7/8/2021 2 PUC NEET 16 TH GROUP

RVS PU College
2 PUC NEET 16 TH GROUP
08 Jul 2021

1) Incorrect statements about ozone

1)'O-O' bond lengths are 2)O undergoes SP 3)Thermal decomposition of is 4)Bond order of O -molecule is
2 ′ ′
3 O3 3

same hybridisation endothermic 1.5

2) The number of unpaired electrons in the p-subshell of oxygen atom is

1)1 2)2 3)3 4)4

3) Lowest and highest oxidation states of sulphur are observed in which of the following pairs
1)S 8, H2 SO4 2)S 2 Cl2 , H 2 S2 O 8 3)H 2 S, H2 SO3 4)H 2 S, H 2 S2 O 8

4) The acidity of diprotic acids in aqueous solutions increases in the order:

1)H 2S < H2 Se < H2 T e 2)H 2 Se < H2 S < H2 T e 3)H 2T e < H2 S < H2 Se 4)H 2 Se < H2 T e < H2 S

5) In which pair of ions both the species contain S - S bond ?

1)S 2O
2−

7
, S2 O
2−

3
2)S 4O
2−

6
, S2 O
2−

3
3)S 4O
2−

7
, S2 O
2−

8
4)S 4O
2−

6
, S2 O
2−

6) Paramagnetism is exhibited by molecules

1)not attracted into a magnetic field 2)containing only paired electrons 3)containing unpaired electrons 4)carrying a positive charge

7) List-I List-II
(A) O3 + H2 O2 → (1) Blue
(B) O3 + starch KI → (2) Tailing
(C) O3 + Hg → (3) HIO3
(D) O3 + I2 +  H2 O → (4) O2 +  H2 O
  (5) HI

The correct match is

1)A-5, B-2, C-3, D-2 2)A-4, B-1, C-2, D-3 3)A-1, B-4, C-3, D-2 4)A-3, B-2, C-1, D-5

8) Match the pollutants(s) in Column I with the effects(s) in Column II.

Column I Column II
A. Oxides of sulphur 1. Global warming
B. Nitrogen dioxide 2. Damage to kidney
C. Carbon dioxide 3. ‘Blue baby’ 
syndrome
D. Nitrate in drinking  4. respiratory diseases
water
E. Lead 5. red haze in traffic 
and congested areas

1)A-3, B-4, C-2, D-1, E-5 2)A-4, B-5, C-1, D-3, E-2 3)A-4, B-1, C-2, D-5, E-3 4)A-3, B-5, C-1, D-4, E-2

9) X + H2 SO4 → Y , Y is colourless pungent smelling gas

Y + K2 Cr2 O7 + H2 SO4 → green colour solution. X and Y are
1)SO 2−

3
, SO2 2)Cl −
, H Cl 3)Br −
, H Br 4)CO 2−

3
, CO2

10) Which of the following statement is wrong.

1)Oxygen is paramagnetic 2)In S molecule of rhombic
8 3)α, β, γ and χ- forms of sulphur 4)In puckered ring of S molecule
8

while ozone is diamagnetic ∣S − S − S

contain S rings in crown sulphur atoms lie in two parallel
sulphur, ––––––––––––
= 107
0 8

configuration planes.
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11) Identify the correct statements from the following:

i) Sulphuric acid is manufactured by contact process

ii) SO dissolves in H
3 2 SO4 to form pyrosulphuric acid

iii) H 2 SO4 is used in the manufacture of fertilizers such as ammonium sulphate and super phosphate

iv) In the reaction S + 2H 2 SO4 (Conc) → 3SO2 + 2H2 O, H2 SO4 is oxidized to SO 2

1)i,ii,iii,iv 2)i,ii,iv only 3)i,iii,iv only 4)i,ii,iii only

12) Which of the following does not contain ′

S − S
′
bond.
1)Polythionic acid 2)Marshall’s acid 3)Dithionic acid 4)All the above

13) 200 ml. of pure and dry oxygen gas is subjected to silent electric discharge. The volume of ozonised oxygen obtained is 190 ml. What is the
percentage conversion of oxygen to ozone?
1)10 2)15 3)85 4)90

14) In which of the following arrangements the given sequence is not strictly according to the property indicated against it?
1)CO < SiO < SnO < PbO :
2 2 2 2 2)HF < HCI < HBr < HI : 3)H O < H S < H Se< H Te :
2 2 2 2 4)NH < PH < AsH < SbH :
3 3 3 3

increasing oxidising power increasing acidic strength increasing p Ka

values increasing acidic character

15) Which of the following statements regarding sulphur dioxide is not true ?
1)SO is an angular
2 2)SO may be regarded as the resonance hybrid of two
2 3)SO is an ahydride of
2 4)SO is an anhydride of
2

molecule canonical structures sulphuric acid sulphrous acid

16) Hot conc.H 2 SO4 acts as moderately strong oxidising agent. It oxidises both metals and non-metals. Which of the following elements is oxidised by
conc. H 2 SO4 into two gaseous products?
1)Cu 2)S 3)C 4)Zn

17) Match the following.

Column I Column II
(A) Sulphur (i) Detection of
dioxide basic radicals
(B) Ozone (ii) Vulcanisation
(C) Sulphur (iii) Antichlor
(D) Hydrogen (iv) Detection of
sulphide double bond

1)(A)-(iii), (B)-(ii), (C)-(i), (D)- 2)(A)-(iii), (B)-(iv), (C)-(ii), (D)- 3)(A)-(ii), (B)-(i), (C)-(iv), (D)- 4)(A)-(i), (B)-(iii), (C)-(ii), (D)-
(iv) (i) (iii) (iv)

18) Which one of the following is wrong?

1)Oxygen and sulphur belong to the same group 2)Oxygen is a gas while 3)Both show +2, +4 and +6 4)H 2S has no hydrogen
of periodic table sulphur is solid oxidation states bonding

19) In SO two oxygen atoms are linked to the sulphur atom through double bonds. The two π bonds are
2

1)both p π − pπ 2)both p π − dπ 3)both d π − dπ 4)one d π − pπ and one p π − pπ

20) Which of the following group shows the highest boiling point
1)H 2O 2)H 2S 3)H 2 Se 4)H 2T e

21) Which of the following is/are correct ?

1)O 3
+ moist iodine ⟶ H I O3 2)F eCl 3
+ H2 S ⟶ Collodial sulphur 3)O 3
+ Ag ⟶ Black silver 4)All of the above

22) The correct order of acidic strength

1)Cl 2 O7 > SO2 > P4 O10 2)K 2 > CaO > M gO 3)CO 2 > N2 O5 > SO3 4)N a 2O > M gO > Al2 O3

23) (A) + dil. H2 SO4 ⟶ [B] a colour gas with irritating smell

(B) + K2 Cr2 O4 + H2 SO4 ⟶ green coloured solution. Then (A) and (B) are

1)SO 2−

3
, SO2 2)Cl −
, H Cl 3)S −2
, H2 S 4)CO 2−

3
, CO2

24) All the elements of oxygen family are

1)Non-metals 2)Metalloids 3)Radioactive 4)Polymorphic

25) The following gases are evolved when carbon is treated with Conc.H 2 SO4 are
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1)CO 2, SO2 2)CO 2 3)SO 2 4)SO 3, CO3

26) Which shows polymorphism

1)O 2)S 3)Se 4)All

27) Which of the following is not tetrahedral in shape

1)N H 4
+
2)SiCl 4 3)SF 4 4)SO 2−

28) The following molecules are formed in ground, first and second excited states of sulphur respectively
1)SCl 4, SCl2 , SF6 2)SCl 4, SF6 , SCl4 3)SCl 4, SF6 , SCl2 4)SCl 2, SCl4 SF6

29) 200 ml of pure oxygen is subjected to electric discharge, 15% oxygen in converted into ozone. The volume of ozonised oxygen is
1)20 ml 2)30 ml 3)190 ml 4)170 ml

30) The correct order of O − O bond length in O 2, H2 O 2 and O is: 3

1)O 3 > H2 O 2 > O 2 2)O 2 > H2 O 2 > O 3 3)O 2 > O 3 > H2 O 2 4)H 2 O2 > O3 > O2

31) Which of the following statements is not correct?

1)From SO to T eO 2 2 2)The order of boiling points of hydrides of 16 th
3)Rhombic sulphur has S molecules
8 4)The bond angle in
reducing power group elements is while monoclinic sulphur has S 6 Ozone molecule id
decreases H2 S < H2 Se < H2 T e < H2 O molecules 117
0

32) A sample of oleum is labelled 109%. The % of free SO in the free sample is 3

1)40% 2)80% 3)60% 4)9%

33) In the direct estimation of Oxygen which of the following chemical is used.
1)I 2 2)I 2 O5 3)I F 7 4)H I O 3

34) SO2 reduces acidified K 2 Cr2 O7 to

1)Cr 2 (SO4 )
3
2)CrO 3 3)Cr 2 O3 4)chromium

35) Which of the following reaction does not produce SO 2 ?

Δ Δ Δ Δ

1)Ag + H 2 SO4 (con) ⟶ 2)CaSO 4 + C ⟶ 3)F eS 2 + O2 ⟶ 4)Zn + H 2 SO4 (dil) ⟶

36) Which of the following is not oxidized by Ozone

1)KI 2)F eSO 4 3)KM nO 4 4)K 2 M nO4

37) Identify the set of acidic oxides

1)N a 2 O, CaO, BaO 2)ZnO, P bO, BeO 3)CO, N O, N 2O 4)M n 2 O7 , CrO3 , V2 O5

38) In O 2 F2 the bond angle in between ∠F OO is

1)120 0
2)109 0
31
1
3)90 0
4)180 0

39) ZnO when heated with BaO at 1100 0

C gives a compound. Identify the compound
1)BaZnO 2 2)BaO +Zn 2 3)BaCdO 2 4)Ba+ZnO 2

40) Which of the following pairs contains mixed oxides ?

1)Pb 3 O4 , Fe3 O4 2)MnO 2, BaO2 3)KO 2, NaO2 4)Mn 3 O4 , N2 O5

41) In second excited state the possible oxidation number and hybridisation of sulphur respectively are
1)+4, SP , SP , SP d
2 3 3
2)+6, SP , SP , SP d
2 3 3 2
3)+6, SP , SP , SP d
2 3 3
4)+2, SP , SP , SP d
2 3 3 2

42) Sulphur exists as S 8, S6 , S4 and S under different conditions. Which of the following statements is correct?
2

1)Mass of one mole of each of 2)Number of molecules in one mole of 3)Number of atoms in one mole of 4)All are correct
them is same each of them is same each them is same statements

43) Which of the following is incorrect about S molecule 8

1)No.of lone pairs : 16 2)covalency : 2 3)Bond order : 1 4)Bond length : 205.7 pm

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44) The statements regarding halides of S

i) SF and SCl are only Lewis acids

4 4

ii) SF and SCl are only Lewis base

4 4

iii) SF and SCl are Lewis acids & Lewis bases

4 4

The correct combination is

1)Only iii is correct 2)Both i & ii are correct 3)Both ii & iii are correct 4)All are correct

45) No. of atoms in one molecule of sulphur is

1)8 2)4 3)3 4)None of these