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Journal of Building Engineering 31 (2020) 101323

Contents lists available at ScienceDirect

Journal of Building Engineering


journal homepage: http://www.elsevier.com/locate/jobe

A review of the factors affecting the properties and performance of hemp


aggregate concretes
M.P. Sa erez, Professor a, *, M. Brümmer b, 1, J.A. Dura
�ez-P� �rez c, 2
�n-Sua
a
Department of Architectural Constructions, Advanced Technical School of Building Engineering, University of Granada, Spain
b
Program in History and Arts (Territory, Heritage and Environment), University of Granada, Spain
c
University Lecturer, Department of Sculpture, Faculty of Fine Arts, University of Granada, Spain

A R T I C L E I N F O A B S T R A C T

Keywords: New energy-efficient materials are increasingly used in architecture and civil engineering today. Many of these
Hemp concrete are based on the reuse of plants and plant residues from industry and agriculture for the production of bio-
Hemp shives sustainable insulation materials, and as aggregates in concretes. This paper presents the results of our study of
Hemp fibre
research into hemp concrete, an emerging material in the green building sector, since it first appeared about
Green building
Agricultural waste
twenty-five years ago to the present day. The study centres on a growing bibliography over this period,
Hemp aggregates emphasizing some fundamental parameters of hemp raw materials and related building materials, the binders
used in the production of hemp aggregate concretes and assessments of different aspects of their performance.
The most important properties of hemp concrete vary according to the quality of the plant aggregates, the choice
of binders (typically aerial or hydraulic lime), the proportions of the raw materials and the application tech­
niques. Organic aggregates are less stable than inorganic aggregates and are therefore more difficult to use in a
concrete mix with both inorganic and organic binders. Among other reasons, this is due to the disproportionate
amount of water required in the mixing of plant-based concretes and to the release of organic compounds, which
can have serious effects on the hardening process. This problem was identified in scientific studies on the use of
hemp concrete in sustainable, bioclimatic construction, whether applied as a semi-liquid mass or as a precast
element. This new biomaterial offers excellent results in terms of its application on site and has important
physical properties, such as high durability and easy conservation. This study seeks to provide a useful tool for
future research into sustainable building materials, better use of available energy and plant-based resources and
more efficient recycling of the waste produced by human activities.

1. Background and introduction is not only related to the production of building materials and technical
installations, construction, operation, renovation and demolition, as the
Global carbon dioxide levels have risen by over 39% over the past energy used to power and heat buildings during their life-cycle must also
century [1] causing visible changes in the earth’s climate. Climate be taken into account [3,5]. The building sector must therefore urgently
change is caused by human activity, within which building is frequently address the issue of greenhouse gas reduction and encourage the use of
reported as one of the highest energy consuming sectors [2,3]. This has energy-efficient building materials that can be manufactured in an
coincided with large-scale extraction of virgin natural resources since environmentally-friendly manner [2,5,6] with the additional objective
the beginning of the industrial revolution almost to the point of of reducing dependence on fossil fuels. Moreover, significant correla­
exhaustion [4]. The voracious appetite of the building sector in its tions have been found between energy consumption and the symptoms
broadest sense (40% of the world’s energy, 25% of global water and 40% produced by “unhealthy building syndrome”, including various allergies
of global resources – according to the UN Environment Program, 2016) [7], so highlighting the need to take a more user-friendly approach [8].

* Corresponding author. Departamento de Construcciones Arquitect� onicas, Escuela T�ecnica Superior de Ingeniería de Edificaci�
on, Universidad de Granada, C/
Severo Ochoa, s/n; 18071, Granada, Spain.
E-mail addresses: mpsaez@ugr.es (M.P. S�
aez-P�erez), mbrummer@correo.ugr.es, info@cannabric.com (M. Brümmer), giorgio@ugr.es (J.A. Dur� an-Su�
arez).
1
Cannabric, Ca~nada Ojeda 8, 18500, Guadix, Spain.
2
Departamento de Pintura y Escultura, Facultad de Bellas Artes, Universidad de Granada, Avda. Andalucía s/n, Edif. Aynadamar, 18071, Granada, Spain.

https://doi.org/10.1016/j.jobe.2020.101323
Received 8 October 2019; Received in revised form 2 March 2020; Accepted 2 March 2020
Available online 10 March 2020
2352-7102/© 2020 Elsevier Ltd. All rights reserved.
M.P. S�
aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

Fig. 1. Hemp concrete constructions built with pre­


made building blocks (A) and cast, compacted load­
bearing, hemp-clay concrete walls (B). Building
blocks made from hemp shives (2–25 mm) and a clay
binder (C) or hemp shives (2–25 mm) and a lime
binder, with or without addition of mineral pigments
(D). (E) and (F) show different views of a building
made with non-loadbearing, casted hemp-lime con­
crete walls after 20 years exposure to weathering
conditions in Switzerland. (G) Sprayed application of
hemp concrete as an outer coating.

This has led, especially over the last decade, to increasing research already being tested at that time. In 1941, for example, the New York
aimed at developing bio-based, affordable construction technologies Times reported that Henry Ford had developed a bio-plastic for car
[9–11]. One example is the wide range of innovative applications of bodies [25] containing 30% soy flour and a liquid bio-resin and 70%
natural fibres [12,13] that have been created for the green building cellulose from slash pine, straw, hemp and ramie fibre, which was
sector [14,15] amongst others, without compromising on contemporary lighter and had better mechanical performance than steel. Studies
comfort standards and performance specifications [5]. This review fo­ confirmed [26] that the mechanical properties of hemp fibre polymer
cuses on a fibre crop with multiple advantages, which therefore has composites were superior to those made with other natural fibres such as
great economic potential [12,13,16,17]: Hemp (Cannabis Sativa L.). kenaf, coir, sisal and jute. Hemp fibre composites showed the highest
Although its most plausible origin and centre of diversity was in Central tensile (52 MPa) and flexural strength (54 MPa), comparable with glass
Asia [17,18], different authors have concluded that the Cannabis species fibre composites (60 MPa), while requiring significantly lower power
has been grown on the Eurasian continent for at least 6000 years, as consumption and greenhouse gas emission in their manufacture [25]. As
confirmed by archaeological findings [16,17]. Cultivation may even hemp fibre composites can withstand high levels of mechanical and
have begun 10,000 years ago [15,17,18] in parallel with the climatic thermal stress, they have been used in many recently developed prod­
and behavioural changes that took place at the beginning of the ucts in sectors such as aeronautics and space travel [27].
Neolithic period. This crop was farmed for three main purposes: the The long-standing divide between agriculture and the building in­
strong and durable fibre of its stalks; its nutritious, oil-rich seeds; and the dustry during the past century spurred the development of non-
psychoactive and medicinal compounds produced by the glandular hair renewable resources and energy-consuming insulation materials such
on the flowers of the female plants [18,19]. It is known that [18] “Early as glass and rock wool [28]. The result is that today natural fibres have
humans used both, C. sativa and C. indica for fibre and seed but only only a very small share of the insulation market in Europe (e.g. 0.5% in
C. indica has a history of drug use”. The versatility of the annual, fast Germany) because they cost roughly twice as much as petroleum or
growing [20,21] Cannabis plant and its ability to adapt to different cli­ mineral based products [28,29] with comparable thermal conductivities
mates and soil types coupled with its limited need for fertilizers [13], its [28]. Numerous studies have revealed the insulation capacities of con­
biocide-free growth and its important role in crop rotations [13,17,22] cretes containing plant fibre and the energy savings they could bring
are all important factors in its worldwide spread and cultural impact of [30–32], compared to concretes composed of synthetic fibres or min­
this plant, as confirmed by abundant archaeological evidence [12,23] erals. Hemp fibre has the potential for various new technical applica­
and written historical testimonies [17]. It was not until the beginning of tions (e.g. the automotive and building industries, industrial design) but
the last century that, in a process led by the United States, laws started to represents an average of only 20–35% of the stem mass [20], while raw
limit and obstruct the farming [24], selection and crossing of Cannabis. materials based on the woody core of the stem section (hemp shives, also
This not only led to the emergence of a black market in several countries called hurds) are about twice as abundant and cost about half as much as
but also delayed the development of green technologies that were raw bast fibres [29].

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M.P. S�
aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

To this end research focuses on hemp concrete as part of an inno­


vative bio-based economy [2] for building applications, in which, above
all, hemp shives are used as a substitute for the usual mineral aggregates,
along with a binder (mainly lime) and in rare cases additional com­
pounds and additives [33,34]. Hemp concrete began to be used in walls,
slabs and plasters (historic timber buildings, new construction and
repair works) in the early 1990’s in France [34], which then emerged as
the main producer and transformer of hemp in the European Union [17].
As a supplementary example of what was previously reported in timber
frame constructions with tamped hemp concrete infill [33,35,36], Fig. 1
shows two buildings with load-bearing hemp walls, constructed with
prefabricated blocks of hemp concrete (A) and cast, compacted hemp
concrete (B) as well as building blocks made with hemp concretes mixed
with either a clay binder (C) or with NHL3.5 lime (D). (E) and (F) show a
non-loadbearing building with an internal timber structure with cast,
non-rendered hemp-lime concrete. Fig. 2. Section of the stem of the hemp plant and its anatomical parts. A. Bark
It is estimated that about 5000 tons of hemp are used each year in the (composed of epidermis, bast fibre and cambium) B. Woody core (composed of
construction sector in France today. In 2006 it was reported that over xylem and pith). C. Hollow space.
4000 tons were consumed in the same sector with an overall value of 35
million Euros [35]. However, only 15% of the 2010 harvest of hemp common lime binders were used, dry density values ranged from 250
shives in Europe was used in construction [29]. Hemp building materials kg/m3 to 660 kg/m3 [20]. Dry densities were over 410 kg/m3 achieved
have so far been used in just a few large commercial projects [36]. In with stabilized clay [53] and of over 1040 kg/m3 with MgO-cement
order to ensure they move into mainstream production and use, it is [53]. The densest hemp shive concretes made with these last two
important for building-product and green building designers to under­ binders reached over 1100 kg/m3 and 1150 kg/m3 [54,55]. Different
stand these innovative materials in order to be able to optimize their formulations with varying final densities have been used in a range of
thermal, acoustic, hygrothermal and mechanical performance in each applications, e.g. concretes and mortars for walls, plasters, floor-slabs,
context. slabs and roof insulation [49]. While metallic, mineral and polymeric
While Cannabis is grown in 86 countries worldwide [37,38], about fibres have been added to concretes since the 1920’s for mechanical
30 countries have licensed cultivation of fibre-type hemp varieties [39] reasons [56], e.g. to avoid multiple cracking [57], research on hemp
with maximum Delta 9-THC levels of 0.2% or 0.3%, almost half of which concrete has sought to create a multi-performance material that im­
have signed up to this movement in the last 25 years. Given the fact that proves the thermal, hygrothermal and acoustic comfort of the building
very few genotypes have such a low percentage, the possibility of envelope. The plant aggregate itself has a lesser role as reinforcement
extending this limit to 0.6%–0.8% is currently being studied in several due to its porosity [56]. Natural fibres and aggregates of plant or animal
countries, although Switzerland has gone a stage further allowing THC origin have been added to natural binders since ancient times [56] in
levels of up to 1%. Recent laws that regulate the cultivation of Cannabis order, for example, to prevent retractions in clay-based mortars and
exclusively for the production of cannabinoids or seeds are unsustain­ concretes [58–60], although they were often only added in small pro­
able in that a lot of agricultural waste is produced. The best application portions [43,61–64]. While numerous plant species have been recently
involves the utilization of all the plant’s resources [4,17], so reducing rediscovered as additives in green concretes [15,44,65], among which
the impact on the environment [17]. Several authors link the presence of “shives” from sunflower stems and flax stems [8,49] are the most similar
psychoactive components in the plant [40] with a specific deviation of to hemp shives, hemp is particularly attractive from a business point of
agricultural and innovative technical development with hemp towards view because it has both fibres and abundant woody core. Moreover, the
this goal [13,19,38]. Certainly, there is a need for updated legal regu­ fact that hemp shives show strong inter-granular coherence in a dry state
lation in many countries to explore alternative, adaptive models that [66] and that they vary considerably in size allows them to be added to
take into account the historical, ecological and cultural role played by the concrete matrix in proportions equivalent to their bulk density, so
Cannabis in each region. replacing all of the mineral aggregate.

2. Classification and definition of hemp aggregate concrete 2.2. Cannabis stem and its key components

2.1. Conceptual context The stem of the hemp plant is divided into separate parts with
different chemical compositions. As seen in Table 2, the outer section
Fibre crops, and the industrial [41] and agricultural waste they contains long liberian fibres with a low lignin content compared to that
produce [42], can be used as a substitute for mineral aggregate in con­ of the woody core. The liberian fibres vary in length between 5 and 50
cretes, as raw fibre reinforcement, cellulose fibre reinforcement [43–45] mm and they are around 40 μm wide, while the cellulose fibres from the
or in the form of ash, acting as an additive with pozzolanic reactivity [6]. woody core are around 0.55 mm long and about 22 μm wide [67]
Prior to the recent development of applications in green concrete, ani­ (Fig. 2). For important fibre applications, varieties with tall stems, few
mal bedding and biomass [29,46], hemp shives (the chopped woody inter-nodal spaces, small numbers of branches and a small woody core
core of hemp stalk or by-product of hemp fibre decortication) were are used.
either burnt or land-filled, as happens all over the world with numerous According to Ref. [68], some of the best known varieties are Cannabis
other agricultural waste products [6]. An emerging solution to postpone sativa (developed into industrial hemp with a wide range of applications
the reintroduction into the atmosphere of the CO2 sequestered by these other than drug use), Cannabis indica (used in drug, medical and fibre
plants [4,6,42] are building envelopes that store carbon dioxide [15,47] applications) and Cannabis ruderalis (regarded as a wild strain and
and are made with bio-aggregate concretes, e.g. concretes that combine therefore not normally considered for industrial applications but valued
hemp shives with a mineral binder and water [48,49]. The result, after as an aromatic plant).
hardening and drying, is a multi-porous [49] insulating material with Fibre Hemp varieties are often not morphologically distinguishable
dry densities of at least 175 kg/m3 with a silica sol treatment [50] and from varieties grown for drug consumption [4], in that both genotypes
163.60 kg/m3 [51] or 182 kg/m3 [52] with a starch binder. When are very similar [17]. The best ways to distinguish them are by seed size,

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M.P. S�
aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

Table 1
The main components of fibre hemp in percentage terms.
Component % References

Holocellulose 90.3 [72]


Water soluble constituents 1.2 [72]
Klason lignin 4.6 [72]
Acid-soluble lignin 1.5 [72]
Removable lipophilic constituents 0.5 [72]
Ashes 2.0///2-5 [72]///[73]

Table 2
The main chemical components of fibre hemp in percentage terms referred to
mass fractions.
Component Hemp Stem* Hemp Fibre** Hemp Core References

Cellulose – 67 – [28,74] Fig. 3. Hemp shives (CP) in bulk (A) and scanning electron microscope (SEM)
– 60–67 40–52 [28,75] pictures with different magnifications of longitudinal section (B) and cross
– 57–77 40–48 [76] section (C) of a hemp shive particle. Adapted from Ref. [95].
aprox. 59-67 – – [13,28]
– 55 48 [77,79]
– 55 44 [77,79]
proportions of which vary from one species to the next, as do the posi­
– 56.1 – [77,80] tion and function of the cells. The cells also have aromatic compounds
– 58.7 – [77,81] associated with lignins, pectins, waxes, fats and lipids. Ash or mineral
Lignin – 4 – [28,82] compounds can be extracted by calcination [70]. Natural polymers are
3 [28,74]
made of cellulose, hemicellulose and lignin [71]. These facts also
– –
– 5–9 21–24 [76]
– 3–14 22–30 [28,75] explain the specific bearing strengths and characteristics of hemp con­
aprox. 54-62 – – [13,28] cretes. The most common properties of the raw material are directly
– 4 28 [77–79] related to the morphological structure and chemical composition of the
6 [77,80,81]
– –
plant fraction. However, as shown in the following tables, there are a
Hemi-cellulose – 16 – [28,75]
– 9–14 18–24 [76]
wide range of existing references. Typical composition data has been
– 16 12 [77,78] obtained from various sources. But in addition, and as indicated by
– 16 18 [77,79] Ref. [28], theoretically, the plants produced by each grower may vary
– 10.9 – [77,80] due to fermentation, fractionation or alteration of atmospheric condi­
14.2 [77,81]
tions. These changes in the plant can affect its performance as an insu­
– –
Pectin – 1.0 – [28,74]
– 18 6 [77,78] lation material. Table 1 shows the different components of hemp stem
– 14 4 [77,79] and their respective percentages.
– 20.1 – [77,80] Table 2 offers a non-exhaustive overview of the values cited in the
16.8 [77,81]
– –
existing body of literature for the distributions of the primary constit­
Fat and wax – 0.7 – [28,74]
– – 0.5–1.0**** [28,83]
uents of the cell walls of hemp plants likely to produce aggregates that
– – 0.3–1.4***** [28,83] can be used in construction materials and which have now been studied
– 3 4 [77,78] to a relatively advanced level.
– 1 1 [77,79] Table 3 shows the average contents of hemp shives in metals and
7.9 [77,80]
other elements.
– –
– 4.3 – [77,81]
Ash – 4 2 [77–79] For construction purposes, the hollow hemp stem of 1–5 m in length
consists of two main components: the bark on the outside of the vascular
*The variation interval refers to the change of chemical composition due to
cambium of its grooved cross section and the woody core on the inside.
changes in the maturity of the stem.
These two raw materials vary not only in terms of quantity (there is
**There is no available separate data for un-retted and retted fibre.
***Depends on the retting degree. roughly twice as much core as bark) [84] but also show significant
****Spring harvested. morphological and chemical differences that also depend on the harvest
*****Autumn harvested. time [22,85]. Lower bark fractions (minimum 10–15%) were found in
drug strains [86], while hemp fibre usually has bark fractions of at least
terpenophenolic compounds [38] and plant height [39]. The most 20% [20]. The thickness of the fibre normally decreases towards the top
important components of the lignocellular walls of the plant aggregates part of the stem [87] and genotypes with longer vegetative cycles pro­
used in hemp concrete are cellulose, hemicelluloses and lignin [69], the duce more bark [17]. Fibre content [38] and tensile strength [88] are

Table 3
Contents in metals and other elements in mg/kg of hemp stem or percentage of hemp shives.
references [72] [73] [72] [73] [72] [73]

mg/kg % mg/kg % mg/kg %

Al 240.5 – K 2103.3 0.2–0.5 S 371.7 –


B 6.5 – Mg 480.0 0.006–0.02 Sr 17.0 –
Ba 6.6 – Mn 47.1 – Si 19.5 –
Ca 5330.0 1.5–3 Na 26.7 – Ti 3.7 –
Cr 2.9 – Ni 1.2 0.4–1 Zn 4.5 –
Cu 2.0 – P 666.7 – F – –
Fe 207.8 – Pb <1.0 – C – –

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aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

Table 4
Densities and/or mechanical and thermal properties of hemp concretes with different binders (CL ¼ hydrated lime, NHL ¼ natural hydraulic lime; PC ¼ Portland
cement; NC ¼ natural cement), containing either hemp shives or hemp shives and fibres.
binders of hemp concretes densities (kg/m3) compressive flexural thermal specific heat ref.
of tamped, sprayed (*) or compressed (¼) hemp strength (MPa) strength (MPa) conductivity (W/ capacity (J/
concretes with shives or shives and fibres (~) mK) kgK)

CL 374-416 (*) 0.12–0.13 [100]


450 (*) 0.15 [100]
377 0.13 [100]
400 0.10 [92]
298.1–394.8 0.09–0.12 300–469 [158]
300 (¼) 0.10 0.07 1700 [140]
CL þ pozzolanic additive 0.29–0.39 0.06–0.09 [160]
549.7–604.5 0.77–1.14 0.11–0.13 [100]
508 0.14 0.13 0.13 1627 [157]
NHL 450 1.97 0.11 470 [133]
formulated binder (CL þ NHL or 790–1100 0.30–0.73 0.07–0.11 [113]
PC and pozzolanic additive) 587-733 (~) 0.15–0.83 [144]
391-485 (*) 0.18–0.80 [114]
430-607 (*) 0.83–1.21 [114]
417-551 (*) 0.18–0.54 [114]
NC 422.1–488.88 0.32–0.46 [9]
335–327 0.1 [159]
CL þ NHL 0.53 [112]
PC 0.55–2.14 [112]
PC þ chemical pretreatment 819–1055 1.79–8.03 0.1–0.17 [122]
gypsum 0.71 [112]
clay 373.71–509.48 0.39–0.48 [53]
stabilized clay 410.28–577.41 0.47–0.68 [53]
1078.5–1187.81 (~) 1.26–1.33 0.55–0.58 [55]
1054.34–1124.14 1.18–1.20 0.43–0.45 [55]
1100 (¼) 1.40 0.61 0.19 1113 [73]
MgO-cement 1040–1110 1.86–2.73 0.07–0.08 [113]
1040–1150 2.73–5.20 0.11–0.12 [54]
silica sol 175–240 0.49–1.05 0.05–0.06 762–1050.28 [50]
starch 182–188.30 0.57–0.63 0.06–0.07 1264–1288 [52]
163.60–174.30 0.03–0.13 [51]

both increased by higher plant density. The hemp fibres with the best material [98,99] when used in hemp concrete. The result is that the
mechanical properties are reported to be in the middle part of the stem relative impact of all these different parameters makes formulations
[89] with a tensile strength ranging from 300 to 800 MPa [90]. The with plant-based aggregates more difficult to control than those
physical and mechanical properties of the stem material depend on the involving mineral or synthetic aggregates.
variety, section height and diameter, but generally increase towards the
bottom of the stems [91]. The mechanical properties of the porous
woody core, with a density of 320 kg/m3 [92], are quite different from 2.3. Binders
those of both hard and soft woods [89]. Several differences have been
found between C. indica and C. sativa species in terms of wood anatomy, The choice of binder is one of the biggest challenges in the design of a
wood cell distribution, cell wall thickness and cell size [17,93–95]. See hemp concrete, in that it has an important role in the formulation. Either
Fig. 3. The absorption capacity is generally greater in the core than in fluid or mixed with water its function is to envelop and bind the coarse
the bark [93]; a further study revealed that hemp core porosity is in the and fine particles of the aggregate together. The type of binder and the
region of 60%, formed by parallel tubes of more or less 0.08 mm in dosage used can affect the mechanical [49], thermal [100], hygro­
diameter [47,96]. Hemp core particles can be identified by more hy­ thermal [101] and acoustic [66,102] performances of the
drophobic cells in the xylem and hydrophilic cells in the pith. The latter bio-aggregated concrete, some of which are correlated with its dura­
are responsible for a quick initial water intake in the first 2 min of bility. The binders discussed in this article are those referred to in the
submersion (during kneading of the concrete hemp shives can absorb 3 available publications about hemp concretes. The goal of any researcher
times their own weight in water), while xylem cells encourage water is to use the precise quantity of binder needed to obtain optimum results
intake over a long period [96] that can last for days or weeks [55] in one in one or more of the aforementioned aspects. Other aspects investigated
single hemp shive and therefore has consequences for the hydration of include durability when exposed to fire [103], climate conditions [104],
the binders. Other researchers [88] found that water and alkali-soluble mechanical stress [105] and microorganisms [106]. The binder and its
components increase with the maturity of the plant. In fact, the release formulation also have an important influence on the final cost and the
of the polysaccharides present in the hemicellulose, which is more life-cycle impact [107] of a hemp concrete (e.g. embodied energy and
abundant in the hemp core (31%) than in the bark (13%) [22], is CO2 emissions in its manufacture, the possibility of reabsorption of part
associated with a delay or hindering of the setting process with of the carbon dioxide during the hardening process, transport, recycling,
numerous binders in hemp concrete formulations [56]. Macroscopic and etc.). Hemp concrete is frequently reported as a hemp-lime material [33,
microscopic alterations in the plant may be produced by any of the 35,36,108] and the binder most commonly used in combination with
aforementioned parameters (density, porosity, mechanical properties hemp shives is (powdered) aerial lime, also known as hydrated lime,
etc.), together with natural variations within each plant [97] regardless undoubtedly an interesting option given that its porosity does not
of the growing techniques [17], the geographical and growing condi­ detract from the capacity of hemp to absorb, transfer and change the
tions [90], and the retting and decortication methods [25]. These al­ phase of water in vapour and liquid forms. When used in thick walls (e.g.
terations may affect the physical and mechanical properties of the plant external walls), aerial lime formulations certainly harden better in
combination with pozzolanic aggregates [56,109], as the carbonation

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M.P. S�
aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

gypsum [45,112]. See Fig. 4. Apart from diverse chemical pretreatments


and retting methods [123], in order to avoid the consequences of the
interactions observed between hemp shives and organic or mineral
binders [119,122] due to the partial removal of hemicellulose and
lignin, which also reduces the absorption behaviour of hemp shives
[124], lime water pretreatment and moist curing proved unsuccessful at
reducing the delay in the hardening of a hemp-lime concrete [42].
However, calcium ions in the Ca(OH)2 solution react with the pectin
contained in the fibres, forming stable surface structures, a promising
method for improving the mechanical results of hemp concrete [125].
Moreover, non-chemical treatment, involving the previous washing of
the hemp material with water, significantly improved the hydraulic
activity of a cement-based hemp concrete [121], although complete
hydration was not achieved. Hydration of the cement could be further
improved by additional NaOH solution washing [126]. The hindering of
the hydration of the different cement or cement-lime binders is reported
to be more evident when the water obtained by submersion of the shives
is used rather than when the shives are used directly. Plant materials
rich in silicon, such as hemp stem and rice straw, have recently been
Fig. 4. Microstructure of hemp hurds and composite with different binding proposed for possible use with geopolymer binders to form light con­
material: A – hemp hurds ( � 100), B – hemp hurds with cement ( � 10000), C –
cretes by formulating aluminosilicate materials (e.g. fly ash or furnace
hemp hurds with starch ( � 10000), D - hemp hurds with clay ( � 10000).
slag) and alkalescent solutions. The advantages of polymeric Si–O–Al–O
Adapted from Ref. [3].
bonds over Portland cement-based concretes are their high compressive
strength and low levels of shrinkage as well as their environmental
process is usually very slow [42]. This means that CO2 cannot progress
characteristics [127,128]. They have also shown good bonding with
to the centre of the wall due to the fact that vapour penetration only
cellulose materials and good mechanical strength with limited hemi­
happens within the superficial 3.67 cm of a non-plastered hemp concrete
cellulose and lignin addition [54].
wall formulation of 413 kg/m3 [110]. In such cases, walls may harden
superficially and become powdery inside [105]. Research also suggests
2.4. Environmental and economic aspects
that materials like the quite acidic pozzolanic aggregates are thought to
have a favourable influence on the interface between the binder and the
Due to the low cost of processing [42,129], plant fibres are cheaper
natural fibres [56]. The binders set due to hydraulic activity (Portland
than synthetic fibres [44] and they are often locally available [64].
cements, natural cement and hydraulic limes), carbonation (aerial limes
Hemp farming involves only 11,400 MJ/ha, about half the energy
CL-S or CL-S PL, dolomite limes DL and partially natural hydraulic limes
required for other similar yields [107]. Negative aspects of hemp
NHL, hydraulic limes HL and formulated hydraulic limes FL), crystalli­
farming e.g. land and fertilizer use, could be overcome by crop rotation
zation (gypsum) or water loss (clay and some organic binders). Mineral
and organic farming [32]. Carbon emission per kg of hemp shive pro­
binders, used in hemp concrete or hemp mortars, are frequently aerial
duction ranges from 0.085 to 0.19 kg of CO2 [95,107,130] although this
limes [100] and formulated binders with added natural hydraulic limes
is more than countered by the sequestration during growth of 1.5–2.1 kg
or Portland cement [108]. Natural hydraulic lime [111] natural cement
of CO2 [36,107,131]. The result is that hemp concrete generally has a
[102], gypsum [45,112], MgO cement [113] and silica sol binders [50]
positive balance in its climate change indicator [132,133] due to the fact
are also mentioned. According to Table 4, MgO cement achieved the
that carbon dioxide is stored in the plant-based aggregate [32]. The
highest compressive strength value of up to 5.20 MPa in comparative
highest negative contribution is caused by the commercial binders [32,
research with several other binders [44], which in other research was
56,134], in particular Portland cement and to a lesser extent natural
only surpassed by a concrete with chemically pretreated hemp shives
cement and natural hydraulic lime, followed by aerial lime and gypsum.
and Portland cement that reached 8.03 MPa. Due to the fact that there
As a general guideline, several studies agree on values of -0.3 to -1.0 kg
are no data for the flexural strength of this material, it cannot be
CO2 per kg hemp concrete [133]. An unrendered 30 cm thick hemp-lime
compared with all the material specifications shown in Table 4. The
formulation of 1 m2, with a density of 275 kg/m3, sequestrates 82.71 kg
highest flexural strengths reported in the literature consulted on hemp
of CO2, which compensates for the 46.43 kg of CO2 emitted by the
concretes were achieved by formulated binders (1.21 MPa) composed of
materials and during their processing, thus enabling the storage of
aerial lime, a hydraulic binder and pozzolanic additives [114] followed
36.08 kg of CO2 [107]. In a non-load-bearing hemp concrete with a
by stabilized clay. However, few studies have been carried out on MgO
wooden support structure, the lime binder consumes 49% of the primary
cement, natural cement (prompt), gypsum and clay binders [115,116].
energy and 68% of the water and causes 47% of the air pollution, fol­
This might be explained by the fact that these binders are less common
lowed by the wooden structure, the plasters and the hemp shives [32].
(MgO cement and natural cement), water soluble (gypsum and clay) or
Lime burning and calcination (quicklime production) emit 0.42–0.8 kg
impure and non-standardized (local earth containing clay as the binder).
CO2 and 0.7 kg CO2 per kg lime [133]. Calcic lime (CL) usually reaches
As shown in Table 4, organic binders, such as corn starch [51] and
up to 90% reabsorption [107] of the aforementioned 0.7 kg of CO2 per
sapropel [117], did not reach the maximum compressive strengths of
kg of lime, although due to the setting problems that often occur in
formulations with comparable densities containing inorganic sol silica
plant-based concretes [121], the CO2 might not be reabsorbed by
binders [50].
carbonation in the same quantity as in mortars made with mineral ag­
Although the hemicellulose content of hemp fibre (as happens with
gregates. This issue is not considered in the life-cycle assessments of the
cotton, bamboo, coconut and flax) is significantly lower than that of
hemp-lime concretes we studied. A design that takes into account binder
other natural fibres such as wheat straw or wood [118], the delay or
types with the lowest possible environmental impact [5], the transport
hindering of the setting of the binders in a hemp concrete matrix, caused
of the materials, the dosage, the construction system and the application
by polysaccharide leaching from the hemicellulose material was
technology [135] is of vital importance in the final carbon footprint of a
observed by several researchers in both organic binders like starch [119]
hemp concrete: e.g. a hemp-lime plaster formulation can have more
and inorganic binders such as lime [120], cement [121,122] and
impact than a sand-lime coating because more binder is needed [5].

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Fig. 5. Tensile stress-displacement curves for different hemp/binder (starch) ratios. It is verified that the smaller hemp size implies a greater mechanical resistance.
Adapted from Ref. [51].

In spite of an overall positive balance in all the phases of the life cycle application of hemp shives is in concretes and mortars. Over the past 25
of plant-based building materials [32] and their positive health impact years, lightweight hemp concretes in the medium density range of
[65], one clear drawback is their higher price compared with the con­ 200–840 kg/m3 [92], and also in lower [50,51] or higher [54,55]
ventional materials that dominate the market today [32]. This is why at density formulations, have been used in manually cast or sprayed
present plant-based materials are preferred by just a small minority of (Fig. 1) in-situ applications in walls (via filling and tamping of shutter­
customers who value their ecological and environmental qualities and ing), slabs and plasters, as well as in pre-fabricated pieces [35,143] (e.g.
their energy-saving benefits. The building industry represents 10% of blocks and bricks) (Fig. 1). These have proven to be high-performance,
the PIB and 28% of employment worldwide (OECD) and has a vast fire-retardant materials, generally reaching Fire Class B standard [20],
environmental impact [47]. Changes can only be achieved by the although higher density materials (>360 kg/m3) can achieve Fire Class
introduction of appropriate policies, to encourage the development and A2. In a 30-cm-thick hemp brick wall under a load of 3 kg/cm2, a fire
promotion of new, plant-orientated economies in the construction sector resistance of >120 min [73] can be achieved with a denser, clay
[32]. binder-based matrix [144,145]. At present, the data referring to the fire
resistance of hemp mortars are limited, probably due to the lack of
3. Common hemp-building materials and products on the standardization and, in addition, to the high cost of testing [35]. Hemp
market. Methods and solutions concretes are known for their elastic-plastic behaviour and there are
frequent reports of their dependence on a wooden support structure [7,
Hemp fibres are mostly commercialized for dry application. They are 14,51,56,146]. Most common binders are lime or formulated products
seldom seen as loose wools for manual [136] or sprayed application [47], although sand and pozzolanic aggregates may be added to improve
[137], used for example in roof insulation (installed density is 40–50 mechanical performance. Additives may be used for a range of purposes,
kg/m3) or as void filler. Normally, the bark fibres are processed into e.g. to reduce the need for binder [147]. When bound together with
rectangular, thermo-welded insulating panels for roofs, attics, walls and pMDI, natural resins or by geo-polymerisation, hemp shives are pressed
suspended ceilings, containing 85%–90% hemp fibre, 8–10% polymeric into lightweight particle boards with a density range of 350 kg/m3 to
PET-based fibres and 2–5% soda as a fire protector [138]. Occasionally, 1000 kg/m3 [148]. The possibility of creating binder-less particle
these insulating panels are manufactured with plant-based binders such boards was also studied [149]. Hemp shives are generally processed into
as corn starch [139]. The panels (or rolls) are available in densities dust-free 2–25 mm long particles. Shorter and thinner particle sizes of
ranging from 25 to 45 kg/m3 [140] for different thermal performances. 2–15 mm or 2–5 mm [140] allow hemp shives to be used in mortars and
Semi-rigid, thermo-welded insulating panels with densities of 90–100 fine plasters. According to studies by various different authors, the bulk
kg/m3 [141] contain 40% hemp fibres, 40% hemp shives and 20% density of hemp shives ranges from 110 kg/m3 [47] to 130 kg/m3 [92]
PES-binder. After being adhered to façades, they are rendered with depending on particle size. The common fibre content of commercial
formulated mortars. Non-woven felts made with 75% hemp fibre and hemp shives is around 5% (residual fibres of the epidermis). These fibres
25% recycled jute fibre [140] are used as levelling and acoustic underlay are usually not as long as the hemp shives themselves and can influence
for floors, or for impact-reduction purposes between hard materials. the mechanical performance of the hemp concretes. When chopped and
Hemp-fibre reinforced composites are blends of materials ranging from pressed into small granulated pellets (<3 mm), this hemp shive product
thermoplastics such as polypropylene and polyethylene to thermoset is used as an aggregate in mortars and plasters [136], and can be applied
fibres such as polyester. 100% bio-composite materials are now feasible with normal plaster-spraying machines. Hemp powder (a by-product of
when working with plant-based resins from soy, canola or corn. Typical industrial decortication, generally about 15%) is occasionally used as an
applications include automobile interior substrates, furniture and other aggregate in stuccos or pressed into solid pellets with an average
consumer products [17]. Hemp fibre reinforced composites have installed density of 700 kg/m3 [150]. These pellets can be used in dry
recently been developed into sandwich panels for façades, building skins floor slabs, slabs and as roof insulation. Lightweight hemp-lime bricks
and curtain walls [142]. Dust-free hemp shives offer a practical, loose for cladding, internal walls and slabs (the most common density is
filling material, while larger shives, mixed with dry earth and slightly 300–360 kg/m3) are manufactured to order by several producers [140],
compacted, are used in slabs [136]. Despite this, the main construction mainly in France. Load-bearing hemp-clay bricks, using the same

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quantity of plant material as lightweight bricks [34], have been manu­


factured and used since 1999 for solid walls and interior partitions of
1–3 floor buildings in Southern Europe [73]. This system can be adapted
to diverse climates and can be used as a substitute for wood in regions in
which it is in short supply [151]. It enables hemp-building in unfav­
ourable drying conditions and locally sourced binders are normally
used. Premade panels with a wooden framework measuring 3.6 m by
2.4 m and 400 mm thick sprayed hemp concrete were produced for a
large-scale wine warehouse in the UK [34,35], while research into
precast elements [34,152] aims to produce mainstream applications for
hemp concrete. Hempseed oil is occasionally sold for the embellishment
of interior wood [140] and is also found in formulations of oil-based,
ecological varnishes [153].

4. Parameters that can influence the properties of hemp Fig. 6. Tensile stress-displacement curves for samples with perpendicular and
aggregate concretes parallel fiber orientation in hemp-lime mortars. It is hightlighted the greater
mechanical resistance of the mortars with parallel orientation fibers. Adapted
4.1. Mechanical properties from Ref. [48].

The inferior mechanical performance of hemp concretes when While compaction was found to be very effective for improving me­
compared with concretes based on mineral aggregates is due above all to chanical performance, several authors raised doubts about the benefits
their porosity, which makes them deformable [92]. A wall mixture made of the addition of fibres [112,143,146]. Others observed a more positive
with hemp and aerial lime (about 400 kg/m3) can have a porosity of result with the use of chopped, whole stem material [55] although the
over 70%. Apart from the mesopores (0.1–1 mm) within the shives and last reference, shown in Table 4, refers to lime-stabilized hemp-clay
in their contact area with the binder, the mortar also has micropores concretes with a higher density range. Proper compaction, combined
between the hydrates of the binder matrix and macropores (of around 1 with the high deformability of hemp shives, makes hemp building an
cm) in the arrangement of the particles of the plant aggregate [49]. interesting option in seismic regions [143]. As an elastic support for
There are however various methods for increasing the mechanical timber walls, hemp concretes can increase their strength by up to 4 times
strength of hemp concretes without changing the aggregate content by preventing weak axis buckling [105]. Hemp shive particles are an
(more or less equivalent to the bulk density of the hemp shives). The anisotropic material [162] and their particular orientation depends on
most sustainable method involves denser compaction of the concrete so the construction method. In fact, compressive strength is higher and
as to reduce the void volume [56,95]. Void volume can also be reduced stiffness is lower when the particles are orientated parallel to the com­
by adding small-sized aggregates or by reducing the mean particle pacting force (Fig. 1 D), and the concrete is more fragile when loaded
length. This increases the compressive strength [51,64,154] although a perpendicular to the orientation of the particles [48] (Fig. 6).
larger amount of binder is needed to hold the smaller-sized materials
together (Fig. 5). Due to their greater surface area, smaller sized ag­
gregates can also increase the risk of binder setting and hardening 4.2. Thermal performance
problems through the release of polysaccharides [56,155]. Particle size
change augmented the compressive strength in both organic binders The optimisation of the mechanical properties of hemp concretes via
[51] and mineral binders [54]. Plant adapted formulations and pre­ the orientation, compaction and application method can also affect their
treatments can also increase the mechanical performance of hemp thermal conductivity [7,163]. When comparing hemp concretes pre­
concrete [56,122] by preventing setting problems. One of the most pared with different formulations, the choice of binder has little influ­
successful chemical treatments involves the addition of cellulose ether, ence on the thermal properties although it can have significant effects on
which increases the viscosity of the water, so reducing absorption by the the mechanical results [95]. Due to the anisotropic pore structure of
hemp shives and improving the mechanical properties by up to 3 times hemp shives [162], hemp concretes can have up to 30% greater thermal
[156]. The sprayed application also has benefits. Less water (responsible conductivity in the perpendicular direction of compaction [48,95,109]
for the transport of organic compounds) is needed because no previous (Fig. 7). Thermal conductivity also increases in line with the degree of
absorption (e.g. during mixing) takes place and improved compactness moisture and the temperature, while the mechanical properties improve
or particle arrangement can be obtained [7,114]. The mechanical with increased density [7,48,99,109,114], such that “for a hemp per­
strength can also be improved by increasing the dosage of the binder centage in weight between 20% and 40%, the concrete density decreases
[143]. The choice of lime is also important, given that the limes with from 611 to 369 kg/m3 and the thermal conductivity decreases from
higher quantities of pozzolanic compounds achieve better results [154]. 0.14 to 0.094 W/(m⋅K)” [100]. Whereas hemp-lime formulations
With a typical density range of 250–660 kg/m3, hemp concretes with generally show moderate levels of dry thermal conductivity from 0.06 to
different lime-based formulations showed compressive strengths of be­ 0.12 W/mK [164], lower values can be achieved with sprayed applica­
tween 0.25 and 1.15 MPa with a corresponding elastic modulus of be­ tions with a dosage of 1:1 in weight (hemp shives and aerial lime
tween 4 and 160 MPa [92]. Calculating the optimum binder content is a binder). The lower thermal conductivities can also be obtained by using
key factor for obtaining solid hemp concrete [143]. In practice the use of organic binders like sapropel [117]. As shown in Table 4, a recent study
large amounts of hydraulic binders, with high embodied energy, is an of a hemp concrete with a silica sol binder [50] achieved a thermal
unsustainable solution when it comes to increasing compressive conductivity of 0.05 W/mK, a value close to that for the hemp shives
strength. Less energy is embodied in gypsum or clay. Bricks made with themselves, without compromising on its mechanical strength compared
clay binder have been used in hemp buildings with loadbearing walls in to low and medium density hemp concretes. While a smaller particle size
Spain for the last two decades [73]. Within the same density range their of hemp shives has a positive impact on the mechanical strength of hemp
compressive strength is only surpassed by MgO-cement and Portland concretes, its influence on the thermal conductivity is reported to be
cement with pretreated shives (Table 4). Furthermore, variations in the minimal [54]. The reason why lower thermal conductivities were ob­
mechanical results also depend on the curing conditions during the tained with smaller sized aggregates in a study with hemp plasters [165]
drying process, which can affect the hydration of the binders [161]. must therefore be investigated in complementary research. The

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Fig. 7. (A). Conductivity of hemp shives as, function of the saturation degree. It is noted that there is an increase in thermal conductivity depending on the increase
of the saturation and the transversal orientation of the fibers with respect to the longitudinal orientation. Adapted from Refs. [163]. (B). Correlation between
compressive strength and thermal conductivity. The increase in thermal conductivity is observed as a function of the increase in mechanical resistance. Adapted from
Refs. [95].

orientation of the anisotropic aggregates might have a greater impact on techniques, some of which function with small samples of this hetero­
a hemp-plaster coating application than the use of smaller-sized aggre­ geneous, anisotropic material [166]: with densities of around 300 kg/m3
gate. Tests carried out on walls exposed to real weather conditions, the specific heat values observed in different publications varied hugely
proved that U-values alone are not a suitable parameter for evaluating between 300 and 1700 J/kgK, while there was much less variation in
the thermal performance of hemp-lime concretes. Dynamic factors, e.g. thermal conductivity (0.07–0.09 W/mK). Efforts over the past decade
Q24h, should also be taken into account [131]. Hemp concrete is an have tended to focus on thermal insulation and the achievement of
insulation material with semi-structural properties and therefore per­ thermal conductivity values that were as close as possible to those of the
forms well between conventional insulation panels and structural walls shive material itself and comparable with traditional insulation mate­
[166], also regulating thermal comfort by passive solar energy gain rials, according to the climatic requirements of the countries in which
[103]. The disproportionally broad range in the specific heat values of hemp building appeared, with the added benefits of hygrothermal per­
hemp concretes with similar densities reported in the existing body of formance and water vapour permeability. Unfortunately, the few
literature (Table 4) might be due to irregularities in the plant materials available data on specific heat vary too much to enable us to reach
themselves. Such great differences with the same type of binder and conclusions on thermal diffusivity and effusivity according to the den­
commercial hemp shives could also have occurred due to the use of sity range, although depending on the kind of binder and its dosage, the
different measurement methods or to difficulties with the measurement specific heat should be adaptable. In fact, both thermal conductivity and

Fig. 8. Fig. 8. Sorption-desorption curves obtained at 23 � C and 40 � C for the formulation (HC1: Hemp/Binder ¼ 0.33; HC2: Hemp/Binder ¼ 0.42). In the curves of
total sorption and desorption a hysteresis is occurring, that is not observed during the cycles of RH, since the latter entail a reversible linear relationship between the
water content and the RH. On the contrary in the sorption curves, the slope of this linear relationship remains very similar to the two temperatures tested (23 � C and
40 � C). Adapted from Ref. [167].

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specific heat capacity were found to increase with higher amounts of


lime binder. By contrast differences in RH had no significant influence
on the thermal diffusivity and specific heat capacity of the same for­
mulations, although they did have considerable impact on their thermal
conductivity [167]. A study of a hemp concrete wall under summer
conditions in different regions in France suggested that adding a higher
thermal inertia component could avoid overheating in Southern France
due to the low thermal effusivity (231 J/mK) of the hemp concrete wall
formulation of 440 kg/m3 [168]. This example shows that formulations
must be adapted to the particular climate in which the concrete is being
used. In order to dampen the diffusion of external heat, low thermal
diffusivity is required, while high thermal effusivity values can increase
the quantity of stored energy. Since it is difficult to design a hemp
concrete material that meets both criteria, the use of multilayer hemp
concrete walls could be a solution to adapt this material to different
climate conditions.
Fig. 9. Water absorption by capillary suction over time. BM – builder’s mix,
4.3. Hygrothermal behaviour CM – commercial mix, G – lime:GGBS binder, G þ WR – lime:GGBS binder with
water retainer,M–lime:metakaolin binder, M þ WR – lime:metakaolin binder
The thermal conductivity values of hemp concretes (range from very with water retainer. Adapted from Ref. [171].
good results such as those shown in Table 2 [131] between 0.06-0.09
W/mK for the roof insulation and the wall construction, and for pre-cast concretes increased their thermal conductivity by 40% between 0 and
structural the results are 0.14–0.27 W/mK). These values are not as good 50% RH. The specific heat also increases in proportion to the absorbed
as those of traditional insulating materials (expanded polystyrene and humidity [110]. The open porosity of hemp concrete enables it to
glass wool with values of 0.04 W/mK), which hygroscopic behaviour regulate internal air humidity. In this context its macropores make a
contributes to the improved thermal performance associated with the greater contribution to permeability than the micropores of the different
latent heat produced by the process of liquid to vapour phase change binder types, when hemp concretes were compared with aerial lime,
[131] of the water contained in its porous structure in solid, liquid and hydraulic lime and Portland cement [171] (Fig. 9). Heat is transported
gaseous phases [110]. The absorption capacities of hemp shives and from the higher temperature areas to the lower temperature areas and
fibres vary significantly because of their different physical structure and water vapour is transported from the areas with higher concentration to
chemical composition. In addition, the temperature and relative hu­ those with lower concentration. Resistance to water vapour diffusion
midity conditions of hemp concrete samples (HC1: Hemp/Binder ¼ varies depending on the formulation and binder type. For example, a
0.33; HC2: Hemp/Binder ¼ 0.42) are not affected with respect to their wall formulation with natural hydraulic lime NHL2 and a density of 476
saturation and water desorption behavior. (Fig. 8). The dynamic hydric kg/m3 has a vapour diffusion resistance factor of 2.6 μ while the same
behaviour of hemp concretes contributes to a significant level of mois­ dosage made with a natural hydraulic lime NHL3.5 and a density of 563
ture buffering that avoids excessive energy loss due to ventilation. Daily kg/m3 is more resistant at 3.6 μ [110].
cycles of RH between 33% and 80%, with densities ranging from 405 to
510 kg/m3, showed a remarkable mass uptake during the cycle of more 4.4. Acoustic properties
than 110 g/m2 and a vapour penetration depth of more than 4 cm [169].
The MBV values of several hemp concretes vary depending on the The acoustic qualities of hemp concretes depend on their porous
application technique and its thickness. In this way [168], shows values structure [172]. When hemp concretes are rendered the sound absorp­
of 2.3 g/(m/% RH) (sprayed and precasted techniques); values about tion coefficient falls significantly. Unrendered hemp concretes, with an
2.14–2.15 g/(m2/%RH) correspond to sprayed and moulded hemp­ average sound absorption of 40–50% [66] across a certain range of
concrete respectively [101,169]. In relation to the thickness of the frequencies, have specific absorption and reflection qualities depending
hempconcretes the values range from 1.84 (3 cm), to 2.02 (7 cm) on the binder, formulation and fabrication [102]. Surface permeability
g/(m2%RH) [170]. The pores in the hemp shives are tubular and larger varies according to its texture (Fig. 1C and D, Fig. 10A and B), and this
than hemp fibres, and over-retted hemp has a higher absorption capa­ alters the absorption coefficient (α). This varies between 0.3 and 0.9
bility than dried material [94]. As hemp concrete is normally made with depending on the binder dosage and the frequency [92]. In addition,
commercial hemp shives, the available studies on hemp concretes have absorption peaks at low (f � 400 Hz) and medium frequency (f � 1200
tended to focus on formulations with an insignificant fibre content, Hz) are observable as long as the material is less than 20 cm thick. The
usually containing lime binder. Hemp concrete has high open porosity values observed by this author [92] were high, compared to other
which contributes to heat transfer by conduction (in the solid, liquid and building materials tested under equivalent conditions. Moreover, the
gaseous phases), convection (in the pores), radiation (between the pore amplitude of the peaks and their band width decrease with increasing
walls), phase change (vapour evaporation or condensation in the pores) amounts of binder, because the pore size decreases. Greater sound ab­
and water vapour diffusion [110]. The solid and liquid phases are sorption was observed in concretes made with smaller-sized hemp shives
responsible for the heat transfer and the thermal conductivity increases [102] (Fig. 11) and also in concretes made with lime-pozzolanic binders
with rising humidity [92]. This is confirmed by the following results: compared to hydraulic binders [66]. Increasing the thickness of the wall
with a low-density hemp concrete of around 200 kg/m3 (roof formula­ resulted in a concentration of absorption peaks for the frequencies above
tion), the thermal conductivity changes from 0.06 to 0.085 W/(m⋅K) 500 Hz and a shift in the frequency position of the peaks towards low
between relative humidity (RH) ¼ 0% and RH ¼ 50%, reaching 0.10 frequencies. While low density formulations show a net shift in the ab­
W/(m⋅K) with RH ¼ 75%. With medium densities of around 450 kg/m3 sorption peaks towards low frequencies and a stabilization in the level of
(non-loadbearing wall formulation), thermal conductivity increases by α when the thickness increases, a frequency shift of the first absorption
10% between RH ¼ 0% and RH ¼ 50%, from 0.10 to 0.11 W/(m⋅K), peak and a stabilization of the second peak can be observed in medium
reaching 0.13 W/(m⋅K) with RH ¼ 75%. The same study discovered that density formulations, until a constant absorption level of between 500
increasing the density of the hemp concrete up to 700 kg/m3 only and 2000 Hz is reached. In high density formulations there is a steady
increased its thermal conductivity by 15%, while low density hemp decrease in absorption as the frequency increases [92]. Recent studies

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Fig. 10. Wall Finishes showing different textures made from hemp shives (2–25 mm) and NHL3.5 lime (A) or hemp shives (2–5 mm) and clay binder (B).

Fig. 12. Comparison of sound absorption coefficients of samples at 0% before


Fig. 11. Sound absorption of hemp shiv for various sizes of the particles-low
and after W/D cycles. Adapted from [174].
degree of compaction. Adapted from Ref. [102].

found. One of the few examples of research on exposure to the weather


highlight that the acoustic performance depends above all on the con­
in buildings made with unrendered hemp concretes is a tower con­
centration of hemp aggregate in the concrete and is unaffected by binder
structed with this material in Switzerland (Fig. 1) in 1999 [111]. This
types (comparing clay and lime) [173]. Below 375 kg/m3 the acoustic
tower has resisted exposure to the environment for 20 years without
behaviour of hemp concretes containing either of these binders is
suffering serious decay. It was built with a non-loadbearing hemp-lime
strongly marked by a highly absorbent first peak that appears between
concrete wall formulation with 12.5 kg CL-lime, 25 kg NHL-lime and 10
500 and 1200 Hz due to inter-particle pores, while only small differences
kg brick dust on 200 L of hemp shive aggregate, and has a potassium
were observed in the corresponding widths of the absorption peak
water glass coating with a mineral pigment, which was renewed for the
indicating greater roughness of the hemp-lime. Up to a density of 500
first time in 2019. In fact, a study with comparable hemp concretes of
kg/m3 the manufacturing process appears to be the most important
325–327 kg/m3 made with “prompt” natural cement and exposed to
factor in acoustic behaviour, while above 500 kg/m3, transmission loss
accelerated aging through 8 wetting/drying cycles at 30 � C over a period
increases with density. Air resistance is higher for hemp-clay than for
of 75 days, found no differences in their thermal conductivity and hardly
hemp-lime due to its higher binder-density. Further retting and aging
any in their acoustic properties [159] [176] (Fig. 12). With the same
can affect the acoustic absorption capacity of the hemp aggregate by
concrete samples mould growth was only noticed under conditions of
changing the pore size distribution [99]. When the hemp shives are aged
98% relative humidity (RH), once the pH of the samples had fallen
via exposure to real weather conditions they tend to swell up. Greater
below 10. By contrast to these observations on hemp concretes, loose
open porosity was found to have an important influence on acoustic
hemp shives underwent serious deterioration over 2 years exposure to
absorption [99].
wetting/drying cycles under laboratory conditions at 30 � C (every 5
days under RH 95% were followed by 2 days under RH 40%) and real
weather conditions [99]. The shives subject to laboratory conditions
4.5. Durability
suffered decay to the cellulose and lignin while the hemicellulose con­
tent remained unchanged. The shives exposed to real weather conditions
Hemp can be farmed without fungicides or pesticides [14]. It has a
suffered more serious decay, including to the hemicellulose, and a
high silica content (Table 3), which makes it more resistant to biological
significantly higher mass loss of 35.9% compared to 24.2% under lab­
decay than other plant products such as cereal straw [51]. In addition,
oratory conditions. Mass loss, volume variations and greater open
there are no reports of attacks by wood parasites, due to the fact that
porosity were found to have an important influence on water vapour
hemp straw does not contain albumin. A study with hemp shives, treated
sorption. These phenomena had a more significant impact on the shives
with mineral oxides, revealed that termites were capable of traversing
exposed to real weather conditions, which suffered greater pore size
this material but did not survive for long [20], although no other
alterations. Although the binder provides significant protection,
research on the effects of termites on hemp or hemp concretes could be

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Fig. 13. Overall colour difference (ΔE*) of hemp–lime samples during and after the Mediterranean (Csa) Tropical (Af) and Semi-arid (Bwh) weathering tests. Legend:
C, CL90S þ hemp shives mix; N, NHL 3.5 þ hemp shives mix; P, CL90S PL þ hemp shives mix. Adapted from Ref. [104].

especially against microorganisms that can alter the microstructure of concretes also contribute to the reduction of carbon emissions in new
the hemp shives [99], it is important to protect the material against building. The design of hemp concrete materials and technologies is
capillarity uptake and excessive contact with rain. Capillarity uptake therefore becoming an interesting way to help reduce the construction
can be reduced by increasing the hydraulicity of the binder and by sector’s climate change impact.
adding a water retainer, although in all specimens prepared with aerial Research into the functional properties of hemp concretes shows that
lime, hydraulic lime and Portland cement, the speed of capillarity up­ important technological advances have been made with a construction
take fell as time went by Ref. [171]. In Sweden a 25 freeze-thaw cycle material which in practice has already proven a durability of more than
test was carried out on hemp concrete samples, which were exposed to two and a half decades. Studies of the physical and chemical properties
12 h of þ20 � C followed by 12 h of -20 � C [112]: while before the of hemp as a priority objective building material highlight the important
freeze-thaw cycles the best mechanical results were obtained by a and growing number of achievements in this field over the last few
cement-lime formulation, the best values after the test were obtained by years. Apart from its environmental benefits hemp concrete has also
a pure cement binder formulation whose mechanical performance was demonstrated a number of advantageous, user-friendly hygrothermal
improved rather than hampered by the test. Furthermore, gypsum as a and acoustic properties, compared with a large number of energy and
binder showed higher compressive strength in comparison to lime but resource-consuming construction and insulation materials, which still
was expected to have low durability in humid atmospheres [112]. dominate the building sector and which in less than two centuries have
Opting for more vapour-permeable binders avoids water vapour reten­ replaced thousands of years of tradition, knowledge and experience with
tion in the material, which could damage the wooden support structure natural building materials, including natural concretes and mortars
[146]. Unfavourable weather conditions during the hemp harvest can made with plant aggregates. The properties of most building materials
have negative effects in that storing hemp shives with a moisture content are clearly focused on achieving particular mechanical, thermal,
of over 15% can result in poorer quality [99,174] or the growth of mi­ acoustic or economic specifications, and rarely take into account life
croorganisms. Microorganisms may also appear in hemp concretes due cycle assessments of costs and effects on health, while hemp concretes
to unfavourable drying conditions. Recent research [104] reported the have shown clear advances in all these fields.
growth of alkali-tolerant fungi and bacteria on different hemp-lime The present review shows that hemp concrete can be used to replace
plaster samples over the course of a long-term durability study (simu­ the multilayer walls composed of typical construction and insulation
lating Mediterranean, tropical and semiarid climatic conditions). In materials and can also be easily adapted to retrofitting work and
addition, the volume of the material and its appearance remained un­ restoration of historic buildings, without affecting water vapour
changed in most samples, except for the yellowing of the exposed sur­ permeability.
faces and a slight mass uptake after heavy rainfall. This and other [160] Due to the fact that it can be used both as a construction and an
research have also shown that salt weathering did not cause long-term insulation material and the anisotropic behaviour of hemp aggregates,
damage to any of the samples and that [104] “none of the isolated mi­ researchers were faced with various difficulties when trying to measure
croorganisms caused either aesthetic changes or physical breakdown its functional performance. This might explain the often broad range of
during or after the test and this encourages the use of hemp-lime renders values, in particular for specific heat.
under Mediterranean, semiarid and tropical climates”. Insufficient dry­ While great efforts were made to create formulations that lower the
ing of hemp concrete walls before rendering with lime mortars can lead thermal conductivity (the best values were close to those for hemp
to chromatic changes and microbiological, textual or morphological shives themselves), more work must be done on thermal effusivity. The
pathologies, which are more intense with clay than with lime-bounded next generation of research could focus on adjusting formulations to the
hemp concrete supports, while renders made with natural hydraulic environment in which the hemp concrete will be used, taking into ac­
lime show less deterioration then those made with aerial lime [104,116] count local aggregates and binders as well as building techniques spe­
(Fig. 13). The smaller pored hydraulic binders resisted the freeze thaw cifically adapted to the culture and climate.
cycles better, while the porous aerial limes prevent salt crystallization In order to obtain better mechanical results that could minimize the
[160]. structural dimensions and remove its dependence on a support structure,
research could focus on the drawbacks of the leaching of organic com­
5. Conclusions pounds and could also look at the use of the stem material (about which
little research has been conducted) that ends up as agricultural waste
The systematic analysis of the research carried out on hemp con­ from the plants farmed for cannabinoid production.
cretes shows that this relatively novel construction material has many It is obvious that most tests are carried out on a laboratory scale and
advantages resulting from the significant efforts made in the investiga­ mainly with small test samples.
tion of energy-efficient construction over the last 10 years, as manifested With a growing number of hemp-based houses being built in
by the increase in the construction of zero energy buildings. Hemp different climate zones, and an increasingly wide range of hemp

12
M.P. S�
aez-P�erez et al. Journal of Building Engineering 31 (2020) 101323

Fig. 14. Interest in particular aspects of this subject as shown by the percentage of publications on each topic.

concrete formulations and technologies (e.g. tamped and sprayed ap­ - For their part, binders are referred to in about 30% of the research
plications or premade elements), researchers today have an increasing articles. As discussed above, the main binders used in the manufac­
number of possible subjects for case studies, which could envision, ture of hemp concrete and mortars are inorganic binders that harden
among other things, indoor air quality, energy consumption, environ­ by carbonation.
mental gains and the durability of hemp concrete materials in different - About 20% of the studies on hemp concrete focus on its thermal and
climate contexts. acoustic properties, highlighting its advantages in both these aspects
The properties of the final hemp concrete product are affected by the compared to other materials.
natural variation and qualities of the plant aggregate (e.g. genotype, - The hygrothermal behaviour of this material is also a matter of in­
growing conditions, processing, particle size), its final density and terest, with up to 10% of the publications we studied experimenting
texture, the kind of binders used, the drying conditions, the degree of with different densities of material, offering very positive results and
compaction and the application method. It has also been noted that evident improvements.
changes made to the formulation or method in order to improve a - One of the most interesting characteristics is durability, which is
certain aspect of performance, e.g. thermal performance, can also referred to in around 10% of the hemp concrete characterization
improve its acoustic or mechanical properties, while others can cause studies, which describe it as a new material used increasingly widely
unintended side effects. in very varied locations exposed to different climatic conditions.
Based on the results of this review, further research can be tailored
towards more specific purposes. The following graphic (Fig. 14) shows the percentages of the
The main results of this analysis can be summarized in the following bibliographical references to the different topics covered in this review.
sections: The authors believe that the research carried out so far on this subject
has made a significant contribution to the development of materials of
- There has been increasing interest in the study of the physical and this kind and has greatly boosted their use in bio-construction and
chemical composition of hemp, especially over the last 10 years, in retrofit projects.
which great advances have been made in terms of our knowledge of
the material itself and the parts of the plant that may be useful in this Declaration of competing interest
type of application. Researchers have also tried to identify the most
suitable conditions for cultivation, growth and harvesting, although The authors declare that they have no known competing financial
the experimental studies carried out by the different authors pro­ interests or personal relationships that could have appeared to influence
duced widely varying results. Over 35% of all the publications cited the work reported in this paper.
in this research refer to this topic.
- The properties of hemp concrete and its applications account for 65% Acknowledgment
of all research, mainly focused on the characterization and
improvement of these properties, including mechanical strength, This work was supported by the REMINE Programme for Research
thermal and acoustic properties, hygrothermal behaviour and and Innovation Horizon 2020 Marie Skłodowska-Curie Actions and
durability. Project MAT2016-75889-R of the National Plan for Scientific Research,
- As regards the specific studies of hemp concrete as a building ma­ Development and Technological Innovation (Ministry of Science and
terial, 25% are devoted to its mechanical performance, focusing Technology) and was carried out under the auspices of Research Groups
particularly on the compactness and deformability of the material, RNM 0179 and HUM 629 of the Junta de Andalucía. Authors would like
which has a direct impact on its performance as a load-bearing to thank experts and colleagues for providing or exchanging information
material. on the subject of this article, in particular members of ENTPE (France)

13
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