Constants and Units c 1

v= v=
λ λ
h = h / 2π
1
-34
hv = mv 2 + I . E .
h = 6.62618 10 J.s 2
c = 2.997925 108 m.s-1
ψ nlm (r , θ , φ ) = Rnl (r )Yl m (θ , φ )
-23 -1
k B = 1.38066 10 J.K
P (r )dr = Rnl2 (r )r 2 dr
23
N A = 6.02 10
l = l (l + 1)h
β = 9.274 10-24 J.T-1 l z = mh
-31
m e = 9.10953 10 kg E = − hcR H / n 2 + mβB

m H = 1.0 g/mol
∆l = ±1
m D = 2.0 g/mol
J = L + S ,..., L − S
m Br = 79.9 g/mol

1s 2 s 2 p 3s 3 p 4 s 3d 4 p 5s 4d ...
1 eV = 1.602 10-19 J
1 Eh = 27.2 eV P(r ) = r 2 R(r ) 2

1 Å = 10-10 m 1 a 0 = 0.529 Å
b = 1 / 2(n − n*)

〈 Ψ Hˆ Ψ 〉
Elements of Mathematics E=
〈 Ψ Ψ〉

1 ∂  2 ∂
∇ 2r = r  dτ = r 2 dr m1 m2
r 2 ∂r  ∂r  µ= I = µre2
m1 + m2

∞ n!  1 1 k
∫0
x n e − ax dx =
a n +1
E v =  v + hv
 2
v=
2π µ
h
E J = hc BJ ( J + 1) B=
8π 2 Ic
Equations v
v approaching =
1− v /c
∆E = hv

CHEM 333 – Quantum Theory – Final Exam Page 18 of 21

Spherical Harmonics

l m Yl m (θ , φ )
1/ 2
 1 
0 0  
 4π 
1/ 2
 3 
1 0   cos θ
 4π 
1/ 2
 3 
±1 m  sin θ e ± iφ
 8π 
1/ 2
 5 
2 0   (3 cos 2 θ - 1)
 16π 
1/ 2
 15 
±1 m  cos θ sin θ e ± iφ
 8π 
1/ 2
 15 
±2   sin 2 θ e ± 2iφ
 32π 
1/ 2
 7 
3 0   (5 cos 3 θ - 3 cos θ )
 16π 
1/ 2
 21 
±1 m  (5 cos 2 θ − 1) sin θ e ± iφ
 64π 
1/ 2
 105 
±2 m  sin 2 θ cos θ e ± 2iφ
 32π 
1/ 2
 35 
±3 m  sin 3 θ e ± 3iφ
 64π 

CHEM 333 – Quantum Theory – Final Exam Page 19 of 21

Hydrogenic Radial Wavefunctions

Orbital n l Rnl
3/ 2
Z
1s 1 0 2  e −ρ / 2
 a0 
3/ 2
1 Z 1
2s 2 0   (2 − ρ ) e −ρ / 4
2 2  a 0  2
3/ 2
1 Z 
2p 2 1   ρ e−ρ / 4
4 6  a 0 
3/ 2
1 Z  1 2 −ρ / 6
3s 3 0   (6 − 2 ρ + ρ )e
9 3  a0  9
3/ 2
1 Z  1
3p 3 1   (4 − ρ ) ρ e − ρ / 6
27 6  a 0  3
3/ 2
1 Z 
3d 3 2   ρ 2 e −ρ / 6
81 30  a 0 

ρ = 2Zr / a0

CHEM 333 – Quantum Theory – Final Exam Page 20 of 21

The electromagnetic spectrum
Adapted from Quantics, Rudiments of Quantum Physics, Lévy-Leblond and Balibar, Elsevier, 1989.

Visible: typically 400-800 nm

1nm = 10 −9 m

CHEM 333 – Quantum Theory – Final Exam Page 21 of 21