Electrochemistry Exercises

21st October 2019

David Sizer Lecture Theatre
For each of the following reactions below, draw a voltaic cell. In your drawing include the anode,
cathode, and show the flow of electrons. Balance the equation and calculate the E∘cell.

E0 (Zn2+/Zn)= -0.763 V
E0 (Ag+/Ag)= 0.337 V
E0 (Rb+/Rb)= -2.93 V
E0 (Hg2+/Hg)= 0.86 V
E0 (O2/H2O)= 1.229 V
E0 (F2/F-)= 2.886 V

Answer:
 F = 96 485 C/ mol e-

What are the ΔG∘ for the reactions below?

E0 (Ti+/Ti)= -1.63 V
E0 (Cr2+/Cr)= -0.90 V
E0 (Sn4+/Sn2+)= 0.154 V
E0 (Cu2+/Cu+)= 0.159 V
E0 (O2/H2O)= 1.229 V
E0 (Cl2/Cl-)= 1.358 V

Answer:
 E0 (S2O82-/SO42-)= 2.01 V
E0 (BrO3-/Br2)= 1.478 V

Answer:
 A voltaic cell has an Ecell value of 1.536 V. What is the concentration of Ag+ in the cell?

E0 (Zn2+/Zn)= -0.763 V
E0 (Ag+/Ag)= 0.800 V

Answer:
 E0 (Al3+/Al)= -1.662 V
E0 (Fe2+/Fe)= -0.447 V
E0 (Co2+/Co)= -0.28 V
E0 (Fe3+/Fe2+)= 0.771 V

Answer:
 E0 (Cu2+/Cu)= 0.342 V
E0 (Ag+/Ag)= 0.7996 V

Answer:
 E0 (Cu2+/Cu)= 0.342 V E0 (Cl2/Cl-)= 1.358 V
E0 (Zn2+/Zn)= -0.763 V E0 (Fe3+/Fe2+)= 0.771 V
E0 (Al3+/Al)= -1.663 V

Answer:
Answer:
E0 (Ag+/Ag)= 0.7996 V

Answer:
E0 (Pb2+/Pb)= -0.125 V
E0 (Cu2+/Cu)= 0.340 V

Answer:
 E0 (Ca2+/Ca)= -2.84 V
E0 (Li+/Li)= -3.04 V
Answer: E0 (H2SO3/S)= 0.449 V
E0 (Fe(CN)64-/ Fe(CN)63-)= 0.361 V
 E0 (Mg2+/Mg)= -2.356 V
E0 (Na+/Na)= -2.713 V
E0 (Cu2+/Cu)= 0.34 V
E0 (F2/F-)= 2.866 V

Answer:
 E0 (Ag+/Ag)= 0.800 V
E0 (Sn4+/Sn2+)= 0.154 V

Answer:
 E0 (Pb2+/Pb)= -0.125 V
E0 (Zn2+/Zn)= -0.763 V

Answer:
 E0 (Mg2+/Mg)= -2.356 V E0 (Cu2+/Cu)= 0.34 V
E0 (Na+/Na)= -2.713 V E0 (F2/F-)= 2.866 V

Answer:
 E0 (V3+/V2+)= -0.255 V
E0 (Ni2+/Ni)= -0.257 V
E0 (Al3+/Al)= -1.662 V
E0 (Br2/Br-)= 1.065 V
E0 (Cu2+/Cu)= 0.342 V
E0 (Sn4+/Sn2+)= 0.151 V
Answer:
Answer:
Tomorrow we will study solutions and
properties.
Thanks!