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(Academic Session : 2020 - 2021)

1. Which two orbitals are located along the axis, and not between the axis ?
(a) d xy ,d z2 (b) d xy , p z

(c) d yz ,p x (d) p z ,d x 2  y2
2. Which of the following set of quantum numbers is impossible for an electron ?
1 1
(a) n  1,l  0, ml  0, ms   (b) n  9,l  7, ml  6, ms  
2 2
1 1
(c) n  2,l  1, ml  0,ms   (d) n  3,l  2,m l  3, ms  
2 2
3. Which of the following statements is correct for an electron having azimuthal quantum number l  2?
(a) The electron may be in the lowest energy shell
(b) The electron is in a spherical orbital
1
(c) The electron must have spin ms  
2
(d) The electron may have a magnetic quantum number  1
4. For an 4p y orbital, there are nodal plane ..... and azimuthal quantum number l....
(a) 1, 0 (b) 0, 1
(c) 1, 1 (d) 2, 1
5. Which of the following statements about an electron with ml  2 is incorrect ?
(a) The electron could be in the third shell (b) The electron is in a non-spherical orbital
1
(c) The electron may have ms  (d) The electron is not in a d  orbital
2
6. The set of quantum numbers, n  3,l  2, m1  0
(a) describes an electron in a 2s orbital (b) is not allowed
(c) describes an electron in a 3p orbital (d) describes one of the five orbitals of same energy
7. Select the correct statement(s):
(a) An orbital with l  0 is symmetrical about the nucleus
(b) An orbital with l  1 is spherically symmetrical about the nucleus
(c) 3d z2 is spherically symmetrical about the z-axis
(d) All are correct
8. The size of an orbital is given by
(a) Principal quantum number (b) Azimuthal quantum number
(c) Magnetic quantum number (d) Spin quantum number
9. The electron in the same orbital may be identified with the quantum number
(a) n (b) l
(c) m (d) s

ALLEN Digital Classroom support Classes and material will continue until lockdown is lifted after which classroom course will commence
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TARGET :JEE(M+A)/NURTURE-2021/DPP-8
10. Orbital with maximum symmetry is
(a) p - orbital (b) s - orbital
(c) d xy  orbital (d) d z2  orbital
11. The number of orbitals of g - type
(a) 5 (b) 7
(c) 9 (d) 11
12. Which of the following orbital does not exist according to quantum theory ?
(a) 5g (b) 4f
(c) 5h (d) 6h
13. The probability of finding Py electron is zero in
(a) XY - plane (b) YZ - plane
(c) XZ - plane (d) Y - axis
14. Which of the following set of quantum numbers is permissible ?
(a) 4,1, 2, 1/ 2 (b) 4,2, 1, 1/ 2
(c) 4,0,0,1 (d) 4,4, 2, 1/ 2
15. The quantum numbers 1 / 2 and 1 / 2 for the electron spin represent
(a) rotation of the electron in clockwise and anticlockwise direction, respectively
(b) rotation of the electron in anticlockwise and clockwise direction, respectively
(c) magnetic moment of the electron pointing up and down, respectively
(d) two quantum mechanical spin states which have no classical analogue.
16. The quantum number which determines the shape of the orbital is
(a) Magnetic quantum number (b) Azimuthal quantum number
(c) Principal quantum number (d) Spin quantum number
17. The maximum number of electrons in 3d z2 orbital is
(a) 2 (b) 4
(c) 5 (d) 10

ALLEN Digital Classroom support Classes and material will continue until lockdown is lifted after which classroom course will commence