SC2 – O’Malley SAT II Review (Solutions)

For 1 – 2: 5. Which is present in greater quantity solute, compared with the amount
a. Molarity in solution? of solvent, in a solution?
b. Formality For 10 – 11:
c. Density 6. Which is the interaction between a. i, ii and iii
d. Molality the solute and the solvent b. i and ii
e. Normality molecules? c. ii and iii
For 7 – 9: d. i only
1. Which is defined as moles of solute a. Dilute e. iii only
per kilogram of solvent? b. Concentrated
c. Unsaturated 10. The ionization of salts in water is
2. Which is defined as moles of solute d. Saturated useful in explaining
per liter of solution? e. Supersaturated i. Their unusually large solubility
in water
For 3 – 6: 7. Which is the condition, unrelated to ii. Their electrical conductivity in
a. Solute quantities, that indicates that the solution
b. Solvent rate going into solution is equal to iii. The lowered freezing points
c. Solubility the rate coming out of solution? and increased boiling points
d. Aqueous solution of their solutions
e. Solvation 8. Which is the condition that exists
when a water solution that has 11. Which of the following describe
3. Which is present in a lesser been at equilibrium is heated to a water?
amount in a solution? higher temperature with a higher i. Solvent for polar solutes
solubility, but no additional solute is ii. Polar molecule
4. Which describes a species in which added? iii. Good conductor of electricity
the solvent is water?
9. Which is the descriptive term that
indicates there is a large quantity of
Q Statement I Because Statement II
12. When a solute is added to pure water, the vapor Because All solutes dissociate into positive and negative ions
pressure of the water will decrease
13. NaCl(aq) is an electrolyte Because It forms ions in solution
14. A salt dissolved in an organic solvent will be a good Because Salts will not dissolve appreciably in an organic solvent
electrical conductor
15. A super saturated solution of glucose in boiling water Because The solubility increases as the temperature decreases
crystallizes as it cools
16. Salt dissolved in water lowers the freezing point Because The change in freezing point is given by: Tf = iKfm
17. Sodium chloride forms aqueous solution of ions Because The sodium has a +1 charge and the chloride has a -1 charge and
they are hydrated by the water molecules

18. What is the molarity if a 500 mL solution 22. About how many grams of sodium chloride
contains 20 g of CaBr2? would be dissolved in water to form a 0.5 26. A 1 molal solution of NaCl results when
a. 0.1 M M solution in 500 mL solution? 58.5 g of sodium chloride is dissolved in
b. 0.2 M a. 7 a. One liter of water
c. 0.5 M b. 29 b. 100 mL of water
d. 1 M c. 14.5 c. one kilogram of water
e. 5 M d. 58 d. 100 g of water
e. 112 e. one cubic meter of water
19. How many moles of sulfate ions are in 200
mL of a 2 M sodium sulfate solution? 23. A one liter solution of 2 M NaOH can be 27. A small crystal of NaCl is added to a
a. 0.2 mol prepared with sodium chloride solution resulting in the
b. 0.4 mol a. 20 g NaOH precipitation of more than 1 gram of
c. 0.6 mol b. 40 g NaOH sodium chloride. This solution had been
d. 0.8 mol c. 60 g NaOH a. Unsaturated
e. 1.0 mol d. 80 g NaOH b. Saturated
e. 100 g NaOH c. Supersaturated
20. A 0.5 m solution could be prepared by d. Dilute
dissolving 20 g NaOH in 24. What is the molarity of a 10 mL solution in e. Concentrated
a. 0.5 L water which 3.7 g KCl are dissolved?
b. 0.5 kg water a. 0.05 M 28. Sodium chloride would be most soluble in
c. 1 L water b. 0.1 M a. Ether
d. 1 kg water c. 1 M b. Benzene
e. 2 L water d. 5 M c. Water
e. 10 M d. Carbon tetrachloride
21. What volume of water would be needed to e. Gasoline
dilute 50 mL of a 3 M HCl solution to 1 M? 25. A solution of 10 M NaOH was used to
a. 25 mL prepare 2 L of 0.5 M NaOH. How many 29. Which of the following would produce a
b. 50 mL mL of the original NaOH solution are highly conductive aqueous solution?
c. 75 mL needed? a. Cyclohexane
d. 100 mL a. 10 mL b. Hydrochloric acid
e. 150 mL b. 100 mL c. Benzene
c. 1000 mL d. Sucrose
d. 200 mL e. Acetic acid
e. 2000 mL
30. A 10% solution of HNO3 would be 47. What is the melting point of 0.2 L water
produced by dissolving 63 g HNO3 in how 39. If 684 g sucrose (MM = 342 g) is dissolved containing 6.20 g C2H6O2?
many mL water? in 2000 g H2O (essentially 2 L), what will a. -1.86 oC
a. 100 be the freezing point of this solution? b. -0.93 oC
b. 300 a. -0.51 oC c. 0 oC
c. 567 b. -1.86 oC d. 0.93 oC
d. 630 c. -3.72 oC e. 1.86 oC
e. 1000 d. -6.58 oC
48. Which of the following are TRUE?
31. What is the boiling point of an aqueous 40. Ten grams of sodium hydroxide dissolved i. Adding a solute raises the vapor
solution containing 117 g NaCl in 1000 g in 1 L of water makes a solution that is pressure & boiling point
H2O? Kb = 0.52 oC kg/mol a. 0.25 M ii. The change in boiling & freezing point
a. 98.96 oC b. 0.5 M depends on molality.
b. 99.48 oC c. 1 M iii. The number of solute particles in a
c. 100.52 oC d. 1.5 M solvent is an important factor in
d. 101. 04 oC e. 4 M determining the boiling point elevation
e. 102.08 oC a. i only
41. How much water, in liters, must be added b. ii only
32. Which of the following sequences lists the to 0.5 L of 6 M HCl to make it 2 M? c. i and ii
relative sizes of particles in a water mixture a. 0.33 d. ii and iii
from smallest to largest? b. 0.5 e. i, ii and iii
a. Solutions, suspensions, colloids c. 1
b. Solutions, colloids, suspensions d. 1.5 Answers:
c. Colloids, solutions, suspensions e. 2 1. D
d. Colloids, suspensions, solutions 2. A
e. Suspensions, colloids, solutions 42. How many grams of NaOH are needed to 3. A
make 100 g of a 5 % solution? 4. D
33. A compound which, when dissolved in a. 2 5. B
water, barely conducts electrical current b. 5 6. E
can probably be c. 20 7. D
a. A strong electrolyte d. 40 8. C
b. An ionic salt e. 95 9. B
c. A strong acid 10. A
d. A strong base 43. What is the boiling point of water at the top 11. B
e. None of the above of a mountain? 12. TF
a. 100 oC 13. T T CE
34. How many grams of HCl must be added to b. > 100 oC since the pressure is less 14. FT
500 mL water to produce a solution that than at ground level 15. TF
freezes at -1.86 oC? (molal freezing c. < 100 oC since the pressure is less 16. T T CE
constant = 1.86 oC kg/mol) than at ground level 17. T T CE
a. 4.6 d. > 100 oC since the pressure is greater 18. B
b. 9.1 than at ground level 19. B
c. 18.3 e. < 100 oC since the pressure is greater 20. D
d. 36.5 than at ground level 21. D
e. 73.0 22. C
44. 1 mol NaCl in 1000 g H2O will change the 23. D
35. A solution can be both boiling point of water to 24. D
a. Dilute and concentrated a. 100.51 oC 25. B
b. Saturated and dilute b. 101.04 oC 26. C
c. Saturated and unsaturated c. 101.53 oC 27. C
d. Supersaturated and saturated d. 101.86 oC 28. C
e. None of these e. 103.62 oC 29. B
30. C
36. The solubility of a solute indicates 45. To what volume, in mL, must 50.0 mL of 31. E
a. The temperature of the solution 3.50 M H2SO4 be diluted in order to make 32. B
b. The quantity of solvent 2 M H2SO4? 33. E
c. The quantity of solute a. 25 34. B
d. The nature of the solute & solvent b. 60.1 35. B
e. All of these c. 87.5 36. E
d. 93.2 37. C
37. A 10% solution of NaCl means that in 100 e. 101 38. C
g of solution there is 39. B
a. 5.85 g NaCl 46. What is the molar mass of a non-ionizing 40. A
b. 58.5 g NaCl solid if 10 g of this solid, dissolved in 100 g 41. C
c. 10 g NaCl of water, formed a solution that froze at - 42. B
d. 94 g NaCl 1.21 oC? 43. C
a. 0.65 g 44. B
38. The molarity of a solution made by placing b. 6.5 g 45. C
98 g H2SO4 in sufficient water to make 500 c. 130 g 46. D
mL of solution is d. 154 g 47. B
a. 0.5 e. 265 g 48. D
b. 1
c. 2
d. 3