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Magnetic materials
Magnetic materials
Magnetic material are the substances which get magnetised in the magnetic field. They are
widely used in industrial electronics, entertainment electronics and computer industry.
Basics parameters to remember (Home Assignment)
Magnetic field:
Magnetic dipole:
Magnetic flux density or magnetic induction (B):
Magnetic field strength or field intensity (H):
The total magnetic moment = orbital magnetic moment + spin magnetic moment
Classification of magnetic materials on the basis of susceptibility value
There are three types of magnetic materials,
(i) Diamagnetic materials:
Materials which are not having any permanent magnetic dipole moment are
diamagnetic materials.
In these substances the individual magnetic moment vectors are randomly oriented and
the resultant magnetic moment is zero.
An external magnetic field can cause rotation of the individual magnetic moment
vector. This field rise to an induced magnetic field opposite to the applied field in such
a manner that the magnetic induction drops to zero. Hence, as we know
B = µ0 (H + M), becomes
0 = µ0 (H + M)
and χm = - (M / H)
Examples of diamagnetic materials are Gold, Germanium, Silicon, etc
The Hysteresis curve shows the behaviour of the magnetic induction (B) with the
variation of the magnetizing field (H).
The Hysteresis curve indicates the energy utilized by ferromagnetic material in the
alignment of the magnetic moments of different domains and adjusting the shape and
size of the domains with the variation of the magnetizing field
Path P TO Q: Along this path as the field H is reduced to zero the induction vector
does not drop to zero, but retains a value -Br.
Path Q TO T: The magnetic induction B drops to zero at the coercive field HC.
The shape of hysteresis loop varies from material to material. Some ferrites have an
almost rectangular hysteresis loop. These materials are used in digital computers as
magnetic information storage device.
The energy lost per unit volume of the ferromagnetic material in one magnetization
demagnetization cycle is given by the area under the hysteresis curve and is written as
W
W=∮
Calculation of Hysteresis loss
Consider a unit volume of the ferromagnetic substance which has N magnetic domains.
Let µm be the magnetic moment of each magnetic domain and each magnetic domain
makes angle θ with the direction of the magnetizing field H. so the total magnetic
moment along H is the intensity of magnetization.
M = ∑ μm cos
Since there is no magnetization perpendicular to H, the total magnetic moment
perpendicular to H is
∑ μm sin = 0
therefore, dM = - ∑ μm sin
is the small decrease in the intensity of magnetization with a small change dθ.
The work done in rotating the magnetic moment vector μm through the elementary
angle dθ is
dW = - µ0 ∑ μm H sin
= µ0 H dM
Now, B = µ0 (H + M)
So, dB = µ0 (dH + dM)
The work done per unit volume of a substance in a complete cycle is
W=∮ = µ0 ∮
= µ0 ∮ ( − dH) = ∮
Since, ∮ =0
W=∮
Reluctance is defined as the ratio of the drop of the magneto motive force to the flux produced
in any part of the circuit. It is written as
S = µ /ɸ Amp-turns / weber
Dielectrics
Dielectric, insulating material or a very poor conductor of electric current. When dielectrics are
placed in an electric field, practically no current flows in them because, unlike metals, they
have no loosely bound, or free, electrons that may drift through the material. Instead, electric
polarization occurs.
Dielectric materials have high electrical resistance (~ 1010
– 1020 Ω) because they possess large energy gap (> 3eV).
There are no free electrons in a dielectric because the
transition of electrons from valence band to conduction
band is not possible under ordinary conditions.
Dielectric Constant
A quantity measuring the ability of a substance to store electrical energy in an electric field, is
called dielectric constant.
It is denoted by εr.
It can also be defined as, the ratio of absolute permittivity of the medium (ε) and the
permittivity of free space (ε0).
i.e. εr = ε /ε0
Since it is a ratio, it is a dimensionless quantity and has no unit. Here ε0 = 8.854 x 10-12 F/m,
is called permittivity of free space. The relative permittivity of air is unity.
Dielectric constant in terms of Capacitance
Let us consider a parallel plate capacitor connected to dc voltage source, V0. The source charges
the capacitor plates till the potential difference across the plates builds to V0. Let the charges
on the plates be +Q0 and –Q0, when the potential difference is V0.
V
The capacitance C0 is related to the quantity of charge stored on either plate. It is given by
= ………………. (1)
Now, let the plates of the capacitor be disconnected from the voltage source V0. The circuit is
open and there is no path by which energy can flow. The magnitude of the charge Q0 on either
plate must remain constant. Suppose now a dielectric in the form of a rectangular parallelepiped
is inserted between the plates, and it completely fills the space between the plates. It is found
that the potential difference V0 decreases to a value V.
When the dielectric slab is pulled out, the potential difference returns to the original value V0.
Thus it is concluded that the original charges on the plates have not been affected by the
introduction of the dielectric and the value of capacitance increased from C0 to C in the
presence of dielectric.
= ………………. (2)
= = = 0
/
= ………………. (4)
εr is a dimensionless quantity which is always greater than unity in case of dielectrics regardless
its shape and size. It is called dielectric constant or relative permittivity.
For a parallel plate capacitor, the capacitance is given by,
ε0
= … … … … … … . (5)
Where ε0 = 8.85 x 10-12 F/m is the permittivity of the free space, A is the area of either plate
and d is the separation between the plates.
In place of parallel plate capacitor completely filled with a dielectric, the capacitance is
ε0
= … … … … … … . (6)
= =
As the electric field E0 is constant between the plates, the energy density U0, which is the stored
energy per unit volume, will be constant. Thus,
= = = ( )2
When a dielectric medium is present between the plates, the energy density is given by
1
2
Induced charges
The electric field E0 in the region between the capacitor plates is given by,
E0 =
According to a theorem of Gauss, the flux of the electric field E0 through a closed surface is
equal to the algebraic sum of the charges enclosed by this surface divided by . It follows that
E0 =
Where, is the magnitude of surface charge density on either plate.
When the dielectric is introduced between the plates, there occurs a reduction in potential
difference across the plates. It implies the reduction in the electric field strength E0 in the
region, which can occur only when there is a reduction in the charge on the plates. As charges
cannot leak off the plates, the reduction in the electric field strength suggests that the effect of
some of the original charges is annulled by the charges of opposite sign appearing on the two
surfaces of the dielectric. This dielectric is said to be polarized. The induced surface charge on
the dielectric give rise to an induced electric field Ei which opposes the external field E0.
Therefore, the net electric field E in the dielectric has a magnitude given by
E = E0 – Ei
The induced electric field Ei is related to the induced charge density σp through the relation
Ei = σp / ε0
The net surface charge density that contributes to the electric field E within the dielectric is
(σ - σp). Applying Gauss theorem, we get
−
=
Therefore, E= = =
Therefore, = 1−
Polarization
The process of formation of atomic dipoles inside a dielectric material under the influence of
an external electric field is called polarization. For a dielectric slab inserted between the plates
of a parallel plate capacitor. Imagine that the dielectric is divided into a large number of
identical cells of volume dV. The intensity of polarization P is defined as the total dipole
moment per unit volume of the material. Thus,
The magnitude of polarization is directly proportional to the intensity of the electric field.
P = χ ε0 E …………………………. (2)
χ is the proportionality constant and is called the dielectric susceptibility of the material.
Dielectric susceptibility characterizes the ease with which a dielectric material can be
influenced by an external electric field.
Let the surface charge density be σp and the distance between the plates be d, which is the
thickness of the slab. Thus the dipole moment of the entire slab is given by
µ = (A σp ) d = σp V …………………………. (3)
P = σp …………………………. (5)
where A is the area of the slab and V is the volume.
Field Vectors
The effective field E in the dielectric is given by
E = E0 – Ei = −
ε0 E = σ – σp
or using eq. (5) ε0 E = σ – P …………………………. (6)
εr = 1 + χ …………………………. (8)
A molecule can be considered as a distribution of positive and negative charges. Molecule may
be classified as (i) polar molecule and (ii) non-polar molecule. In non-polar molecule center of
gravity of positive and negative charges coincides, the molecule has no resultant charge and
zero dipole moment. A polar molecule is one which has a permanent electric dipole moment,
albeit the total amount of positive and negative charges on the molecule are equal and the
molecule is electrically neutral, but the distribution of the two kinds of charges are different,
such that positive and negative charges are centered at points separated by a distance of
molecular dimensions, forming a dipole moment.
When two opposite charges +q and –q are separated by a distance d, then a dipole is formed
and its dipole moment is given by qd. In a molecule q will be of the order of magnitude of
electric charge, that is, of the order 10–10 e.s.u., while d will be of the order of the molecular
dimensions 10–8 cm (one Angstrom unit). The dipole moment, usually represented by the
symbol , is thus of the order of magnitude 10–18 e.s.u. The unit 10–18 e.s.u. is called a debye,
and dipole moments are commonly measured in debye, abbreviated as D. The magnitude of
the dipole moment depends on the size and symmetry of the molecule. Molecules having center
of symmetry are non-polar, while molecules having no center of symmetry are polar.
εr = 1 + χ = 1 + =1+
εr = 1 + …………………………. (9)
In case of monoatomic gas it is found that the electronic polarization is given by,
αe = 4Π ε0 R3 …………………………. (10)
εr = 1 + 4Π N R3…………………………. (11)
αo = …………………………. (13)
Po = …………………………. (14)
Which states that the orientation polarization is inversely to the temperature and
proportional to the temperature and proportional to the square of the permanent dipole
moment.
Total polarization
In a material which can experience all forms of polarization, the total polarizability is equal to
the sum of the electronic, ionic and orientation polarizabilities.
α = αe + αi + αo
α = αe + αi + …………………………. (15)
Here the charge is induced due to the induced field so the the electric flux density D changes
to the electric polarization P
Since we have considered that the specimen is non polar dielectric material, at the center of the
specimen the dipole moment is zero and hence the electric field intensity at the center is zero
due to symmetric structure.
Now consider a circle from the centre of the dielectric material. In order to calculate the electric
field intensity E4 on the surface of spherical cavity, the polarization should be calculated by
resolving it into two components.
As we know the polarization P is the induced charge per unit area
++++++
++ +A
Here the polarization changes to its component we have
divide in the figure a and the charge changes to dq where the
_
E_ __p
r R
___ ____
q
dA
Now this equation can be solved by finding out the values of the charge dq in the surface are
ds. We know the Electric field intensity E
Now by applying all the present condition for the above equation we
In the above equation ds should be calculated. Consider the spherical cavity and mark the points
R and Q on the sphere of radius 'r' as shown in the above figure and drop vertical line from Q
and mark it as S. By applying the surface area of a sphere formula we get,
Now consider the right angled triangle OQS from the figure
Now substituting all the values in the electric field intensity on the spherical cavity E4 we
get,
we know polarization from the relation between polarization and dielectric constant
The above equation is known as Clausius-Mosotti equation which is valid for non-polar solids
having cubic crystal structure.
Ferroelectrics and Piezoelectrics
There are two types of dielectric materials,
Active dielectrics: These are the dielectrics which are used to generate, amplify, modulate and
modify electrical signals. This type of materials can store electrical energy.
Examples: Ferroelectrics, Piezoelectrics (a type of ferroelectric material).
Passive dielectrics: These are used as insulating materials to resist electric current.
Examples: Ceramics, mica etc.
Ferroelectrics
Ferroelectrics are the materials which exhibit electric polarization even in the absence
of an external electric field. This polarization is called spontaneous polarization.
Ferroelectric materials are polar dielectrics.
The dielectric constant of a ferroelectric material is temperature dependent and is given
by
εr = - C/ (T - Tc) (for T > Tc)
where C is the curie constant, Tc is the curie temperature, and T is the temperature of the
dielectric in K.
Examples: Rochelle salt, barium titanate, potassium phosphate etc.
Things to remember
Curie temperature (Tc): Curie temperature is the temperature at which certain
magnetic materials undergo a sharp change in their magnetic properties.
Curie Constant (C): The Curie constant is a material-dependent property that relates
a material's magnetic susceptibility to its temperature.
Applications of Piezoelectrics
(i) Inverse Piezoelectric effect is widely used in ultrasonic generator.
(ii) Quartz is used in ultrasonic transducer, watches, clocks, gas stove lighters etc.