ANALYTICAL CONTROL SCHEDULE

For Unit 210, operating over JSC SIE NEFTEHIM SI-2 oхide Isometization Catalyst

Sample difinitions

Sc-1: Hydrotreated naphtha at the inlet of 210-DR1A/B liquid feed dryers.

S-1: Lead reactor effluent.

S-5: Recycle gas.

S-6: Stabilizer Off Gas.

S-13: Make up hydrogen gas from CCR unit.

S-14: Stable Isomerate downstream of 210-W5 cooler

1. START UP Period
Once a shift Once a day Weekly
Feed (Sc-1):
• Density at 20°С, kg/m3. +
• Fractional composition, °С
+
- IBP
- EBP
• Hydrocarbon composition, wt. %,
+ +
including С1-С4, С5H12, С7+
hydrocarbons, benzene and naphthenic С6
• Sulfur content, wt% +
• Nitrogen content, wt% +
• Oxygenate content, wt. % +
• Moisture content, wt.% +
• Chloride content, wt. % +
• Fluoride content, wt. % +
• Copper strip test +
• Research Octane Number. +
Feed of reactor section
• Hydrocarbon composition, wt. %,
including С1-С4, С5H12, С7+ +
hydrocarbons, benzene and naphthenic С6
  Sulfur content, wt% +
 Moisture content, wt.% +
Recycle hydrogen gas (S-5)
 Hydrogen content, vol. % +
 Moisture content, vol. % + +
 Н2S content, vol. % +
Make up hydrogen gas (S-13)
 Hydrogen content, vol. % + +
 Moisture content, vol. % +
 Н2S content, vol. % +
Stable isomerate (S-14):
 Hydrocarbon composition, wt. %, including
- isomers ratio in isomerate + +
iС5 /∑С5Н12 + 2,2DMB/∑С6Н14
- aromatic and olefin hydrocarbons
 Reid vapour pressure, kPа Once/10 days
 Density at 20°С, kg/m3. +
Stabilizer Off Gas (S-6):
 Hydrocarbon composition, wt. %, including +
С5+ vol. %
 1. NORMAL OPERATION

Once a day Once a two Weekly

days
Feed (Sc-1):
 Hydrocarbon composition, wt. %,
including С1-С4, С5H12, С7+ +
hydrocarbons, benzene and naphthenic
С6
 Sulfur content, wt% +
 Nitrogen content, wt% +
 Oxygenate content, wt. % +
 Moisture content, wt.% +
 Research Octane Number. +
Feed of reactor section
 Hydrocarbon composition, wt. %,
including С1-С4, С5H12, С7+ +
hydrocarbons, benzene and naphthenic
С6
 Sulfur content, wt% 2 times
 Moisture content, wt.% +
Recycle hydrogen gas (S-5)
 Hydrogen content, vol. % +
 Moisture content, vol. % +
 Н2S content, vol. % +
Make up hydrogen gas (S-13)
 Hydrogen content, vol. % +
 Н2S content, vol. % 2 times
Stable isomerate (S-14):
 Hydrocarbon composition, wt. %, including
- isomers ratio in isomerate +
iС5 /∑С5Н12 + 2,2DMB/∑С6Н14
- aromatic and olefin hydrocarbons
 Reid vapour pressure, kPа Once/10 days
Stabilizer Off Gas (S-6):
 Hydrocarbon composition, wt. %, including
+
С5+ vol. %
 
 3. UPON REQUEST

Feed (Sc-1):

1. Density at 20°С, kg/m3.

2. Fractional composition, °С
- IBP
- EBP
3. Mechanical impurities content, wt. %
4. Chloride content, wt. %
5. Fluoride content, wt. %
6. Arsenic content, ppm vol. %
7. Lead content, ppb wt. %
8. Copper content, ppb wt. %
9. Iron content, ppb wt. %
10. Sodium content, ppb wt.
11. Copper strip test

Feed of isomerization reactor section (New Point)

1. Density at 20°С, kg/m3.

Recycle hydrogen gas (S-5)

1. Hydrocarbon composition, vol. %

2. Density, kg/m3

Make up hydrogen gas (S-13)

1. Moisture content, vol. %

2. NH3 content, vol. %
3. HCl content, vol. %
4. Carbon oxides content СО, CO2, vol. %
5. Hydrocarbon composition, vol. %

Unstable isomerate

1. Hydrocarbon composition, wt. %

2. Н2S content, vol. %
3. Moisture content, wt. %

Stable isomerate (S-14):

1. Density at 20°С, kg/m3.

2. Mechanical impurities content, wt. %
3. Sulfur content, ppm wt

Stabilizer Off Gas (S-6):

Н2S content, vol. %

 DETECTOR TUBES analyses

Make up and Recycle hydrogen and Stabilizer Off gases:

1. H2S content, vol. % (PPM)vol.

2. NH3 content, vol. % (PPM)vol.
3. HCl content, vol. % (PPM)vol.
4. Carbon oxides content СО, CO2, (PPM)vol.

On line Gas moisture Analyzer:

Hydrogen gas moisture: (PPM) vol.

On line liquid feed moisture Analyzer:

Liquid feed moisture: (PPM)wt.

 ANALYTICAL CONTROL SCHEDULE
(Usual one on UOP I-8 & IS 614A)

Sample difinitions

Sc-1: Hydrotreated naphtha at the inlet of 210-DR1A/B liquid feed dryers.

S-1: Lead reactor effluent.

S-5: Recycle gas.

S-6: Stabilizer Off Gas.

S-13: Make up hydrogen gas from CCR unit.

S-14: Stable Isomerate downstream of 210-W5 cooler

On Daily basis:

Feed Sulfur (Sc-1).

Octane Number for feed, reactor effluent and product (Sc-1, S-1 and S-14)

Specific gravity for feed and product (Sc-1 and S-14)

Composition for feed and product (Sc-1 and S-14)

Two times a week:

Gas composition for Recycle gas, Stabilizer Off Gas and Make up hydrogen gas (S-5,
S-6 and S-13)

On Weekly basis:

Feed Nitrogen (Sc-1)