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Learning goal
After studying this chapter, you should be able to:
• describe the methods for the extraction of metals from their ores such as the physical method,
heating alone and heating with carbon
4.3 • recognize that limestone, chalk and marble are different forms of calcium carbonate in nature
4.4 • understand that chemicals may change through the actions of heat, water and acids
4.6 • demonstrate how to carry out tests for the presence of calcium and carbonate in a sample
Chapter 4 Rocks and minerals
Hong Kong Geopark is made up of eight areas distributed across Sai Kung Volcanic Rock Region
2
and Northeast New Territories Sedimentary Rock Region. It covers about 50 km of land.
Hexagonal columns in Sai Kung Volcanic Rock Region Sedimentary rocks in Tung Ping Chau of Northeast New
Territories Sedimentary Rock Region
Rock is usually a mixture of minerals from the Earth’s crust which contains compounds of
different elements. These elements include aluminium, iron, calcium, potassium, sodium,
magnesium, silicon, oxygen, etc. Many different elements and useful chemicals can be extracted
from rocks.
Think about...
What is a rock?
A rock is a solid mass of a mineral or a mixture of minerals.
The rock marble contains mostly the mineral calcite (Figure 4.1). The
chemical composition of calcite is calcium carbonate.
mineral 礦物
I Planet Earth
(a) Bauxite – the main ore of aluminium. (b) Copper pyrite – the main ore of copper.
It is mostly aluminium oxide. It is mostly copper iron sulphide.
Figure 4.3 Some examples (c) Haematite – the main ore of iron. It is (d) Galena – the main ore of lead. It is
of common ores. mostly iron(III) oxide. mostly lead(II) sulphide.
Physical change
When a substance undergoes a physical change, some of its properties
(i.e. appearance and physical state) are changed. However, the substance
does not change to another substance.
Key point
A physical change is a change in which no new substances are
produced.
aluminium oxide 氧化鋁 copper iron sulphide 二硫化鐵銅 haematite 赤鐵礦 ore 礦石
4 4 bauxite 鋁土礦 copper pyrite 黃銅礦 iron(III) oxide 氧化鐵(III) physical change 物理變化
chemical change 化學變化 galena 方鉛礦 lead(II) sulphide 硫化鉛(II)
4 Rocks and minerals
ice
For example, the melting of ice is a physical change. Even though ice
and water look different, they consist of identical particles, i.e. water
molecules (Figure 4.4). Change of state is a common example of physical
change, in which no new substances are produced. See Figure 4.5.
sublimation
solid gas
deposition
liquid water
n
Figure 4.4 Melting of ice is CE2006(II)4
tio
fre
sa
a physical change.
en
zin
g
me
nd
ilin
g
co
ltin
heat absorbed
bo
g
heat given out
Note 1 Some substances such as dry ice (solid carbon dioxide) and iodine,
More examples of physical changes:
• Cutting a piece of paper into two change directly from the solid state to the gaseous state on heating (Figure
halves (change in appearance) 4.6). This kind of change is called sublimation. Sublimation is also a
• Grinding a tablet into powder in a
mortar (change in appearance) physical change. When the vapour is cooled, it changes to solid directly. N1
• Dissolving some white sugar in
water (change in state) evaporating
dish
water
iodine solid
iodine
iodine solid
vapour
Figure 4.6 Iodine solid sublimes to form
vapour on heating. When in contact with a
cool surface, the iodine vapour changes Bunsen
back directly to iodine solid, without flame
passing through the liquid state.
Key point
Figure 4.7 Burning a piece A chemical change is a change in which one or more new substances
of paper is a chemical are produced.
change.
deposition 凝華 ash 灰燼
sublimation 昇華
5 4
I Planet Earth
combustion
spoon
copper
powder brown
chlorine
copper(II)
chloride
(a) (b)
Figure 4.8 The reaction between copper and chlorine is a chemical change.
(a) Heating copper powder to red hot (b) Reaction of hot copper with chlorine to form
brown copper(II) chloride.
Note 3
In the process of gold panning,
since gold has a high density, it
N3
will sink to the bottom on the
pan but other materials such as
sand and mud will be shaken
out of the pan.
Note 4
Detailed description of the Chemical methods used to extract metals from
various chemical methods used
for metal extraction will be their ores N4
discussed in Chapter 10.
Heating the metal ore alone
Some unreactive metals, such as mercury and silver, are extracted by
* Book 1, Section 10.3, p.8 *heating their ores in air. For example, silver can be extracted from
silver oxide (found in some silver ores) by heating it strongly in air.
heat
CE2005(I)2(a) silver oxide silver + oxygen
molten 熔融的
I Planet Earth
Activity 4.1
Limestone cave in Carlsbad, New Chalk cliffs in Sussex, England. Marble canyon in Taroko Gorge,
Mexico. Taiwan.
In other words, limestone, chalk and marble are three different rocks
that contain naturally occurring calcium carbonate. Marble is very
hard. Limestone is hard while chalk is slightly softer.
To make glass
Limestone
cement 水泥
construction material 建築材料
9 4
skeleton 骨骼
I Planet Earth
eventually a piece
rainwater gathers ice of rock breaks off
in a crack
water freezes
and expands
stalactite
stalagmite
CE2004(II)11
CE2011(II)40 Test for carbon dioxide
Limewater turns milky when carbon dioxide is passed into it for a few
seconds (Figure 4.18). This is because carbon dioxide reacts with calcium
hydroxide solution to give a white insoluble solid which is calcium
carbonate.
carbon dioxide
calcium
carbonate
calcium limewater
carbonate limewater
heat
Key point
Carbon dioxide is a colourless gas. It turns limewater milky.
pass excess
pass carbon carbon dioxide
dioxide into it into it
Figure 4.19 (a) Limewater (b) The limewater turns milky when carbon dioxide is passed into it. (c) The milky
limewater becomes colourless when excess carbon dioxide is passed into it.
Solution
(a) The calcium carbonate granules dissolve and colourless gas bubbles are given out.
(b) calcium carbonate + dilute hydrochloric acid calcium chloride + water + carbon dioxide
(c) The calcium carbonate granules do not dissolve in water. A white suspension forms.
carbon dioxide
given off
calcium hydroxide
calcium oxide
CE2008(II)42
solution
(quicklime)
(limewater)
PowerPoint Experiment Investigating the actions of heat, water and acids on calcium carbonate
Video In this experiment, you are going to investigate the actions of heat, water and
acids on calcium carbonate.
CE2009(I)1(b)
CE2011(II)41 Test for the presence of carbonate
Dilute hydrochloric acid is added to a sample. If carbonate is present,
carbon dioxide is produced, which turns limewater milky. See Figure
4.22.
delivery tube
limewater
solid sample
under test
Figure 4.22 Test for the presence of carbonate using limewater test.
Limestone, chalk and marble all give a brick-red flame in the flame
test and positive results in the limewater test.
4 16
4 Rocks and minerals
Key terms
PowerPoint
3. chalk 白堊 8
5. erosion 侵蝕作用 10
6. limestone 石灰石 8
7. limewater 石灰水 12
8. marble 大理石 8
9. mineral 礦物 3
10. ore 礦石 4
12. rock 岩石 3
15. sublimation 昇華 5
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I Planet Earth
Progress check
PowerPoint
Can you answer the following questions? Put a ‘✓’ in the box if you can. Otherwise, review the relevant
part on the page as shown.
Page
1. What is a rock? 3
2. What is a mineral? 3
3. What is an ore? 4
6. What are the common methods for extraction of metals from their ores? 6–7
8. What is weathering? 10
9. What is erosion? 10
10. What are the effects of the action of heat on calcium carbonate? 11
11. What are the effects of the action of water on calcium carbonate? 13
12. What are the effects of the action of acids on calcium carbonate? 13
13. What is the relationship between limestone, quicklime, slaked lime and limewater? 14
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4 Rocks and minerals
Summary
PowerPoint
3. An ore is the type of rock that contains minerals, from which a high proportion of useful
elements (usually contains metal) can be extracted. Some common ores include bauxite, copper
pyrite and haematite.
5. A chemical change is a change in which one or more new substances are produced.
Example: burning a piece of paper
7. Limestone, chalk and marble are common rocks that contain naturally occurring calcium
carbonate.
8. Limestone is a very useful rock. Refer to p.9 for some of its uses.
9. Weathering of rocks is a slow process (usually taking place over thousands of years) in which
exposed rocks are broken down into smaller pieces or changed into other substances.
10. Erosion of rocks refers to a slow process in which weathered rock pieces are transported away
by gravity, wind and water.
12. On strong heating, calcium carbonate decomposes to calcium oxide (quicklime) and carbon
dioxide.
heat
calcium carbonate calcium oxide + carbon dioxide
(quicklime)
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I Planet Earth
13. When calcium oxide (quicklime) is treated with water, it changes to calcium hydroxide (slaked
lime).
calcium oxide + water calcium hydroxide
(slaked lime)
14. imewater is a saturated solution of calcium hydroxide. It is a colourless solution, which turns
L
milky when carbon dioxide is passed into it for a few seconds. It can be used to test for the
presence of carbon dioxide.
calcium hydroxide + carbon dioxide calcium carbonate + water
colourless solution white solid
15. If excess carbon dioxide is passed into limewater, the milky solution will become colourless
because the insoluble calcium carbonate reacts with the excess carbon dioxide and water to
form soluble calcium hydrogencarbonate.
calcium carbonate + carbon dioxide + water calcium hydrogencarbonate
white solid colourless solution
16. Calcium carbonate reacts with dilute hydrochloric acid to give carbon dioxide.
calcium carbonate + dilute hydrochloric acid calcium chloride + water + carbon dioxide
4.6 Tests for the presence of calcium and carbonate in a sample of limestone/chalk/marble
18. Calcium carbonate gives off carbon dioxide when it reacts with dilute hydrochloric acid.
4 20
4 Rocks and minerals
Concept map
PowerPoint
Erosion
Weathering
calcite
methods of
containing
extracting metals
from their ores
• Physical methods
• Heating the metal ore alone
Limestone Chalk Marble • Heating the metal ore with
carbon
(Hints: brick-red, calcite, carbon, carbonate, chalk, electrolysis, erosion, limestone, ores, quicklime,
slaked lime, weathering)
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I Planet Earth
Chapter exercise
Fill in the blanks Section 4.3
chalk marble
8. Limestone, and
Section 4.1
are different natural forms of the same compound,
mineral
1. A rock is a solid mass of or a calcium carbonate.
mixture
of minerals.
Section 4.4
2. Minerals are naturally occurring chemicals that Weathering
elements 9. is a slow process in which
make up the rocks. They may be
exposed rocks are broken down into smaller
or compounds.
pieces.
Section 4.2
Section 4.5
physical
3. Sublimation is a change in
10. Calcium oxide is
commonly known as
which no new substances are produced. quicklimewhile calcium hydroxide is
commonly known as slaked lime .
4. A chemical change is a change in which one or
new substances
more are produced.
11. When carbon dioxide gas is passed into limewater,
milky
5. Silver can be extracted by heating the limewater turns .
silver oxide in air.
Section 4.6
brick-red
6. Lead can be extracted from an ore called 12. Calcium compounds give a
galena
. The extraction method is heating flame in the flame test.
carbon
the ore with .
Practice questions
Questions 13–19: complete the following word equations.
Section 4.2
heat silver oxygen
13. silver oxide +
heat lead carbon dioxide
14. lead(II) oxide + carbon +
Section 4.5
heat calcium oxide carbon dioxide
15. calcium carbonate +
calcium hydroxide
16. calcium oxide + water
calcium carbonate water
17. calcium hydroxide + carbon dioxide +
calcium hydrogencarbonate
18. calcium carbonate + carbon dioxide + water
Section 4.6
calcium chloride carbon dioxide water
19. calcium carbonate + dilute hydrochloric acid + +
4 22
4 Rocks and minerals
23 4
I Planet Earth
Structured questions
Section 4.4
29. The following picture shows a special rock in Taiwan which contains
limestone. It is slowly worn away by weathering.
(a) Rainwater can attack rocks and cause weathering. Explain briefly with
the help of word equations.
(b) State THREE uses of limestone.
29. (a) Rainwater is slightly acidic because carbon dioxide in air dissolves slightly in it, forming
carbonic acid.
carbon dioxide + water carbonic acid
The carbonic acid formed reacts with calcium carbonate in limestone, forming calcium
hydrogencarbonate.
calcium carbonate + carbonic acid calcium hydrogencarbonate
The calcium hydrogencarbonate is soluble in water and thus the rock is slowly worn away.
(b) To make cement/to make glass/to build statue/as construction material for some footpaths/
to neutralize acidic soil (Any THREE)
Section 4.5 30. (a) Calcium carbonate
30. A student is going to carry out an experiment to demonstrate the thermal decomposition of limestone.
heat
(a) Name the major component of limestone. 30. (b) calcium carbonate calcium oxide + carbon dioxide
(b) Write a word equation for the thermal decomposition of limestone.
(c) A gas will be given off during thermal decomposition of limestone. Draw a labelled diagram of the
set-up used to test for this gas. 30. (c)
heat
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4 Rocks and minerals
31. A flow diagram below shows the chemical changes involving calcium carbonate.
Calcium hydroxide
solution
31. (a) Limestone/marble/chalk (Any ONE)
(b) A is calcium oxide and B is carbon dioxide.
(a) Name ONE common rock which contains calcium carbonate.
(c) (i) Quicklime
(b) What are A and B? (ii) Limewater
(d) The calcium hydroxide solution turns milky.
(c) What are the common names for calcium hydroxide + carbon dioxide calcium carbonate + water
(i) A? (e) The calcium hydroxide solution turns milky and then becomes colourless again
quickly. This is because the insoluble calcium carbonate reacts with the excess
(ii) calcium hydroxide solution? carbon dioxide and water to form soluble calcium hydrogencarbonate.
(d) State the expected observation when B is passed into calcium hydroxide solution, and write a word
equation for the reaction involved.
(e) What would be observed if excess B is passed into calcium hydroxide solution? Explain your answer.
Section 4.6
* 32. You are given a sample of crushed chalk. Describe briefly the procedure of the flame test used to show the
presence of calcium in the sample.
32. Moisten a clean platinum wire with concentrated hydrochloric acid. Then, dip the wire into the sample of crushed chalk. After that, heat the
end of the wire strongly in a non-luminous flame. If calcium is present in the sample, a brick-red flame is seen.
25 4
I Planet Earth
A. (1) only 3
7. If 100 cm of water can dissolve a maximum of
B. (2) only
30 g of salt Y at room temperature, which of the
C. (1) and (3) only
A following would produce a saturated solution?
D. (2) and (3) only
3
(1) Add 20 g of salt Y to 50 cm water at room
3. Which of the following statements does NOT temperature.
describe a chemical property? 3
(2) Add 50 g of salt Y to 100 cm water at room
A. Iron rusts in air. 3. Sublimation of dry ice is a temperature.
physical change. 3
B. Dry ice sublimes. (3) Add 40 g of salt Y to 200 cm water at room
C. Oxygen supports burning. temperature. 7. If 100 cm3 of water can
B
D. Sodium reacts with chlorine. A. (1) and (2) only
dissolve a maximum of 30 g
of salt Y, in other words,
B. (1) and (3) only 3
50 cm of water can dissolve a
4. Which of the following statements about nitrogen
C. (2) and (3) only maximum of 15 g of salt Y or
are correct? 3
A
D. (1), (2) and (3) 200 cm of water can dissolve
(1) It is a mixture. a maximum of 60 g of salt Y.
(2) It is one of the components of air. 8. To obtain sodium chloride from sea water, the
(3) It cannot be broken down into simpler methods that need to be used include:
substances by electrolysis. (1) Filtration
A. (1) and (2) only 4. (1): Nitrogen is an element, (2) Evaporation 8. The sample of sea water is first
which is a pure substance. filtered to remove any insoluble
B. (1) and (3) only (3) Distillation substances. Common salt can
C. (2) and (3) only A. (1) and (2) only then be separated from the filtered
C
D. (1), (2) and (3) B. (1) and (3) only sea water by evaporation.
16. Which of the following combinations of test and 18. Solid P is tested and the results are shown below.
observation can indicate that the gas sample
contains carbon dioxide? Test Observation
Test Observation
A golden yellow flame
A. Test with a burning Burning splint burns Flame test
can be observed.
splint with a ‘pop’ sound
B. Test with limewater Limewater turns Adding dilute
No observable change.
milky hydrochloric acid
C. Test with a glowing Glowing splint
A white precipitate
splint relights Silver nitrate test
forms.
D. Test with dry Cobalt(II) chloride
cobalt(II) chloride paper turns from blue
Solid P may contain
paper to pink
B
A. calcium carbonate.
16. Refer to p.12 of chapter 4 for details.
B. sodium chloride.
17. Which of the following results indicates that a C. sodium carbonate.
B
sample of white solid contains carbonate? D. calcium chloride.
A. It produces a brick-red flame in the flame 19. Which of the following processes produce a white
test. precipitate?
B. It does not react with water.
(1) Passing carbon dioxide into calcium hydroxide
C. Gas bubbles of carbon dioxide are given off
solution.
when dilute hydrochloric acid is added to it.
(2) Adding silver nitrate solution to sea water.
D. It does not turn dry cobalt(II) chloride paper
(3) Adding water to anhydrous copper(II)
from blue to pink.
sulphate.
C
17. The carbonate in a sample reacts with dilute
A. (1) and (2) only
hydrochloric acid to give carbon dioxide.
B. (1) and (3) only
18. Solid P gives a golden yellow flame in the flame test.
C. (2) and (3) only
This shows that solid P may be a sodium-containing
A
compound. D. (1), (2) and (3)
Solid P has no reaction with dilute hydrochloric acid. 19. (1): Carbon dioxide reacts with calcium hydroxide solution to give a
This shows that P does not contain carbonate. white precipitate of calcium carbonate.
The positive result of silver nitrate test shows that P (2): Silver nitrate solution reacts with the chloride in sea water to give
contains chloride. a white precipitate of silver chloride.
Structured questions (3): Water only turns white anhydrous copper(II) sulphate to blue. No
white precipitate would form.
20. The table below compares the amount of dissolved substances in Dead Sea water and ordinary sea water:
Amount of dissolved
254 g 35 g
substances in 1000 g of water
(a) Suggest ONE reason why the Dead Sea water contains a much higher amount of dissolved substances
than that of ordinary sea water in 1000 g of water. Hence, state whether Dead Sea water or ordinary sea
water is a more concentrated solution.
(b) Name ONE compound found in the dissolved substances in Dead Sea water.
(c) Can we obtain pure common salt crystals from Dead Sea water by crystallization? Explain your answer.
20. (a) This may be because Dead Sea water evaporates more quickly than ordinary sea water. Hence, Dead Sea water is a more concentrated
solution. OR
This may be because there are no rivers connected to drain the Dead Sea water.
(b) Sodium chloride/magnesium chloride/calcium chloride, etc. (Any ONE)
(c) We cannot obtain pure common salt crystals from Dead Sea water by crystallization because Dead Sea water contains other salts
4 28 apart from sodium chloride. These salts will crystallize out together with common salt from Dead Sea water.
I Planet Earth
21. Sea water can be converted to useful chemicals X, Y and Z by the following experimental set-up.
(a) What are X, Y and Z?
X Y
(b) State whether the above process is a physical
change or a chemical change. Explain your
answer.
(c) Write a word equation for the above conversion
process. Z
(d) State the potential hazard of X, Y and Z graphite electrode graphite electrode
respectively.
21. (a) X: hydrogen; Y: chlorine; Z: sodium hydroxide (solution)
(b) The process is a chemical change because new substances
(hydrogen, chlorine and sodium hydroxide) are produced during
the electrolysis of sea water. direction of
electron flow
electrolysis
(c) sea water hydrogen + chlorine + sodium hydroxide
(d) X: flammable; Y: toxic; Z: corrosive
22. Oxygen, nitrogen and hydrogen are common elements in our daily life.
(a) Suggest ONE daily use of nitrogen and ONE daily use of oxygen.
(b) (i) When some oxygen and some nitrogen are put together inside an enclosed container, are the
contents of this container a pure substance? Explain briefly.
(ii) Is the process in (b)(i) a physical change or a chemical change? Explain your answer.
(c) (i) When hydrogen burns in oxygen, a product is produced. Name the product and state whether it is
an element, a mixture or a compound.
(ii) Is the process in (c)(i) a physical change or chemical change? Explain your answer.
(d) (i) Name the industrial process of separation of oxygen and nitrogen from air.
(ii) Oxygen and nitrogen can be separated due to the difference in one property of the gases. Name
this property and state whether it is a physical property or a chemical property.
23. Lime kilns are the constructions in which limestone is heated and decompose to quicklime.
(a) Write the chemical name of the major chemical constituent in
waste gases limestone
(i) limestone. 23. (a) (i) Calcium carbonate
(ii) Calcium oxide
(ii) quicklime.
(b) Write ONE word equation for the process occurring in lime
kilns. heat
(b) calcium carbonate calcium oxide + carbon dioxide
(c) Suggest ONE of the major components in the waste gases.
(d) State ONE use of quicklime. (c) Carbon dioxide hot air hot air
(d) It can be used to neutralize acidic soil.
22. (a) Nitrogen: used to fill food packets/as a refrigerant/making ammonia (Any ONE)
Oxygen: to support breathing for divers, fire-fighters, etc./to help patients with breathing
difficulties/to support burning of fuels (Any ONE)
(b) (i) No. Oxygen and nitrogen inside the container mix to form a gaseous mixture. A mixture quicklime
is an impure substance.
(ii) It is a physical change as no new substances are produced during the process.
(c) (i) The product is water. It is a compound.
(ii) It is a chemical change as a new substance, water, forms during the process.
(d) (i) Fractional distillation of liquid air
(ii) This property is boiling point, which is a physical property of substances.
29 4
I Planet Earth
24. (a) Since the sample gave a brick-red flame in the flame test, the sample may contain calcium.
Since the sample evolved carbon dioxide when reacted with dilute hydrochloric acid, the sample may contain carbonate.
24. A sample of white powder which is a mixture of two compounds was tested and the results are shown
below. Since the sample gave a positive result in the silver nitrate test, the sample may contain chloride.
Thus, the sample should be a mixture of calcium carbonate and calcium chloride.
Test Observation
(a) What can be concluded from the results of the above tests? Explain your answer.
(b) Suggest, with the aid of TWO labelled diagrams, how you would separate out the two compounds from
the mixture.
(c) A student deduced that the colourless gas evolved from the sample after addition of dilute hydrochloric
acid is carbon dioxide.
(i) Suggest a test for carbon dioxide.
(ii) State the expected observation and write a word equation for the reaction involved.
* 25. You are given two samples, both in the form of a white solid. One of the samples is potassium chloride and
the other is calcium carbonate. Suggest THREE methods to distinguish the two samples and state the
expected observations.
24. (b) Add distilled water to the mixture to dissolve the calcium chloride.
Filter the mixture, the residue left on the filter paper is calcium carbonate.
filter paper
calcium carbonate
filter funnel
evaporating dish
calcium chloride solution
wire gauze
heat tripod
31 4
I Planet Earth
Structured questions
9. Explain why filtration can be used to remove mud
particles from muddy water, but cannot be used to
remove sodium chloride from sea water.
(3 marks)
(HKCEE 2003 Paper 1 Q7(c))
Gas Solid
4 32