Sample set

Q.1) In the following pair of compounds which compound will undergo faster SN1 reaction?

(A-I, B-I) (b) (A-I, B-II) (c) (A-I, B-II) (d) (A-II, B-I)

Q.2) In which reaction carbocation is form as an intermediate?

A) SN2. B) SN1. C) SNi. D) NGP

Q.3) Which one of the following statement is correct for the reactivity of SN2 reaction?

Q.4) concentration of nucleophile will may directly affect the rate of........ reaction.

A) SN1 B)SN2. C) Both SN1 And SN2. D) both a and c

Q.5) Which among the following compound will undergo ArSN2 reaction?
Q.6) Which among the following is aromatic in nature:

Q.7) In NGP two successive nucleophilic attack takes place, where first one is.....and second is .....

A) Intramolecular, Intermolecular

B) Intermolecular, Intramolecular

C) both are Intramolecular

D) both are Intermolecular

Q.8) Following compound is…..

(a)Aromatic (b)Antiaromatic (c) Nonaromatic (d) Homoaromatic

Q.9) In the following pair of compounds which compound will undergo faster SN1 reaction?
 (A-I, B-I) (b) (A-I, B-II) (c) (A-I, B-II) (d) (A-II, B-I)
Q.10) Which among the following is the best nucleofuge?

Q.11) Consider the following reaction:

Q.12) Which one of the following is one step process?

A) SN1. B) SN2 C) ArSN1. D) NGP

Q.13) Which among the following compound is antiaromatic?

Q.14) Following compound is…..

 Aromatic (b) Nonaromatic (c) Antiaromatic (d) Homoaromatic

Q.15) In neighbouring group participation first nucleophilic attack takes place by.....

A) external nucleophile

B) internal nucleophile

C) leaving group

D) electrophile

Q.16) Using the given codes, arrange the following compounds in decreasing order the rate of the
solvolysis by the SN1 mechanism:

Q.17) which one of the reaction gives racemic mixture formation

A)SN1. B) SN2. C) SNi. D) NGP

Q.18) Which on of the following is most reactive towards the SN2 reaction?

Q.19) SN1 reaction is....

A) 1st order. B) 2 nd order. C) zero order D) 3re order

Q.20) Which of the following compound will undergo aromatic nucleophilic substitution through
benzyne intermediate?
Q.21) In SNi reaction what is responsible for retention of configuration?

A) formation of carbocation

B) formation of ion pair

C) because of excess of nucleopile

D)formation of carbanion

Q.22) Which among the following compound is aromatic?

Q.23) NGP gives Product with.....

A) Inversion of configuration

B) racemic mixture

C) retention of configuration

D) both a and c

Q.24) Following compound is…..

 Antiaromatic (b) Aromatic (c) Quasiaromatic (d) Nonaromatic

Q.25) In which reaction carbocation is form as an intermediate?

A) SN2. B) SN1. C) SNi. D) NGP

Q26).The reaction below is .........

a) clemmensen reduction

b) Wolff kishner reduction

c)birch reduction

d)none of these

Q.27)Substance sensitive to........ can't be reduced by clemmensen reduction

a)acid.

b)base.

c) both of these.

d) none of these

Q.28) Major application of clemmensen reduction is.....

a) preparation of aniline.

b) preparation of alkanes.

c) preparation of nitriles.
d) none of these

Q.29) the reaction involved in in conversion of carbonyl group into methylene group.....

a) clemmensen reduction

b) Wolff kishner reduction

c)birch reduction

d)none of these

Q.30)The mechanism given below is......

a) clemmensen reduction

b) Wolff kishner reduction

c)birch reduction

d)none of these

Q 31)birch reduction occurs in presence of....

a) sodium in liquid ammonia and alcohol

b) lithium in liquid ammonia and alcohol

c)both a and b

d)alcohol

Q.32)Oppenauer oxidation is opposite to...

a) schmidt reaction

b) wolff kishner reduction

c) meerwein-Ponndorf -Verly reduction

d) claisen Schmidt rearrangement

Q.33)All true about Oppeneaur oxidation except

a) used to prepare aldehyde

b) uses of aluminium tertiary butoxide

c) used to prepare ketone

d) uses excess acetone

Q.34) Synthetic application of Oppeneaur oxidation is......

a) to prepare analgesic

b) synthesise hormones

c) synthesise steroid derivative

d) all of these

Q.35)........ Reaction is closely related to baeyer villager oxidation

a) Schmidt rearrangement

b) dakin reaction

c) meerwein-Ponndorf -Verly reduction

d) claisen Schmidt rearrangement

Q.36) phenol can be prepared from.........byz oxidation with hydrogen peroxide in presence of base by
dakin reaction

a) aryl aldehyde

b) aryl ketone

c) both a and b

d) none of these

Q.37)dakin reaction is useful for synthesis of...

a) carboxylic acid

b) alcohol

c) aldehyde

d) phenol
Q.38)In dakin reaction the OH or NH2 group must be present at .......position of the reactant.

a) Ortho position

b)para position

c)both a & b

d)meta position

Q.39)addition of hydrogen with electron and removal of oxygen is called as..........

a)Oxidation.

b)reduction.

c)halogenation.

d)sulfonation

Q.40) chloranil is use for...........

a)hydrogenation.

b) dehydrogenation.

c)halogenation.

d)dehalogenation

Q.41) which reagent is used in Etard oxidation?

a)SeO2.

b)CrO3.

c)CrO2Cl2.

d)IBX

Q.42)CrO3 is.............

a)Collins reagent.
b)Corey's reagent.

c) cornforth reagent

d)Jones reagent

Q.43).all the reactions form isocyanate as an intermediate except......

a)Hofmann reaction

b)curtius reaction

c) Schmidt reaction

d) dakin reaction

Q.44)dakin reaction is useful for synthesis of...

a) carboxylic acid

b) alcohol

c) aldehyde

d) phenol

Q.45) of aldehyde and ketone into alkane using zinc amalgam and HCL.......m

a) clemmensen reduction

b) Wolff kishner reduction

c)birch reduction

d)none of these

Q.46).......is cornforth reagent.

a)DCC.

b)PDC.

c)CrO3.
d)DMSO

Q.47) the treatment of alkene in presence of KMnO4 to give........

a) 1,1-diiol

b)1,2- diol

c)aldehyde.

d) ketone

Q.48)...............is Collins reagent.

a] PCC

b] K2Cr2O7

c] CrO3

d] PDC

Q.49).............is reducing agent.

a) NaBH4

b)Cro3

c)H2O2

d)DMSO

Q.50)The reaction given below is.......

a) Schmidt reaction

b) Oppenauer oxidation

c)dakin reaction

d) Wolff kishner reduction