HOMEWORK.NO.

(4)

ELZUBAIR BABIKER FADLULMOULA HUSSAIN

INDEX:152011

:PROPLEM 2.B

Degree of freedom table:

# of stream variables 4
R 1
Temperatures 2
Q 1
∑ 8
Givens
M.B 3
Conversion 1
Basis 1
E.B 1
Temperatures 1
Q 1
∑ 8
DF ZERO

Independent Unknown variables:

Stream 1 2 ∑
#Independent 4 + 1R =
0 3
variables 5
T 0 1
F2, M2 , H2,
Selection - r
T2
+ Number of independent equations = MB equations + EB equations
conversion = 3 + 1 + 1 = 5 (O.K) equal to the number of independent
.variables

THE CODE
function f=zubair_homework4(x)

basis CH3OH =1000mol/h%

:variable heat capacities%
;Tref=25+273
;T1=675+273
Hr(at 25) = 20.38kcal/mol%
;M2=x(1);H2=x(2);F2=x(3);r=x(4);T2=x(5)
;ah=13704*10^-3;bh=40085*10^-5;ch=-23092*10^-8
;am=75.75*10^-3;bm=16.83*10^-5
;af=34.28*10^-3;bf=4.268*10^-5
:material balance%
;f(1)=M2-1000+r
;f(2)=H2-r
;f(3)=F2-r
:conversion relation%
;f(4)=((1000-M2)/1000)-0.25
;HH=ah*(T2-Tref)+bh/2*(T2^2-Tref^2)+ch/3*(T2^3-Tref^3)
;HM2=am*(T2-Tref)+bm/2*(T2^2-Tref^2)
;HM=am*(T1-Tref)+bm/2*(T1^2-Tref^2)
;HF=af*(T2-Tref)+bf/2*(T2^2-Tref^2)
:energy balance%
f(5)=r*(20.38*1000)+(((H2*HH)+(F2*HF)+(M2*HM2))*(T2-298))-1000*HM(T1-
;298)
end
:script file
;x0=10*ones(1,5)
;x= fsolve (@zubair_homework4,x0)
;M2=x(1);H2=x(2);F2=x(3);r=x(4);T2=x(5)
fprintf('The temperature of stream 2 = %6.3f \n',T2)
 NO. of variables 8
EXTENT OF REACTION 1
Temperature 3
Q 1
Basis 2
Material Balance 5
Temperature 3
Energy Balance 1
Conversion 1
relation 1
DF Zero
Problem 3: a

:DF table

:TABLE OF INDEPENDENT UNKOWN VARIABLEs

.STREAM NO 1 2 3 SUM
Number of - 1 5 5+1+2
variable
Variable N N,O,NO,W,A Q,,r
SELECTION

Number of independent eq=8

M.B=5

E.B=1

RELATION=1
Conv.=1

D.F=NUM. OF I. VARIABLE - NUM. OF I. EQ=8-8=0

correctly specified

:MATERIAL BALANCES
A3-1+4*r=0 /NH3 BALANCE
o3-2.4-5*r=0 /O2 BALANCE
N2: N3-N2=0 /N2 BALANCE
NO3-4*r=0 /NO BALANCE
W3-6*r=0 /H2O BALANCE

:Conversion equation

N3-0.9=0-1

:RELATION%
N2-(2.4*0.79/0.29)=0

:E.B%
Q=r*-1630.52*1000+
(W3*4.18/18+A3*2.2/19+O3*0.918/32+N3*1.04/14+NO3*0.995/30)*(920-25)-(750-
25)*(2.2*0.918/32+N2*1.04/28)

:FUNCTION
function f=zubair_tut4(x)
%Basis:
%O2 = 2.4 mol
%NH3= 1 mol
%Variables:
N2=x(1);N3=x(2);O3=x(3);NO3=x(4);W3=x(5);A3=x(6);Q=x(7);r=x(8);
%Equations:
%Material Balance Equation:
f(1)= A3-1+4*r;
f(2)=o3-2.4-5*r;
f(3)= N3-N2;
f(4)=NO3-4*r;
f(5)=W3-6*r;
%Conversion Equation:
f(6)=1-N3-0.9;
%Air Relation:
f(7)=N2-(2.4*0.79/0.29);
%Energy Balance:
f(8)=-Q+r*-1630.52*1000+
(W3*4.18/18+A3*2.2/19+O3*0.918/32+N3*1.04/14+NO3*0.995/30)*(920-25)-
(750-25)*(2.2*0.918/32+N2*1.04/28);
end

SCRIPT:

%Initial guess 10 for all 8 Variables:

x0=10*ones(1,8);
x= fsolve (@zubair_tut4,x0);
fprintf('THE VLAUE OF RATE OF HEAT ROMOVAL PER 1 MOLE NH3=
%6.2f\n',x(7))