Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super60 Jee-Main Date: 05-10-2020
Time:08.00Am to 11.00Am WTM-38 Max.Marks:300

Key Sheet

MATHEMATICS

1 1 2 4 3 3 4 1 5 2
6 4 7 3 8 2 9 2 10 3
11 2 12 1 13 4 14 4 15 1
16 4 17 4 18 1 19 1 20 1
21 5.00 22 0.58 23 0.07 24 233.00 25 0.16

PHYSICS

26 1 27 1 28 3 29 2 30 3
31 3 32 1 33 4 34 2 35 3
36 2 37 3 38 2 39 2 40 3
41 4 42 1 43 3 44 2 45 2
46 8.00 47 25.00 48 990 49 2.45 50 3.84

CHEMISTRY

51 3 52 2 53 1 54 4 55 3
56 3 57 3 58 2 59 4 60 1
61 3 62 3 63 1 64 3 65 1
66 4 67 3 68 3 69 1 70 2
71 4 72 1 73 3 74 4 75 4
Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s

SOLUTIONS
Mathematics

1. Required probability  P  GBB   P  BGB   P  BBG 

3 2 3 1 2 3 1 2 1 13
 . .  . .  . . 
4 4 4 4 4 4 4 4 4 32
2. P(missing at least one test)
 1  P (missing no test)
2
 3 7
 1   
 4  16
3. Let P,Q,R be the events that A is ridden by P,Q,R respectively
3 2 1
 P  P   , P Q   , P  R  
6 6 6
E – event that A wins.

E E E

 P  E   P  P  .P    P  Q  .P    P  R  .P  
P Q R
3 1 2 2 1 3
 .  .  .
6 8 6 8 6 8
3  4  3 10 5
  
48 48 24
4. Required probability
1 6 2 7 4 5 26
 .  .  . 
3 10 9 10 9 10 45
5. A be the event of guessing the answer correctly
B be the event of copying the correct answer
C be the event of knowing the correct answer
E be the event of that his answer is correct
 P  E   P  A  E   P  B  E   P C  E 
E E E
 P  A  .P    P  B  .P    P  C  .P  
 A B C
 C  P  C  E  P  C  .P  E / C  24
P    
E PE PE 29
1 3 4 1 7
6. Required probability  .  . 
5 4 5 4 20
7. E1  A wins the match at the end of 11th
E2  B wins exactly one game
E  9
P 2  
 E1  11
60
8. A – diagnose correctly  P  A  
100
40
 
P A 
100

Sec: Sr.Super60 Page 2

Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
40
B1 - death after correct diagnosis  P  B1  
100
70
B2 - death after wrong diagnosis  P  B2  
100
 B1 
P  A  .P  
 B1   A
P  
 A  P A .P  B1   P A .P  B2 
   
 A
 
 
 A
60 40

100 100 4 6 6
   
60 40 40 70 24  28 6  7 13
.  
100 100 100 100
9. E – two balls are white
A – two balls are white
B – three balls are white
C – four balls are white
E
P  C  .P  
C  C
P  
E E E E
P  A  . P    P  B  . P    P  C  .P  
 A B C 
1 4C2
.
3 4C2 6 3
  
1 2C 1 3 C 1 4C
. 2  . 2  . 2 1 3 6 5
3 4C2 3 4C2 3 4C2
10. Possibilities are 1R, 2G,3B  or  2 R,1G, 3B 
 Required probability
 3C .3C 1C .2C .3C   3C .3C 1C .2C .3C 
 2 1  1 1 1  1 2  1 1 1 
 6C3 6C3   6C3 6C3 
 3.3 1.2.3  27
 2  
 20 20  100
11.  P X  K  1

 K  1.a  1  a 1.1  2  1   3  1   4  1 3  .....   1
 3k
  
 3
 2
3 
 
 3

k 0  
 1 
 1. 
 1 3 
 a.   2
1
1  1 1  1  
 3  3  
3 3 4
a    1 a 
2 4 9
n
Cr .q n  r . p r
12. n is independent of n and r
Cn r .q r . p n r

Sec: Sr.Super60 Page 3

Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
n 2r
q
   is independent of n and r n Cr  n Cn  r 
 p
q
  1  p  q ____(1)
p
But p  q  1____(2)
1
 1 ,  2   p  q 
2
nC4 nC nC
13. P  X  4  n
, P  X  5  n 5 , P  X  6   n6
2 2 2
nC4 nC5 nC6
 n , n , n are in A.P
2 2 2
 nC4 , nC5 , nC6 are in A.P
2
  n  10   n  2  n  7 or 14

14.  x P  x  x   1.3  mean

i i

 0.P  x  0  1.P  x  1  2.P  x  2   3.P  x  3  1.3

 0  1.P  x  1  2.  0.3  6 P  x  1  1.3
 7 P  x  1  1.3  0.6  0.7
 P  x  1  0.1 and P  x  3  0.2
But P  X  0   P  X  1  P  X  2   P  X  3  1
P  X  0   0.1  0.3  0.2  1  P  X  0  0.4
15. Sum of all probabilities = 1

Ck C C2 C3
k 1 K
 1 
1 2

3
 ....  1

 eC  1  1
 e c  2  C  log e2
50 49
16. 100
C50 1  P  .P 50 100 C51 1  P  .P 51
100
1 P C51 100  51  1 50
   100

P C50 51 51
51
 51  51P  50 P  P 
101
2 1
.
2
17. P (actually one)  3 6 
2 1 1 5 7
.  .
3 6 3 6
18. P(getting 9) = P (getting 9 on dice) + P (getting 9 from the set)
7 4 8 3 28 24 121
 .     
15 36 15 7C2 15  36 15  21 945
e  . 2 9.e   . 4 90.e  . 6
19.  
2 4 6
 2 9 4 90 6
  
2 24 720
Sec: Sr.Super60 Page 4
Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
 4 2  3 4   6
  4  3 2  4  0
   2  4   2  1  0    1
Mean    1 and S .D    1  1
0
e0.02   0.02 
20.  P  X  0   e0.02
0
 no of lots  10000  e 0.02  9980
n 1 1 7
21. .  .1 
n 1 2 n 1 12
14  n  1
 n2
12
 6n  12  7 n  7  n  5
22. Required probability  P  RRR   P  RBR   P  BRR   P  BBR 
6 5 6 6 6 5 4 4 7 4 7 6 32
              0.58
10 11 10 10 11 10 10 11 10 10 11 10 55
23.
X  xi 0 1 2 3
P  X  xi  5
3
 1  5 
2 2
1 5 1
3

  3C1     3C2      
6  6  6   6  6 6

3  5 1 16 2
P (at least 2) = P  X  2   P  X  3 
 3 3  0.074
63 6 6 27
24. P (at least 3 dies to show 5 or 6)  P  X  3
 1   P  X  0   P  X  1  P  X  2 
6 5 2 4
 2  1  2   1   2  
 1  6C0    6C1      6C2     
 3  3  3   3   3  
496
 1
729
 496 
 Expectation  729 1    233.00
 729 
1 1
.
25. Required probability  3 10
1 1 1 2 1 1
.  .  .
2 5 6 5 3 10
1 1
   0.16
3  2 1 6

Sec: Sr.Super60 Page 5

Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
PHYSICS
26. Conceptual
27. I C RL  VCE  8  4  10 3  RL  4  1  8
 RL  1k 
28. Conceptual
29. i  nevA  i  nv
i  nv
i1 n1v1 v 7 5 5
  1   
i2 n2 v2 v2 4 7 4
R 5
30. Power gain  L   2   60  60  9000
Rin 2
31. Conceptual
32. Conceptual
33. Conceptual
Vi  VL V  VL
34. IL  n IL    n  1 I L  RS  i
Rs  n  1 I L
35. Resistance of metals increases and of semi conductors decreases with increase
in temperature.
36. Conceptual
37. Conceptual
38. Fermi energy level is nearer to conduction band for n-type and valence band for p-
type semiconductors
 15  10 10   1 1 
39. IZ    A   1000 mA
 500 1500   100 150 
 20  10
  10   mA  mA  3.33mA
 3  3
I  5  1
40. IC  100  I B  I B  C   3    5 105 A
100  10  100
RB  I B  10 (neglecting VBE )
 RB  5  10 5  10  RB  2  105 
41. Truth table corresponds to OR gate
Y  A B
 Output of X  B , which is A.B
42. The combination corresponds to  A  B  .  A.B 
(A OR B) AND (NOT (A AND B))
43. Photodiode detects presence of light by producing current proportional to intensity
of incident light.
44. Electrons are negatively charged;
Holes behave like positive charges.
45. Conceptual
P V'
46. I  where V '  2.6  0.6  2 volts
V R

Sec: Sr.Super60 Page 6

Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
150  10 3 2
 
0.6 R
2  0.6 120
R 3
  8
150  10 15
I 2.5 1
47. I B  C  3
 106  A  25 A
 2 10 15
 0.99
48.     99
1   0.01
R 10
 Voltage gain AV    L  99   990
Ri 1
P 1 P
49. I  2
  0 E02 c  E02 
4 d 2 2 d 2 0c
0.1 104
E02    5.995
2 12  8.85 1012  3  108 6  88.5
 E0  2.45V / m
50.   e  h  h  ne e  , here ne e is negligible
 1.6  10 19  5  1020  0.048  3.84 1m 1

CHEMISTRY

N
51) Kb of H = 1.3×10–3
=2.5×10-4
N
Kb of N =2.3×10–9; Kb of H
Hence, decreasing order of basicity is III > I > II
OH OH

 3 2
CH CO O

Pyridine/Room temp.

NH2 NHCOCH3
52)
53) pKb
CH3CH2NH2 3.29
CH 3CH 2  NHCH 2 CH 3 3.00
CH3

H3C N CH3 4.22

CH3

Ph  N  H 9.30
1
pK b 
Basicity
Hence, the correct order is S < R < P < Q.
NH2
NaNO2

Aq. HCl ,0.5C

54)
Sec: Sr.Super60 Page 7
Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s

N2 OH
H 2O
 
 N2
 


55)
COOH COONH4 CONH2 NH2

 Br2 / KOH
NH3
    
Hoffmann

Bromamide
reaction C
A B
(C7H6O2) Benzamide Aniline
Benzoic acid (C6H7N)

56)
O O O
C OEt C H N
OEt DIBAL H

 i ) Ni / H 2

  
H2O

CN
CH 2  CH 2  NH 2 CH2 CH2 NH2

57) As carbylamines test is given by primary amines only, thus C3H9N should be a
primary amine.
CH 3CH 2CH 2 NH 2 or CH3  CH  CH3
NH2
Amide gives primary amine on reaction with Br2/NaOH. Thus, X is
CH3CH2CH2CONH2.
58) (2), (3) and (4) are localized lone pairs and available for protonation.
59) LiAlH4 reduces aldehyde and carboxylic acids to alcohols and nitro group to amino
group.
C C
But LiAlH4 cannot reduce
O OH OH

LiAlH 4  excess 
 
CH3 CH3

NO2 O NH2 OH
60)
CN CH  NH
CHO
i ) DIBAL H 
  ii ) H 3O

O O OH
H
O OH O
61) More nucleophilic is the nitrogen in the compound, more reactive it will be with
alkyl halide. Hence, the correct order is B < A < C < D.
62)

Sec: Sr.Super60 Page 8

Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
H3C O H3C O
C NH2 C OH
i ) NaNO2 / H 
O 
 O

ii) CrO3/H+

HO
 H3C O COOH
H , C
CH3COOH 
 H 2O

O
O
63)
NH2 N NCl- Cl
NaNO2 / HCl
   CuCl / HCl
 


Sandmeyer's
reaction
64)
CH3 CH3 CH3 CH3

NaNO2 CuCN / KCN H 2O


HCl   
H
 05 C 
NH2 N2+Cl- CN COOH
p-Toluic acid
65) H 3C  CH 2  CH 2  CH 2  NH 2
n-Butylamine (Primary amine)
CH 3  CH 2  NH  CH 2  NH 2
Diethylamine (secondary amine)
 CH 3 2 N  C2 H 5
N,N-Dimethylethyl amine (Tertiary amine)
Primary amines have two hydrogen atoms available for hydrogen bond formation,
while 20 amines have only hydrogen atom. 30 amines do not have intermolecular
association due to absence of isomeric atom. Thus, order of boiling points of
isomeric amines is as follows:
30  20  10 or III  II  I .
66)
NH2 NH2 N2Cl- Cl
Br Br Br Br Br Br
Br2 / H 2O NaNO2 / HCl Cu2Cl2
      HCl

05C

aniline Br
Br Br
(X) (Y) 2,4,6-Tribromo
chlorobenzene
(Z)

67)    NH 2  is close to –COOH, in    NH   , the lone pair of electrons is involved

in resonance, and the lone pair on    N   is intact on N-atom.
68. Conceptual
69. Only primary amine can be prepared by Gabriel phthalimide reaction with better
SN 2
Sec: Sr.Super60 Page 9
Sri Chaitanya IIT Academy 05-10-2020_Sr.Super60(In Com)_Jee-Main_WTM-38_Key & Sol’s
70. Basic strength in aq.solution  C2 H 5 2 NH  C2 H 5 NH 2  NH 3
71.
CH 3

CH 3CH 2CH 2CH 2 CH 3CH 2CH  CH 2 CH 3  C  NH 2

CH 3
NH 2 NH 2 CH3  CH  CH 2 NH 2 CH 3
1) 2) 3) 4)
72. CH 3CN
73. Lone pair on ‘N’ which involves in delocalization is less basic
74.
CH 3
CH 2CH 3 CH 2  NH  CH 3
CH 2CH 2CH 3 CH  CH 3

CH 2 NH 2 CH 3
NH 2 NH 2
75. Amines ‘N’ is no directly attached to benzene ring.

Sec: Sr.Super60 Page 10