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[1] Szargut J, Morris DR, Steward FR. Exergy analysis of thermal, chemical and
metallurgical processes. New York: Hemisphere Publishing Corp; 1988.
[2] Kotas TJ. The exergy method of thermal plant analysis. Malabar (FL):
Krieger Publishing Company, 1995.
[3] Reikert L. The efficiency of energy-utilization in chemical processes,
Chemical Engineering Science, 1974, 29, 1613-1620
[4] Sorin M., Bonhivers J., Paris J. Exergy efficiency and conversion of
chemical reactions, Energy Conversion and Management, 1998, 39, 1863-1868
[5] Leites I.L., Sama D.A., Lior N. The theory and practice of energy saving in
the chemical industry: some methods for reducing thermodynamic irreversibility
in chemical technology processes, Energy, 2003, 28, 55-97
[6] Sorin M., Paris J. Combined Exergy and pinch Approach to process analysis,
Computer and Chemical Engineering, 1997, 21, S23-S28
[7] Sorin M.V., Brodyansky V.M. A Method for thermodynamic optimization,
Energy Conversion and Management, 1992, 17, 1019-1031
[8] Goran W., Gong M. Exergy analysis versus pinch technology, ECOS, 1996,
451-455