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BASIC CONCEPTS
AND DEFINITIONS
Thermodynamics is the branch of science which treats of various phenomena of energy, and especially of the laws of
transformations of heat into other forms, and vice versa.
The science that is devoted to understanding energy in all its forms such as, mechanical, electrical, chemical, and how
energy changes forms.
Derived from the Greek words, therme, meaning heat and dynamis, meaning strength, particularly applied to motion.
Flow
through a pipe (Open System)
Piston cylinder assembly (Closed
System)
3) Isolated System is a system where neither mass nor energy passed through its boundaries.
MIT - School of Mechanical Engineering
THERMODYNAMICS-I : Basic Concepts and Definitions chapter. I - 2 of 12
subs. g o gcVsubs.
S.G.
std. subs. go gcVstd. subs.
but
ma 1kgm 2
1slug 1 Ft 2
Vsubs Vstd.subs.
1m s
S.G.
subs.subs.
subs.
std. subs.std. subs.Water at 4 deg. Celsius
g s
c
F 1N 1lbf S.G. subs.subs
g 1 kgm m 9.8066 kg f 1000kg
For Solids (Using Archimedes 362.4lb m
Principle)
c m ft 3
s2N s2N
1 slug Ft 32.174lbm Ft S.G. Weight in air
Weight in air Weight in water
s 2 lbf s 2 lbf
mV
Pressure Variation with Liquid
Column VVV V 0.01V
0.01m3
For a substance of constant density (such as a m 1 2 2 1
liquid), m m m VV
m m
1 2
1 1 22
the pressure at any vertical position due to the self-weight Vm 100L 0.01m3
of
the substance above the datum is dependent of the V 0.01V V 0.01 V kg
surface
2 1
area and is given by the 1 1 2 1 1 1 2 800
m
0.01m3 0.01m m3
equation: 3
Pgage h 800
kg
m3
0.01m3 0.01m3
V
1
1 2 2
800
kg
0.01m 0.01m 500 kg
3 3
V1 m3 m3 0.003m3
kg
500
1500
m3
V2 0.01 V1 0.01 0.003
0.007m3
kg
m V 1500 0.003m 3
4.5 kg
1 1 1
m3
+h -h
kg
m V 500 0.007m 3
3.5 kg
2 2 2
m3
mm m1 m2 4.5 8 kg
3.5
SAMPLE PROBLEMS
m
8kg 9.675
m g s2
1.1 A pump discharges into a 3 m per side cubical 7.8926N
tank. W m o
g
The flow rate is 300 liters/min, and the fluid has a m
kg m
c 9.8066 2
density s N
1.2 times that of water (density of water ρ=1000.0
kg/m3).
a 5gO
FW W W W mg
1.3The mass of a given airplane at sea level (g=32.10 gO gO 6 g O
6W C
c f Solution :
m
go ft
32.10
s2
m 20,046.106lbm C 0C F 32F C F 32
1kg
m 20,046.106lb m 9,092.854kg 9 0C
100C 212 32F 1005 180
2.2046lb
m
F C 32 and C F 32
m
m
m slug 623.053slug 5 9
20,046.106lb 32.174lb
1.6 At what temp is the Fahrenheit and Celsius
scale has the same reading?
b) Weight lbf and N Solution : (F = C = A)
mg o
W
gc
623.053slug 32.10 3.33x106 50,000
ft
C 0C F 32F C F 32
s2
slug ft
1
s 2 lb 100C 0C 212 100 180
f
32F
W 19,896.263lbf C F 32 A A 32
9.8066N 100 180 100 180
1kg A 40 C or F
W 19,896.263lbf f
2.2046lb 1kg
f f
W 88.503.444 N of earth’s standard gravity. If the take-off is vertical, what force
does he exert on the seat?
1.4 During take-off in a space ship, an 80 kg astronaut
is subjected to an acceleration equal to 5 times the pull
1.7 At what temperature will the Fahrenheit scale be 64°
more that the Celsius scale? F = 64 + C
Solution : C0 F 32F C 64 C 32
Solution: 100C 0C 212 32F 100 180
C C 32
5 9
C 40 C or F 104F
1000N
m 3
s2
Pgage 2.942
From Newton’s 3rd Law of Motion : Action and kPa
Reaction
14.7 psi
Wa
R gO Pabs Patm Pgage 13.95 psi 2.942kPa
101.325kPa
Fv 0 Fup Fdown FRW
Pabs 14.3768psia
1.9 Compute for the value of h based on the figure.
EXERCISES
PII
gg 500kPa
o
a well stirred oil bath, thermometer A registers 51C while B
0.4m
water water
0.5mHg 2m
c
m registers 50C. Determine the reading on the thermometer A
9.8
kg
2
kg s 1kN when B reads 25C. (Ans.25.75°C)
PII 2.4m1000
0.5m13590
m 3 kg m 1000 N
m3 2
s N
500k Pa (8) A beer barrel has a mass of 10 kg and a volume of
PII 456.929kPa 20 liters. Assuming the density of beer is 1000kg/m3,
determine
the total mass and weight of the barrel when it is filled 75cm2. The spring exerts a downward force of 100 N on the
with beer. (Ans.294N) piston, and atmospheric pressure is 100 kPa. Determine the
pressure of the gas. (126.4 kPa)
(9) A certain thermometer is calibrated using ice and
steam points as fixed points designating them as being
temperature 0C & 100C respectively, then the
thermodynamic function chosen to establish the scale
is t
= alnx + b; instead of the line scale t=ax+b. (a)
Determine the constant a & b and (b) Developed a
relation to express t = f (x,xi,xs).
(26) Consider a 70 kg woman who has a total foot (31) The barometer of a mountain
imprint area of 400cm2. She wishes to walk in the hiker reads 930 mbars at the beginning of a hiking trip and
snow, but the snow cannot withstand pressure greater 780 mbars at the end. Neglecting the effect of altitude on
than 0.5 kPa. Determine the minimum size of the snow the local gravitational acceleration, determine the vertical
shoes needed (imprint area per shoe) to enable her distance climbed. Assume an average air density of 1.20
to walk on the snow without sinking. kg/m3. (Ans. 1274m)
(27) The gage pressure in a liquid at a depth of 3m (32) Determine the pressure exerted on a diver at 30m
is read to be 28 kPa. Determine the gage pressure in below the free surface of the sea. Assume a barometric
the same liquid at depth of 12m. pressure of 101 kPa and a specific gravity of 1.03 for
seawater. (Ans.
(28) The absolute temperature in water at a depth of 404.0 KPa)
5m is read to be 145 kPa. Determine (a) the local
atmospheric pressure, and (b) the absolute pressure (33) Determine the force necessary to accelerate a mass of
at a depth of 5m in a liquid whose specific gravity is 20 lbm at a rate of 60 ft/s2 vertically upward. (Ans.53.3 lbf)
0.85 at the same location.
(34) The weight of a10 lb mass is measured at a location
(29) A vacuum gage connected to a tank reads 30 where g=32.1 ft/s2 on a spring scale originally calibrated in
kPa at a location where the barometric reading is 755 a region where g=32.3 ft/s2. What will be the reading?
mmHg. Determine the absolute pressure in the tank.
Take ρHg=13,590kg/m3. (Ans. 70.6 kPa) (35) A gas is contained in a vertical, frictionless piston
cylinder device. The piston has a mass of 4 kg and a
(30) A pressure gage connected to a tank reads 50 cross sectional area of 35 cm2. A compresses spring above
psi at a location where the barometric reading is 29.1 the piston exerts a
force of 60 N on the piston. If the atmospheric pressure is m2, having dimensions that are small compared with their
95 kPa, determine the pressure inside the cylinder. separation distance R, is given by Newton’s third law,
F=Gm1m2/R2, where G=6.67259x10-11 N-m2/kg2. What is
the total gravitational force that the sun (1.97x1030 kg) and the
earth (5.95x1024 kg) exert on the moon (7.37x1022 kg) at an
instant when the earth, moon, and sun form a 90° angle? The
earth-moon and sun-moon distances are 380x10 3 km and)
150x106 km, respectively
pressure buildup and keeps the pressure inside at a planet. A space probe weighed 100 kN on the earth sea
constant value. Determine the height (H) and diameter level. Determine (a) the mass of the probe. (b) Its weight
(D) of the petcock of a pressure cooker whose operating on the surface of the planet (c) Its weight at an elevation
pressure is 105 kPa gage and has an opening cross- of 200 km above the surface of the planet. (Ans.
sectional area of 4.5 mm2 (steam opening for pressure 10197.2141 kg, 40.79 kN, 37.53 kN
relief). Assume an atmospheric pressure of 101 kPa and
the density of the metal used is 4625 kg/m3. (54) A bell jar 250mm in diameter sits on a plate and is
evacuated until a vacuum of 700mmHg exists. The local
(51) The average temperature of the atmosphere in barometer reads 760mmHg. Find the absolute pressure
the world is approximated as a function of altitude by inside the jar, and determine the force required to lift the
the relation jar off the plate. Neglect the weight of the bell jar. (Ans.
Tatm 288.15 6.5z 8005 Pa, 4584 N)
Air A
Reservoir
5"
B
Mercury (SG=13.59)
30°