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Unit 3 - Week 1

Course outline
Assignment 1
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The due date for submitting this assignment has passed. Due on 2020-02-12, 23:59 IST.
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Practice Assignment
1) Initial temperature of an ideal gas is 27°C. The temperature of the gas is increased to 927°C. Find the ratio of final Vrms to the initial Vrms: 1 point

Week 1 3:1
1:3
Review of Classical
2:1
Thermodynamics 01
1:2
Review of Classical
No, the answer is incorrect.
Thermodynamics 02
Score: 0
Review of Classical Accepted Answers:
Thermodynamics 03 2:1

Review of Classical
Thermodynamics 04
Review of Classical
Thermodynamics 05
Quiz : Assignment 1
Advanced Chemical
Thermodynamics and Kinetics
: Week 1 Feedback Form
Assignment 1 solutions
Week 2
Week 3
Week 4
Week 5
2) A vessel of volume 22.4 dm3 contains 3 mol H2 and 5 mol Cl2 at 273 K. Calculate (i) the mole fractions of each component, (ii) their total pressure, 1 point
and
(iii) their partial pressures
(i) 0.375, 0.625 (ii) 8 atm (iii) 3 atm, 5 atm
(i) 0.275, 0.625 (ii) 5 atm (iii) 3 atm, 5 atm
(i) 0.375, 0.525 (ii) 8 atm (iii) 5 atm, 3 atm
(i) 0.375, 0.625 (ii) 5 atm (iii) 5 atm, 3 atm
No, the answer is incorrect.
Score: 0
Accepted Answers:
(i) 0.375, 0.625 (ii) 8 atm (iii) 3 atm, 5 atm
3) The compression factor of a gas is 0.72 at 310 K and 25 atm. Determine (i) the volume occupied by 8.2 mmol of the gas under these conditions and 1 point
(ii) an approximate value of the second virial coefficient B at 300 K
(i) 6.5 cm3 (ii) 0.20 dm3 mol-1
(i) 6 cm3 (ii) -0.20 dm3 mol-1
(i) 6 cm3 (ii) -0.30 cm3mol-1
(i) 6.5 cm3 (ii) -0.20 cm3mol-1

No, the answer is incorrect.

Week 6 Score: 0
Accepted Answers:
Week 7 (i) 6 cm3 (ii) -0.20 dm3 mol-1

4) Assuming there is no chemical reaction, the change in entropy when 3 mol of N2 and 4 mol of H2 and 6 mol of NH3 are mixed at constant 1 point
Week 8 temperature is :

Week 9 -114.34 JK-1

214.34 JK-1
Week 10 -214.34 JK-1
113.73 JK-1
Week 11 No, the answer is incorrect.
Score: 0
Week 12 Accepted Answers:
113.73 JK-1

Download Videos 5) The fugacity coefficient of a oxygen gas at 298 K and 4.1 MPa is 0.86. Calculate the difference of its molar Gibbs energy from that of a perfect gas in 1 point
the same state

0.37 kJ mol-1
-0.37 kJ mol-1
-0.37 J mol-1
0.73 kJ mol-1

No, the answer is incorrect.

Score: 0
Accepted Answers:
-0.37 kJ mol-1

6) The standard enthalpy of a certain reaction is approximately constant at +125 kJ mol−1 from 800 K up to 1500 K. The standard reaction Gibbs 1 point
energy
is +22 kJ mol−1 at 1120 K. Estimate the temperature at which the equilibrium constant becomes greater than 1

1.4 x 103 K
1.4 x 102 K
2.1 x 103 K
5.6 x 103 K

No, the answer is incorrect.

Score: 0
Accepted Answers:
1.4 x 103 K

7) For the liquid ⇄ vapour equilibrium of a substance, change in pressure with respect to temperature at 1 Bar & 400 K is 8 x 10-3 Bar K-1. If the molar 1 point
volume in vapour form is 200 L mol -1 and in liquid form is negligible, the molar enthalpy of vapourisation is :

35 kJ mol-1
102 kJ mol-1
64 J mol-1
64 kJ mol-1

No, the answer is incorrect.

Score: 0
Accepted Answers:
64 kJ mol-1

8) The isothermal compression coefficient (β) at critical point is 1 point

−1
No, the answer is incorrect.
Score: 0
Accepted Answers:
∞
9) For a cell reaction involving a three electron change, the standard e.m.f. of the cell is found to be 0.1971 V at 25 0 C. The equilibrium constant of 1 point
the reaction at 25 0 C will be

0.01
100
1 x 10-10
1 x 1010

No, the answer is incorrect.

Score: 0
Accepted Answers:
1 x 10-10

10) The addition of 5.00 g of a compound to 250 g of Naphthalene lowered the freezing point of the solvent by 0.620 K. Calculate the molar mass of the 1 point
compound

223.87 g mol-1
223.87 kg mol-1
243 g mol-1
122 g mol-1

No, the answer is incorrect.

Score: 0
Accepted Answers:
223.87 g mol-1