DMK5013

BASICS OF QUALITY MANAGEMENT

IN OIL AND FAT INDUSTRY
J A B ATA N T E K N O L O G I K I M I A D A N M A K A N A N
POLITEKNIK TUN SYED NASIR SYED ISMAIL
 TOPIC 3:
SAFETY DATA
SHEET
 DEFINITION

An up-to-date hand-out or information sheet

containing relevant information pertaining to the
hazardous chemical or preparation which is
vital for establishing arrangements in safe use
of the chemical or preparation at work.

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 OBJECTIVE
 To make users understand safety recommendations
and the rationale for these recommendations.
 To create awareness among users of the consequences
of failure to comply with the recommendations.
 To ensure that users recognise the symptoms of
overexposure.
 To encourage the users of hazardous chemicals to provide
inputs in establishing strategies and recommendations
for the safe use of the hazardous chemicals.

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 WHO IS RESPONSIBLE FOR PROVIDING CSDS?

The supplier as stipulated under Regulation 9(1) of the

Occupational Safety and Health (Classification,
Packaging and Labelling of Hazardous Chemicals)
Regulations 1997.
 Primarily the Manufacturer (or importer, or wholesale
distributor).
 Retail Distributors are only required to provide CSDS to
commercial customers who make requests.

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 WHAT MUST BE PROVIDED ON AN MSDS?

1) The chemical product itself including

 trade or common name of the chemical
 company identification with details of the supplier
2) The composition of the ingredients
3) Hazard identification
4) First-aid measures
5) Fire-fighting measures

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 WHAT MUST BE PROVIDED ON AN MSDS?

6) Accidental release measures

7) Handling and storage
8) Exposure controls and personal protection
9) Physical and chemical properties
10)Stability and reactivity
11)Toxicological information

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 WHAT MUST BE PROVIDED ON AN MSDS?

12)Ecological information
13)Disposal information
14)Transport information
15)Date of preparation of the Chemical Safety Data Sheet

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 GLOBALLY HARMONIZED SYSTEM (GHS)
CHANGE FROM
MATERIAL SAFETY DATA SHEET (MSDS)
TO
SAFETY DATA SHEET (SDS)

https://www.sigmaaldrich.com/safety-center/globally-harmonized.html

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 History of GHS
 Major Changes Under GHS
 What Do You Need to Do
 Step by Step Compliance

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 HISTORY OF GHS

• An international mandate to harmonize labels was adopted at the

United Nations Conference on the Environment and Development
(UNCED) in 1992 in Brazil:
• A globally-harmonized hazard classification and compatible labeling system,
including material safety data sheets and easily understandable symbols,
should be available, if feasible, by the year 2000.

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 HISTORY OF GHS

IN MARCH 2012, OCCUPATIONAL SAFETY AND HEALTH

ADMINISTRATION (OSHA) PUBLISHED A FINAL RULE TO
ALIGN ITS HAZARDOUS COMMUNICATION STANDARDS
(HCS) REGULATIONS WITH THE GLOBALLY HARMONIZED
SYSTEM (GHS) OF CLASSIFICATION AND LABELING OF
CHEMICALS

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 HISTORY OF GHS

THE PRIMARY GOAL OF GHS IS IMPROVED PROTECTION OF

HUMAN HEALTH AND THE ENVIRONMENT BY PROVIDING
CHEMICAL USERS AND HANDLERS WITH ENHANCED AND
CONSISTENT INFORMATION ON CHEMICAL HAZARDS.

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 HISTORY OF GHS

THE GHS IS BASED ON MAJOR EXISTING SYSTEMS FOR

INDUSTRIAL CHEMICALS, PESTICIDES, CONSUMER
CHEMICALS, AND CHEMICALS IN TRANSPORT, BUT
IMPLEMENTATION OF THE GHS WOULD REQUIRE SOME
CHANGES IN ALL EXISTING SYSTEMS IN ORDER TO ACHIEVE
HARMONIZATION.

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 HISTORY OF GHS

HOWEVER, IT IS IMPORTANT FOR GROWERS WHO USE

FEDERALLY REGULATED PESTICIDES TO NOTE THAT THE
ENVIRONMENT PROTECTION AGENCY (EPA) HAS NOT YET
MOVED TO AMEND ITS PESTICIDE LABELING REGULATIONS
UNDER THE FEDERAL INSECTICIDE, FUNGICIDE, AND
RODENTICIDE ACT (FIFRA) TO ALIGN WITH THE GHS.

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Why the switch from MSDS to SDS?

UNDER THE HAZCOM 2012, THE MSDS

WILL BE REPLACED WITH A SAFETY DATA
SHEET (SDS).

*Hazard Communication Standard

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 Why the switch from MSDS to SDS?

Before the HazCom 2012, there were several

acceptable MSDS formats. OSHA’s adoption of
Global Harmonization Standards (GHS) requires
the use of a single format.
All SDS will have 16 sections that appear in a
specific order.

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MAJOR CHANGES UNDER GHS

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 CHANGES

• MSDS to SDS Format

• Labeling Requirements/Pictograms
• Hazard Classification

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 CHANGES

• MSDS to SDS Format

 MSDS will now be referred to as Safety Data Sheets (SDS).
 There is now a specified 16-section format that must
be followed.

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 SECTION 1
IDENTIFICATION OF SUBSTANCE AND SUPPLIER

• Includes:
 Product identifier (Product Name).
 Manufacturer’s or distributor’s name, address and
phone number.
 Emergency phone number.
 Recommended use.
 Restrictions on use.

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 SECTION 2
HAZARD IDENTIFICATION

• Includes:
 All hazards regarding the chemical.
 Required label elements:
• Pictograms.
• Signal Word.
• Hazard Statements.

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 SECTION 2
HAZARD IDENTIFICATION

Signal Words (OSHA):

Warning.
Danger.

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 SECTION 3
COMPOSITION/INFORMATION ON INGREDIENTS

• Includes:
 Composition/information on ingredients:
• Common Name.
• CAS number
• a unique numerical identifier assigned by the Chemical
Abstracts Service (CAS) to every chemical substance
described in the open scientific literature, including organic
and inorganic compounds, minerals, isotopes, alloys and
non-structurable materials. https://www.cas.org/
• Concentration.
 Information on chemical ingredients.
 Trade secret claims.

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 SECTION 4
FIRST AID MEASURES

• Includes:
 Important symptoms.
 Acute symptoms.
 Delayed symptoms.
 Required treatment based on route of
exposure.

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 SECTION 5
FIREFIGHTING MEASURES

• Includes:
 Suitable extinguishing techniques.
 Equipment needed.
 Chemical hazards from fire.

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 SECTION 5
FIREFIGHTING MEASURES

CLASS OF FIRES https://aito.com.my/fire-extinguisher-types-malaysia/

•Class A – Fires of solid or organic
materials, such as wood, plastics, paper,
textiles, or coal.
•Class B – Fires of flammable liquids, such
as gasoline, petroleum oil, paint, or diesel.
•Class C – Fires of flammable gases, such
as propane, butane, or methane.
•Class D – Fires of combustible metals,
such as magnesium, lithium, sodium,
potassium, titanium, or aluminium.
•Class F/ Class K – Fires of cooking oils
and fats, such as vegetable oil, sunflower
oil, olive oil, maize oil, lard, or butter.
•Class E – Electrical fires of live equipment
and electrical sources.

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 SECTION 6
ACCIDENTAL RELEASE MEASURES

• Includes:
 Emergency procedures.
 Protective equipment.
 Proper methods of containment and cleanup.

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 SECTION 7
HANDLING AND STORAGE

• Includes:
 Precautions for safe handling.
 Precautions for safe storage.
 Incompatibilities.

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 SECTION 8
PRECAUTIONS TO CONTROL EXPOSURE/PERSONAL PROTECTION

• Includes:
 OSHA’s Permissible Exposure Limits (PELs).
 Threshold Limit Values (TLVs).
 Appropriate engineering controls.
 Personal Protective Equipment (PPE)
requirements.

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 SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES

• Includes:
 Chemical’s characteristics.

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 SECTION 10
STABILITY AND REACTIVITY

• Includes:
 Stability of chemical.
 Chemical characteristics.
 Chemical stability when used in
the technical sense in chemistry,
means thermodynamic stability
of a chemical system.
 Thermodynamic stability occurs
when a system is in its lowest
energy state, or chemical
equilibrium with its environment.

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 SECTION 11
TOXICOLOGICAL INFORMATION
LC50 is the LD50 is an
• Includes: concentration of
the chemical in
abbreviation for
"Lethal Dose,
 Routes of exposure. the air or water 50%" or median
that will kill 50% lethal dose.
 Related symptoms. of the test animals
 Acute effects. with a single
exposure.
 Chronic effects.
 Numerical measures of toxicity.
 LD50 values and LC50 values.

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 SECTION 12
ECOLOGICAL INFORMATION

• Includes:
 Eco-toxicity.
 Mobility.
 Does it move in air, soil, or water.
 Degradability.
 Is it biodegradable.
 Bioaccumulation.
 Bioaccumulation is the gradual accumulation of substances, such as
pesticides or other chemicals, in an organism.
 Bioaccumulation occurs when an organism absorbs a substance at a
rate faster than that at which the substance is lost or eliminated by
catabolism and excretion.

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 SECTION 13
WASTE DISPOSAL CONSIDERATION

• Includes:
 Advise to contact local wasted disposal
authority for direction on disposal.
 Information that directs washing
liquids should not be allowed to enter
drains.
 Directions for container disposal.
 Recommendations for disposal if
recycling is not an option.

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 SECTION 14
TRANSPORTATION INFORMATION

• Includes:
 Proper shipping name.
 Hazard class.
 Secondary risk.
 Identification information.
 Packing group.
 Label required.
 Marine pollutant identification.

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 SECTION 15
REGULATORY INFORMATION

For pesticides this is the area where any FIFRA

information would be included, for example:
The Federal Insecticide,
“Pesticide Registration: Fungicide, and
Rodenticide Act
This chemical is a pesticide product registered by the (FIFRA) is a United
Environmental Protection Agency and is subject to States federal law that
certain labeling requirements under federal pesticide set up the basic U.S.
law. These requirements differ from the classification
system of pesticide
criteria and hazard
regulation to protect
information required for safety data sheets, and for applicators, consumers,
workplace labels of non-pesticide chemicals. Following and the environment.
is the hazard
information as required on the pesticide label:”

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 SECTION 16
OTHER INFORMATION

• Includes:
 Department issuing SDS.
 Email address.
 Training necessary.
 Reissue date/reason for reissue.
 General intended use of the product.

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PICTOGRAMS

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 PICTOGRAMS

• Health Hazard
 Carcinogen
 Respiratory sensitizer
 Reproductive toxicity
 Target Organ toxicity
 Mutagenicity
 Aspiration toxicity.

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 PICTOGRAM

• Flame
 Flammables
 Self-Reactives
 Pyrophorics (material can spontaneously ignite
in air)

 Self-Heating
 Emits flammable gas
 Organic peroxides (ROOR′)

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 PICTOGRAMS

• Exclamation Mark
 Skin and eye irritant
 Skin sensitizer
 Acute toxicity
 Narcotic effects
 Respiratory tract irritant

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 PICTOGRAMS

• Gas Cylinder
 Gas Under Pressure

• Flames Over Circle

 Oxidizer

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 PICTOGRAMS

• Corrosion
 Corrosives
 Damaging
 Destroys materials

• Skull and Crossbones

 Acute Toxicity (Severe)

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 PICTOGRAMS

• Exploding Bomb
 Explosives
 Self-Reactive
 Organic peroxides

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 PICTOGRAMS

• Environment
 Aquatic Toxicity

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