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Answer keys : AIATS For One Year JEE(Advanced)-2021 (XII Studying)_Test-7A_Paper-2

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AIATSOY12JA21T7AP2_Section_1
SECTION - 1
One or More Option Correct Type

This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which
one or more than one is/are correct.

Question : 1

A planet of mass ‘M’ and radius ‘R’ is having a smooth tunnel as shown in figure. A particle of mass ‘m’ is released from
surface of planet into the tunnel. Then choose the correct statement(s).

Options:

Velocity of particle when it reaches Q is

Velocity of particle constantly increases

Velocity of particle first increases and then decreases

Velocity of particle at Q is independent of path taken

Solution :

Answer (A, C, D)

Hint :

Solution :

Using energy conservation

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Question : 2

A particle of mass ‘m’ tied to a string is projected horizontally with velocity where ‘R is length of string as

shown in figure. A force always acts tangentially opposite to the velocity of particle. Then

Options:

Velocity of particle when angle made by string is 60° with vertical is

Velocity of particle when angle made by string is 60° is

Tension in the string at point P is

Tension in the string at point P is 4mg

Solution :

Answer (A, C)

Hint :

Apply work-energy theorem and dynamics of circular motion.

Solution :

Using work energy theorem between starting point and point P.

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Question : 3

Kinetic energy of a particle moving under the action of conservative force is given as k = cx2, where c is a positive constant,
k = kinetic energy, x = displacement. Then choose the correct graph. (Given at t = 0, x = a)

Options:

Solution :

Answer (A, B, C)

Hint :

Solution :

k = cx2

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Question : 4

A particle of mass 5 kg constrained to move along a straight line is acted upon by a time varying force, whose acceleration
vs time relation is drawn in the diagram. Initially velocity of particle is 5 m/s. Then choose the correct statement for t = 0 to
20 seconds interval.

Options:

Maximum force acting on the particle is 50 N

Maximum speed of particle is 30 m/s

Maximum speed of particle is 20 m/s

Speed of particle at t = 20 s is 20 m/s

Solution :

Answer (A, B, D)

Hint :

Area of a-t curve gives change in velocity.

Solution :

So,

= Area under the curve from 0 - t sec.

at t = 10 s

Speed of particle at t = 20 s = 20 m/s

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Question : 5

If the potential difference applied across the X-ray tube is increased then which of the following statement(s) is/are true?

Options:

Minimum wavelength of radiation will increase

Minimum wavelength of radiation will decrease

Intensity of radiation will increase

Characteristic wavelengths will decrease

Solution :

Answer (B, C)

Hint :

Solution :

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Question : 6

A conductor of mass m, length l and resistance R is pulled towards right with constant horizontal force F. There is magnetic
field of magnitude B acting into the plane of paper. Initially speed of rod is zero. Then, choose the correct statement(s).

Options:

Maximum velocity of rod is

Maximum velocity of rod is

Maximum current in the circuit is

Maximum current in the circuit is

Solution :

Answer (A, D)

Hint :

Solution :

F – Fm = ma

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Question : 7

Ammeter shown is ideal. Voltmeters used are non-ideal having resistance of

Case I : Voltmeter is connected across R1; Reading of ammeter is I1.

Case II : Voltmeter is connected across R2; Reading of ammeter is I2.

Case III : Two voltmeters are connected across R1 and R2 respectively. Reading of ammeter is I3. Then, choose the correct
statement(s).

Options:

I1 = 4 A

I2 = 3 A

I3 = 4.8 A

I3 = 4 A

Solution :

Answer (A, B, C)

Hint :

Apply KCL and KVL.

Solution :

Case I :

Similarly for case II and case III.

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Question : 8

When a photon of energy falls on a metallic surface, photoelectrons are ejected from it. Work function of metallic

surface is Then choose the correct statement(s).

Options:

Maximum kinetic energy of photoelectrons is

Kinetic energies of all photoelectrons are

Minimum kinetic energy of photoelectrons is zero

If number of photons falling on metallic surface is doubled then maximum kinetic energy is also doubled

Solution :

Answer (A, C)

Hint & Solution:

Conceptual

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AIATSOY12JA21T7AP2_Section_2
SECTION - 2
Integer Value Correct Type

This section contains 6 questions. The answer to each of the questions is a double-digit integer, ranging from 00 to 99. For
example, if the correct answers to question numbers X, Y and Z (say) are 76, 0 and 9, respectively, then mark 76, 00 and 09.

Question : 9

Current density through a long straight conductor is given as where from axis of

conductor. Magnetic field due to conductor is same at two points from axis of conductor. One point is lying away from

axis and other lies at ‘KR’ distance from axis. Find K.

Options:

Correct Answer User Answer

08 08

Solution :

Answer (08)

Hint :

Solution :

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Question : 10 skipped

Both the springs are in relaxed condition in equilibrium situation. If solid cylinder is disturbed slightly from this position, it

starts doing simple harmonic motion. There is no sliding at any place. If time period of oscillation is then C

= …….

Options:

Correct Answer User Answer

03

Solution :

Answer (03)

Hint :

Restoring torque,

Solution :

Total energy of SHM

Differentiating with respect to time,

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Question : 11 skipped

A viscous liquid is flowing through a tube of length ‘L’ and radius ‘R’ in such a way that velocity of liquid is given as

where ‘r’ is distance from axis of tube. If the pressure difference required across the tube to keep the

liquid flow steady is then find ‘k’. coefficient of viscosity of liquid.

Options:

Correct Answer User Answer

06

Solution :

Answer (06)

Hint :

Solution :

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Question : 12

Focal length of equiconvex lens is 30 cm and radius of curvature is 60 cm. One face of lens is silvered and a point object is
placed 20 cm from the lens. Find location of image (in cm) w.r.t. lens.

Options:

Correct Answer User Answer

20 60

Solution :

Answer (20)

Hint :

Combination behaves like an concave mirror.

Solution :

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Question : 13 skipped

In the given cyclic process internal energy at A and B are 10 J and 70 J respectively. If the efficiency of cycle is then

find K.

Options:

Correct Answer User Answer

04

Solution :

Answer (04)

Hint :

Solution :

= 220 J

QBC and QCA are negative

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Question : 14

In YDSE intensity at central maxima is 4I0. There are two points on screen, which are and away from central

maxima ( fringe width). If intensities at those two points are I1 and I2, then is

Options:

Correct Answer User Answer

02 02

Solution :

Answer (02)

Hint :

Solution :

At A,

At B,

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AIATSOY12JA21T7AP2_S15
SECTION -3
Matching List Type

This section contains 2 List-Match sets. Each List-Match set has 2 Multiple Choice Questions. Each List-Match set has two lists:
List-I and List-II. List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U). Four options
are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.

Answer the following by appropriately matching the lists based on the information given in the paragraph

In List-I circuit involving galvanometer is given. Full scale deflection of galvanometer is at current of 50 mA. List-II gives the
maximum value of current I which can flow through the circuit. Match the entries in List-I with List-II.

List-I List-II

I. (P) 200 mA

II. (Q) 150 mA

III. (R) 100 mA

IV. (S) 250 mA

(T) 175 mA
(U) 350 mA

Question : 15

If galvanometer’s resistance G = R, then correct match is

Options:

Solution :

Answer (B)

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Hint :

Based on KCL and KVL.

Solution :

A:

B:

C:

D:

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AIATSOY12JA21T7AP2_S16
Answer the following by appropriately matching the lists based on the information given in the paragraph

In List-I circuit involving galvanometer is given. Full scale deflection of galvanometer is at current of 50 mA. List-II gives the
maximum value of current I which can flow through the circuit. Match the entries in List-I with List-II.

List-I List-II

I. (P) 200 mA

II. (Q) 150 mA

III. (R) 100 mA

IV. (S) 250 mA

(T) 175 mA
(U) 350 mA

Question : 16

If galvanometer resistance G = 3R, then correct match is

Options:

Solution :

Answer (C)

Hint :

Based on KCL and KVL.

Solution :

A:

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B:

C:

D:

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AIATSOY12JA21T7AP2_S17_18
Answer the following by appropriately matching the lists based on the information given in the paragraph

A harmonic wave of amplitude A is travelling in string 1. At a junction with string 2 it is partly reflected and partly transmitted.
Linear mass density of string 1 is and string 2 is Frequency of incident wave is and wavelength of incident wave is
Frequency of transmitted wave in medium 2 is and wavelength of transmitted wave is Match the entries in List-I
with List-II.

List-I List-II
I. Ratio of amplitude of transmitted wave to that of incident wave is (P) 1

II. Value of is (Q) 8/9

III. Value of is (R) 1/2

IV. Ratio of power transmitted to that of power (S) 2/3


of incident wave is (T) 1/3
(U) 3/4

Question : 17 skipped

If n = 9, then correct match is

Options:

Solution :

Answer (A)

Hint :

Solution :

Frequency remain unchanged.

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AIATSOY12JA21T7AP2_S17_18
Answer the following by appropriately matching the lists based on the information given in the paragraph

A harmonic wave of amplitude A is travelling in string 1. At a junction with string 2 it is partly reflected and partly transmitted.
Linear mass density of string 1 is and string 2 is Frequency of incident wave is and wavelength of incident wave is
Frequency of transmitted wave in medium 2 is and wavelength of transmitted wave is Match the entries in List-I
with List-II.

List-I List-II
I. Ratio of amplitude of transmitted wave to that of incident wave is (P) 1

II. Value of is (Q) 8/9

III. Value of is (R) 1/2

IV. Ratio of power transmitted to that of power (S) 2/3


of incident wave is (T) 1/3
(U) 3/4

Question : 18 skipped

If n = 4, then correct match is

Options:

Solution :

Answer (B)

Hint :

Solution :

Frequency remain unchanged.

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AIATSOY12JA21T7AP2_Section_1
SECTION - 1
One or More Option Correct Type

This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which
one or more than one is/are correct.

Question : 19

B and C are polar and neutral respectively, ‘A’ is non-polar and acidic, ‘C’ gas is condensed and liquid formed has pH = 7.
The correct statement(s) about A, B, C is/are

Options:

A gives milky white ppt with lime water

C is sp3 hybridised while A and B are sp hybridised at the central atom

B is non poisonous compound

B acts as a reducing agent while C does not

Solution :

Answer (A, B, D)

Hint :

Dehydration of oxalic acid with conc. H2SO4 gives CO, CO2 and H2O vapours.

Solution :

CO2 (A) is non-polar acidic, turns lime water milky

CO2 (A), CO (B) are sp hybridised while H2O (C) is sp3 hybridised.

CO (B) is poisonous

CO (B) acts as reducing agent, H2O (C) does not act as reducing agent.

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Question : 20

Halogens combine with each other to form compounds called inter halogens. Which of the following statement(s) is/are
correct?

Options:

Inter halogens are more reactive than any halogen

ClF reacts with water to form HCl and HOF

ClF3 has bent T shape

Total number of lone pair of electrons in BrF5 molecule is 16

Solution :

Answer (C, D)

Hint :

Interhalogen compounds are more reactive than their constituent halogens except F2.

Solution :

· Inter halogens are more reactive than halogens except F2.

More EN halogen gives hydrogen halide.

· ClF3, sp3d, AB3E2 type, L.P of electron present at equitorial positions.

So bent ‘T’ shape.

· BrF5

Central Br has one L.P. of electrons

Five ‘F’ each has 3 L.P of electrons

5 × 3 = 15

Total lone pair of electrons in BrF5

= 1 + 15 = 16

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Question : 21

Select the correct statement(s) about the carboxylic acids.

Options:

will give HVZ reaction

Formic acid (HCOOH) is more acidic than benzoic acid (C6H5COOH)

Maleic acid and fumaric acid are geometrical isomers

is more acidic than

Solution :

Answer (B, C, D)

Hint :

Carboxylic acids having at least one α H-atom undergoes HVZ reaction.

Solution :

(a) does not have α-hydrogen, so it does not give HVZ reaction.

(b) HCOOH (pKa = 3.77) is more acidic than benzoic acid (pKa = 4.17). Lesser the pKa, more the acidic strength.

(c) Maleic and Fumaric acids are geometrical isomers.

(d) Due to ortho effect (pKa = 3.91) is more acidic than (pKa = 4.17)

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Question : 22

The correct statement(s) about the products A, B, C and D is/are

Options:

A and C are aromatic while B is non aromatic

D reacts with conc. KOH to form disproportionation products

Compound C easily undergoes SN1 reaction

Degree of unsaturation changes in the conversion of A to C, not in the conversion of A to B

Solution :

Answer (A, B)

Hint :

n-Hexane on heating in presence of Cr2O3 and Al2O3 get oxidised to benzene which shows electrophilic aromatic substitution
reactions.

Solution :

(a) A and C are aromatic, B is non-aromatic.

(b)

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(c) Haloarenes not easily undergo SN1 reaction.

(d) DBE changes in the conversion of

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Question : 23

Which of the following statement(s) is/are not correct?

Options:

Buna-S is condensation copolymer

Nylon 6-6 is amide linkage copolymer

Bakelite is thermosetting copolymer

Terylene is fibre homopolymer

Solution :

Answer (A, D)

Hint :

Buna-S is an addition co-polymer and terylene is a fibre co-polymer.

Solution :

(a) Buna-S addition copolymer.

(b) Nylon-6, 6 amide linkage copolymer.

(c) Bakelite is thermosetting copolymer.

(d) Terylene is fiber copolymer.

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Question : 24

Which of the following statement(s) is/are correct?

Options:

AgBr shows both Frenkel and Schottky defects

Non stoichiometric NaCl is a yellow solid

Fe0.98O has non stoichiometric metal excess defect

Schottky defect in crystals is observed when the sizes of cation and anion are in large difference

Solution :

Answer (A, B)

Hint :

Schottky defects and Frenkel defects are shown by higher CN ionic solids and lower CN ionic solids respectively.

Solution :

(a) AgBr shows both Frenkel and Schottky defect.

(b) Non stoichiometric NaCl is yellow solid. (F-centre)

(c) Fe0.98O has non stoichiometric metal deficiency defect.

(d) Schottky defect in crystals is observed when the sizes of cation and anion are in small difference.

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Question : 25

A binary solution of two volatile liquids A and B is in equilibrium with their vapours at 353 K and a total pressure of 200 mm
Hg. At 353 K the vapour pressure of pure ‘A’ and ‘B’ are 230 and 170 mm Hg, respectively and these compounds form a
nearly ideal solution.

Select the correct relation(s).

Options:

The mole fraction of B in liq. phase = 0.6

The mole fraction of A in liq. phase = 0.5

The mole fraction of B in vapour phase = 0.425

The mole fraction of A in vapour phase = 0.425

Solution :

Answer (B, C)

Hint :

According to Raoult’s law, total vapour pressure of an ideal solution of two volatile liquids is given by

Solution :

Given,

nA = Number of moles of A (liquid + vapour)

nB = Number of moles of B (liquid + vapour)

, ,

We know PT = PA + PB

Mole fraction of A in vapour phase

YB, mole fraction of ‘B’ in vapour phase

= 1 – 0.575 = 0.425

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Question : 26

In an iodometric estimation, 0.2 mol of CuSO4 was added to excess of KI solution and the liberated iodine required 200 ml
of sodium thiosulphate. About this titration which is/are correct?

Options:

In this titration oxidation state of Cu decreases from +2 to +1

The strength of sodium thiosulphate is 158 g/lit

The indicator used is starch

Equivalent weight of sodium thiosulphate is

Solution :

Answer (A, B, C)

Hint :

CuSO4 oxidises KI to I2 and itself gets reduced to Cu2I2.

Solution :

O.S. of Cu changes from +2 to +1.

n-factor of sodium thiosulphate is 1.

So, Eq. Wt. =

· Number of equivalents of CuSO4 = Number of equivalents of I2

= Number of equivalents of Na2S2O3

× Normality of Na2S2O3

∴ Normality of Na2S2O3 = 1

Molarity N2S2O3 = 1 M = 158 g/lit

( Mwt of Na2S2O3 = 158)

· In iodometric titration starch is used as indicator.

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AIATSOY12JA21T7AP2_Section_2
SECTION - 2
Integer Value Correct Type

This section contains 6 questions. The answer to each of the questions is a double-digit integer, ranging from 00 to 99. For
example, if the correct answers to question numbers X, Y and Z (say) are 76, 0 and 9, respectively, then mark 76, 00 and 09.

Question : 27

(i)

(ii)

Then p + q + x + y = ________.

Options:

Correct Answer User Answer

12 11

Solution :

Answer (12)

Hint :

Amides react with Br2 and KOH to give amine and butanone gives iodoform with I2 and KOH.

Solution :

(i)

(ii)

p + q + x + y = 3 + 4 + 1 + 4 = 12

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Question : 28

From the standard potentials shown in the following diagram, calculate the value of to the nearest integer.

Options:

Correct Answer User Answer

17 15

Solution :

Answer (17)

Hint :

For a reduction process involving gains of ‘n’ electrons, the standard free energy change is related to Eo by the following
equation.

Solution :

(i)

(n = 5 – 1 = 4 e–)

(ii)

(n = 1 – 0 = 1)

(n = 5 – 0 = 5)

From (i) & (ii)

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(iii)

From (i), (ii), (iii)

= 1.1353 V

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Question : 29

If 0.50 g of the organic compound on heating with NaOH gives NH3, which is neutralised by 100 mL of 0.1 M H2SO4. The
percentage of nitrogen in the organic compound would be

Options:

Correct Answer User Answer

56 56

Solution :

Answer (56)

Hint :

Nitrogen present in an organic compound is estimated by volumetric analysis of NH3 gas evolved from a known mass of the
organic compound.

Solution :

0. 1 M H2SO4 = 0.1 × 2 = 0.2 N;

V = 100 mL, Wt = 0.50 g

%N=

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Question : 30

The screening constant values for 4 s electron of zinc is ‘x’. The screening constant value for 2 p electron of oxygen is ‘y’.
Then find the value of (x + y) to the nearest integer.

Options:

Correct Answer User Answer

29 28

Solution :

Answer (29)

Hint :

Screening constant of valance electrons is determined by Slater’s rule.

Solution :

The electronic configuration of zinc (30) is

1 s2 2 s22 p6 3 s23 p6 3 d10 4 s2

σ = (10 × 1.0) + (18 × 0.85) + (1 × 0.35)

= 25.65 = x

The electronic configuration of oxygen 1 s2 2 s2 2 p4

σ = (2 × 0.85) + (5 × 0.35) = 3.45 = y

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Question : 31

, calculate the standard internal energy change to the nearest integer (in kJ) during the

course of above reaction at equilibrium at 300 K. Given KP = 10–10 bar–2 and ΔSo = 5 J K–1.

Options:

Correct Answer User Answer

64 64

Solution :

Answer (64)

Hint :

For a gaseous equilibrium mixture,

and

Solution :

ΔGo = –2.303 RT log Kp

= –2.303 × 8.314 × 300 × log 10–10

= –2.303 × 8.314 × 300 × (–10) J

= 57.44 kJ

Now,

57. 44 kJ = ΔHo – 300 × 5 × 10–3 kJ

{ ΔS = 5 JK–1 = 5 × 10–3 kJ K–1]}

Also,

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Question : 32

The van der Waal’s constants for a gas are a = 1.92 atm L2 mol–2 and b = 0.06 L mol–1. If R = 0.08 L atm K–1 mol–1, the
difference in value of Boyle's temperature (Tb) and critical temperature (in K) of the gas = 10 × T, then find the value of T in
kelvin to the nearest integer.

Options:

Correct Answer User Answer

28 28

Solution :

Answer (28)

Hint :

Boyle temperature (Tb) and critical temperature of a real gas are related to van der Waal’s constant as

and

Solution :

Boyle temperature

Critical temperature

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AIATSOY12JA21T7AP2_S33
SECTION -3
Matching List Type

This section contains 2 List-Match sets. Each List-Match set has 2 Multiple Choice Questions. Each List-Match set has two lists:
List-I and List-II. List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U). Four options
are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.

Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I includes starting reactants and reagents of selected chemical reactions. List-II contain tests of intermediates and (or) final
products from the reactions of List-I.

List-I List-II

I. (P) 2, 4-DNP

II. (Q) Tollen’s reagent

III. (R) Br2/CCl4

IV. (S) Haloform test

(T) Ammonical cuprous chloride


(U) Lucas reagent (at room temperature)

Question : 33 skipped

Which of the following options has correct combination considering List-I and List-II?

Options:

I → Q, T, U

II → R, S, U

III → P, Q, R, S, T

IV → Q, S, T

Solution :

Answer (C)

Hint :

Vinyl halide undergoes dehydrohalogenation with NaNH2 to give ethyne which on hydrolysis give acetaldehyde.

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AIATSOY12JA21T7AP2_S34
Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I includes starting reactants and reagents of selected chemical reactions. List-II contain tests of intermediates and (or) final
products from the reactions of List-I.

List-I List-II

I. (P) 2, 4-DNP

II. (Q) Tollen’s reagent

III. (R) Br2/CCl4

IV. (S) Haloform test

(T) Ammonical cuprous chloride


(U) Lucas reagent (at room temperature)

Question : 34 skipped

Which of the following options has correct combination considering List-I and List-II?

Options:

II → Q, S, U

IV → P, R, S, T

III → P, Q, T, U

I → P, Q, S

Solution :

Answer (D)

Hint :

Ethyl chloride reacts with aq. KOH to give ethanol which is oxidised by hot Cu to acetaldehyde.

Solution :

(I)

It gives test with 2, 4 DNP (P), Tollen’s reagent (Q), Haloform test (S)

I → P, Q, S

(II)

It gives test with 2, 4 DNP (P), Tollens’ reagent (Q)

II → P, Q

(III)

41/65
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It gives test with 2, 4 DNP (P), Tollen’s reagent (Q), Haloform test (S) with Br2/CCl4 (R), Ammonical cuprous chloride (T), CH ≡
CH give test.

III → P, Q, R, S, T

(IV)

It gives test with 2, 4 DNP (P), Haloform test (S).

IV → P, S

42/65
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You scored 0 of 3

AIATSOY12JA21T7AP2_S35_36
Answer the following by appropriately matching the lists based on the information given in the paragraph

Consider the hybridisation, structure, magnetic nature and magnetic moment based on VSEPR theory and CFT. (List-II) about
the following complexes given in List-I.

List-I List-II

I. [Cu(NH3)4]+2 (P) sp3

II. [NiCl4]–2 (Q) dsp2 or sp2d

III. [Ni(CN)4]–2 (R) Paramagnetic

IV. [Ni(CO)4] (S) Diamagnetic

(T) Magnetic moment μ = 2.828


(U) High spin complex

Question : 35 skipped

Which of the following options has the correct combination considering List-I and List-II.

Options:

I → P, R

II → P, R, T, U

III → Q, R, T

IV → P, R, T, U

Solution :

Answer (B)

Hint :

[NiCl4]–2 is paramagnetic and an outer orbital high spin complex.

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You scored 3 of 3

AIATSOY12JA21T7AP2_S35_36
Answer the following by appropriately matching the lists based on the information given in the paragraph

Consider the hybridisation, structure, magnetic nature and magnetic moment based on VSEPR theory and CFT. (List-II) about
the following complexes given in List-I.

List-I List-II

I. [Cu(NH3)4]+2 (P) sp3

II. [NiCl4]–2 (Q) dsp2 or sp2d

III. [Ni(CN)4]–2 (R) Paramagnetic

IV. [Ni(CO)4] (S) Diamagnetic

(T) Magnetic moment μ = 2.828


(U) High spin complex

Question : 36

Which of the following options has the correct combination considering List-I and List-II.

Options:

IV → Q, S, U

III → Q, S, U

I → Q, R

II → P, S, U

Solution :

Answer (C)

Hint :

[Cu(NH3)4]2+ is paramagnetic square planar complex.

Solution :

(I) [Cu(NH3)4]+2 :

sp2d (Q), square planar, paramagnetic (R), magnetic moment = 1.732

I → Q, R

(II) [NiCl4]–2 : Ni+2, Cl– → WFL

sp3 (P), paramagnetic (R), μ = 2.828 (T), High spin complex (U).

II → P, R, T, U

(III) [Ni(CN)4]–2, Ni+2, CN– → SFL

44/65
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dsp2 (Q), diamagnetic (S), μ = 0, low spin complex

III → Q, S

(IV) [Ni(CO)4]; Ni0, CO → SFL

sp3 (P), diamagnetic (S), low spin complex

IV → P, S

45/65
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You scored 2 of 4

AIATSOY12JA21T7AP2_Section_1
SECTION - 1
One or More Option Correct Type

This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which
one or more than one is/are correct.

Question : 37

If tangent of any member of family of hyperbola , is not a normal to member of family of

circles where λ is a parameter, then θ belongs to

Options:

Solution :

Answer (A, B, C)

Hint :

Any tangent to is

Solution :

Any tangent to is

If it is normal to any circle of given family, it will pass through (1, 1)

for non real roots D < 0

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You scored 4 of 4
Question : 38

Let where and . If α and β are real roots of f(x) = 0 such that

, then the number of ordered pairs (q, p) is

Options:

A prime number

Composite number

Even number

An odd number

Solution :

Answer (A, D)

Hint :

Solution :

Hence 5 ordered pairs are possible for (q, p).

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You scored 4 of 4
Question : 39

Let a differentiable function satisfy the relation and , f(0) = 1, then which of

the following is/are correct?

Options:

Number solutions of f(x) = x2 is 2

Number of solutions of f(x) = x2 is 1

Solution :

Answer (A, D)

Hint :

Put y –1 = t

Solution :

Let y – 1 = t

then

Partially differentiating w.r.t. t, we get

and t = 0

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You scored 2 of 4
Question : 40

A rod of length 2 units whose one end is (1, 0, –1) and the other end lies on the plane then

Options:

The rod sweeps a figure of volume π cubic units

The area of the region which the rod traces on the plane is 2π sq. units

The length of the projection of the rod on the plane is units

The centre of the region which the rod traces on the plane is

Solution :

Answer (A, C, D)

Hint :

The rod sweeps a cone of height 1 and radius units

Solution :

If M is foot of perpendicular for A to the plane then

⇒ and AM = 1

⇒ Radius =

Volume of the cone =

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You scored 4 of 4
Question : 41

If x satisfies the equation (0 < α < π). Then the value(s) of x

is/are

Options:

Solution :

Answer (A, B)

Hint :

When 0 < x < π,

Solution :

Clearly

and also ( it is an odd function)

⇒ ⇒

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You scored 0 of 4
Question : 42 skipped

If a parabola touches the line y = x and y = –x at A(3, 3) and B(1, –1) respectively, then which of the following is/are correct?

Options:

Equation of directrix is 2x + y = 0

Equation of line through origin and focus is x + 2y = 0

Focus is

Directrix passes through (1, –2)

Solution :

Answer (A, B, D)

Hint :

(0, 0) lies on the directrix

Solution :

y = x and y = –x are perpendicular

⇒ (0, 0) lies on the directrix

Line joining midpoint of AB and (0, 0) is parallel to axis. Equation of AB is 2x – y – 3 = 0

⇒ Focus =

Equation of directrix is y = –2x

Equation of line through origin and focus is x + 2y = 0

51/65
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You scored 1 of 4
Question : 43

The function f(x) is given as . Then, which of the following is/are true?

Options:

f(x) has 3 inflection points

f(x) is strictly increasing for and strictly decreasing for

f(x) is concave down in

Area enclosed by the curve lying in the fourth quadrant is square units

Solution :

Answer (B, C, D)

Hint :

Draw graph of y = f(x)

Solution :

and x = 0 gives vertical tangent gives inflection point.

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You scored 4 of 4
Question : 44

Let and Then

Options:

Solution :

Answer (B, C)

Hint :

Solution :

where and f(x) is increasing function

53/65
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You scored 0 of 3

AIATSOY12JA21T7AP2_Section_2
SECTION - 2
Integer Value Correct Type

This section contains 6 questions. The answer to each of the questions is a double-digit integer, ranging from 00 to 99. For
example, if the correct answers to question numbers X, Y and Z (say) are 76, 0 and 9, respectively, then mark 76, 00 and 09.

Question : 45 skipped

and g(x) is a differentiable function satisfying

, then the maximum value of is

Options:

Correct Answer User Answer

04

Solution :

Answer (04)

Hint :

Solution :

and maximum value of

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You scored 3 of 3
Question : 46

If the equation of the curve on reflection of the ellipse about the line x – y – 2 = 0 is

then is equal to

Options:

Correct Answer User Answer

33 33

Solution :

Answer (33)

Hint :

Let be a point on the ellipse.

Solution :

Let be a point on the ellipse

The reflection of p about the x – y + 2 is (h, k)

Then,

The equation of image is

So, and

55/65
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You scored 0 of 3
Question : 47 skipped

Let the coefficients a, b, c of be in A.P and be positive real numbers. If α, β are the integral roots of the

quadratic equation, then the value of is equal to

Options:

Correct Answer User Answer

07

Solution :

Answer (07)

Hint :

b = a + d, c = a + 2d

Solution :

⇒ d = ak

α, β are roots of

⇒ = 12

k + q = 9 and k – q = 5

⇒k=7

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You scored 3 of 3
Question : 48

Let A and B be 3 × 3 matrices that are non-singular. Given that and and the sum of

digits in the value of (det A)2 + (det B)2 is k, then k is equal to

Options:

Correct Answer User Answer

11 11

Solution :

Answer (11)

Hint :

Apply transpose in one equation and substitute in other.

Solution :

...(i)

...(ii)

Using (i) in (ii) we get

But BT = A is only possible

⇒ ⇒ ,

∴ k = 11

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You scored 0 of 3
Question : 49 skipped

Let and if . Then, number of positive integral divisors k

which are greater than 10 is

Options:

Correct Answer User Answer

97

Solution :

Answer (97)

Hint :

Replace x by –x and add.

Solution :

Replace x by –x and adding we get

⇒ Number of divisors of k = 101

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You scored 3 of 3
Question : 50

Let be any function where A is a set containing the positive integral solution of the inequality

and B is the set of all divisors of the number 2010. If . If the total

number of mapping from A to B is λ then

Options:

Correct Answer User Answer

51 51

Solution :

Answer (51)

Hint :

Solution :

Clearly

⇒ x = 1, 2, 3

Number of mapping required

∴ λ = 816

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You scored 3 of 3

AIATSOY12JA21T7AP2_S51
SECTION -3
Matching List Type

This section contains 2 List-Match sets. Each List-Match set has 2 Multiple Choice Questions. Each List-Match set has two lists:
List-I and List-II. List-I has Four entries (I), (II), (III) and (IV) and List-II has Six entries (P), (Q), (R), (S), (T) and (U). Four options
are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these four options satisfies the
condition asked in the Multiple Choice Question.

Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I contains statements of probability and List-II contains the value of variable.

List-
List-I
II
I. If the probability of getting at least one head is greater than or equal to 0.8 in n trials then the value of n can be (P) 2
A mapping is selected at random from all mappings of the set S = {1, 2, 3, ....n} into itself. If the probability of the
II. (Q) 3
mapping being injective is , then the value of n can be

2
III. A number k is selected at random from {1, 2, 3, ....10}. If the probability that the quadratic equation 2x + 2kx + (R) 4
(k + 1) = 0 has real roots is p, then the value of 5p is greater than
A man is firing at a distant target. There is 20% chance to hit the target in one shoot. If p is the probability of
IV. (S) 5
hitting the target in n attempts where 20p2 – 13p + 2 ≤ 0, then the value of n is less than
(T) 6
(U) 7

Question : 51

Which of the following is only correct combination?

Options:

II → P, Q

I→P

III → P, Q

II → U

Solution :

Answer (C)

Hint :

Prob (at least one hit) = 1 – Prob (no hit)

Solution :

(I)

(II)

(III) k = 3, 4, 5, .....10 ⇒ 5p = 5

(IV)

60/65
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⇒n=2

You scored 3 of 3

AIATSOY12JA21T7AP2_S52
Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I contains statements of probability and List-II contains the value of variable.

List-
List-I
II
I. If the probability of getting at least one head is greater than or equal to 0.8 in n trials then the value of n can be (P) 2
A mapping is selected at random from all mappings of the set S = {1, 2, 3, ....n} into itself. If the probability of the
II. (Q) 3
mapping being injective is , then the value of n can be

2
III. A number k is selected at random from {1, 2, 3, ....10}. If the probability that the quadratic equation 2x + 2kx + (R) 4
(k + 1) = 0 has real roots is p, then the value of 5p is greater than
A man is firing at a distant target. There is 20% chance to hit the target in one shoot. If p is the probability of
IV. (S) 5
hitting the target in n attempts where 20p2 – 13p + 2 ≤ 0, then the value of n is less than
(T) 6
(U) 7

Question : 52

Which of the following is only incorrect combination?

Options:

II → S, T

I → Q, R, S

II → R

IV → Q, R

Solution :

Answer (A)

Hint :

Prob (at least one hit) = 1 – Prob (no hit)

Solution :

(I)

(II)

(III) k = 3, 4, 5, .....10 ⇒ 5p = 5

(IV)

⇒n=2

61/65
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You scored 3 of 3

AIATSOY12JA21T7AP2_S53_54
Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I contains equations List-II contains the values of variables.

List-
List-I
II

I. If , then 2k is less than (P) 3

II. If (in lowest form) then (m + n) is divisible by (Q) 4

Number of integral ordered pairs of (x, y) satisfying is greater


III. (R) 5
than
2 –1 –1
IV. The smallest positive integral value of n for which (n – 2)x + 8x + (n + 4) > sin (sin 12) + cos (cos12) ∀ x (S) 8
∈ R is less than
(T) 9
(U) 10

Question : 53

Which of the following is only correct combination?

Options:

II → P, T

III → R, S

II → R, S

III → T, U

Solution :

Answer (C)

Hint :

Solution :

(I) where n = 1, 2, 3, 4

(II) We have

62/65
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∴ m = 19, n = 21

(III) Using

⇒ (x – 10) (y – 10) = 101

(11, 111), (111, 11), (9, –91), (–91, 9) are 4 required ordered pairs.

(IV) Clearly

⇒ and

⇒ ⇒

So, smallest value of n = 5

63/65
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You scored 3 of 3

AIATSOY12JA21T7AP2_S53_54
Answer the following by appropriately matching the lists based on the information given in the paragraph

List-I contains equations List-II contains the values of variables.

List-
List-I
II

I. If , then 2k is less than (P) 3

II. If (in lowest form) then (m + n) is divisible by (Q) 4

Number of integral ordered pairs of (x, y) satisfying is greater


III. (R) 5
than
2 –1 –1
IV. The smallest positive integral value of n for which (n – 2)x + 8x + (n + 4) > sin (sin 12) + cos (cos12) ∀ x (S) 8
∈ R is less than
(T) 9
(U) 10

Question : 54

Which of the following is only correct combination?

Options:

IV → T, U

I → P, Q

IV → Q, R

III → S, T

Solution :

Answer (A)

Hint :

Solution :

(I) where n = 1, 2, 3, 4

(II) We have

64/65
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∴ m = 19, n = 21

(III) Using

⇒ (x – 10) (y – 10) = 101

(11, 111), (111, 11), (9, –91), (–91, 9) are 4 required ordered pairs.

(IV) Clearly

⇒ and

⇒ ⇒

So, smallest value of n = 5

65/65

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