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ISOMETRIC (V=C)

P 1 P2
PVT relationship =
T1 T 2
ΔH (enthalpy) mC p Δ T ISENTROPIC (PVk=C)
ΔU (internal energy) mC v Δ T T 1 P1 k−1
k V 2 k−1
PVT relationship =( ) =( )
Wn (Work non-flow) 0 T 2 P2 V1
Ws (Work steady-
V ΔP ΔH (enthalpy) mC p Δ T
flow) ΔU (internal
Q (heat) mC v Δ T mC v Δ T
energy)
T2 Wn (Work non- P 2 V 2−P1 V 1
ΔS (entropy) mC v ln
T1 flow) 1−k
Ws (Work steady-
kWn
flow)
ISOBARIC (P=C) Q (heat) 0
V1 V2 ΔS (entropy) 0
PVT relationship =
T 1 T2
ΔH (enthalpy) mC p Δ T
POLYTROPIC (PVn=C)
ΔU (internal energy) mC v Δ T
T 1 P1 n−1 V 2 n−1
Wn (Work non-flow) P ΔV PVT relationship
n
=( ) =( )
Ws (Work steady- T 2 P2 V1
0 mC p Δ T
flow) ΔH (enthalpy)
Q (heat) mC p Δ T ΔU (internal
mC v Δ T
T energy)
ΔS (entropy) mC p ln 2 Wn (Work non- P 2 V 2−P1 V 1
T1
flow) 1−n
Ws (Work steady-
nWn
ISOTHERMAL (T=C) flow)
PVT relationship P1 V 1=P2 V 2 mC n Δ T
ΔH (enthalpy) 0 Q (heat) k −n
C n=C v
ΔU (internal energy) 0 1−n
V2 T
Wn (Work non-flow) P1 V 1 ln ΔS (entropy) mC n ln 2
V1 T1
Ws (Work steady- V
−P1 V 1 ln 2
flow) V1
V2
Q (heat) P1 V 1 ln
V1
V
ΔS (entropy) m R ln 2
V1

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