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Balanced equation: Mg(s) + HCl(aq) salt (magnesium chloride) + hydrogen gas (H2)
Mg + 2 HCl MgCl2 + H2
Element Reactants Products
Mg 1 1
H 1 2
Cl 1 2
Fe + 2HNO3 Fe(NO3)2 + H2
Elements Reactants Products
Fe 1 1
H 1 2
NO3 1 2
3. Metal carbonate + acid a salt+ carbon dioxide gas (CO2) + water (H2O)
4. Metal hydrogencarbonate + acid a salt+ carbon dioxide gas (CO2) + water (H2O)
Practice equation
(a) Zn(s) + 2 HCl(aq)
(b) MgCO3(aq) + H2SO4(aq)
(c) NaOH(aq) + HCl (aq)
(d) ZnCO3 (aq) + H2SO4(aq)
(e) Mg(OH)2 + 2 HCl (aq)
Basicity of acids
HCl (hydrochloric acid), HNO3 (nitric acid), H2SO4 (sulfuric acid), CH3COOH (ethanoic acid)
The basicity of an acid is the number of H+ ions produced per molecule of acid when an acid
dissolves in water. Acids can be placed into the following different categories based on their
basicity:
Monobasic acids- produce one H+ ion per molecule.
E.g., HCl(aq) H+(aq) + Cl-(aq) (hydrochloric acid)
HNO3(aq) H+(aq) + NO3-(aq) (nitric acid)
Dibasic acids- produce two H+ ions per molecule.
E.g., H2SO4(aq) 2H+(aq) + SO42-(aq) (sulfuric acid)
H2CO3(aq) 2H+(aq) + CO3 2-(aq) (carbonic acid)
Tribasic acids- produce three H+ ions per molecule.
E.g., H3PO4(aq) 3H+ (aq) + PO43-(aq) (phosphoric acid)
Acid anhydrides
An acid anhydride is a compound that reacts with water to form an acid. Many of them are acidic
oxides.
Examples are carbon dioxide (CO2), sulfur dioxide (SO2), sulfur trioxide (SO3) and nitrogen
dioxide (NO2)
CO2(g) + H2O(l) ⇌ H2CO3(aq) (carbonic acid)
SO2(g) + H2O(l) ⇌ H2SO3(aq) (sulfurous acid)
SO3(g) + H2O(l) H2SO4(aq) (sulfuric acid)
2NO2(g) + H2O(l) HNO2(aq) + HNO3(aq) (nitrous acid and nitric acid)
Bases
Bases are opposite to acids. They are metal oxides and metal hydroxides.
Examples: aluminum oxide (Al2O3), sodium hydroxide (NaOH), zinc oxide (ZnO), copper (II)
oxide (CuO), Aluminum hydroxide (Al(OH)3), magnesium hydroxide (MgO), Iron(II) oxide
(FeO), Potassium hydroxide (KOH), Calcium oxide (CaO)
Definition of base: a proton (H+) acceptor.
As bases react with acids, the O2- or OH- ions of the base accepts H+ ions (protons) from the acid
to form water.
For example, when an acid reacts with a base: OH-(aq) + H+(aq) H2O(l)
Alkalis
Most bases are insoluble in water. An alkali is a base that is soluble in water. This is a base
which dissolves in water to form a solution containing OH- ions.
Examples of alkalis:
Potassium hydroxide (KOH), sodium hydroxide (NaOH) and calcium hydroxide (Ca(OH)2).
Calcium hydroxide is only slightly soluble in water.
NaOH(s) + water Na+(aq) + OH-(aq)
Ammonia gas (NH3), potassium oxide (K2O), sodium hydroxide (Na2O) and calcium oxide
(CaO).
NH3(g) + H2O(l) ⇌ NH4+(aq) + OH-(aq)
Physical properties of alkalis
They have a bitter taste.
They are corrosive.
They feel soapy.
They change red litmus to blue.
They have a pH value greater than 7.
They are electrolytes.
Chemical reactions of bases
1. Base + acid a salt + water (H2O)
NaOH(aq) + HCl(aq)NaCl(aq) + H2O(l)
CaO (aq) + H2SO4(aq) CaSO4 (s) + H2O (l)
Na2O (aq) +2 HNO3(aq) 2 NaNO3(aq) + H2O (l)
Elements Reactants Products
Na 2 1
O 1 1
H 1 2
NO3 1 1
Classification of oxides
There are four different ways that oxides can be classified:
Acidic oxides- these are oxides of some non-metals which react with alkalis to form a
salt and water. Examples include carbon dioxide (CO2), sulfur dioxide (SO2), sulfur
trioxide (SO3), nitrogen dioxide (NO2) and silicon dioxide (SiO2). Most acidic oxides can
react with water form an acid. Therefore, they are acid anhydrides.
2NaOH(aq) + CO2(g) Na2CO3(aq) + H2O(l)
Basic oxides- these are oxides of metals that react with acids to form salt and water.
Examples include magnesium oxide(MgO), iron(III) oxide, (Fe2O3) and copper(II) oxide (CuO).
MgO(s) + H2SO4(aq) MgSO4(aq) + H2O(l)
Some metal oxides such as potassium oxide (K2O), sodium oxide (Na2O) and calcium oxide
(CaO) are basic oxides which are classified as alkalis as they react with water to form a solution
containing OH- ions.
Na2O(s) + H2O(l) 2NaOH(aq)
Amphoteric oxides- are oxides of some metals which react with both acids and strong
alkalis to form salt and water.
Examples include aluminum oxide (Al2O3), zinc oxide (ZnO) and lead(II) oxide (PbO).
Neutral oxides- these are oxides of some non-metals which do not react with acids or
alkalis.
Examples include carbon monoxide (CO), nitrogen monoxide (NO) and dinitrogen monoxide
(N2O).
The oxides and hydroxide of aluminum, zinc and lead are amphoteric. Examples: aluminum hydroxide,
aluminum oxide, zinc hydroxide, zinc oxide, lead hydroxide and lead oxide.
Amphoteric oxide Amphoteric hydroxide Salt formed when Anion present in the
reacting with a strong salt
alkali
Aluminum oxide (Al2O3) Aluminum hydroxide aluminates AlO2-
(Al(OH)3)
Zinc oxide (ZnO) Zinc hydroxide zincates ZnO22-
(Zn(OH)2)
Lead(II) (PbO) Lead hydroxide plumbates PbO22-
(Pb(OH)2)
Table 1. Common ionic compounds that are soluble in water
Compounds Solubility in water Exceptions
Potassium, sodium, and Soluble None.
ammonium compounds
Nitrates Soluble None.
Chlorides Soluble Silver chloride (AgCl) is
insoluble.
Lead(II) chloride (PbCl2) is
insoluble in cold water but
moderately soluble in hot
water.
Sulfates Soluble Lead(II) sulfate (PbSO4) and
barium sulfate (BaSO4) are
insoluble.
Calcium sulfate (CaSO4) is
slightly soluble.
Ethanoates Soluble None.
Hydrogencarbonates Soluble None.
Calcium hydroxide
(Ca(OH)2) is slightly soluble.
Metal oxides Insoluble Potassium oxide (K2O),
sodium oxide (Na2O) and
calcium oxide (CaO) react
with water to form soluble
hydroxides.
Measuring pH of solutions
The pH Scale
This is a scale of numbers from 0 to 14. It is used to show how acidic or alkaline a solution is.
Indicators
Indicators are one color in an acid and another in a base. They can be used to distinguish acids
and alkalis in aqueous solution.
Indicator Color in acids Color in alkali
Litmus Red Blue
Methyl orange Red Yellow
Screened methyl orange Red Green
Phenolphthalein Colorless Pink
Using a universal indicator
A universal indicator is a mixture of colored compounds that shows a range of colors depending
on the pH of the substance. The universal indicator works by dipping it into a solution and then
the color of the indicator is matched with a color chart showing the pH corresponding to different
colors.
Using a pH meter
This is a pH electrode that is connected to a pH meter that can measure the pH of a solution
directly. A pH meter is more accurate than a universal indicator.
Concentrated or dilute
A concentrated acid solution contains more particles of acid per dm3 than a dilute solution. It
does not speak to how strong or weak the acid is.
A concentrated alkali solution contains more particles of alkali per dm3 than a dilute solution. It
does not speak to how strong or weak the alkali is.
The strength of acids and alkali
Acids
Alkali
NaOH(aq)Na+(aq) + OH-(aq)
(ii) Acid salts- the H+ ions in an acid are only partially replaced by metal or ammonium
ions. Only dibasic ( have 2 hydrogens) and tribasic (have 3 hydrogens) acids can form
acid salts.
KOH(aq) + H2SO4(aq) KHSO4(aq) + H2O(l)
Acid salt
Acid
Water of crystallization
This is a fixed proportion of water molecules which is held within their crystal lattice. Salts
which contain water of crystallization are said to be hydrated and the water of crystallization is
shown in the formula.
An example is hydrated copper(II) sulfate CuSO4.5H2O
Water in the molecules is responsible for the shape and sometimes the color of the crystals. The
water of crystallization can be removed by heating causing the salt to become anhydrous. This
causes if to lose its crystalline structure and color.
CuSO4.5H2O(s) CuSO4(s) + 5H2O(l)
Blue crystals-hydrated white powder-anhydrous
Solubility Rules
Soluble compounds Insoluble compounds
All salts of Group I elements
All nitrates and ammonium salts
Most chlorides, bromides, and iodides Chlorides, bromides and iodides of silver and
lead
Most sulfates Sulfates of calcium, barium, and lead
Group I hydroxide and carbonates Most hydroxides and carbonates
Group I and II oxides react with water Most metal oxides
Filter to
separate the
precipitate.
Wash the
precipitate
(residue) with
distilled water.
Dry the
residue.
Direct Anhydrous A suitable Heat the metal AlCl3 2Al(s) +
Combination chlorides metal to in a stream of 3Cl2(g)
supply the chlorine gas in 2AlCl3(s)
cations. a fume
Chlorine gas cupboard.
to supply Cl-
ions.
Reactive metal Soluble salts A suitable Add the metal ZnCl2 Zn(s) + 2HCl
with an acid of the metal to to the acid and (aq) ZnCl2
following supply the warm if (aq) + H2 (g)
reactive cations. A necessary.
metals: suitable acid Keep adding
magnesium, to supply until
aluminum, anions. effervescence
zinc, and iron (bubbling)
stops and the
metal is
present in
excess.
Dip a piece of
blue litmus
paper into the
solution; it
should remain
blue.
Filter to
remove the
excess metal,
collect the
filtrate.
Evaporate the
water or
evaporate
some water
and leave to
crystallize.
(see below)
Insoluble base Soluble salts A suitable Add the base MgSO4 MgO (s) +
with an acid except insoluble to the acid and H2SO4
potassium, base to warm if MgSO4 (aq) +
sodium, and supply the necessary. H2O(l)
ammonium cations. Keep adding
salts A suitable until Or
acid to effervescence
supply the (bubbling) Mg(OH)2 (s) +
anions. stops and the H2SO4
base is present MgSO4 (aq) +
in excess. 2H2O(l)
Dip a piece of
blue litmus
paper into the
solution; it
should remain
blue.
Filter to
remove the
excess base,
collect the
filtrate.
Evaporate the
water, or
evaporate
some water
and leave to
crystallize
Insoluble Soluble salts A suitable Add the Cu(NO3)2 CuCO3 (s) +
carbonate with except insoluble carbonate to 2HNO3 (aq)
an acid potassium, carbonate to the acid and Cu(NO3)2 (aq)
sodium, and supply the warm if + CO2 (g) +
ammonium cations. necessary. H2O (l)
salts. A suitable Keep adding
acid to until
supply the effervescence
anions. (bubbling)
stops and the
carbonate is
present in
excess.
Dip a piece of
blue litmus
paper into the
solution; it
should remain
blue.
Filter to
remove the
excess metal,
collect the
filtrate.
Evaporate the
water, or
evaporate
some water
and leave to
crystallize
Titration Potassium, Two Place the acid K2SO4 2KOH(aq) +
sodium, and solutions: in the burette H2SO4 (aq)
ammonium An alkali or and find the K2SO4 (aq) + 2
salts carbonate volume needed H2O (l)
solution to to neutralize a
supply K+ , fixed volume
Na+ and of alkali or
NH4+ ions. carbonate KHSO4
A suitable solution, KOH(aq) +
acid to measured in a H2SO4 (aq)
supply the pipette by KHSO4 (aq) +
anions performing a H2O (l)
titration using
a suitable
indicator.
Add the
volume of acid
found above to
the fixed
volume of
alkali or
carbonate
solution
without adding
the indicator to
make a normal
salt.
Evaporate the
water or
evaporate
some water
and leave to
crystallize.
Crystallization
This is used to separate and retain the solid solute from the liquid solvent in a solution. It
is useful if the solute decomposes on heating or if a solid containing water of
crystallization is required.
Uses of Salts in Everyday Life
Salt Use Notes
Sodium A component of baking powder Baking powder also contained a
hydrogencarbonate used to make cakes rise. weak acid and when mixed with the
(NaHCO3) liquid in the cake mixture, the two
active components react and form
carbon dioxide.
Carbon dioxide forms bubbles in the
cake. The bubbles cause the cake to
ride as they expand on heating.
Sodium benzoate To preserve food Used to preserve foods which have a
(C6H5COONa) lower pH, eg fruit juices and fizzy
drinks. At a low pH it is converted to
benzoic acid which prevents the
growth of microrganisms.
Sodium Chloride To preserve food Used to preserve food such as meat
NaCl and fish.
Sodium nitrate To preserve food Used to preserve meat, eg bacon and
(NaNO3) ham. They destroy bacterial which
Sodium nitrite cause food poisoning, slow oxidation
(NaNO2) of fats and oils which causes
rancidity, give an attractive red
colour to the meat and add flavour.
They are often used together with
sodium chloride.
Calcium carbonate To manufacture cement used in When heated in a kiln, it decomposes
(limestone) the construction industry. to form calcium oxide.
(CaCO3) CaCO3(s) CaO(s) + CO2 (g)
Calcium oxide is blended with the
other materials in the kiln to form
clinker which is then ground with
calcium sulfate to make cement
Calcium sulfate To manufacture plaster of Paris Plaster of Paris is made of anhydrous
(gypsum) used as a building material and calcium sulfate. When water is
(CaSO4.2H2O) for setting broken bones. added, heat is given off and a paste
forms. The paste is used to coat walls
and ceilings, and bandages
impregnated in it are used to make
orthopaedic casts.
Magnesium sulfate For various medicinal purposes Has numerous health benefits. Added
(Epsom Salt) to bath water it relieves stress, eases
(MgSO4.7H2O) aches, and pains, reduces
inflammation and halt cure skin
In agriculture problems. Taken orally it works as a
laxative.
Improves plant growth.
Sodium chloride (NaCl) Can lead to hypertension (high blood pressure) if consumed in
excess.
Sodium nitrate May increase the risk of developing cancer.
And Sodium nitrite May cause brain damage in infants