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Acid & Base (Che, Sci)
Acid & Base (Che, Sci)
CHAPTER 2
Acids, Bases and Salts
+ H 2 O (l)
Zn (s) + 2NaOH (aq) " Na 2 ZnO 2 (aq) + H 2 (g) (Water)
Sodium zincate
3.3.1 pH of Salt Solutions
3.2.6 Reactions of Bases with Non-metallic 1. The salt of a strong acid and a weak base
Oxides gives acidic solution (pH less than 7).
Bases react with acidic oxides to form salt and
NH 4 Cl (s) + H 2 O (l) NH 4 OH (aq)
water.
Heat
2NaHCO 3 Na 2 CO 3 + H 2 O + CO 2 that is loosely attached to a certain number of
water molecules is called hydrated salt. These
NaHCO 3 + H+ $ Na+ + H 2 O + CO 2 water molecules are water of crystallisation.
2. Hygroscopy : Those substances which
3.3.8 Uses of Baking Soda absorb moisture from atmosphere at
It is used in cooking and as an antacid to correct ordinary temperature, are called hygroscopic
the acidity of stomach. It is used in making substances, and the property is known as
effervescent drinks and in fire extinguishers, and hygroscopy, e.g., conc. H 2 SO 4, etc.
also in preparing baking powder. 3. Deliquescence : Those substances which
absorb moisture from atmosphere at ordinary
3.3.9 Bleaching Powder temperature and ultimately dissolve in the
The chemical name of bleaching powder is absorbed water to form a solution are called
calcium oxychloride (CaOCl 2). It is obtained by deliquescent substances and the phenomenon
passing Cl 2 gas over dry slaked lime. is called deliquescence, e.g., NaOH, KOH,
30cC − 35cC etc.
Ca (OH) 2 (s) + Cl 2 (g) CaOCl 2 (s)
4. Efflorescence : Certain hydrated salts when
+ H 2 O (l) exposed to air at ordinary temperature lose
their water of crystallisation either partially
3.3.10 Uses of Bleaching Powder or completely, are called efflorescent salts
and the phenomenon is called efflorescence,
It is used for bleaching of wood pulp, cotton,
e.g., washing soda, epsom salt, etc.
and as a disinfectant.
8. Which of the following salts does not increasing order of acidic strength?
contain water of crystallization? (a) Water 1 Acetic 1 Hydrochloric
(a) Blue vitriol (b) Water 1 Hydrochloric 1 Acetic
(b) Baking soda (c) Acetic 1 Water 1 Hydrochloric
(c) Washing soda (d) Hydrochloric 1 Water 1 Acetic
(d) Gypsum
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Sol : www.cbse.site/sc/bm108
23. Which of the following is acidic in nature? 25. Which of the following is used for dissolution
(a) Lime juice of gold?
(b) Human blood (a) Hydrochloric acid
(c) Lime water (b) Sulphuric acid
(d) Antacid (c) Nitric acid
(d) Aqua regia
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Sol : www.cbse.site/sc/bm125
30. Equal volumes of hydrochloric acid and 33. Which of the following are present in a
sodium hydroxide solutions of same dilute aqueous solution of hydrochloric
concentration are mixed and the pH of acid?
the resulting solution is checked with a pH (a) H 3 O+ + Cl−
paper. What would be the colour obtained? (b) H 3 O+ + OH−
(c) Cl− + OH−
(d) Unionized HCl
Sol : www.cbse.site/sc/bm133
(a) Red
(b) Yellow
34. Identify the correct representation of
(c) Yellowish green
reaction occurring during chlor-alkali
(d) Blue process.
Sol : www.cbse.site/sc/bm130 (a) 2NaCl (l ) + 2H 2 O (l ) " 2NaOH (l )
+ Cl 2(g) + H 2(g)
(b) 2NaCl (aq) + 2H 2 O (aq) " 2NaOH (aq)
31. Which of the following is (are) true when + Cl 2(g) + H 2(g)
HCl (g) is passed through water? (c) 2NaCl (aq) + 2H 2 O (l ) " 2NaOH (aq)
1. It does not ionise in the solution as it is + Cl 2(aq) + H 2(aq)
a covalent compound. (d) 2NaCl (aq) + 2H 2 O (l ) " 2NaOH (aq)
2. It ionizes in the solution. + Cl 2(g) + H 2(g)
37. Which of the following are correctly 40. Which of the following are correctly
matched? matched?
48. Some of the substances used in making of a 51. A salt can be produced by reaction between
modern safety match box are listed below : 1. a weak acid and weak base.
1. Antimony trisulfide 2. metal oxide and water.
2. Glass powder 3. metal and a mineral acid.
3. Potassium chlorate 4. metal oxide and a mineral acid.
4. Red phosphorus (a) 1, 2 and 3
The head of modern safety match stick (b) 2, 3 and 4
contains : (c) 3, 4 and 1
(a) 1 and 4
(d) 4, 1 and 2
(b) 2 and 3
(c) 3 and 4 Sol : www.cbse.site/sc/bm151
(d) 3 and 1
Sol : www.cbse.site/sc/bm148 52. Which of the following is true about the
two statements?
Statement I : Reactivity of aluminium
49. Calamine is used to reduce the irritating decreases when it is dipped in nitric acid
effect of ant bite/sting because it reacts Statement II : A protective layer of
with (X ) released due to the bite/sting of aluminium nitrate is formed when
ants with (Y ) present in calamine. Then aluminium is dipped in nitric acid.
(X ) and (Y ) respectively are : (a) I is correct but II is incorrect
(a) Sodium hydrogen carbonate and (b) I is incorrect but II is correct
formic acid (c) Both the statements are correct and
(b) Formic acid and zinc carbonate II is also the correct explanation of I
(c) Acetic acid and common salt (d) Both the statements are correct but II
(d) Hydrochloric acid and zinc oxide is not correct explanation of I
Sol : www.cbse.site/sc/bm149 Sol : www.cbse.site/sc/bm152
50. A metal carbonate X on treatment with 53. A silvery white metal X reacts with water
a mineral acid liberates a gas which when at room temperature to produce a water
passed through an aqueous solution of a soluble compound Y and a colourless gas
substance Y on reaction with the gas Z . The reaction is highly exothermic and
obtained at anode during electrolysis of the Z catches fire immediately during
brine gives a compound Z which can de- the reaction. The solution of Y in water
colourise coloured fabrics. The compounds on reacting with stoichiometric amount of
54. Match the items of Column I with the items 57. The reaction that differs from the rest of
of the Column II the reaction given is-
(a) formation of calcium oxide from
Column I Column II
limestone
(i) NH 4 OH + CH3 COOH (A) Thermal
" CH3 COONH 4 + H2 O decomposition (b) formation of aluminium from
(ii) 2AgBr " 2Ag + Br2 (B) Thermite aluminium oxide
reaction (c) formation of sodium carbonate from
(iii) ZnCO3 " ZnO + CO2 (C) Photochemical sodium hydrogen carbonate
reaction
(d) formation of mercury from mercuric
(iv) 2Al + Fe2 O3 " 2Fe + Al2 O3 (D) Neutralization oxide
reaction
Solution pH
A 2.4 79. In an experiment of pH paper four students
B 14.0 takes the following observation?
C 7.5 Student Sample pH paper colour
D 9.0 A Water Blue
Arrange the above solution in the increasing B Dilute HCl Red
order of OH- ion concentration.
C Dilute NaOH Blue
(a) D 1 C 1 B 1 A
(b) A 1 C 1 D 1 B D Dilute Orange
Ethanoic
(c) C 1 D 1 B 1 A
acid
(d) B 1 D 1 C 1 A
Which student takes the incorrect
Sol : www.cbse.site/sc/bm175 observation?
(a) B
(b) C
76. Which of the following is more acidic in (c) D
nature?
(d) A
(a) Baking soda
(b) Lime water Sol : www.cbse.site/sc/bm179
(c) Lemon
(d) Apple
80. Which of the following acid is present in
Sol : www.cbse.site/sc/bm176 the vinegar?
(a) Acetic acid
(b) Tartaric acid
77. Which one of following property of base is
93. Read the following statements: 95. Hard water required for an experiment
I. When a red litmus paper is dipped into is not available in a school laboratory.
the reaction mixture of a saponification However, following salts are available in
reaction, it turns blue and the reaction the laboratory. Select the salts which may
be dissolved in water to make it hard for
(c) Red litmus turns blue and blue litmus 103. The pH of soft drink is .......... and they are
turns red. .......... .
(d) Red litmus becomes colourless and (a) less than 7, acidic
blue litmus remains blue. (b) more than 7, basic
Sol : www.cbse.site/sc/bm200 (c) equal to 7, neutral
(d) less than 7, basic
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101. A student takes about 6 ml of distilled
water in each of the four test tubes A, B,
C and D , then dissolves in equal amount 104. When acidified potassium dichromate
four different salts name sodium chloride solution is added to a jar containing sulphur
in A Potassium Chloride in B , Calcium dioxide gas, the solution becomes:
Chloride in C and magnesium chloride in (a) colourless
D . He then adds 10 drop of soap solution
(b) brown
to each test tube and shakes its contents.
The test tube(s) in which he would observe (c) dark orange
a good amount of lather is: (d) green
(a) A and B Sol : www.cbse.site/sc/bm204
(b) Only A
(c) C and D
(d) Only B 105. When you add a few drops of acetic acid to
a test-tube containing sodium bicarbonate
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powder, which one of the following is your
observation?
(a) No reaction takes place.
102. Hard water is not available for an
(b) A colourless gas with pungent smell is
experiment in the school and its vicinity.
released with brisk effervescence.
However, some salts as given below are
available in the school laboratory. (c) A brown coloured gas is released with
1. Sodium Chloride brisk effervescence.
2. Sodium Sulphate (d) Formation of bubbles of a colourless
3. Calcium Chloride and odourless gas.
4. Calcium Sulphate Sol : www.cbse.site/sc/bm205
5. Potassium Chloride
6. Magnesium Sulphate
Select form the following a group of these 106. A student require hard water for an
salts, each member of which may be experiment in his laboratory which is not
dissolved in water to make it hard. available in the neighbouring area. In the
(a) 1, 2, 5 laboratory there are some salts, which when
(b) 1, 3, 5 dissolved in distilled water can convert it
(c) 3, 4, 6 into hard water. Select from the following
(d) 2, 4, 6 groups of salts, a group, each salt of which
when dissolved in distilled water will make
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it hard.
(a) Sodium chloride, Potassium chloride
(b) Sodium sulphate, Potassium sulphate 111. When acid and base is mixed together than
(c) Sodium sulphate, Calcium sulphate which of the following is formed?
(d) Calcium sulphate, Calcium chloride (a) Salt
(b) Base
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(c) Acid
(d) Hydrogen
107. To a sample of turmeric adulterated with Sol : www.cbse.site/sc/bm211
metanil yellow, concentrated hydrochloric
acid was added. The colour of the reaction
mixture 112. Mixing of an acid or base with water is
(a) became green known as .......... .
(b) became blue (a) dilution
(c) remained the same (b) neutralisation
(d) disappeared (c) indicators
Sol : www.cbse.site/sc/bm207 (d) offertory inductors
Sol : www.cbse.site/sc/bm212
123. Which of the following is the organic acids? 127. An acid produces .......... ions in water.
(a) HCl (a) Hydrogen
(b) HNO 3 (b) Helium
(c) H 2 SO 4 (c) OH-
(d) CH 3 COOH (d) None of these
Sol : www.cbse.site/sc/bm223 Sol : www.cbse.site/sc/bm227
124. Arrange the following acids on their basicity 128. Which of the following is the strong acid?
in the table: (a) CH 3 COOH
A = HCl , B = HNO 3 , C = H 3 PO 4 (b) HCN
Type of acid Acid (c) HBr
(d) HF
1. Monobasic
2. Dibasic Sol : www.cbse.site/sc/bm228
3. Tribasic
(a) 1-A, 2-B, 3-C 129. Which of the following pair is not correct?
(b) 1-C, 2-B, 3-A
Acid Example
(c) 1-A, 2-C, 3-B
(d) 1-B, 2-C, 3-A (a) Monobasic acid HNO 3
(b) Dibasic acid H 3 PO 3
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(c) Tribasic acid H 3 PO 4
(d) Monobasic acid H 2 SO 4
125. .......... is used in bathing soaps.
(a) Sodium hydroxide Sol : www.cbse.site/sc/bm229
(b) Potassium hydroxide
(c) Magnesium hydroxide
130. .......... acid is used in car battery.
(d) Ammonium hydroxide (a) Nitric
Sol : www.cbse.site/sc/bm225 (b) Sulpharic
(c) Carbonic
(d) Tartaric
126. Which of following in not a natural
indicator? Sol : www.cbse.site/sc/bm230
(a) Red cabbage
(b) China rose
131. A body wanted to remove the grease strain
(c) Turmeric
from our shirt. So he used a X solution.
(d) Onion Here X solution is:
Sol : www.cbse.site/sc/bm226 (a) Ammonium hydroxide
(b) Magnesium hydroxide
(c) Calcium hydroxide
(d) Sodium hydroxide
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For Answer and Explanation Question Click the Link in Pink Color.
149. Bleaching powder is soluble in cold water 153. Assertion : Olfactory indicators are those
giving a milky solution due to- whose colour changes in acidic and basic
(a) The absorption of carbon dioxide from medium.
atmosphere Reason : They react with acidic and basic
(b) available chlorine solutions.
(c) lime present in it (a) Both Assertion and Reason are true
and Reason is the correct explanation
(d) calcium carbonate formation
of the Assertion.
Sol : www.cbse.site/sc/bm249 (b) Both Assertion and Reason are
true but Reason is not the correct
explanation of the Assertion.
150. A blue litmus paper was first dipped in (c) Assertion is true but the Reason is
dil. HCl and then in dil. NaOH solution. It false.
was observed that the colour of the litmus (d) Both Assertion and Reason are false.
paper-
(a) remains blue in both the solutions Sol : www.cbse.site/sc/bm253
(b) changed to red
(c) changed first to red and then to blue
154. Assertion : Active metals react with acids
(d) changed blue to colourless
to liberate Hydrogen gas.
Sol : www.cbse.site/sc/bm250 Reason : It is an example of displacement
reaction.
(a) Both Assertion and Reason are true
151. Bleaching powder gives smell of chlorine and Reason is the correct explanation
because it- of the Assertion.
(a) contains excess of chlorine (b) Both Assertion and Reason are
(b) is a mixture of chlorine and slaked true but Reason is not the correct
lime explanation of the Assertion.
(c) is unstable (c) Assertion is true but the Reason is
(d) gives chlorine on exposure to false.
atmosphere (d) Both Assertion and Reason are false.
Sol : www.cbse.site/sc/bm251 Sol : www.cbse.site/sc/bm254
152. A solution reacts with crushed egg-shells to 155. Assertion : Acids contain H+ ions.
give a gas that turns lime-water milky. The Reason : H+ ions neutralise acids.
solution contains (a) Both Assertion and Reason are true
(a) KCl and Reason is the correct explanation
(d) Both Assertion and Reason are false. and Reason is the correct explanation
of the Assertion.
Sol : www.cbse.site/sc/bm260
(b) Both Assertion and Reason are
true but Reason is not the correct
explanation of the Assertion.
161. Assertion : Limestone, chalk and marble
react with acids to form salt, carbon dioxide (c) Assertion is true but the Reason is
and water. false.
Reason : Limestone, chalk and marble are (d) Both Assertion and Reason are false.
different forms of calcium carbonate. Sol : www.cbse.site/sc/bm263
(a) Both Assertion and Reason are true
and Reason is the correct explanation
of the Assertion.
164. Assertion : HCl produces hydronium ions
(b) Both Assertion and Reason are (H 3 O+) and chloride ions (Cl-) in aqueous
true but Reason is not the correct solution.
explanation of the Assertion. Reason : In presence of water, base give
(c) Assertion is true but the Reason is H+ ions.
false. (a) Both Assertion and Reason are true
(d) Both Assertion and Reason are false. and Reason is the correct explanation
of Assertion.
Sol : www.cbse.site/sc/bm261
(b) Both Assertion and Reason are
true but reason is not the correct
explanation of Assertion.
162. Assertion : In a neutralisation reaction,
metal and non-metal react to form salt. (c) Assertion is true but Reason is false.
Reason : Metal contains H+ ions and non- (d) Assertion is false but Reason is true.
metal OH- ions. Sol : www.cbse.site/sc/bm264
(a) Both Assertion and Reason are true
and Reason is the correct explanation
of the Assertion.
165. Assertion : If the pH inside the mouth
(b) Both Assertion and Reason are decreases below 5.5, the decay of tooth
true but Reason is not the correct enamel begins.
explanation of the Assertion. Reason : The bacteria present in mouth
(c) Assertion is true but the Reason is degrades the sugar and left over food
false. particles and produce acids that remains in
(d) Both Assertion and Reason are false. the mouth after eating.
(a) Both Assertion and Reason are true
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and Reason is the correct explanation
of Assertion.
(b) Both Assertion and Reason are
163. Assertion : Non-metallic oxides are acidic
true but Reason is not the correct
is nature.
explanation of Assertion.
Reason : Non-metallic oxides react with
base to form salt and water just like an (c) Assertion is true but Reason is false.
acid reacts with a base. (d) Assertion is false but Reason is true.
(a) Both Assertion and Reason are true Sol : www.cbse.site/sc/bm265
(a) red
(b) yellow
(c) violet
(d) green (a) no gas is evolved in either of the two
beakers.
Sol : www.cbse.site/sc/bm279 (b) gas is evolved in beaker II but not in
beaker I.
(c) gas is evolved vigorously in both.
181. A student takes some zinc granules in a
(d) gas is evolved vigorously in beaker I
test tube and adds dilute hydrochloric acid
but not in beaker II.
to it. He would observe that the colour of
the zinc granules changes to Sol : www.cbse.site/sc/bm282
(a) Red
(b) Black
(c) Green 184. You have four test tubes, P, Q, R, and
(d) Yellow S containing sodium carbonate, sodium
chloride, lime water and blue litmus
Sol : www.cbse.site/sc/bm280 solutions respective. Out of these the
material of which test tube/test tubes
would be suitable for the correct test of
182. On putting few drops of an unknown liquid acetic/ethanoic acid.
on pH strip, the colour of pH strip changed (a) Only P
to green. The liquid taken is likely to be: (b) P and Q
(a) dilute sodium hydroxide solution (c) R and S
(b) lemon juice (d) P and S
(c) dilute hydrochloric acid
Sol : www.cbse.site/sc/bm283
(d) water
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185. A student took two test tubes containing
2 mL of dilute hydrochloric acid and
183. 10 mL of HCl and 10 mL of NaOH solutions added zinc granules to test tube (P) and
are contacted in two separate beakers, solid sodium carbonate to test tube (Q) as
213. Among the given solutions in the above Solutions Colour Colour
table, the most basic in nature is change with change with
(a) pure water phenolphthalein methyl
indicator orange
(b) oven cleaner
indicator
(c) household bleach
P Pink Yellow
(d) gastric juice
Q Colourless Orange
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R Colourless Red
214. The acid having highest hydrogen ion 217. The acidic solution is
concentration is one with (a) P
(a) pH = 2.5 (b) Q
(b) pH = 1.8 (c) R
(c) pH = 7 (d) None of these
(d) pH = 10
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