Topic #7 Exam ~ We’ve Got all the Solutions Version C

QUESTION #1

(a) Write the complete balanced molecular equation for the reaction that occurs between aqueous calcium
chloride reacting with aqueous lead (II) acetate. Include phases for all substances. (3)

CaCl2(aq)+Pb(C2H3O2)2(aq)=PbCl2(s)+Ca(C2H3O2)2(aq)

(b) Write a balanced net ionic equation for the reaction that occurs between aqueous calcium chloride
reacting with aqueous lead (II) acetate. Include phases for all substances. (2)

(c) Using the balanced equation, calculate the theoretical yield, in grams, of precipitate that can form when
25mL of 0.032M aqueous calcium chloride reacts with 75.0 mL of 0.0025 M aqueous lead (II) acetate.
(3)

0.03mol < 1.28mol

because the lead (II) acetate is the limiting reactant and have a1:1 ratio to PbCl2, mole of PbCl2 produced will be
0.03mol.

(d) What are the molar concentrations of each of the ions present in the calcium chloride solution? Defend
your answers. (2)

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QUESTION #2
Answer the following questions about the solubility of SrSO4(s) Ksp = 2.8 x 10-7
a) Write the balanced chemical equation representing the dissociation of SrSO4(s) in pure water. Include
phases for all substances. (1)

b) Write the Ksp expression for the dissociation equation in part (a). (1)

c) Calculate the molar solubility of SrSO4(s) (2)

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 d) In the box below, complete the particle representation diagram that includes FOUR water molecules
with proper orientation around the ion shown. (1)
water

Sr+2

e) Identify the intermolecular force that that is disturbed between water molecules in order to create new
intermolecular forces between the water and the ion in the particle diagram you created in part (d). (1)

dipole-dipole force

f) A solution is prepared by mixing 40.0mL of 1.9 x 10-2M Mg(NO3)2 with 30.0 mL of 1.5 x 10-2 M NaF.
Determine if the solution created will form a precipitate if the Ksp for MgF2 = 6.4 x 10-9. Defend your
answer with a mathematical calculation. (2)

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QUESTION #3
In an experiment the following redox reaction occurs in acidic solution. Balance the following redox reaction in
acid solution using the half reaction method.

Cu + SO4-2 → Cu2+ + SO2

(a) Write the balanced reduction half reaction (1)

(b) Write the balanced oxidation half reaction (1)

(c) Write the complete balanced Redox reaction in an acidic solution. (1)

(d) Identify the oxidation state for the bold/underlined element in each of the following compounds. SHOW
YOUR WORK! (3)

OF2 IO– H2O2

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QUESTION #4
1. A student investigates the enthalpy of solution ∆Hsoln, for KNO3(s).
The molar mass of KNO3= 101.1g/mol
To measure the ∆Hsoln for KNO3 student adds 80.0g of water initially at 25.20C to a calorimeter and adds
11.4 g of KNO3 (s), stirring to dissolve. After the KNO3(s) dissolves completely, the maximum
temperature reached by the solution is 16.30C.
a. Calculate the quantity of heat (in joules) during the dissolution process, assuming that the
specific heat capacity of the solution is 4.18 J/g•0C. Include units with your answer. (2)

b. Determine the value of ∆Hsoln for KNO3 in kJ/mol (2)

c. Calculate percent error for the heat of solution of KNO3obtained using the value determined in
part (b). The accepted value of the heat of solution for LiCl = +34.89 kJ/mol. (1)

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