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PROGRAMME KOREA

YEAR/SEMESTER AUG – NOV 2021

EXAMINATION DETAILS TEST 1

COURSE CODE KRCH10

COURSE NAME CHEMISTRY PART 1


DATE 6.10.2021
TIME 1Hour 30 Minutes
TOTAL NUMBER OF PAGES 6

NAME

SID CLASS

INSTRUCTIONS TO CANDIDATES
1. Write your name, SID number and class on all the work you hand SECTION MARKS

in.
A
2. Write in dark blue or black pen.
3. You may use an HB pencil for any diagrams or graphs. B
4. Do not use staples, paper clips, glue or correction fluid.
TOTAL
INFORMATION FOR CANDIDATES

1. The total mark of this paper is 40 marks.


2. Answer all questions.
3. Electronic calculators may be used.
4. You may lose marks if you do not show your working or if you do not
use appropriate units.
5. A Periodic Table is provided at the last page.
Section A

1. What volume of 10.0 M H2SO4 is required to prepare 4.0 L of 0.50 M H2SO4?


A) 0.20 L 10 ✗ V ,
= 0.5×4
B) 0.40 L
v, =
o
-

2L
C) 0.50 L
D) 1.0 L
E) 4.0 L

2. A solution of silver nitrate is mixed with a solution of potassium fluoride. If a precipitate forms,
the precipitate is:
a) Silver fluoride
b) Potassium nitrate
c) Potassium fluorate
d) Nitric fluoride
e) No precipitate is formed

3. If 5.0 mol of both hydrochloric acid and sodium sulfide are mixed and reacted according to the
equation below, how many moles of hydrogen sulfide (H2S) are produced?
2HCl + Na2S → H2S + 2 NaCl
a) 1 mol 5. 0

b) 1.25 mol
c) 2.5 mol
d) 3 mol
e) 5 mol

4. Which of the following is not a physical process?


a) distillation
b) filtration
c) chromatography
d) evaporation
e) none of the above

5. On the basis of the solubility rules, which of the following is insoluble?


a) K2O
b) Na2CO3
c) PbS
d) (NH4)2SO4
e) Ba(C2H3O2)2

6. What mass of CaCl2 is required to prepare 500.0 mL of a 0.200 M solution of CaCl2?


a) 0.200 g
b) 0.100 g
c) 22.2 g
M =

m
d) 11.1g
0-200 M = %÷ [6]
1- I l
g #
= '

mass
Section B

6. Complete the following table (all empty cells):

NAME FORMULA
Calcium chlorate Ca ( Clos ) ,

carbon Tetra bromide CBr4

Ammonium phosphate ( NH a) 31004

Iron ( 111) oxide Fe2O3


[4]
7. Complete the following table (all empty cells in both rows):

# of # of atomic mass
Symbol # of protons
neutrons electrons number number
51
V+5 23 28 18 23 51
34s
-2
16 18 18 16 34

[4]
8. Selenium, an element used in the manufacture of solar energy devices, forms an oxide that contains
only one atom of selenium (per formula unit) and is 37.8% oxygen by mass. What is the molecular
formula of the oxide?
In a 100g sample :
8.7¥ :#
0.788

oxygen
1,gM÷g
36m01 O
:

37.8g ✗
=
2- l :3

i.
Seong
selenium : 62.2 ✗ 1m€ =
0-788 mul Se
7-8.96
[3]

9. What volume of 0.150 M of NaOH is needed to react completely with 3.45g iodine according to
the equation :

3 I2 + 6 NaOH → 5 NaI + NaIO3 + 3 H2O


3.45g

y}j?÷ §¥ 2m01 NaOH


-

✗ = 2-72×10

M= m% 0.150 M= 27-2×10-2
[2]
L

10. Identify the oxidation numbers of each element in the following compounds or ions: L 181mL
=

#
=

a) Zn (s) zn=O CO 181L) -

b) K2O2 1<=1 0=-1


,

c) FeBO3 Fe = +3 B : -13 0=-2


,
,

d) O2 (g) Oz :O

e) Mg(NO3)2 Mg = -12 ,
N = -15,0=-2

[5]
11. Solid sulfur and oxygen gas react to produce sulfur trioxide as shown below. In a particular
experiment, 5.0 g of O2 are reacted with 6.0 g of S8. Balance the equation below :

S8 (s) + O2 (g) → SO3 (g)

a) If we assume complete consumption of the limiting reactant, what is the mass and identity of the
reactant that still remains at the end of the reaction?
Ss +
1202cg) → 8503cg)

%56.gr ✗ 8 = O '
1817 not Sg
limiting reactant .

8molS→ ←
%z ✗
= 0-1042 moi O
,
12m01 02 [5]
0 -
1042 Mol ✗ 80.06 so =
8- 34g Balance :
,
a) What is the % yield of SO3 in this experiment if 7.9 g of SO3 are isolated? 11g -834g
= 2-
66g
#
% yield = TI ✗ 100% = 95%
# [1]
8- 34

12. For the following reactions, complete the equation and determine if there are any insoluble products
(precipitates). If there is a precipitate, write the balanced ionic and net ionic equations. If there is no
precipitate, write the balanced molecular and ionic equations.
Nico H) Cs)
a) 2 NaOH (aq) + Ni(NO3)2 → 2Nd NO
,
Caq) +
,

2M¢
"
NICOHJ
2¥ 2¥05 2¥
-

t Cs)
-1 201T + Ni caq) + → + ,

>+
Ni
-

201-1 caq) -1
Caq) → Nicoll ) ,
Cs )
[3]
Cs)
b) MgCl2 (aq) + (NH4)2CO3 (aq) → 2MHz, CI caq) + Mgcoz
"
Mg
"
-1 2¢ -1 2M¥ + coj
-


2¥ can '
taq + Mgcoi
"
+ co }
-

Caa) CO ( s) [3]
Mg caq) → Mg ,

13. For the following redox reactions, balance the equation, identify the species being oxidized, the
species being reduced, the oxidizing agent, and the reducing agent:

I Ni (s) + ___
a) ___ I NiCl (s)
1 Cl2 (g) → ___ 2

Ni is oxidized 1 reducing agent


Cla is reduced / oxidizing agent
[2]
3 Fe(NO3)2 (aq) + ___ 2
3 Fe (s) + ___
2 Al (s) → ___
b) ___ Al(NO3)3 (aq)

agent
Fest ) is oxidizing
-

is reduced Fe CNO , ,
,

oxidized reducing agent


.

Al is ,
[2]
1 18
1
IUPAC Periodic Table of the Elements 2

H He
hydrogen helium
1.008 2 Key: 13 14 15 16 17 4.003

3 4 atomic number 5 6 7 8 9 10

Li Be Symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
6.941(2) 9.012 standard atomic weight 10.81 12.01 14.01 16.00 19.00 20.18

11 12 13 14 15 16 17 18

Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
22.99 24.31 3 4 5 6 7 8 9 10 11 12 26.98 28.09 30.97 32.07 35.45 39.95

19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36

K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39.10 40.08 44.96 47.87 50.94 52.00 54.94 55.85 58.93 58.69 63.55 65.38(2) 69.72 72.64 74.92 78.96(3) 79.90 83.80

© 2010 IUPAC, the International Union of Pure and Applied Chemistry


37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85.47 87.61 88.91 91.22 92.91 95.96(2) 101.1 102.9 106.4 107.9 112.4 114.8 118.7 121.8 127.6 126.9 131.3

55 56 57-71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

Cs Ba lanthanoids Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
132.9 137.3 178.5 180.9 183.9 186.2 190.2 192.2 195.1 197.0 200.6 204.4 207.2 209.0

87 88 89-103 104 105 106 107 108 109 110 111 112

Fr Ra actinoids Rf Db Sg Bh Hs Mt Ds Rg Cn
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71

La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
138.9 140.1 140.9 144.2 150.4 152.0 157.3 158.9 162.5 164.9 167.3 168.9 173.1 175.0

89 90 91 92 93 94 95 96 97 98 99 100 101 102 103

Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
232.0 231.0 238.0

www.iupac.org/reports/periodic_table This periodic table is dated 19 February 2010

Useful Conversion Factors and Constants


1 mol = 6.022141 × 1023 R = 0.082058205 L-atm/mol-K

1 m = 1.0936 yd = 8.314472 J/mol-K

4.184 kJ = 1 kcal � = 3.1415927

1 in = 2.54 cm (exact) c = 2.99792458× 108 m/s

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