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FeM
REVISED : MARCH 1973 FERROUS ALLOYS
AUTHOR = DR. R. P. WEI
1. GENERAL 1.06212 Sand castings. BHN 255 to 311 after normalizing and
This alloy is a modification of Type 410 stainless steel tempering (see 1.0522 and 1.055). Rockwell C 38
with Increased chromium and carbon contents and an minimum after austenitizing 1875 to 1925F, 30 min,
Fe
addition of about 2 percent nickel. It is on the borderline oil quench and tempering 650 to 700 F, 3 hr, air cool (8). 0.2 C
of a heat treatable stainless steel. Because of the rather 1.06213 Investment castings. Rockwell C 24 to 34 after normal¬
broad composition limits, it may require special consid¬ izing and tempering, (see 1.0522 and 1.055), Rockwell 16 Cr
erations regarding heat treatment, (see 1.09). It is nor¬ C 38 to 49 after austenitizing and tempering, (see 1.054
mally used at temperatures up to 800 F where moderate and 1.055)(7). 2 Ni
strength is required and provides corrosion resistance 1.0622 ASTM specified hardness. BHN 241 maximum for ASTM
superior to other hardenable chromium stainless grades. A296- Grade CB-30 (castings) (9),
It is frequently used in highly stressed parts where good 1.063 Effect of tempering temperature on hardness of invest¬ TYPE 431
corrosion resistance is important in design, such as air¬ ment castings, Figure 1.063.
craft fittings, pump shafts and valve parts (1, p.20)(2, Stainless
pp. 3- 4)(3)(4, p. 1)(5){6)(7)(8). 1.07 Forms and Conditions Available Steel
This alloy is available in bars, wire, rods, tubings, for¬
1.01 Commercial Designation gings and castings. Bars (over 2.75 in) are hot finished
Type 431. and annealed. Bars (less than 2.75 in) , wire and mech¬
anical tubing are annealed and cold finished (6)(7)(8)(17).
1.02 Alternate Designations
AISI 431; SAE 51431 (wrought); ASTM A -3 14, Type 431; 1.08 Melting and Casting Practices
ASTM A -276, Type 431; 431 Mod (cast); ASTM A-296, Electric furnace air melt, Induction vacuum melt and
Grade CB-30 (cast). consumable electrode vacuum melt (21, p. 5).
CODE 1404
PAGE 1
FeM
FERROUS ALLOYS REVISED : MARCH 1973
CODE 1404
PAGE 2
FeM
REVISED: MARCH 1973 FERROUS ALLOYS
Fe-(0.2C)-l6Cr-2Ni
o EWEST CA5 T
Source ASTM (9) ASTM /23M241
J h ARDEN 18 25F, 1 HR RAC
Alloy Fe-<0.2C) -l6Cr-2Ni ~3
Form Castings Bars and Billets "40
Percent Percent
Min Max Min Max
u
Carbon - 0.30 - 0.20 S
Chromium 18.0 21.0 15.0 17.0
Copper 0.90* 1.20* - -
Manganese - 1.0 - 1.0
Nickel - 2.00 1.25 2.50
Silicon - 1.50 - 1.00
--
Phosphorus - 0.04 0.040 400 800 1200 1600
Sulfur
Iron
- Balance
0.04 0.030
Balance
TEMPERING TEMP F -
* Optional FIG. 1.063 EFFECT OF TEMPERING TEMPER¬
ATURE ON HARDNESS OF INVEST¬
TABLE 1.0412 ASTM SPECIFIED COMPOSITION MENT CASTINGS. (11, p.21)
240
Fe-(0.2C)-16Cr-2Ni
1IN BAR
200
ftu /
300
Fe-(0.2C)-16Cr-2N
w
200
120 O
80
1A
u
• ÿ
100 A
o
X
w
a. %
__ e
O AN
ÿ HARDEN *
A HARDEN + CV t
0 0 20 40 60
1500 1600 1800 1700 PICKLING TIME - MIN (AT 150F)
AUSTENITIZING TEMP F -
FIG. 1.0542 EFFECT OF AUSTENITIZING FIG. 1.0911 SUSCEPTIBILITY OF 0.06 IN
TEMPERATURE ON ROOM DIAMETER WIRE TO EMBRIT-
TEMPERATURE TENSILE TLEMENT AS A FUNCTION OF
PROPERTIES OF AS-QUENCHED PICKLING TIME IN 7 PERCENT
BAR. (14) HC1. (18, p. 429)
CODE 1404
PAGE
FeM
FERROUS ALLOYS REVISED: MARCH 1973
10
Source (21, P. 46) <1?) 1(11, p. 20, 21)
Fe-(0.2C)-16Cr-2Ni
Fe Alloy .
Fe- (0 2 C)- 16Cr-2Ni
b. Form Bar Wire Sand Prec Cast Cast
0.2 C CS Cast
16 Cr
g 8
MEAN :OEF LINE AR Conditioa Ann Ann Soft Ann Ann Hardened As cast
z THERM AL EXPAN SION +CD Temper LD HD
Thickness - in All 1 0.250 - - - - -
2 Ni
-
Fm ksi
Fty - ksi
125
95
130
110
135
115
75
50
120
90
180
130
140
100
109
85
TYPE 431 -
e (2 in) percent 20 15 10 5 15 10 15 3
Source (6)(7)(8)
Alloy Fe-(0.2C -16Cr-2Ni
Form Bar Wire Mech. Sand Investment
Tubing Castings Castings
Condition Ann. + Ann. + Ann. + Norm. + Aust. + Norm + Aust. +
HF or CF CF CF Temper Temper Temper Temper
Fÿ - ksi - min - - - -
180 (b) 170 (d) -
max - 140 - - - - -
Fÿr - ksi min- - - - -
140 (b) - 130 (d)
-
e (4D) min-percent
Hardness
- - - -
8(b) - 2 (d)
- max
RC min - - -- - 38 (b) 24(c) 38 (c)
- - - - 34(c) 49 (c)
BHN - min - - - 255 (a) - - -
max 302
(a) Castings and test specimens.
- 285 311 (a) - - -
(b) Test specimens produced with castings; normalized and tempered with castings +
austenitize 1875 to 1925 F, 30 min, oil quench, temper 650 to 700F, 3 hr, air cool.
(c) Castings.
(d) Specimens representing master heat or master heat lot.
CODE 1404
PAGE 4
FeM
REVISED: MARCH 1973 FERROUS ALLOYS
Fe-<0. 2C)-16Cr-2Ni
BAR (0.505 IN DIA SPECIMEN)
1850F, 30 MIN, OQ + TEMPER 450F,
' Fe-<0 .2C) -16C r-2Ni
INVEST CAST Fe
0.2 C
16 Cr
160
2 Ni
TYPE 431
Stainless
Steel
E-
2
U
O
C£
w
a
•AS TEMPERED
A 1/2 HR EXPOSURE 700F
ÿ 400 HR EXPOSURE 7 OOF
O
---
1825F, 1 HR, RAC + TEMPER
(0. 12-0.20C)
(0.06-0. 12C)
160 53
Source (22)
Alloy Fe-{0. 2C)-16Cr-2Ni
Form Extruded Bar (L)
• asj}
(14) 1800F, OQ
1900ÿÿ
Condition
Ftu ~ tei
1750F, 1/2 hr, AC 1800F, 1/2 hr, OQ
+1250F, 2 hr, AC + 550F, 2 hr, AC
126 207
a
Fjy - ksi 104 159
40
80
RA
-
e (2 in) percent
- percent
21
59
15
27
6-
Z
w RA TABLE 3. 02143 EFFECT OF TEMPERING TREATMENT
o ON TENSILE PROPERTIES OF EX¬
CS
TRUDED BAR
e(2 IK)
CODE 1404
PAGE 5
FeM
FERROUS ALLOYS REVISED : MARCH 1973
100
Fe-(o.2C)-16Cr-2N
Fe 1800F, OQ + TEMP ER
0.2 C
/
i
80
16 Cr
2 Ni
//
_ IE IZOI V
TYPE 431
Stainless
* 40
Steel
// \
TABLE 3.0232 IMPACT STRENGTH OF BAR, BILLET AND FORGING AT ROOM TEMPERATURE AND -40 F.
Source (20)
Alloy Fe-(0.2C)-16Cr-2Ni
Form 1 in Dia Bar
Condition 1200 F, 1/2 hr, AC+I900F 1200 F, 1/2 hr, AC+19Q0F
1/2 hr,OQ+doubIe temper 1/2 hr, OQ+- -140F, 2 hr
550F, 2 hr, AC -ÿdouble temper 550 F,
2 hr. AC
As AS
Tempered(b) Strained(a) Terapered(c) Strained(a)
IE Charpy V Temp.
ft lb RT 53.5 27.3 24.0 17.7
(Avg. of 4)
-40F 23. S 12.S 7.0 4.7
(a) Strained to 138 percent of Fÿ.
(b) ÿ
-
= 216 ksi, Ffy 145 ksi, e(l in) 20.6 percent, RA = 59.5
percent.
(c) Ftu = 224 ksi, = 158 ksi, e(l in) * 17.2 percent, RA o 58. 7
percent.
CODE 1404
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FeM
REVISED: MARCH 1973 FERROUS ALLOYS
»
J 1 1
Fe-(0.30C)-15.6Cr-1.9Ni-lMn-lSi
5/8 SQ
IN BAR JL Fe-<0.2C)-16Cr-2Ni
BAR
Fe
1800F, 1/2 HR, OQ.1225F, 4 HR, OQ 1850F, 30 MEN, OQ +
TEMPER 450F. 1 HR
0.2 C
AC 16 Cr
2 Ni
TYPE 431
Stainless
Steel
O NORMAL NITROGEN
---'-
"HIGH NITROGEN (0.063%) DATA AVG OF 3 SPECIMENS
D* L
3.0 3.5 4.0 5.0
BAR DIAMETER IN -
FIG. 3.0351 EFFECT OF SIZE AND EXPOSURE AT 700F
ON SHEAR STRENGTH OF BAR AT ROOM
TEMPERATURE AND 7 OOF. (16)
u 40
e(2 IN)
Fe-(0.2C)-16Cr-2Nl
OQ + TEMPER 1200F
280
Fe-<0.2C)'16Cr-2Ni < 900F
BAR (0.252 IN DLA SPECIMEN)
1850F, 30 MIN, OQ + TEMPER 450F, 1HR , AC
240
NITROGEN
NORM HIGH(0.063 PERCENT)
O & RUPTURE
200 TU En
A
•
A lPERCENT
CREEP
. hoof
160
Fty
1200F
120
CODE 1404
PAGE
FeM
FERROUS ALLOYS REVISED : MARCH 1973
REFERENCES
Fe
0.2 C Republic Steel Corp., "Republic Enduro Stainless Steel,
-
Chromium Types 400 Series", Adv. 1125 R4a-10M-1-
16 Cr 66 (1964).
Dieter, G. E. , "Effect of Mic rostructure and Heat Treat¬
2 Ni ment on the Mechanical Properties of AISI Type 431
Stainless Steel", ASM Trans. , Vol. 50 (1957).
Jones & Laughlin Steel Corp., "J & L Type 431, Stain¬
TYPE 431 less Steel", Data Sheet DS-45S-8 (July 1958).
Crucible Steel Co. , "Crucible 431 Stainless Steel", Data
Stainless *' Sheet DS 163-5M-11/60, Issue #4, and "Resistal 431
Stainless Steel", Data Sheet DS 163-10M-2/57 (issued
Steel August 1947), Revision #3 (September 1954).
Brown, W. F. , Jr., Personal Communication (October 2,
1961).
AMS 5628C (Rev. May 1, 1970).
AMS 5353 (September 15, 1957).
AMS 5372 (March 1, 1955).
9. ASTM A296-68, Grade CB-30 (1968).
10. Alloy Casting Institute, "Corrosion Resistant Type CB-
30", Data Sheet 4-54-75 CI (June 1954).
11. Haynes Stellite Co., "Haynes Investment- Cast Steels",
(April 1958).
12. Fiorentino, R.J. , Roach, D. B., and Hall, A.M., "Heat
Treatment of High- Strength Steels for Airframe Applica¬
tions", DM1C Rept. 119 (November 27, 1959).
Mishler, H.W., Monroe, R.E., and Rieppel, P.J.,
"Welding of High- Strength Steels for Aircraft and Missile
Applications", DMIC Rept. 118 (October 12, 1959).
14. Allegheny Ludlum Steel Corp., "Blue Sheet for Allegheny
Metal 12-2, 16-1, Stainless Steel".
15. Irish, C.R., and Rosenberg, S.J., "Heat Treatment of
Type 431 Stainless Steel", National Bureau of Standards
(September 1959).
16. Republic Aviation Corp. , "Compilation of Unpublished
Materials Information", First Quarterly Rept. No. RAC
767-251(357), (July 14, 1961), and AD 269710 (June 1961).
17. Alloy Digest, "AISI Type 431", Filing Code SS-88 (May
1959).
18. ASM Metals Handbook, Vol. 1, Sth Edition, "Properties
and Selection of Metals" (1961).
19. "Some Physical Properties of Martensitic Stainless
Steels", DMIC Memo 68 (September 28, 1960).
20. Feinberg, I.J. , "Effect of Refrigeration and Strain on the
Charpy V- Notch Properties of Type 431 Stainless Steel11,
National Bureau of Standards Rept. 10-015 (April 1969).
21. American Iron and Steel Institute, "Stainless and Heat
Resisting Steels1.', Steel Products Manual (April 1963).
22. Fiorentino, R. J., and Sabroff, A.M., "Availability and
Mechanical Properties of High-Strength Steel Extrusions",
DMIC Rept. 138 (October 1960).
23. ASTM A -276-67, Type 431 (1967).
24. ASTM A -3 14-63, Type 431 (1963).
CODE 1404
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