CÁLCULOS:

a) Datos iniciales: - VT= 10ml (fenol y agua)

- ρ FENOL= 1.07 g/cm3 y ρ H20= 0.997 g/cm3

m fenol 1 a m fenol ρ fenol∗V fenol 1 a

 Para fenol al 25%: = = =
mt 4 a m H 2O ρ H 2 O∗V H 2O 3 a
V fenol 1∗( 0.997 ) k
=
V H 2 O 3∗(1.07)k
Vfenol +VH2O = VT = 10ml
0.997k + 3.210k =10ml
4.207k = 10
K = 2.377

Vfenol = 2.370 ml mfenol = 2.536 g

VH2O = 7.630 ml mH2O = 7.607 g

m fenol 7 a m fenol ρ fenol∗V fenol 7a

 Para fenol al 35%: = = =
mt 20 a m H 2O ρ H 2O∗V H 2O 13 a
V fenol 7∗( 0.997 ) k
=
V H 2 O 13∗(1.07)k
Vfenol +VH2O = VT = 10ml
6.979k + 13.91k=10ml
20.889k = 10
K = 0.479

Vfenol = 3.340ml mfenol = 3.574 g

VH2O = 6.660 ml mH2O = 6.640 g

m fenol 9 a m fenol ρ fenol∗V fenol 9a

 Para fenol al 45%: = = =
mt 20 a m H 2O ρ H 2O∗V H 2O 11 a
V fenol 9∗( 0.997 ) k
=
V H 2 O 11∗(1.07)k
Vfenol +VH2O = VT = 10ml
8.973k + 11.77k =10ml
20.743k = 10
K = 0.482

Vfenol = 4.330 ml mfenol = 4.633 g

VH2O = 5.670 ml mH2O = 5.653 g
 m fenol 11a m fenol ρ fenol∗V fenol 11 a
 Para fenol al 55%: = = =
mt 20 a m H 2O ρ H 2O∗V H 2O 9 a
V fenol 11∗( 0.997 ) k
=
V H 2 O 9∗(1.07) k
Vfenol +VH2O = VT = 10ml
10.967k + 9.630k =10ml
20.597k = 10
K = 0.486

Vfenol = 5.330 ml mfenol = 5.703 g

VH2O = 4.670 ml mH2O = 4.656 g

m fenol 13 a m fenol ρ fenol∗V fenol 13 a

 Para fenol al 65%: = = =
mt 20 a m H 2O ρ H 2O∗V H 2O 7 a
V fenol 13∗( 0.997 ) k
=
V H 2 O 7∗(1.07)k
Vfenol +VH2O = VT = 10ml
12.961k + 7.490k =10ml
20.451k = 10
K = 0.489

Vfenol = 6.338 ml mfenol = 6.782 g

VH2O = 3.662 ml mH2O = 3.651 g

m fenol 3 a m fenol ρ fenol∗V fenol 3 a

 Para fenol al 75%: = = =
mt 4 a m H 2O ρ H 2 O∗V H 2O 1 a
V fenol 3∗( 0.997 ) k
=
V H 2 O 1∗(1.07)k
Vfenol +VH2O = VT = 10ml
2.991k + 1.07k =10ml
4.061k = 10
K = 2.462

Vfenol = 7.360 ml mfenol = 7.875 g

VH2O = 2.640ml mH2O = 2.632 g

m fenol 17 a m fenol ρ fenol∗V fenol 17 a

 Para fenol al 85%: = = =
mt 20 a m H 2 O ρ H 2O∗V H 2 O 3 a
V fenol 17∗( 0.997 ) k
=
V H 2 O 3∗(1.07)k
Vfenol +VH2O = VT = 10ml
16.959k + 3.21k =10ml
20.169k = 10
K = 0.496

Vfenol = 8.410 ml mfenol = 8.999 g

VH2O = 1.590 ml mH2O = 1.585 g
d) Hallar las fracciones molares de cada uno de las concentraciones:

Datos: Masa molarfenol = 94.11 g/mol y Masa molarH2O = 18.0 g/mol

 Para fenol al 25%: mfenol = 2.536 g nfenol = m/M= 0.027 mol

mH2O = 7.607 g nH2O = m/M= 0.423 mol ntotal = 0.450 mol

Xfenol = nfenol / ntotal = 0.06

XH2O = nH2O / ntotal = 0.94

 Para fenol al 35%: mfenol = 3.574 g nfenol = m/M= 0.038 mol

mH2O = 6.640 g nH2O = m/M= 0.369 mol ntotal = 0.407 mol

Xfenol = nfenol / ntotal = 0.093

XH2O = nH2O / ntotal = 0.907

 Para fenol al 45%: mfenol = 4.633 g nfenol = m/M= 0.049 mol

mH2O = 5.653 g nH2O = m/M= 0.314 mol ntotal = 0.363 mol

Xfenol = nfenol / ntotal = 0.135

XH2O = nH2O / ntotal = 0.865

 Para fenol al 55%: mfenol = 5.703 g nfenol = m/M= 0.061 mol

mH2O = 4.656 g nH2O = m/M= 0.259 mol ntotal = 0.320 mol

Xfenol = nfenol / ntotal = 0.191

XH2O = nH2O / ntotal = 0.809

 Para fenol al 65%: mfenol = 6.782 g nfenol = m/M= 0.072 mol

mH2O = 3.651 g nH2O = m/M= 0.203 mol ntotal = 0.275 mol

Xfenol = nfenol / ntotal = 0.262

XH2O = nH2O / ntotal = 0.738

 Para fenol al 75%: mfenol = 7.875 g nfenol = m/M= 0.084 mol

mH2O = 2.632 g nH2O = m/M= 0.146 mol ntotal = 0.230 mol

Xfenol = nfenol / ntotal = 0.365

XH2O = nH2O / ntotal = 0.635
  Para fenol al 85%: mfenol = 8.999 g nfenol = m/M= 0.096 mol
mH2O = 1.585 g nH2O = m/M= 0.088 mol ntotal = 0.184 mol

Xfenol = nfenol / ntotal = 0.522

XH2O = nH2O / ntotal = 0.478

e) Tabular los valores de fracción mol y concentración:

% en masa Fracción molar (x)

C1 25 0.060
C2 35 0.093
C3 45 0.135
C4 55 0.191
C5 65 0.262
C6 75 0.365
C7 85 0.522