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Acid
+
1. An acid is a substance that forms hydrogen (H ) ions as the only positive ion when dissolved in water.
2. There are two types of acids: mineral acid (or inorganic acid) and organic acid.
a. Mineral acids are acids that are derived from one or more mineral elements or inorganic matter and can
normally be prepared in the laboratory. Phosphoric acid (H3PO4), sulfuric acid (H2SO4), hydrochloric acid
(HCI), carbonic acid (H2CO3) and nitric acid (HNO3) are examples of mineral acids.
b. Organic acids are obtained from plants and animals and are mainly naturally occurring organic compounds
with acidic properties. They include malic acid (C4H6O5) which is found in apples, ethanoic acid (C2H4O2) that
can be found in vinegar and citric acid (C6H8O7) that is present in citrus fruits like lime and lemon.
3. Strength of an acid refers to the extent to which an acid molecule dissociates or ionises in an aqueous solution to
form ions.
a. Strong acids are acids that are completely dissociated in water to produce a high concentration of hydrogen
ions. Hence, strong acids ionise completely. Strong acids have a pH in the region of about 1. Sulfuric acid,
nitric acid and hydrochloric acid are examples of strong acids.
+ -
HCI (aq) H (aq) + CI (aq)
(dilute hydrochloric acid contains only hydrogen and chloride ions; no HCl molecules are present)
+ 3-
H3PO4 (aq) 3H (aq) + PO4 (aq)
b. Weak acids are acids that are partially dissociated in water to produce a low concentration of hydrogen ions.
E.g. carbonic acid and ethanoic acid where only a few of its molecules ionises. Weak acids have a pH in the
region of about >2.5. Other examples include citric acid and malic acid.
+ -
CH3COOH (aq) H (aq) + CH3COO (aq)
(dilute ethanoic acid contains mainly acid molecules that remain unchanged in the water; very few molecules
dissociate to produce hydrogen ions)
+ 3-
C6H8O7 (aq) 3H (aq) + C6H5O7 (aq)
E.g. a 10M ethanoic acid (weak acid) is more concentrated than a 1M hydrochloric acid (strong acid).
An acid is said to be either strong or weak. Its strength cannot be changed.
The concentration can be changed, i.e. can be increased by adding more acid, or decreased by adding more
water.
a. Acids react with most metals to form salt and hydrogen gas.
(Observation: effervescence or bubbling of a colourless and odourless gas that extinguishes a burning splint
with a pop sound, which confirms the presence of hydrogen gas.)
All metals except copper (Cu) and silver (Ag) react with acid to produce hydrogen.
Lead reacts slowly with dilute hydrochloric acid and dilute sulfuric acid. Initially, the reactions produce a
layer of lead (II) chloride or lead (II) sulfate respectively. This layer is insoluble in water and forms a
coating around the metal that prevents further reaction with the acids.
2- -
b. Acids react with carbonates (CO3 ) and hydrogen carbonates (HCO3 ) to produce carbon dioxide gas.
(Observation: effervescence of a colourless and odourless gas that forms a white precipitate in limewater
[Ca(OH)2], which confirms the presence of carbon dioxide gas.) Precipitate refers to insoluble solid particles
produced in a liquid in a chemical reaction.
All carbonates react with acids to produce carbon dioxide. This is a chemical test that can be used to
confirm the presence of an acid or a carbonate salt.
c. Acids react with bases in a reaction called neutralisation to form salt and water. Bases refer to metal oxides
or metal hydroxides.
(Observation: test-tube feels warm as heat is given off.)
b. turn damp blue litmus paper red, with pH value less than 7, due to the presence of hydrogen ions.
c. Acid conducts electricity due to its abundance of mobile hydrogen ions and anions when dissociated in water.
But in other solvents, it would not conduct electricity. For example, hydrogen chloride in methylbenzene:
hydrogen chloride does not ionise to produce ions and remains as molecules. Hence, it does not conduct
electricity.
Quiz 2a: Why is the above a physical property and not a chemical property of acid?
Quiz 2b:
(1) Will a solution of hydrogen chloride in methylbenzene chemically react with metals to liberate hydrogen?
(2) Will a solution of hydrogen chloride in methylbenzene chemically react with carbonates to liberate carbon dioxide?
(3) Will a solution of hydrogen chloride in methylbenzene chemically react with alkalis?
For neutralisation, HX + NaOH NaX + H2O, where X represents an anion with a charge of –1.
To achieve neutralisation, the ratio of the acid reacting to the base is 1: 1.
Overall equation for complete neutralisation: H2X + 2NaOH Na2X + 2H2O, where X represents an anion with
a charge of –2.
To achieve neutralisation, the ratio of the acid reacting to the base is 1: 2.
Overall equation for complete neutralisation: H3X + 3NaOH Na3X + 3H2O, where X represents an anion with
a charge of –3.
To achieve neutralisation, the ratio of the acid reacting to the base is 1: 3.
a. to remove rust; the industrial process to strip rust from steel is known as pickling where the rusted steel is
dipped into phosphoric acid
2H3PO4 (aq) + 3Fe2O3 (s) 2Fe3(PO4)2 (aq) + 3H2O (l)
b. as food preservatives and flavor enhancers like in vinegar (ethanoic acid – CH3COOH).
9. A base is a substance that reacts with an acid to form salt and water only.
10. Bases form a class of chemical substances which include all metal oxides and metal hydroxides. E.g. magnesium
oxide (MgO), copper (II) oxide (CuO), and calcium hydroxide [Ca(OH)2].
-
a. Soluble bases are called alkalis. An alkali is a substance that forms hydroxide ions (OH ) when dissolved in
water. e.g. sodium hydroxide (NaOH), calcium hydroxide [Ca(OH)2], aqueous ammonia (NH4OH).
b. Insoluble bases would be unable to produce hydroxide ions in water and thus would not cause pH indicators
to change colour.
11. Strength of an alkali refers to the extent to which an alkali molecule dissociates or ionises in an aqueous solution
to form ions.
a. Strong alkalis are alkalis that are completely dissociated in water to produce a high concentration of hydroxide
ions. Hence, strong alkalis ionise completely. Strong alkalis have a pH in the region of about 13. Sodium
hydroxide, potassium hydroxide (KOH) and calcium hydroxide are examples of strong alkalis.
- +
NaOH (aq) OH (aq) + Na (aq)
(dilute sodium hydroxide contains only sodium and hydroxide ions, the ionic lattice structure of the hydroxide
breaks down to allow free ions to form)
- +
KOH (aq) OH (aq) + K (aq)
- 2+
Ca(OH)2 (aq) 2OH (aq) + Ca (aq)
b. Weak alkalis are alkalis that are partially dissociated in water to produce a low concentration of hydroxide ions.
Weak alkalis have a pH in the region of about 11. Aqueous ammonia is the example of a weak alkali.
- +
NH3 (g) + H2O (l) OH (aq) + NH4 (aq)
(aqueous ammonia has most of its molecules remaining unchanged in water; only a small fraction of ammonia
molecules dissociate to produce hydroxide ions)
12. Concentration refers to the number of alkali molecules in unit volume of a solution.
E.g. a 10M aqueous ammonia (weak acid) is more concentrated than a 1M sodium hydroxide (strong acid).
An alkali is said to be either strong or weak. Its strength cannot be changed.
The concentration can be changed, i.e. can be increased by adding more alkali, or decreased by adding more
water.
a. Alkalis and insoluble bases react with acid to form salt and water.
(Observation: test-tube feels warm as heat is given off.)
All alkalis and bases react with acids to produce water molecules.
All ammonium salt reacts with bases to produce ammonia molecules under gentle warming. This is a chemical
test that can be used to confirm the presence of an alkali or an ammonium salt.
c. Alkalis react with a solution of one metal salt to give metal hydroxide and another metal salt.
(Observation: metal hydroxide appears as insoluble white or coloured precipitates.) By observing whether a
precipitate is formed, we can identify the metal cation in the salt.
Alkali (with metal ion A)+ Salt (with metal ion B) Salt (of metal ion A) + Metal Hydroxide (of metal ion B)
Quiz 3: Given three samples containing either an acid, alkali or water each, describe 2 chemical tests that can be used
to identify the substances in each sample. Describe 1 possible physical test that can also be used to distinguish each
of the samples.
b. turns damp red litmus paper blue with a pH value greater than 7 due to the presence of hydroxide ions.
c. conduct electricity in aqueous solutions due to its abundance of mobile hydroxide ions and cations when the
base dissolves in water.
15. Plants grow best when the pH value is about 6.5. Calcium hydroxide (slaked lime)/calcium oxide (quicklime) or
calcium carbonate can be added if the soil is too acidic.
Quiz 4: Between calcium oxide, calcium hydroxide and calcium carbonate, which is the preferred choice for
neutralising an acidic soil? Note that ammonium salts is also used as a fertiliser for plant growth. Explain.
a. dissolve dirt and grease (sodium hydroxide), like in eye lotions and household cleaning agents (aqueous
ammonia).
b. relieve gastric pain and for making refractory bricks (magnesium oxide).
17. The pH is a measure of the acidicity/alkalinity of a solution. It is related to the concentration of hydrogen ions or
hydroxide ions present in a solution.
18. The pH scale is a set of numbers from 0 to 14 which is used to indicate whether a solution is acidic, neutral or
alkaline.
o
19. At a temperature of 25 C, the pH scale can be explained as follows:
+ -
pH range Concentration of H and OH in solution Solution is Litmus paper
+ -
pH < 7 Concentration of H > concentration of OH acidic Blue Red
+ -
pH = 7 Concentration of H = concentration of OH neutral No colour change
+ -
pH > 7 Concentration of H < concentration of OH alkaline Red Blue
3
20. pH is defined as the negative logarithm to the base 10 of the hydrogen ion concentration in mol/dm . (Not in
Syllabus)
pH = - log 10 [H+]
where [H+] is the concentration of H+ ions in the solution
o -7 3
a. For pure water at 25 C, [H+] = [OH-] = 1 x 10 mol/dm pH = 7
b. Example 1:
-3 3
[HNO3] = 1 x 10 mol/dm
-3
pH value = - log1010 = 3 because
acid is monobasic and a strong acid so all the molecules dissociate to form ions
-3 3
[H+] = [HNO3] = 1 x 10 mol/dm
c. Example 2:
-3 3
[CH3COOH] = 1 x 10 mol/dm
-5
pH value = - log1010 = 5 because
acid is a weak acid and only some of the molecules dissociate to form ions
-5 3
[H+] << [CH3COOH]; and [H+] = 10 mol/dm
21. A pH indicator is a substance or mixture of substances that when added to the solution gives a different colour
depending on the pH of the solution.
22. Common liquid pH indicators are litmus solution, methyl orange, screened methyl orange and phenolphthalein.
Most of these indicators are organic compounds.
23.
The pH meter as shown can be used to determine the
pH of a solution. It has a probe that can be calibrated to
+
determine the concentration of H in a solution.
A pH meter
Chemistry – Acids, Bases and Salts
Page 9 of 20
24. Colour changes of various acid-base indicators are summarized below.
25. Universal indicator is a mixture of indicators that show a variety of colours in accordance to pH values,
depending on the acidity and alkalinity of the solutions tested. It comes in the form of a solution or pH paper.
0 1 2 3 4 5 6 7 8 9 10 11 12 13 14
Red Pink Orange Yellow Green Greenish-blue Blue Violet
Acidic Neutral Alkaline
Increasing Acidity Increasing Alkalinity
a. Many plants or plant parts contain chemicals from the naturally-colored anthocyanin family of compounds. They
are red in acidic solutions and blue in basic. Anthocyanins can be extracted with water or other solvents from a
multitude of colored plants or plant parts, including leaves of a red cabbage; flowers of geranium, poppy,
or rose petals; berries from blueberries, blackcurrant; and stems of a rhubarb. Extracting anthocyanins from
household plants, especially red cabbage, to form a crude pH indicator is a popular introductory chemistry
demonstration.
b. Litmus, used by alchemists in the Middle Ages and still readily available today, is a naturally occurring pH
indicator made from a mixture of lichen (fungus) species. The color changes between red in acid solutions and blue
in alkalis.
Quiz 5b: Are all metal oxides basic? Explain your answer.
Quiz 5c: How does the property of the oxides change along Period 3 of the Periodic Table?
Quiz 5f: Are all basic oxides and amphoteric oxides soluble in acids?
Quiz 5g: Are all acidic oxides and amphoteric oxides soluble in alkalis?
(2) CO2 + H 2O
(3) SO3 + H 2O
(2) K2O + H 2O
(4) MgO + H2 O
magnesium hydroxide; highly insoluble
31. A salt is substance formed when one or more hydrogen ions of an acid is replaced by a metallic ion or an
ammonium ion.
E.g. the salt sodium chloride (NaCl) is formed when the hydrogen ion of the hydrochloric acid (HCl) is replaced by
the sodium ion, a cation (metallic ion) of sodium hydroxide (NaOH).
33. The cation of a salt comes from a metal, a carbonate, a base or an alkali.
Possible Reactants
Salt Formed
Metal/Carbonate/Base/Alkali Acid
zinc (Zn) hydrochloric acid (HCl) zinc chloride (ZnCl2)
copper (II) carbonate (CuCO3) nitric acid (HNO3) copper (II) nitrate (Cu(NO3)2)
magnesium oxide (MgO) sulfuric acid (H2SO4) magnesium sulfate (MgSO4)
potassium hydroxide (KOH) phosphoric acid (H3PO4) potassium phosphate (K3PO4)
a. Hydrated salts have water molecules attracted to the crystal lattice ions during the formation of the crystals.
These water molecules that are formed as part of the crystals may affect the shape and colour of the crystals,
and are called the water of crystallisation. Hydrated salts are prepared as follows: heat a solution (to reduce
the amount of solvent) to obtain a saturated solution, before cooling to crystallise the hydrated salt.
b. Anhydrous salt comprises crystals that have lost their water of crystallisation. Anhydrous salt can be obtained
by drying the hydrated salt crystals. This can be done by warming the crystals over a steam bath, or
evaporation to dryness. The anhydrous salt of copper (II) sulfate is white, after it loses its water of
crystallisation.
Means Challenges
Solid-Acid Reaction
Metal-Salt Displacement • Soluble salts except Group I and ammonium salts.
Reaction • Excess solid reactants (namely metal, insoluble base or carbonate) are added so
Metal + Salt Solution Salt that all the acid is completely used up, leaving behind the salt solution and excess
+ Metal of salt solution solid reactants. Otherwise, the salt produced will be contaminated with the acid.
Metal + Acid Salt + • Filter to remove excess (unreacted) metal/base/ carbonate that is added as residue.
Hydrogen • Salt solution is obtained as filtrate.
Insoluble Base + Acid • Obtain salt through heating crystallisation or filtration drying by
Salt + Water evaporation/filter paper.
Insoluble Carbonate +
AcidSalt + Carbon
dioxide + Water
Titration
Alkali + Acid Salt + • Soluble salts of Group I and ammonium only.
Water • Titration is first done with an indicator to determine the volume of alkali and acid
required for the complete reaction so that salt and water are the only products (the
Soluble Carbonate + Acid reactants will then be completely used up).
Salt + Water + Carbon nd
• 2 titration is to be done with the known volume of acid and alkali but without the
dioxide indicator.
• Salt is obtained by crystallisation or drying.
Precipitation
Reaction between Two • Salt must be insoluble.
Aqueous Solutions • Two aqueous solutions are chemically reacted to precipitate the insoluble salt. One
of the reagents provides the cation, while the other provides the anion of the salt.
• Normally, a nitrate solution is added with an acid or Group I salts to precipitate the
salt. (All nitrates, acids and Group I salts are soluble)
• Two solutions can be mixed together in any proportion.
• Salt is obtained by filtration or drying.
Titration Method
Is the salt a • Pipette a fixed volume of an alkali into
a conical flask. There is a need to add indicator because
Group I or both the reactants (acid and alkali) and
+
NH4 salt? Yes • Add an indicator to the alkali in the
flask. the products (salt and water) are
• Put an acid in a burette. colourless solutions.
• Titrate the alkali with the acid until
There is a need to repeat the titration
reaction is completed. Record the
without adding the indicator because the
volume of the acid used.
indicator added would contaminate the
• Repeat titration without indicator.
salt formed.
• Put the same volume of the alkali in
the flask, then add known volume of
No the acid to the alkali.
• Heat and cool solution to crystallise the
salt.
• Filter crystallised salt and dry the salt
with filter paper.
a. Precipitation
b. Titration
c. Solid-Acid
Quiz 6: Explain how the following dry salt crystals can be obtained by stating the chemical reagents required and the
means of obtaining pure and dry crystals.
b. To produce all nitrate salts, only the titration method can be used.
c. To the use precipitation method to produce a salt XY (where X is a metal and Y is non-metal/s), we can always use
a solution of X nitrate and a solution of Group I Y.
Quiz 8. State 2 possible means of obtaining calcium chloride. For each method, explain how the salt can be obtained.