Tugas Kelompok ke-2

(Minggu 5 / Sesi 5)

1. CH4 + O2 → CO2 + H2O

a. How many molecules of carbon dioxide are formed when 400 g of oxygen are
consumed?
b. How many g mass of methane are needed for 90 g of water to be formed?
c. How many liters (STP) of oxygen gas combine with 3.2 kg of methane?

CH4 + 2 O2 → CO2 + 2 H2O

𝑚𝑎𝑠𝑠 400 𝑔𝑟
a. n O2 = = = 12,501 mol
𝑀𝑟 (2 𝑥 15,999) 𝑔𝑟/𝑚𝑜𝑙
𝑐𝑜𝑒𝑓 CO2 1
n CO2 = x mol O2 = 2 x 12,501 mol = 6,250 mol
𝑐𝑜𝑒𝑓 O2

molecule CO2 = 6,250 mol x 6,022 x 1023 molecule/mol

= 3,764 x 1024 molecule

𝑚𝑎𝑠𝑠 90 𝑔𝑟
b. n H2O = = ((2 𝑥 1,008) + 15,999)𝑔𝑟/𝑚𝑜𝑙
= 4,996 mol
𝑀𝑟

𝑐𝑜𝑒𝑓 CH2 1
n CH4 = x mol H2O = 2 x 4,996 mol = 2,498 mol
𝑐𝑜𝑒𝑓 H2O

m CH4 = n CH4 x Mr
= 2,498 mol x (12,011 + (4 x 1,008)) gr/mol
= 40,075 gr

𝑚𝑎𝑠𝑠 3200 𝑔𝑟
c. n CH4 = = (12,011 +(4 𝑥 1,008))𝑔𝑟/𝑚𝑜𝑙
= 199,464 mol
𝑀𝑟
𝑐𝑜𝑒𝑓 O2 2
n O2 = x mol CH4 = 1 x 199,464 mol = 398,928 mol
𝑐𝑜𝑒𝑓 CH4

V O2 = mol O2 x 22,4 L/mol = 398,928 mol x 22,4 L/mol

= 8935,987 L

SCIE6007- Industrial Chemistry

2. The fermentation of sucrose produces carbon dioxide and ethanol according to the
following equation:
C12H22O11 (s) + H2O (l) -----------> CO2 (g) + C2H5OH (l)
a. How many g of sucrose needs to produce 88 g of carbon dioxide?
b. How many molecules of sucrose are needed to produce 250 g of ethanol?
c. What volume of carbon dioxide at STP will be produced from 5.00 kg of
sucrose?
d. How may molecules of carbon dioxide are produced when 1.00 g of sucrose
ferments?

C12H22O11 + H2O → 4 CO2 + 4 C2H5OH

𝑚𝑎𝑠𝑠 88 𝑔𝑟
a. n CO2 = = = 1,999 mol
𝑀𝑟 (12,011+(2 𝑥 15,999)) 𝑔𝑟/𝑚𝑜𝑙
𝑐𝑜𝑒𝑓 C12H22O11 1
n C12H22O11 = x mol CO2 = 4 x 1,999 mol = 0,4998 mol
𝑐𝑜𝑒𝑓 𝐶𝑂2

m C12H22O11 = n C12H22O11 x Mr
= 0,4998 mol x ((12,011 x 12) + (1,008 x 22) + (15,999 X 11)) gr/mol
= 171,080 gr

𝑚𝑎𝑠𝑠 250 𝑔𝑟
b. n C2H5OH = = = 5,427 mol
𝑀𝑟 46,069 𝑔𝑟/𝑚𝑜𝑙
𝑐𝑜𝑒𝑓 C12H22O11 1
n C12H22O11 = x mol C2H5OH = 4 x 5,427 mol = 1,357 mol
𝑐𝑜𝑒𝑓 C2H5OH

molecule C12H22O11 = 1,357 mol x 6,022 x 1023 molecule/mol

= 8,172 x 1023 molecule

𝑚𝑎𝑠𝑠 5000 𝑔𝑟
c. n C12H22O11 = = = 14,607 mol
𝑀𝑟 342,297 𝑔𝑟/𝑚𝑜𝑙
𝑐𝑜𝑒𝑓 CO2 4
n CO2 = 𝑐𝑜𝑒𝑓 C12H22O11 x mol C12H22O11 = 1 x 14,607 mol = 58,428 mol

V CO2 = n CO2 x 22,4 L/mol = 58,428 mol x 22,4 L/mol

= 1308,787 L

SCIE6007- Industrial Chemistry

 𝑚𝑎𝑠𝑠 1 𝑔𝑟
d. n C12H22O11 = = = 2,921 x 10-3 mol
𝑀𝑟 342,297 𝑔𝑟/𝑚𝑜𝑙
𝑐𝑜𝑒𝑓 CO2
n CO2 = 𝑐𝑜𝑒𝑓 C12H22O11 x mol C12H22O11
4
= 1 x 2,921 x 10-3 mol

= 1,168 x 10-2 mol

molecule CO2 = (1,168 x 10-2 mol) x (6,022 x 1023 molecule/mol)
= 7,034 x 1021 molecule

3. 150 g propane combusted as following reaction :

C3H8 + O2 ----------→ CO2 + H2O
a. How many liters (STP) of oxygen are necessary to react completely
b. How many molecules of carbon dioxide will produce?
c. How many g waters will produce?

C3H8 + 5 O2 → 3 CO2 + 4 H2O

𝑚𝑎𝑠𝑠 150 𝑔𝑟
n C3H8 = = = 3,402 mol
𝑀𝑟 44,097 𝑔𝑟/𝑚𝑜𝑙

𝑐𝑜𝑒𝑓 O2 5
a. n O2 = 𝑐𝑜𝑒𝑓 C3H8 x mol C3H8 = 1 x 3,402 mol = 17,010 mol

V O2 = n O2 x 22,4 L/mol = 17,010 mol x 22,4 L/mol

= 381,024 L

𝑐𝑜𝑒𝑓 CO2 3
b. n CO2 = 𝑐𝑜𝑒𝑓 C3H8 x mol C3H8 = 1 x 3,402 mol = 10,206 mol

molecule CO2 = 10,206 mol x 6,022 x 1023 molecule/mol

= 6,146 x 1024 molecule

𝑐𝑜𝑒𝑓 H2O 4
c. n H2O = 𝑐𝑜𝑒𝑓 C3H8 x mol C3H8 = 1 x 3,402 mol = 13,608 mol

m H2O = n H2O x Mr = 13,608 mol x ((2 x 1,008) + 15,999) gr/mol

= 245,148 gr

SCIE6007- Industrial Chemistry