David Keffer, Department of Chemical Engineering, University of Tennessee

Bridgman Tables
Convenient for Single-component Volume Explicit Equations of State

I. Pressure

 ∂V 
1. (∂V )p = −(∂p)V =  
 ∂T p

2. (∂T )p = −(∂p)T = 1

Cp
3. (∂S)p = −(∂p)S =
T

 ∂V 
4. (∂U)p = −(∂p)U = Cp − p 
 ∂T p

5. (∂H)p = −(∂p)H = Cp

  ∂V  
6. (∂A )p = −(∂p)A = − S + p  
  ∂T p 

7. (∂G)p = −(∂p)G = −S

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 David Keffer, Department of Chemical Engineering, University of Tennessee

II. Temperature

 ∂V 
1. (∂V )T = −(∂T)V = − 
 ∂p T

2. (∂p)T = −(∂T )p = −1

 ∂V 
3. (∂S)T = −(∂T)S =  
 ∂T p

 ∂V   ∂V 
4. (∂U)T = −(∂T )U = T  + p 
 ∂T p  ∂p T

 ∂V 
5. (∂H)T = −(∂T )H = − V + T 
 ∂T p

 ∂V 
6. (∂A )T = −(∂T ) A = p 
 ∂p  T

7. (∂G)T = −(∂T)G = − V

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 David Keffer, Department of Chemical Engineering, University of Tennessee

III. Volume

 ∂V 
1. (∂p)V = −(∂V )p = − 
 ∂T p

 ∂V 
2. (∂T )V = −(∂V )T =  
 ∂p T

1   ∂V   ∂V  
2

3. (∂S )V = −(∂V )S =  p
C   + T   
T   ∂p T  ∂T p 

2
 ∂V   ∂V 
4. (∂U)V = −(∂V )U = Cp   + T 
 ∂p  T  ∂T p

2
 ∂V   ∂V   ∂V 
5. (∂H)V = −(∂V )H = Cp   + T  − V 
 ∂p  T  ∂T p  ∂T p

 ∂V 
6. (∂A )V = −(∂V )A = −S 
 ∂p  T

  ∂V   ∂V  
7. (∂G) V = −(∂V )G = −  V   + S  
  ∂T  p  ∂p  T 

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 David Keffer, Department of Chemical Engineering, University of Tennessee

IV. Entropy

Cp
1. (∂p)S = −(∂S )p = −
T

 ∂V 
2. (∂T )S = −(∂S )T = − 
 ∂T p

1   ∂V   ∂V  
2

3. (∂V )S = −(∂S)V = −  p
C   + T   
T   ∂p T  ∂T p 

p   ∂V   ∂V  
2

4. (∂U)S = −(∂S)U = Cp   + T  

T   ∂p  T  ∂T p 

Cp
5. (∂H)S = −(∂S)H = − V
T

p   ∂V   ∂V  
2
 ∂V 
6. (∂A )S = −(∂S)A = 
 p
C 
 + T    + S 
T   ∂p T  ∂T p   ∂T p

V  ∂V 
7. (∂G)S = −(∂S )G = − Cp + S 
T  ∂T p

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 David Keffer, Department of Chemical Engineering, University of Tennessee

V. Internal Energy

 ∂V 
1. (∂p) U = −(∂U) p = −C p + p 
 ∂T  p

  ∂V   ∂V  
2. (∂T )U = −(∂U)T = − T  + p  
  ∂T p  ∂p T 

  ∂V   ∂V  
2

3. (∂V )U = −(∂U)V = − Cp   + T  

  ∂p  T  ∂T p 

p   ∂V   ∂V  
2

4. (∂S )U = −(∂U)S = − Cp   + T  

T   ∂p T  ∂T p 

  ∂V     ∂V   ∂V  
2

5. (∂H)U = −(∂U)H = − V Cp − p   − p Cp   + T  

  ∂T p    ∂p T  ∂T p 

  ∂V   ∂V  
2
  ∂V   ∂V  
6. (∂A )U = −(∂U)A = p Cp   + T   + S  T  + p  
  ∂p T  ∂T p    ∂T p  ∂p T 

  ∂V     ∂V   ∂V  
7. (∂G)U = −(∂U)G = − V Cp − p   + S T  + p  
  ∂T p    ∂T p  ∂p T 

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VI. Enthalpy

1. (∂p)H = −(∂H)p = −Cp

 ∂V 
2. (∂T )H = −(∂H)T = V − T 
 ∂T p

2
 ∂V   ∂V   ∂V 
3. (∂V )H = −(∂H)V = −Cp   − T  + V 
 ∂p  T  ∂T p  ∂T p

Cp
4. (∂S )H = −(∂H)S = V
T

  ∂V     ∂V   ∂V  
2

5. (∂U)H = −(∂H)U = V Cp − p   + p Cp   + T  

  ∂T p    ∂p T  ∂T p 

  ∂V     ∂V    ∂V 
6. (∂A )H = −(∂H)A = − S + p   V − T   + pCp  
  ∂T p    ∂T p   ∂p T

 ∂V 
7. [ ]
(∂G)H = −(∂H)G = − V Cp + S + TS 
 ∂T p

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VII. Helmholtz Free Energy

  ∂V  
1. (∂p)A = −(∂A )p = S + p  
  ∂T p 

 ∂V 
2. (∂T )A = −(∂A )T = −p 
 ∂p  T

 ∂V 
3. (∂V )A = −(∂A )V = S 
 ∂p  T

p   ∂V   ∂V  
2
 ∂V 
4. (∂S )A = −(∂A )S = − Cp   + T   − S 
T   ∂p T  ∂T p   ∂T  p

  ∂V   ∂V  
2
  ∂V   ∂V  
5. (∂U)A = −(∂A )U = −pCp   + T   − S  T  + p  
  ∂p  T  ∂T p    ∂T p  ∂p T 

  ∂V     ∂V    ∂V 
6. (∂H)A = −(∂A )H = S + p    V − T   − pCp  
  ∂T p    ∂T p   ∂p  T

  ∂V    ∂V 
7. (∂G)A = −(∂A )G = S  V + p   + pV  
  ∂p T   ∂T p

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 David Keffer, Department of Chemical Engineering, University of Tennessee

VIII. Gibbs Free Energy

1. (∂p)G = −(∂G)p = S

2. (∂T )G = −(∂G)T = V

  ∂V   ∂V  
3. (∂V )G = −(∂G)V =  V   + S  
  ∂T  p  ∂p  T 

V  ∂V 
4. (∂S)G = −(∂G)S = Cp − S 
T  ∂T p

  ∂V     ∂V   ∂V  
5. (∂U)G = −(∂G)U = V Cp − p   − S  T  + p  
  ∂T p    ∂T p  ∂p  T 

 ∂V 
6. [
(∂H)G = −(∂G)H = V Cp + S − TS] 
 ∂T p

  ∂V    ∂V 
7. (∂A )G = −(∂G)A = −S  V + p   − pV  
  ∂p  T   ∂T p