OFFER

FOR

A SYNTHETIC DETERGENT POWDER PLANT

WITH

CAPACITY OF 2 t/h PRODUCT POWDER

FOR

--- CUSTOMER

BY

ASIA CHEMICAL ENGINEERING CO.,LTD

CHINA

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 2 t/h Synthetic Detergent Powder Plant Offer
ASIA CHEMICAL ENGINEERING CO.,LTD

Dear Sirs,

We are very pleased in submitting this quotation for a synthetic detergent powder
plant with a capacity of 2 t/h finished detergent powder.

1. Scope of Delivery

Process equipment, electric equipment, control and instrumentation, and

engineering & know-how.

For detail please refer to Appendix A

2. Capacity

The said plant is to yield two (2) metric tons per hour of detergent powder based
on working 8 hours a shift, 3 shifts per day and 300 working days per year.

3. Delivery Time
100 (HUNDRED) days since reception of L/C.

4. Price

The Total Contract Price of Seller’s Supply is in FOB USD810,

592.00 (say in US Dollars eight hundred and ten thousand five
hundred and ninety two).

(Please see Appendix A)

5. Validity of the Offer

The offer is valid until

We are fully open to discuss all matters if required. If there is any problem please do
not hesitate to tell us.

Truly Yours,

Xiang Hongyue

General Manager

For ASIA CHEMICAL ENGINEERING CO.,LTD

Included are:

Appendix A PRICE BREAKDOWN OF THE DELIVERY

Appendix B TECHNICAL DESCRIPTION

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Appendix C DOCUMENTS DELIVERED BY THE SELLER

Appendix D LIST OF EQUIPMENT AND MACHINERY WITH PRICE BREAKDOWN
Appendix E PROCESS FLOW SHEETS
Appendix F REFERENCE LIST

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APPENDIX A

Price Break-Down of the Delivery

FOB Price
S. No. Item Remarks
in (USD)
See Appendix D LIST OF
EQUIPMENT AND
1 Process equipment 605,392.00
MACHINERY WITH PRICE
BREAKDOWN
See Appendix D LIST OF
Instrumentation and
EQUIPMENT AND
2 electric equipment 91,200.00
MACHINERY WITH PRICE
and materials
BREAKDOWN
All of the steel structure of

platform, bracket,
Piping materials,
3 93,600.00
installation materials ladders(include spray tower

operation room and ladder)

Engineering and
4 20,400.00 should be in the charge of the
know-how
Total FOB Price of Seller’s Supply 810,592.00

Remarks:

The total Contract Price of Seller’s Supply is in FOB USD810,

592.00 (say in US Dollars eight hundred and ten thousand five hundred
and ninety two).

APPENDIX B

TECHINICAL DESCRIPTION

B.1 General

This is a semi-automatic detergent powder plant using sulfonic acid as main

raw material to produce anionic detergent powder of specified formulation.

The plant is composed of Tank Farm (Section 100), Slurry Preparation (Section

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ASIA CHEMICAL ENGINEERING CO.,LTD

200), Slurry Transfer (Section 300), Spray Drying (Section 400), and Post
Blending (Section 500).

B.2 Process description

B.2.1 Tank Farm (Section 100)(Buyer’s supply)

Dodecylbenzene sulfonic acid bought from outside, packed in drums, is

unloaded into Sulfonic Acid Unloading Tank (101) manually, then pumped to
Sulfonic Acid Tank (103) by Sulfonic Acid Pump (102). Caustic soda solution
from tank truck is unloaded into Caustic Soda Unloading Tank (107) then
pumped to Caustic Soda Tank (109) by Caustic Pump (108). Sodium silicate in
liquid form in charged to Silicate Unloading Tank (104) then to Silicate Tank
(106) by Silicate Pump (105). Diesel oil is unloaded into Fuel Tank (110), and by
Fuel Pump (111) sent to Spray Drying (Section 400).

B.2.2 Slurry Preparation (Section 200)

Sulfonic acid comes by Sulfonic Acid Pump (213) into Head Tank (204), and
then is dosed in Weighing Hopper for Sulfonic Acid (206), while caustic soda,
process water and silicate come into their respective head tank (203,201 and
202), by respective pumps, and are dosed in Weighing Hopper for Liquids
(205).

The sulfonic acid is neutralized by caustic soda in Crutcher (207), equipped with
powerful agitator. The reaction results in forming sodium alkybenzene solfonate
(active matter). The two crutchers work alternatively.

Solid materials, such as STPP (sodium tripolyphosphate), sodium carbonate,

and sodium sulfate, CMC in bags are transported to workshop and lifted by
Motor Hoist (214), moving along overhead rail, up to 3 rd floor where they are
feed through duct manually and by gravity fall into the Crutcher (207) already
loaded with other feed materials.

The contents are subject to mixing and heating. The slurry then flows by gravity
through Mechanical Filter (208) and Magnetic Filter (209), then to the Aging
Tank (210), where it is aged and homogenized, ready to be spray dried.

B 2.3 Slurry Transfer (Section 300)

The slurry is further homogenized in Homogenizing Pump (301), and then

comes into High-Pressure Pump (302). By the pump the detergent slurry is
transferred to the spray jets in the Spray Drying Section.

The recovered slurry is sent back to Crutcher (207) by Pump (305).

There are two sets of Homogenizing Pump and High Pressure Pump; when
one is in operation the other set is in stand-by. The above mention sets have
Mono-Pump (306) for each; the mono-pump is act as a booster pump to raise
the working efficiency of the homogenizing pump.

There are Surge Cylinders (303 A/B) to smooth off the pressure pulsation.

B.2.4 Spray Drying (Section 400)

The slurry is dried in the Spray Drying Tower (402) by hot air, which is
prepared in the Hot Air Generator (407). Burner burning diesel oil is used to
generate heat. The hot air is diluted by cool air supplied by Quench Air Fan

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(409).

The spray tower is working in counter-current way. The detergent particles fall
down from top where the spray jets are located, and hot air produced by Hot
Air Generator (407) comes into tower near the lower part of the tower. The
detergent particles are dried and formed into hollow beads with specified bulk
density and come out the tower on the Belt Conveyor at Tower Bottom (411).
The powder is transferred from here into the inlet of the Airlift Duct and carried
by air sucked in by an Air Lift Fan (414), moving upwards into Airlift Separator
(412) where the powder is separated from air and falls down onto a Vibrating
Sieve (415). The target powder is falling into Product Powder Silos (513
A/B/C/D) in Post-Blending Section.

The exhaust air is drawn out at the top of the tower by Exhaust Air Fan (406).
The air contains detergent fines will separated from the contained fines in the
Exhaust Air Cyclone Unit (405), and Exhaust Air Bag Filter (416) before it is
vented to atmosphere. The fines collected in the unit are discharged by gravity
to be recycled.

The air going out from the top of Airlift Separator (412), which contains
detergent fines, which are filtered out in Airlift Bag Filter (413) on top of the
separator, before it is vented to atmosphere.

B.2.5 Post Blending (Section 500)

In this section the base powder is mixed with heat sensitive solid and liquid
ingredients, e.g. perborate, CMC, non-ionic, perfume etc., so the product
detergent powder will meet the specified formulation.

The base powder from Vibrating Sieve (415) is stored in the Base Powder Bin
(501). From there the base powder is dosed by Base Powder Weighing Belt
(502). Perborate, from an Perborate Bin (503), is dosed by a separate
Perborate Weighing Belt (504). The base powder and perborate are then go
together by gravity into a Post Blending Rotary Mixer (509). The liquid
ingredients, e.g. nonionic, perfume are dosed by Nonionic Dosing Pump (506)
and Perfume Dosing Pump (508) respectively fed by respective kettles, are
sent into the same rotary mixer (509). The solid and liquid ingredients will be
mixed together in there. The mixed powder from here is transported by a
Distributing Belt (512) and fed to one of the Product Powder Silo (512A/B/C),
ready to feed to the packaging machines. That is three bagging machine and
one cartooning machine by others.

There is a dedusting system that sucks in dusty air to be filtered out, before
vent to the atmosphere.

B.3. Specification of feed material and product

B.3.1 Specifications of feed materials

B.3.1.1 Dodecylbenzene sulfonic acid (DDBS)

Sulfonic acid 96 % min.

Sulfuric acid 1.2 % max.
Free oil 0.9 % max.
Water 1.2 % max.
Average molecular weight 366
Neutralization value 128 mg NaOH/mg sulfonic acid

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Appearance Dark brown liquid

B.3.1.2 Sodium hydroxide of commercial grade

Sodium hydroxide 95 % min.

Sodium carbonate 3.0 % max.
Chloride (as Cl) 0.01 % max.
Sulfate (as SO4) 0.02 % max.

B.3.1.3 Sodium tripolyphosphate (STPP)

Appearance White and clean

P2O5 content 56 % min.
Water non-solubles 0.1 % max.
pH (1 % solution) 9.5 to 10.1
STPP content 90 % min.

B.3.1.4 Sodium sulfate

Na2SO4 content 98 % min.

Water non-solubles 0.5 % max.
Total calcium and magnesium (as Mg) 0.15 % max.
Chlorite (as Cl) 0.3 % max.
Iron (as Fe) 100 ppm max.
Moisture 0.5 % max.
pH 7 to 9
Color 80 min.
Sieve residue (250 m sieve) 10 %

B.3.1.5 Sodium silicate

SiO2 / Na2O Module 2.2 to 2.5

Density (at 20C) 40 to 42 Be"
Sodium oxide (Na2O) content 9.5 % min.
Silica (SiO2) content 22.1 % min.
Iron (Fe) 0.02 % max.
Water non-solubles 0.2 % max.

B.3.1.6 Sodium carbonate

Total alkalinity (as Na2CO3) 98 % min.

Sodium chloride (NaCl) content 1.0 % max.
Iron oxide (as Fe2O3) 0.01 % max.
Water non-solubles 0.5 % max.
Combustion losses 0.5 % max.

B.3.1.7 P-Toluene sulfonate

P-Toluene sulfonate content 79 % min.

Inorganic salts 9 % max.
Moisture 4 % max.
pH (12 % water solution) 9 to 10
Chlorides 2.5 % max.
Sodium sulfate 5 % max.

B.3.1.8 Carboxymethylcellulose (CMC)

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2 % water solution viscosity 1200 Cp min.

Sodium (Na) 6.5 to 8.5 %
Ph 6.5 to 8
Moisture 10 % max.
Chloride (as NaCl) 3 % max.
Heavy metal (as Fe) 0.03 % max.
Arsenic (As) 0.0002 % max.

B.4 Product Powder

TAB. B.4.1 TYPICAL DETERGENT POWDER FORMULATION (1)

Bulk Density 350 g/L

Item No. Ingredient Percentage (%) Remarks

1 LAS 10
2 STPP 16
3 Nonionic- 2
4 Sodium sulfate 36
5 Sodium silicate 12
6 Sodium carbonate 8
7 Soap- 2
8 CMC 1
9 Brightener 0.1
10 Sodium Toluene sulfonate- 2
11 Enzyme- 5
12 Perfume 0.1
13 Moisture 5.8
Total 100

TAB. B.4.2 TYPICAL DETERGENT POWDER FORMULATION (2)

Bulk Density 280 g/L

Item No. Ingredient Percentage (%) Remarks

1 LAS 21

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2 STPP 21
3 Sodium carbonate 3.05
4 Sodium sulfate 38
Sodium silicate (on dry
5 9.2
basis)
6 CMC 1
Sodium P-toluene
7 1.5
sulfonate
8 Perfume + Alcohol 0.25
9 Moisture 5
Total 100

B.5 Utility requirements

 Cooling water

Temperature max. 30 C
Temperature increase approx. 7 C
Pressure min. 3 bar g
pH-value neutral
Cl-content max. 60 mg/l
Free from solid matter.

 Electric power

3 phase a.c 3 PNE 50 Hz

Service voltage 220/380 V AC
Admissible variations:
voltage 5 %
Frequency 3 %

 Steam

Pressure min. 3 bar g

Saturated and dry

 Instrument air

Pressure min. 6 bar g

Particle size max. 5 m
Particle density max. 1 mg/Nm3
Oil content max. 1 mg/Nm3
Dew point min. –20 C

B.6 Technical and economic parameters

B.6.1 Capacity

Two (2) t/h product detergent powder when the plant comes into normal
operating conditions.

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B.6.2 Operating conditions

Operating data (for reference only)

Slurry concentration (%) 60 to 65

Slurry temperature (C) 65 to 70
Spray pressure (bar) 20 to 40
Hot air at the inlet of the Drying Tower (C) 300 to 360
Hot air temperature at the outlet of Hot Air Generator (C) 320 to 380

Exhaust air temperature (C) 90 to 95

Negative pressure at the top of the Drying Tower mm H2O -5 to -10
Negative pressure in the Hot Air Generator mm H2O -1 to -3

B.6.3 Raw material consumption

Sulfonic acid per kg of active matter LAS (sodium dodecylbenzene

sulfonate):

970 kg

Caustic soda per kg of active matter (LAS):

120 kg (dry).

Others are dependent on the detergent powder formulation,

B.6.4 Utility consumption per metric ton of finished powder

 Electric power approx. 60 kWh

 Steam max. 100 kg
 Process water max. 1,300 kg
 Instrument air max. 0.3 Nm3
 Diesel oil 60 kg

All utilities have to be understood as average values (tolerance  8 %) at

continuous uninterrupted operation with one and the same feedstock and
constant and equal supply of the utilities.

B.7 Effluents

There are no liquid effluents emitted during normal plant operation.

Gaseous effluents emitted are the air from filters at different section, however,
the max. dust contents in these air streams are 100 mg/m3 max （ GB3548-
83）.

B.8 Control System

The plant is controlled by conventional instruments.

The seller’s scope of supply includes the field instrumentation and the hardware

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of the system.

B.9 Electric System

The electric system is composed of:

- Electric power distributing panel

- Electric motors
- Cables and accessories for electric power distribution

B.9.1 Electric Power distribution panel

It includes equipment for the control and protection of all electric users in the
Battery Limits.

The panel is of cabinet type, made from stiffened plates foreseen for easy
extension by movable shoulders.

The outdoor panel protection is IP41, while the indoor protection is IP20.

The panel also includes a 380/220V (or 380/110V upon the buyer’s request)
transformer for control and auxiliary circuits.

Lamps will be fed at 24 V A.C.

The panel includes:

- Selector switches for connecting or control and related signal lamps

- Remote control switches
- Thermal protection
- Power fuses and auxiliary fuses
- Star-delta starters for the motors with power over 22 kW and DOL starters
for other motors
- Main switch
- Voltmeter
- Ammeters
- Terminal boards for connection of electric cables
- Feeding of local control panels (if any)

The start/stop of motors can be made either through the electric power
distribution panel selector switches or through the working station of
supervisory system.

B.9.2 Cables

The electric power distribution cables will be multi-core type, insulation PVC
quality R2 Class 4 suitable for normal voltage up to 500 V A.C.

The cables will be installed inside cable trays for main runs and introduced in
conduits for connections from cable trays up to the users.

B.9.3 Accessories

Accessories mean all the materials for the installation connections of cables,
i.e. cable trays, conduits, and fittings.

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B.10 Building

About 1000 square m of floor area is required. Raw material warehouse is

about 800 square m, finished product warehouse is about 800 square m.

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APPENDIX C

DOCUMENTS TO BE SUPPLIED BY THE SELLER

C.1 Engineering

The seller will provide basic design and detailed design within Battery Limits.

Engineering documents will be in English, using metric system and in

accordance with the standards/codes listed in Para.

The seller will supply two copies of the following documents:

C.1.1 Basic Design

 Process description
 Material balance
 Design basis
- Plant capacity
- Products specification
- Raw material specification
- Chemicals specification
- Catalysts specification
- Effluents
- Raw materials, chemicals and catalyst consumption
- Battery limits condition
 Utility data
- Utility consumptions
- Battery limits condition
 Equipment and machinery
- Equipment list
- Machinery specifications
 Piping
- Line list (process streams)
- Piping classes
 Instrumentation
- Instrument list
- Instrument data sheet
 Electrical
- Load list
 Drawings
- P&I Diagram
- Preliminary overall plant payout
- Preliminary factory plot plan

C.1.2 Detail Design

C.1.2.1 Piping

 Plot plan (and sections)

 Opening on slabs
 Utility diagram
 One line diagram with loads for steel structure
 Piping layout
 Foundation plans and wall openings (with loads and anchoring bolts)
 Underground piping layout
 General piping support plan

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 Summary of piping materials

C.1.2.2 Equipment Design

 Equipment specification sheet (final)

 Construction drawings (for those supplied by the buyer only)
 Calculation chart (for equipment subject to official approval)

C.1.2.3 Electrical/Instrumentation Design

 Instrument specification and schedules

 Wiring diagrams
 Process, electrical/pneumatic connection sketches
 Instrumentation layout
 Erection material and cable list
 Load list and one line diagrams
 Power panel specification and wiring diagrams
 Power distribution layout

APPENDIX F

REFERENCE LIST

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ASIA CHEMICAL ENGINEERING CO.,LTD

The following projects are done by Hangzhou Asia Chemical

Equipment Co. Ltd. Our company designed and (or) supplied the
equipment & machine and automatic control system to the following
detergent powder plants.
I. For joint-venture corporations in China:
1. Unilever company in Hefei factory with capacity of 20 tons
per hour.
2. P& G company in Guangzhou with capacity of 10 tons per
hour.
3. Henkel company in Siping, Liaoning province with capacity
of 10 tons per hour.
4. Benckiser Detergent & Cleaning Product Co.,Ltd (German
company) in Hubei Province (Dosia) with capacity of 15
tons per hour
5. P& G company 20t/h capacity for post-blending section.
6. P& G company reform from 20t/h to 25t/h capacity.
II. For Domestic Companies:
1. Nice Head company in Lishui City. （ Phase I ， Phase
II，Phase III Projects）each phase with the capacity of 20
tons per hour.
2. Nice Company in Yiyang City with the capacity of 20 tons
per hour.
3. Nice Company in Chengdu City with the capacity of 20 tons
per hour..
4. Nice Company in Zhengding City with the capacity of 20
tons per hour.
5. Nice Company in Siping City with the capacity of 15 tons
per hour..
6. Guangzhou Libai Company with capacity of 10 tons per
hour.
7. Guangzhou Lanqi Company with capacity of 7 tons per
hour.
8. Hunan Lichen Enterprises with capacity of 10 tons per
hour..

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9. Jiangxi Detergent Factory with capacity of 7 tons per hour

10. Hangzhou Wanli Chemical Factory with capacity of 7 tons per
hour
11. Nanjing Lab Factory with capacity of 7 tons per hour
12. Hubei Puzzle Oil refinery and Chemical Factory with
capacity of 5 tons per hour.
13. Wuhu Daily-use Chemical Factory with capacity of 10 tons
per hour
14、Fangchao Daily-use Chemical Co. Ltd, Anhui, with
capacity of 5 tons per hour.
15、Henan Maodun Group with capacity of 10 tons per hour
16、Minghua Group, Luoyang, Henan with capacity of 10 tons
per hour
17、Libo Daily-use Chemical Company, Shandong with
capacity of 10 tons per hour
18、Lihua Daily-use Chemical Company, Shandong with
capacity of 7 tons per hour
19、Tesely Daily-use Chemical Company, Shandong with
capacity of 5 tons per hour.

20、Zhangjiakou Daily-use Chemical Company, Hebei with

capacity of 7 tons per hour
21、Heilongjiang Detergent Factory with capacity of 7 tons per
hour
22、Shenyang Sanwei Daily-use Chemical Company, with
capacity of 7 tons per hour
23、Mimi Yinchuan Daily-use Chemical Company, with
capacity of 5 tons per hour
24、Xinjiang Salt Lake Chemical Factory with capacity of 5
tons per hour
25、Sichuan Mingtian Daily-use Chemical Company, with
capacity of 8 tons per hour
26、Sichuan Lanli Daily-use Chemical Company, with capacity
of 5 tons per hour

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27、Zhongqing Nature Group with capacity of 7 tons per hour

28、Light Industrial Group, Yilan STPP Factory with capacity
of 10 tons per hour
29、Kunming Daily-use Chemical Company, with capacity of 7
tons per hour
30、Jiangsu, Longliqi Group with capacity of 7 tons per hour
31、Shangdong Libo factory with capacity 20tons per hour
32、Shenyang Sanwei factory with capacity 15tons per hour
33、Hunan Lichen Enterprises with capacity of 20 tons per
hour.
III. Exporting to other countries:
1．Yemen with capacity of 5 tons per hour
2．Saudi Arab with capacity of 7 tons per hour
3．Burma with capacity of 10 tons per hour
4．Kirghiziatan with capacity of 3 tons per hour
5．Algeria with capacity of 5 tons per hour
6．Somali with capacity of 5 tons per hour
7．Iran YAZD company with capacity of 3 tons per hour
8．Iran ZAHEDAN company with capacity of 3 tons per hour
9．Iran Tolypers company with capacity of 4 tons per
hour(condensed powder)
10．Libya with capacity of 3 tons per hour
11．Thailand with capacity of 2 tons per hour
12．Kenya with capacity of 3 tons per hour
13.Ethiopia with capacity of 3 tons per hour
14. Peru with capacity of 8 tons per hour
15.Iran Pakshoo company with capacity of 12tons per hour
16. Pars International Manufacturing Co of 30tons per hour
17 Brazil company of 10tons per hour
18 Philippines ACS Manufacturing Corporation of 5 tons per
hour
19. Iran YAZD company 8 tons per hour (extension project)
20. South Africa 30t/h detergent powder plant.

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21. Pakistan 2t/h detergent powder plant

22. Uzbekistan 3t/h detergent powder plant
23. Syria 1t/h detergent powder capacity.
24.Tanzania 10t/h detergent powder plant
25. Sudan 3t/h detergent powder plant
26.Iran Pars Idea Sabz company with 3t/h detergent powder
plant
27.Zambia with 5t/h detergent powder plant.
28.Iraq 2t/h detergent powder plant
29.Saudi Arabia 5t/h detergent powder plant
30.Another Algeria project with capacity of 5t/h detergent
powder plant.
31.Sudan Kambal Factory 8t/h detergent powder plant
32..Pakistan 1t/h detergent powder plant.
33.Russia 15t/h detergent powder plant
34.Ukrain 10t/h detergent powder plant
35. Mexico 20t/h detergent powder plant.
36. Egypt 10t/h detergent powder plant

Our company has undertaken the above-mentioned projects and

plants in domestic and aboard with high reputation and quality with
good performance. At present, we are the only one who can provide
the engineering design, complete set of equipment & machines,
installation & commissioning (supervision service), training-workers
and technical formula-supplying in China.

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