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3+ – O
Cr (aq) + 3e → Cr(s) E = –0.74 V
3+ – 2+ O
Fe (aq) + e → Fe (aq) E = +0.77 V
What will be the cell potential, in V, of a voltaic cell in which the following reaction takes
place?
3+ 2+ 3+
Cr(s) + 3Fe (aq) → 3Fe (aq) + Cr (aq)
A. –1.51
B. –0.03
C. +0.03
D. +1.51
(Total 1 mark)
2. Which changes could take place at the positive electrode (cathode) in a voltaic cell?
2+
I. Zn (aq) to Zn(s)
–
II. Cl2(g) to Cl (aq)
2+
III. Mg(s) to Mg (aq)
A. I and II only
D. I, II and III
(Total 1 mark)
IB Questionbank Chemistry 1
3. What are the features of a standard hydrogen electrode?
I. A temperature of 298 K
5
III. Hydrogen gas at 1.01 × 10 Pa (1 atm) pressure
A. I and II only
D. I, II and III
(Total 1 mark)
4. The standard electrode potential for a half-cell made from iron metal in a solution of iron(II)
2+
ions, Fe (aq), has the value –0.45 V.
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
......................................................................................................................................
(2)
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......................................................................................................................................
(1)
(Total 3 marks)
IB Questionbank Chemistry 2
5. Consider the following table of standard electrode potentials.
O
E /V
2+ –
Fe (aq) + 2e Fe(s) –0.45
2+ –
Sn (aq) + 2e Sn(s) –0.14
1
+ – 0.00
H (aq) + e 2 H2(g)
4+ – 2+
Sn (aq) + 2e Sn (aq) +0.15
3+ – 2+
Fe (aq) + e Fe (aq) +0.77
+ –
Ag (aq) + e Ag(s) +0.80
1
+1.07
2 Br2(l) + e– –
Br (aq)
......................................................................................................................................
......................................................................................................................................
(1)
4+ 2+ 2+
(ii) Deduce which species can reduce Sn (aq) to Sn (aq) but will not reduce Sn (aq) to
Sn(s) under standard conditions.
......................................................................................................................................
......................................................................................................................................
(1)
IB Questionbank Chemistry 3
2+
(iii) Deduce which species can reduce Sn (aq) to Sn(s) under standard conditions.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 3 marks)
(i) Use Table 14 of the Data Booklet to deduce the equation for the spontaneous reaction
occurring in this cell.
......................................................................................................................................
......................................................................................................................................
(1)
......................................................................................................................................
......................................................................................................................................
(1)
IB Questionbank Chemistry 4
(iii) State the conditions necessary for the potential of the cell to equal that calculated in part
(ii) using the data from Table 14.
......................................................................................................................................
......................................................................................................................................
(1)
(Total 3 marks)
7. D
[1]
8. A
[1]
9. B
[1]
(ii) the electrons flow from the half-cell to the standard hydrogen
electrode / the half-cell forms the negative electrode when
connected to the standard half-cell / Fe is a better reducing
agent than H2 / Fe is above H2 in electrochemical series; 1
Accept “the half reaction is not spontaneous”.
[3]
(ii) hydrogen/H2; 1
IB Questionbank Chemistry 5
(iii) iron/Fe; 1
Ignore coefficients for Br2, H2 or Fe.
[3]
2+ 2+
12. (i) Sn + Cu → Sn + Cu; 1
Ignore state symbols.
Penalize once only.
–3
(iii) 1.0 mol dm solutions and 25 °C/298 K; 1
[3]
IB Questionbank Chemistry 6