete or quantised levels.
2. The number of charge carriers can be changed by ‘doping’ 3. Low frequencies cannot be transmitted to long distances.
of a suitable impurity in pure semiconductors. Such Therefore, they are superimposed on a high frequency carrier
semiconductors are known as extrinsic semiconductors. signal by a process known as modulation.
These are of two types (n-type and p-type). 4. In modulation, some characteristic of the carrier signal like
3. In n-type semiconductors, ne >> n h while in p-type amplitude, frequency or phase varies in accordance with the
semiconductors nh >> ne. modulating or message signal. Correspondingly, they are called
4. n-type semiconducting Si or Ge is obtained by doping with Amplitude Modulated (AM), Frequency Modulated (FM) or
pentavalent atoms (donors) like As, Sb, P, etc., while p-type Phase Modulated (PM) waves. In the process of modulation,
Si or Ge can be obtained by doping with trivalent atom new frequencies called sidebands are generated on either side
(acceptors) like B, Al, In, etc. (higher and lower than the carrier frequency) of the carrier by
5. p-n junction is the ‘key’ to all semiconductor devices. When an amount equal to the highest modulating frequency.
such a junction is made, a ‘depletion layer’ is formed consisting 5. If an antenna radiates electromagnetic waves from a height
of immobile ion-cores devoid of their electrons or holes. This hT, then the range dT is given by 2 RhT where R is the
is responsible for a junction potential barrier. radius of the earth.
9
CHEMISTRY
PHYSICAL CHEMISTRY
ATOMIC STRUCTURE (c) Species Bond order Magnetic properties
H2 1 Diamagnetic
n 2h 2 æ n2 ö H2+ 0.5 Paramagnetic
1. rn = = 0.529 çç ÷÷ Å, rn = n2 × r1 Li2 1 Diamagnetic
4 p 2 mZe 2 è Z ø
1
PE Z2 5. Q= [ V + SA - (±q) ]
2. ET = – KE = = –13.6 2 eV , 2
2 n
æ 1 ö
hc 2p 2 me 4 æ 1 1 ö 6. Formal charge = V - ç L + S ÷
DE = = ç 2- 2÷ è 2 ø
3. l çn ÷
h2 è 1 n2 ø 7. VSEPR theory
é1 (a) (LP-LP) repulsion > (LP-BP) > (BP-BP)
1 1 ù
4. u= = RZ2 ê 2 - 2 ú , [R = 1.0968 × 107 m–1] (b) For NH3 ® Bond Angle 106º45' in case of water it
l ëê n1 n 2 ûú decreases to ® 104º27' because H2O molecule contains
n(n - 1) 2LP and 2BP whereas NH3 has 1LP and 3BP.
5. Total no. of spectrum lines = 8. Bond angle :
2
Decrease in bond angle down the gp is due to LP-BP repulsion
6. Heisenberg Uncertainty Principle (Dx) (Dp) ³ h/4p
(a) NH3 > PH3 > AsH3 (b) H2O > H2S > H2Se
13.7
7. Moseley’s law : n = a(Z – b), En = - eV / atom
CHEMICAL EQUILIBRIUM
n2
8. Nodes (n – 1) = total nodes, l = angular nodes, Δn g
(n – l – 1) = Radial nodes 1. K p = K c (RT) where Dng = nP – n R
1 2 2. Free Energy change (DG)
9. Photoelectric effect : hn = hn0 + mv (a) If DG = 0 then reversible reaction would be in
2
h equilibrium.
10. Orbital angular momentum : l (l + 1) (b) If DG = (+) ve then equilibrium will be displace in
2p
backward direction.
CHEMICAL BONDING (c) If DG = (–) ve then equilibrium will displace in forward
direction.
Actual dipole moment 3. (a) Kc unit ® (moles/lit)Dn,
1. % ionic character = ´ 100
Calculated dipole moment (b) Kp unit ® (atm)Dn
2. Fajan’s Factors : Following factors are helpful in inducing (c) Total moles at equilibrium = [total initial moles + Dn]
covalent character in Ionic compounds (d) Time required to establish equilibrium µ 1/Kc
(a) Small cation (b) Big anion (e) If in any heterogenous equilibrium solid substance is
(c) High charge on cation (d) High charge on anion also present then its active mass & partial pressure is
(e) Cation havin g pseudo inert gas configuration assumed 1.
(ns2p6d10) e.g. Cu+, Ag+, Zn+2, Cd+2 4. Le chatelier’s principle
(i) Increase of reactant conc. (Shift forward)
1
3. – DH f = HS + H d + IE + DH EG - E L (ii) Decrease of reactant conc. (Shift backward)
2 (iii) Increase of pressure (from more moles to less moles)
4. M.O. theory : (iv) Decrease of pressure (from less moles to more moles)
(a) Bond order = ½(Nb–Na) (v) For exothermic reaction decrease in temp. (Shift
(b) Higher the bond order, higher is the bond dissociation forward)
energy, greater is the stability, shorter is the bond length. (vi) For endothermic increase in temp. (Shift forward)
10
ACID BASE 3. Second Order Reaction :
When concentration of A and B taking same.
1. (a) Lewis Acid (e– pair acceptor) ® CO2, BF3, AlCl3, ZnCl2,
FeCl3, PCl3, PCl5, SiCl4, SF6, normal cation 1 æ x ö
(b) Lewis Base (e– pair donor) NH3, ROH, ROR, H2O, K2 = ç ÷
t è a(a - x) ø
RNH2, R2NH, R3N, normal anion When concentration of A and B are taking different -
2. Dissociation of Weak Acid & Weak Base ®
(a) Weak Acid ® Ka = Cx2/(1 – x) or Ka = Cx2 2.303 b(a - x)
K2 = log a(b - x)
(b) Weak Base ® Kb = Cx2/(1 – x) or Kb = Cx2 t(a - b)
3. Buffer solution : 4. Zero Order Reaction :
(a) Acidic ® pH = pKa + log {Salt/Acid} for Maximum
a - at
buffer action pH = pKa K= 0
Range of Buffer pH = pKa ± 1 t
(b) Alkaline ® pOH = pKb + log {Salt/Base} for max. a0
Buffer range for basic buffer = pKb ± 1 x = Kt & t1/2 =
2K
Moles / lit of Acid or Base Mixed The rate of reaction is independent of the concentration of
(c) Buffer Capacity = the reacting substance.
change in pH
5. Arrhenius equation :
dCBOH dCHB -E a
B= =- k = Ae–Ea/RT & slope =
dpH dpH 2.303R
4. Necessary condition for showing neutral colour of Indicator
pH = pKln or[HIn] = [In–] or [InOH] = [In+] (
- E / RT
When T ® ¥, then K = A Q e a =1 )
IONIC EQUILIBRIUM æ k2 ö Ea æ T2 - T1 ö
6. log ç k ÷ = 2.303R ç T T ÷
1. Relation between ionisation constant (Ki) & degree of è 1ø è 1 2 ø
ionisation(a):-
OXIDATION - REDUCTION
a2 a2 C
Ki = = (Ostwald’s dilution law) 1. Oxidant itself is reduced (gives O2)
(1 - a)V (1 - a)
It is applicable to weak electrolytes for which a <<1 then Or Oxidant ¾¾ ® e– (s) Acceptor
Reductant itself is oxidised (gives H2)
Ki Or reductant ¾¾ ® e– (s) Donor
a= Ki V = or V C ¯ a
C 2. (i) Strength of acid µ O.N
2. Common ion effect : By addition of X mole/L of a common (ii) Strength of base µ 1/ O.N
ion, to a weak acid (or weak base) a becomes equal to 3. (a) Electro Chemical Series:- Li, K, Ba, Sr, Ca, Na, Mg, Al,
Ka æ Kb ö Mn, Zn, Cr, Fe, Cd, Co, Ni, Sn, Pb, H2, Cu, I2, Hg, Ag,
X çè or X ÷ø [where a = degree of dissociation] Br2, Cl2, Pt, Au, F2.
3. (A) If solubility product = ionic product then the solution (b) As we move from top to bottom in this series
saturates. (1) Standard Reduction Potential
(B) If solubility product > ionic product then the solution is (2) Standard Oxidation Potential ¯
unsaturated and more of the substance can be dissolved (3) Reducing Capacity ¯
in it. (4) Ip
(C) If ionic product > solubility product the solution is (5) Reactivity ¯
super saturated (principle of precipitation). 4. (a) Formal charge = Group No. – [No. of bonds
4. Salt of weak acid and strong base : + No. of non-bonded e—s]
pH = 0.5 (pKw + pKa + log c) (b) At Anode ® Oxidation, Cathode ® Reduction
Salt of weak base and strong acid :
pH = 0.5 (pKw – pKb – log c) VOLUMETRIC ANALYSIS
Salt of weak acid and weak base :
pH = 0.5 (pKw + pKa – pKb ) Atomic wt of the element
1. Equivalent weight of element =
CHEMICAL KINETICS n factor
1. Unit of Rate constant : 2. Equivalent weight of compound
K = mol1–Dn litDn–1 sec–1 Formula wt of the compound
2. First Order reaction : =
n factor
2.303 a 0.693
K= log10 (a - x) & t½ = formula wt (or At. Wt.)of ion
t K 3. Equivalent wt. of an ion =
[A]t = [A]0e–kt its valency
11
dN 2.303 N0 a 3a 2a
– = l.N & l = log10 or N = N0e–lt Simple cubic = r = bcc r = fcc =
dt t N 2 4 4
4. Relationship between radius of void (r) and the radius of the
Total life time of all the atoms
5. Average life (tAV) = sphere (R) : r (tetrahedral) = 0.225 R ; r (octahedral) = 0.414 R
Total number of atoms 5. Paramagnetic : Presence of unpaired electrons [attracted by
¥ magnetic field]
=
ò0 tdN
=
1
= 1.44 t1/2
6. Ferromagnetic : Permanent magnetism [ ]
N0 l 7. Antiferromagnetic : net magnetic moment is zero [ ¯ ¯]
8. Ferrimagnetic : net magnetic moment is three [ ¯ ¯ ]
GASEOUS STATE
1. Ideal gas equation : PV = nRT SURFACE CHEMISTRY & COLLOIDAL STATE
(i) R = 0.0821 litre atm. K–1 mole–1 1. Higher is the valency of active ion, the greater is its
(ii) R = 62.4 litres mm Hg K–1. mole–1 coagulating power.
(iii) R = 8.314 × 107 ergs K–1 mole–1 2. Emulsion : Colloidal soln. of two immiscible liquids [O/W
(iv) R = 2 cals K–1 mole–1 emulsion, W/O emulsion]
(v) R = 8.314 JK–1 mole–1
3. Emulsifier : Long chain hydrocarbons are added to stabilize
2. Velocities related to gaseous state
emulsion.
3PV 3RT 3P 4. Lyophilic colloid : Starchy gum, gelatin have greater affinity
RMS velocity C = = = for solvent. Solution Can be easily prepared by bringing in
M M d
contact with solvent and warming.
8RT 2RT 5. Lyophobic colloid : No affinity for solvent, special methods
Average speed = & Most probable speed =
pM M are used to prepare sol. [e.g. As2S3, Fe(OH)3 sol]
Average speed = 0.9213 × RMS speed 6. Preparation of colloidal solution :
RMS speed = 1.085 × Average speed (i) Dispersion methods (ii) Condensation method.
MPS = .816 × RMS; RMS = 1.224 MPS 7. Properties of colloidal solution :
MPS : A.V. speed : RMS = 1 : 1.128 : 1.224 (i) Tyndall effect (ii) Brownian movement (iii) Coagulation
1 (iv) Filtrability.
3. Rate of diffusion µ
density of gas
13
INORGANIC CHEMISTRY
PERIODIC TABLE BORON FAMILY
1. General electronic configuration (of outer orbits) 1. Stability of +3 oxidation state : B > Al > Ga > In > Tl
s-block ns1–2 p-block ns 2 np 1–6 2. Stability of +1 oxidation state : Ga < In < Tl
d-block (n–1)d1–10 ns1–2 3. Reducing nature : Al > Ga > In > Tl
f-block (n–2) s2p6d10f1–14(n–1)s2p6d0 or 1 ns2 4. Basic nature of the oxides and hydroxides :
2. Properties Pr (L To R) Gr (T to B) B < Al < Ga < In < Tl
(a) atomic radius ¯ 5. Relative strength of Lewis acid : BF3 < BCl3 < BBr3 < BI3
(b) ionisation potential ¯
(c) electron affinity ¯ CARBON FAMILY
(d) electro negativity ¯ 1. Reactivity : C < Si < Ge < Sn < Pb
(e) metallic character or ¯ 2. Metallic character : C < Si < Ge < Sn < Pb
electropositive character 3. Acidic character of the oxides :
(f) alkaline character ¯
CO2 > SiO2 > GeO2 > SnO2 > PbO2
of hydroxides
Weaker acidic (amphoteric)
(g) acidic character ¯
(h) density (i)firstly increases 4. Thermal stability and volatility of hydrides :
(ii)in between max CH4 > SiH4 > GeH4 > SnH4 > PbH4
(iii)then decreases 5. Reducing nature of hydrides
(i) reducing property ¯ CH4 < SiH4 < GeH4 < SnH4 < PbH4
(j) oxidising property ¯ 6. Thermal stability of tetrahalides
(k) non metallic character ¯ CCl4 > SiCl4 > GeCl4 > SnCl4 > PbCl4
1 1 7. Thermal stability and volatility of tetrahalide with a common
3. IP µ µ central atom
Metallic character Reducing character MF4 > MCl4 > MBr4 > MI4
1 1 8. Oxidising character of M+4 species
µ µ Basic nature of Hydroxide GeCl4 < SnCl4 < PbCl4
Basic Nature of oxide
9. Ease of hydrolysis of tetrahalides
1 SiCl4 > GeCl4 > SnCl4 > PbCl4
4. EA µ µ nuclear charge.
size 10. Reducing character of dihalides
Second electron affinity is always positive. GeCl2 > SnCl2 > PbCl2
Electron affinity of chlorine is greater than fluorine.
5. The first element of a group has similar properties with the NITROGEN FAMILY
second element of the next group. This is called diagonal
relationship. 1. Acidic strength of trioxides : N2O3 > P2O3 > As2O3
2. Acidic strength of pentoxides
EXTRACTIVE METALLURGY N2O5 > P2O5 > As2O5 > Sb2O5 > Bi2O5
1. Floatation is a physical method of separating a mineral from 3. Acidic strength of oxides of nitrogen
the gangue depending on differences in their wettabilities N2O < NO < N2O3 < N2O4 < N2O5
by a liquid solution. 4. The stability of pentoxides
2. Roasting is the process of heating a mineral in the presence P2O5 < As2O5 > Sb2O5 > N2O5 > Bi2O5
of air. 5. Basic nature, bond angle, thermal stability and dipole
3. Calcination is the process of heating the ore in the absence moment of hydrides
of air. NH3 > PH3 > AsH3 > SbH3 > BiH3
4. Electrolytic reduction : Highly electropositive metals are 6. Reducing power, covalent nature of
extracted by the electrolysis of their oxides and hydroxides. hydrides : NH3 < PH3 < AsH3 < SbH3 < BiH3
s-BLOCK ELEMENTS 7. Stability of trihalides of nitrogen : NF3 > NCl3 > NBr 3
8. Ease of hydrolysis of trichlorides
1. Atomic radii : Li < Na < K < Rb < Cs NCl3 > PCl3 > AsCl3 > SbCl3 > BiCl3
2. Ionic radii : Li+ < Na+ < K+ < Rb+ < Cs+ 9. Lewis acid strength of trihalides of P, As and Sb
3. Electronegativity : Li > Na > K > Rb > Cs PCl3 > AsCl3 > SbCl3
4. First ionization potential : Li > Na > K > Rb > Cs 10. Lewis acid strength among phosphorus trihalides
5. Melting point Li > Na > K > Rb > Cs PF3 > PCl3 > PBr3 > PI3
6. Density : Li > Na < K > Rb > Cs 11. Bond angle, among the halides of phosphorus
7. Colour of the flame Li - Red, Na - Golden, K - Violet, Rb- Red, PF3 < PCl3 < PBr3 < PI3
Cs - Blue, Ca - Brick red, Sr - Blood red, Ba-Apple green
8. Rb and Cs show photoelectric effect. OXYGEN FAMILY
9. Stability of hydrides : LiH > NaH > KH > RbH > CsH
10. Basic nature of hydroxides : [LiOH < NaOH < KOH < RbOH 1. Melting and boiling point of hydrides
< CsOH] H2O > H2Te > H2Se > H2S
14
2. Volatility of hydrides 14. Oxidising power of oxides of chlorine
H2O < H2Te < H2Se < H2S Cl2O > ClO2 > Cl2O6 > Cl2O7
3. Thermal stability of hydrides 15. Acidic character of oxyacids of chlorine
H2O > H2S > H2Se > H2Te HClO < HClO2 < HClO3 < HClO4
4. Reducing nature of hydrides 16. Strength of conjugate bases of oxyacids of chlorine
H2S < H2Se < H2Te ClO– > ClO2– > ClO3– > ClO4–
5. Covalent character of hydrides 17. Oxidising power of oxyacids of chlorine
H2O < H2S < H2Se < H2Te HClO > HClO2 > HClO3 > HClO4
6. Bond angle & Dipole moment of hydrides 18. Thermal stability of oxyacids of chlorine
H2O > H2S > H2Se > H2Te HClO < HClO2 < HClO3 < HClO4
(104°) (92°) (91°) (90°) 19. Stability of anions of oxyacids of chlorine
7. Ease of hydrolysis of hexahalides : SF6 > SeF6 > TeF6 ClO– < ClO2– < ClO3– < ClO4–
8. The acidic character of oxides (elements in the same oxidation
state) TRANSITION ELEMENTS (D-BLOCK ELEMENTS
SO2 > SeO2 > TeO2 > PoO2 1. The element with exceptional configuration are
SO3 > SeO3 > TeO3 Cr24[Ar] 3d54s1, Cu29[Ar] 3d104s1
9. Acidic character of oxide of a particular element (e.g. S) Mo42[Kr] 4d55s1, Pd46[Kr] 4d105s0
SO2 < SO3 Ag47[Kr] 4d105s1, Pt78[Xe] 4f145d106s0
10. Stability of dioxides Au79[Xe] 4f145d10 6s1
SO2 > TeO2 > SeO2 > PoO2 2. Ferromagnetic substances are those in which there are large
HALOGEN FAMILY number of electrons with unpaired spins and whose magnetic
moments are aligned in the same direction.
1. Bond energy of halogens : Cl2 > Br 2 > F2 > I2
COORDINATION COMPOUNDS
2. Bond length in X2 molecule : F2 < Cl2 < Br2 < I2
3. Solubility of halogen in water : F2 > Cl2 > Br2 > I2 1. Coordination number is the number of the nearest atoms or
4. Oxidising power : F2 > Cl2 > Br2 > I2 groups in the coordination sphere.
5. Enthalpy of hydration of X– ion : F– > Cl– > Br– > I– 2. Ligand is a Lewis base donor of electrons that bonds to a
6. Reactivity of halogens : F > Cl > Br > I central metal atom in a coordination compound.
7. Ionic character of M - X bond in halides 3. Paramagnetic substance is one that is attracted to the
M – F > M – Cl > M – Br > M – I magnetic field, this results on account of unpaired electrons
8. Reducing character of X– ion : I– > Br– > Cl– > F– present in the atom/molecule/ion.
9. Thermal stability of hydrides : HF > HCl > HBr > HI 4. Effective atomic number EAN
10. Acidic strength of halogen acids : HI > HBr > HCl > HF = (Z – Oxidation number) + (2 × Coordination number)
11. Conjugate base strength of halogen acids 5. Factors affecting stability of complex
I– < Br– < Cl– < F– (i) Greater the charge on the central metal ion, greater is the
12. Reducing power of hydrogen halides stability.
HF < HCl < HBr < HI (ii) Greater the ability of the ligand to donate electron pair
13. Dipole moment of hydrogen halides (basic strength) greater is the stability.
HF> HCI > HBr> HI (iii) Formation of chelate rings increases the stability.
ORGANIC CHEMISTRY
GOC Electrophiles : electron deficient.
Two types : 1. Cations 2. Neutral molecules with vacant
1. The order of decreasing electronegativity of hybrid orbitals
orbitals (Lewis acids).
is sp > sp2 > sp3.
2. Conformational isomers are those isomers which arise due 8. Inductive effect is due to s electron displacement along a
to rotation around a single bond. chain and is permanent effect.
3. A meso compound is optically inactive, even though it has 9. +I (inductive effect) increases basicity, – I effect increases
asymmetric centres (due to internal compensation of rotation acidity of compounds.
of plane polarised light) 10. Resonance is a phenomenon in which two or more structures
4. An equimolar mixture of enantiomers is called racemic can be written for the same compound but none of them
mixture, which is optically inactive. actually exists.
5. Tautomerism is the type of isomerism arising by the migration ALKANES
of hydrogen. 1. Pyrolytic cracking is a process in which alkane decomposes
6. Reaction intermediates and reagents : to a mixture of smaller hydrocarbons, when it is heated
Homolytic fission ® Free radicals strongly, in the absence of oxygen.
Heterolytic fission ® Carbocation and carbanion
2. Combustion is a process in which hydrocarbons form carbon
7. Nucleophiles – electron rich
dioxide and H2O(l) when they are completely burnt in
Two types : 1. Anions 2. Neutral molecules
air/O2.
with lone pair of electrons (Lewis bases)
15