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SAFETY DATA SHEET

Wavistrong® EASY-FIT Adhesive - Resin Conductive


Revision date: 12.01.2017
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
COMPANY/UNDERTAKING
1.1 Product identifier

Trade name Wavistrong® EASY-FIT Adhesive - Resin Conductive

Product type L10201 ADHESIVE (paste) Organic solvent, Industrial use.

Version number 1.0

1.2 Relevant identified uses of


the substance or mixture and
uses advised against
Uses of the chemical 33.150 Repair and maintenance of ships and boats.
09.109 Other activities auxiliary oil and gas.
Industrial and professional use.
Uses advised against Restricted to professional users. The product is not recommended for private use.
1.3 Details of the supplier of the
safety data sheet
Distributor Stangeland Glassfiber Produkter AS
Bedriftsvegen 33
4353 Klepp Stasjon
Norge
Telefon: +47 51 78 60 90
http://www.glassfiber.no
E-mail post@glassfiber.no

Responsible Stangeland Glassfiber Produkter AS

Manufacturer Future Pipe Industries B.V.


J.C. Kellerlaan 3
7772 SG Hardenberg
Nederland
Telefon: +31 523 280500
Fax: +31 523 280700
http://www.futurepipe.com/
Author Sensor Chemcontrol AS

1.4 Emergency telephone Poison Information Centre: +47 22 59 13 00.


number

SECTION 2: HAZARD IDENTIFICATION

2.1 Classification of the


substance or mixture
Classification according to Aquatic Chronic 2; H411: Toxic to aquatic environment.
1272/2008EC Skin Irrit 2; H315: Skin corrosion/irritation.
Eye Irrit 2; H319: Serious eye irritation.
Skin Sens 1; H317: Skin sensitization.
2.2 Label elements
Pictogram

GHS07 GHS09

Signal word Warning


Hazard statement(s) H411 Toxic to aquatic life with long lasting effects.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H315 Causes skin irritation.
EUH205 Contains epoxy constituents; May produce an allergic reaction.

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Precautionary statements
Prevention P261 Avoid breathing dust /fume /gas /mist /vapours/spray.
P264 Wash exposed skin thoroughly after handling.
P272 Contaminated work clothing should not be allowed out of the workplace.

Response P321 Specific treatment, see information on this label.


P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
Ingredients for label Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight <=
700)
Trimethylolpropane epichlorohydrin copolymer

2.3 Other hazards The chemical does not meet the criteria for PBT or vPvB in accordance with REACH Annex XIII.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2 Mixtures

Ingredients Identification Classification Note Weight%


Reaction product: bisphenol-A-(epichlorhydrin) Reach nr: 01-2119456619-26 Skin Irrit 2; H315 9 > 50
epoxy resin (number average molecular weight <= Ec/Nlp nr: 500-033-5 Skin Sens 1; H317
700) Cas nr: 25068-38-6 Eye Irrit 2; H319
Index nr: 603-074-00-8 Aquatic Chronic 2; H411

Trimethylolpropane epichlorohydrin copolymer Ec/Nlp nr: 608-489-8 Skin Irrit 2; H315 2,5 - 10
Cas nr: 30499-70-8 Skin Sens 1; H317
Eye Irrit 2; H319
Aquatic Chronic 3; H412

Generic concentration limits and


M-factors

Ingredients Generic concentration limit and M-factor


Reaction product: bisphenol-A-(epichlorhydrin) Skin Irrit. 2; H315: C >= 5%
epoxy resin (number average molecular weight <= Eye Irrit. 2; H319: C >= 5%
700)

Explanation Eye Irrit 2: Serious eye damage/eye irritation.


Aquatic Chronic 2: Toxic to aquatic environment.
Aquatic Chronic 3: Hazardous to the aquatic environment.
Skin Irrit 2: Skin corrosion/irritation.
Skin Sens 1: Skin sensitization.
Hazard phrases with full text is found in section 16.
Ingredients comments All concentrations are listed as weight percent.
The classification applies to each substance, not the product.

Note 9: The substance is harmonized and the classification is obtained from ECHA (European
Chemicals Agency) C&L Inventory database.

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid


measures
Inhalation Inhalation is not an expected route of exposure. Seek medical attention if breathing is difficult. Fresh
air, warmth and rest, preferably in a comfortable, half-sitting position. If breathing stops, perform
artificial respiration. Keep respiratory tract open.
Skin contact Remove contaminated clothes and shoes. Rinse and wash skin thoroughly with soap and water. Wash
with plenty of soap and water. In all cases of doubt, or when symptoms persist, seek medical attention.
Wash contaminated clothing before reuse.
Eye contact In case of contact with eyes, rinse immediately with plenty of water.

Ingestion Seek medical advice immediately and show container or label. DO NOT INDUCE VOMITING. Rinse
mouth with water (only if the person is conscious).

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4.2 Most important symptoms Irritating to skin. May cause an allergic skin reaction.
and effects, both acute and
delayed

4.3 Indication of any immediate By accident or malaise, consult a doctor immediately. Show instructions for usage or the MSDS if
medical attention and special available.
treatment needed
Additional information Data Sheet are for base / hardener separately. After mixing and curing, the product is not harmful unless
the product is sanded and grinding dust inhaled. In some epoxy products, there may be organic solvents.
They can damage health if they inhaled. Some can also be absorbed through the skin.The symptoms may
be that they become nauseous, dizzy and get headaches. Such solvents may also lead to being jaded, so
that responsiveness and vigilance against dangers drops.

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media


Suitable extinguishing media Water spray, foam, CO2 or powder.

Use extinguishing agent suitable for the conditions and environments.


Extinguishing media which shall Avoid using directed water jets during extinguishing work.
not be used
5.2 Special hazards arising from Releases flammable vapours which can form an explosive mixture with air. In the event of fire, CO,
the substance or mixture CO2, NOx and black smoke may develop. Note that there is a danger of formation of poisonous gasses.

5.3 Advice for firefighters Firefighters should use standard protective flame resistant jacket, helmet with face shield, gloves,
rubber boots and self-contained breathing apparatus in confined areas.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, Keep persons and animals away from contaminated area. Only trained personnel should perform the
protective equipment and cleanup of spills. Wear suitable protective clothing. Respiratory protection: half or full breathing mask
emergency procedures with filter for organic vapors, or self-contained breathing equipment depending on the size of the spill
and potential exposure degree.
6.2 Environmental precautions Prevent entry into drains. Prevent entry into waterways, sewers, basements or confined areas.

6.3 Methods and material for Soaked up with volcanic ash, earth, sand, kiselguhr or other suitable material and collected. Deliver to
containment and cleaning up nearest refuse disposal terminal.
6.4 Reference to other sections See section 7 for information on safe handling.
See section 8 for information on personal protection equipment.
See section 12 for information on ecology.
See section 13 for waste disposal.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling Use only in well ventilated areas. Provide good ventilation when working. Use compressed air or
respirator in confined spaces. Avoid contact with eyes, skin and clothes. Wear suitable gloves. Handle
in accordance with good hygiene and safety practice. Operating instructions should be followed to
ensure safe use and best results.
7.2 Conditions for safe storage, The product is flammable and should not be exposed to open flames. Keep away from oxidizing
including any incompatibilities substances. Keep container in a well-ventilated place. Should be stored standing and in original
container.
Special precautions May cause sensitization by skin contact.
7.3 Specific end use(s) Industrial and professional use.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters


Limit values notes Contains no substances with occupational exposure limits.

Derived no effect level (DNEL) Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average
molecular weight <= 700)
Acute local effect Acute systemic effect Chronic local effect Chronic systemic effect

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Employee -inhalation Hazard unknown (no 12.25 mg/m³ Hazard unknown (no 12.25 mg/m³
further information further information
necessary) necessary)
-skin contact Medium hazard (no 8.33 mg/kg bw/day No hazard identified 8.33 mg/kg bw/day
threshold derived)
Consumer -inhalation Hazard unknown (no Hazard unknown (no Hazard unknown (no Hazard unknown (no further
further information further information further information information necessary as no
necessary) necessary as no exposure necessary) exposure expected)
expected)
-skin contact Medium hazard (no 3.571 mg/kg bw/day No hazard identified 3.571 mg/kg bw/day
threshold derived)
-oral 750 µg/kg bw/day 750 µg/kg bw/day

8.2 Exposure controls


Exposure controls Mechanical ventilation and point evacuation can be necessary.
Common sense and safety precautions should always be used when handling chemicals. Ensure that all
containers are properly labeled to prevent accidental ingestion or improper use. Ensure good working
hygiene. Make use of recommended safety equipment. Provide adequate exhaust ventilation, or
ventilation in the workplace. Avoid contact with eyes and skin.
Respiration protection It is recommended the use approved respirator when working in confined spaces or in areas without
natural ventilation or local exhaust ventilation: A respirator with gas and vapor filter against organic
gases boiling over 65 ° C class 1, type A1 with filter color brown, according to the standard
(NS-EN-14387), or fresh air overpressure mask according to the standard (EN-137 , EN-270).
Respiratory equipment with gas filter may only be used combined with good routines for mesh
adaptation and filter change.
Eye protection Equipment for eye washing must be available, preferably also a shower. Eye protection shall be in
accordance to EN 166 standard.
Hand protection Protective gloves of Nitrile, Neoprene or PVA is recommended. Glove thickness of 0.35 mm according
to standard EN-374.
During continuous contact: Use gloves with penetration time above 480 minutes.
By short-term splash / exposure (up to 30 minutes): Use gloves with penetration time above 60 minutes.
All specific glove information provided is based on published literature and glove manufacturer data.
Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the
glove manufacturer for specific advice on glove selection and breakthrough times for your use. Check
and possibly replace worn or damaged gloves. If contact with forearms is likely, wear gauntlet style. CE
standards EN420 and EN374 provide general requirements and lists of glove types.
Skin protection Wear suitable protective clothing.

Additional information It is good industrial hygiene practices to avoid skin contact as much as possible. Do not wear rings,
watches, etc, which are suitable for keeping the product and thereby cause skin reactions. Barrier creams
may help to protect exposed skin, but can not substitute for gloves. Remove contaminated clothing to
prevent skin contact. After washing the skin apply oily skin cream to replace lost skin oils. Keep good
order. Specific Hygiene Measures: Always observe good personal hygiene such as washing after
handling product and before eating, drinking and / or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard contaminated clothing and shoes that can not be
washed.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical


and chemical properties
Form Paste

Colour n/a

Odour n/a

Smell limit n/a

pH - conc. ca 7
Melting point n/a

Boiling point n/a

Flash point 150 °C

Relative evaporation rate n/a

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Flammability (solid, gas) n/a

Explosion limits n/a

Vapour pressure 1000 hPa ( 50 °C)

Vapour density n/a

Relative density 1.6 g/cm3

Solubility n/a

Solubility water 0 % (Non soluble)

Partition coefficient n/a


n-octanol/water
Auto-ignition temp. n/a

Decomposition temperature n/a

Viscosity 100000 s ISO cup 6 mm (ved 23 °C)

Explosive properties n/a

Oxidising properties n/a

Solvent separation test : 3%

9.2 Other information n/a

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity n/a

10.2 Chemical stability Stable under normal conditions.

10.3 Possibility of hazardous Polymerizing exothermically with amines at room temperature or higher.
reactions
10.4 Conditions to avoid Keep away from open flames, sparks and all other forms of ignition.

10.5 Incompatible materials Avoid amines, acids and alkalis.

10.6 Hazardous decomposition In case of fire CO, CO2, NOx and black smoke will develop.
products

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological


effects
Acute toxicity Inhalation is not an expected route of exposure. Ingestion of larger quantities can cause symptoms
similar to inhalation. Inhalation of vapours/dust causes headaches, dizziness, tiredness and nausea.
For ingredient reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
<= 700)
LD50 oral 11400 mg/kg (Rotte)
Reference AMA Archives of Industrial Health. Vol. 17, Pg. 129, 1958.

LD50 dermal > 22800 mg/kg (Kanin)


Reference Union Carbide Data Sheet. Vol. 6/6/1969,

Skin corrosion/irritation Removes natural oils from skin, can cause cracks and eczema. Irritating to skin.

Serious eye damage/ irritation Seriously irritates the eyes.

Respiratory or skin sensitisation May cause an allergic skin reaction.

Germ cell mutagenicity None of the substances listed in section 3 is classified as mutagenic.
Carcinogenicity None of the substances listed in section 3 is classified as carcinogenic.

Reproductive toxicity None of the substances listed in section 3 is classified as reproduction toxic.
STOT-single exposure Based on available data, no classification criteria are met.

STOT-repeated exposure Based on available data, no classification criteria are met.


Aspiration hazard Under normal use, no health effects are anticipated.

Additional information Probable route of exposure: Skin contact. Inhalation of vapors.

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Mixture

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with low solubility.
For ingredient reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight
<= 700)
LogKow 3.242 @ 25 °C
12.2 Persistence and Solvents oxidize quickly due to photochemical reactions in air. Solvents expected to be potentially
degradability biodegradable.

12.3 Bioaccumulative potential No bio-accumulation is indicated.

12.4 Mobility in soil Tempered or solidified product is immobile. The product is not soluble in water. The product is viscous
and will spread very little.
12.5 Results of PBT and vPvB The chemical does not meet the criteria for PBT or vPvB in accordance with REACH Annex XIII.
assessment This product does not contain a PBT or vPvB.
12.6 Other adverse effects Under normal conditions, pollutes the air when releasing solvent vapours. After curing the product
represents no toxicity risks.

SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods


Disposal group EWC: 08 01 11 waste paint and varnish containing organic solvents or other dangerous substances.
EWC: 08 01 12 other waste from paint and lacquer then mentioned in 08 01 11.
The EWC code are for illustrative purposes only. Always check the waste codes in view of the current
state the product is in. The final waste groups and tags must be determined by the user, based on the
actual use of the product.
Packings EWC: 15 02 02 Contaminated rags and the like.
EWC: 15 01 10 Packing which contains remnants or is contaminated with dangerous waste.
Additional information Discharge into the environment must be avoided.
The product shall not be allowed to enter drains, waterways, groundwater or the evironment. Avoid
contact with skin.

SECTION 14: TRANSPORT INFORMATION

14.1 UN number UN 3082

14.2 UN proper shipping name


Item name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S

IMDG proper shipping name Environmentally hazardous substance, liquid, n.o.s.

14.3 Transport hazard class(es)


Label 9
GHS09: Environment.
ADR/RID class 9

ADR/RID classification code M6

ADR/RID danger number 90

ADR/RID free quantity 5 L / E1

IMDG class 9

IMDG EmS F-A, S-F

IATA class 9

14.4 Packing group III: Less dangerous substances.

14.5 Environmental hazards Toxic to aquatic life with long lasting effects.

14.6 Special precautions for user n/a

14.7 Transport in bulk according n/a


to Annex II of MARPOL73/78
and the IBC Code

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and COMMISSION REGULATION (EU) 2015/1221 av 24 july 2015 (ATP7).
environmental regulations/ Norwegian Regulations: "FOR-2012-06-16-622 Forskrift om klassifisering, merking og emballering av
legislation specific for the stoffer og stoffblandinger (CLP).".
substance or mixture European Parliament and Council Regulation (EC) 1272/2008.
COMMISSION REGULATION (EU) 2015/830 of 28 May 2015 amending Regulation (EC) No
1907/2006 of the European Parliament and of the Council on the Registration, Evaluation,
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Authorisation and Restriction of Chemicals (REACH).
Transport of hazardous goods: ADR, RID, IMDG, IATA (2015).
Regulations regarding OAR values.
FOR 2004-06-01 nr 922: Norwegian regulations on the restriction of use of hazardous chemicals and
other products "produktforskriften".
ECHA (European Chemicals Agency) C&L Inventory database.
Norwegian Waste Regulations (miljøverndepartementet): "FOR 2004-06-01 No. 930: Regulations
relating to the recycling of waste".
FOR-2015-05-19-541 Forskrift om deklarering av kjemikalier til produktregisteret (norwegian
regulation for product declaration).
Ex-ECB databasen.
15.2 Chemical safety Supplier has not carried out a Chemical Safety Assessment for the substance or mixture.
assessment
Additional information
Classification of this product is given on the basis of the available information from the vendor.

SECTION 16: OTHER INFORMATION

Relevant hazard- and risk H315 Causes skin irritation.


phrases given in section 3 H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Key literature references and Material safety data sheet from the supplier.
sources for data
Abbreviations in the document n/a - No relevant information.
PBT - Persistent, Bioaccumulative and Toxic.
vPvB - very Persistent and very Bioaccumulative (require special attention under REACH).
EWC - European Waste Catalogue codes.
First released 12.01.2017

Additional information Revised and quality controlled by:


Sensor Chemcontrol AS
Storgata 30
3611 Kongsberg
Norway
Tlf: +47 32 77 06 60
E-mail: helpdesk@sensor.as.
URL: www.sensor.as.

--- SAFETY DATA SHEET conforming to commission regulation (EC) 1272/2008 and (EU)
2015/830 ---

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