Answer the following:

1) What is the molarity of 60% nitric acid (Sp. Gr.: 1.33, FW: 63)? then describe
how to prepare 0.5 L, 0.2 M diluted solution from this one?

2) If you mixed 50 mL, 0.1 M Na2CO3 and 50 mL 0.1 M NaCl then what is
[Na+]?

3) A solution was prepared by dissolving 0.258 g KI (FW: 166) in 250 mL

volumetric flask. What is % w/v, moalrity of the prepared solution?

4) If the solution in question 3 was diluted within a dilution factor 2:11 then what
is the ppm concentration of KI in the diluted solution?

5) A solution of CuCl2 was prepared by dissolving 0.8327 g CuCl2 assayed

89.31% (w/w) in 150 mL? Calculate the molar conc. of the prepared solution
and [Cl-], Conc. of Cu+2 in ppm?

6) 50 mL of a diluted CdCl2 required 15.43 mL , 0.1 M AgNO3 during titration

CdCl2 + AgNO3 AgCl + Cd+2 + NO3 ¯ (Balance the equation)
Calculate the molarity of CdCl2 ?
If the diluted solution was prepared by transferring 10.0 mL of a stock solution
and diluted with water to 150 mL. What is the molarity of stock solution?

7) If a solution has [Ca+2] = 0.25 M was prepared by dissolving X g of a primary

Ca(NO3)2 (FW: 164) in 500 mL volumetric flask. Calculate the X g?

8) If a Na2S [FW: 78] solution has 1.15% (w/v) concentration, Calculate [Na+]?

9) If [Ca+2] = 0.02 M, for 100 mL solution then what is ppm concentration of

CaCl2 [FW: 110.98]?

10) To standardize a solution of I2 a 0.358 g of Na2S2O3 (FW: 158) was dissolved

in 50 mL and titrated with iodine solution. If titration required 12.17 mL of
I2Solution calculate the molarity of the solution?
I2 + 2 S2O3 ¯2 2 I ¯ + S4O6 ¯2

11) If you have a Na2SO4 solution of 0.15 M and it was diluted within a factor
3:7, what is the molar and ppm concentration of Na+ in diluted solution?
[AM of Na: 23 ]
 12) What is the molarity of 68% (w/w) HNO3 (FW: 63, sp.gr.: 1.4)? If it is diluted
as follows:
68% (w/w) 15 mL 200 ml 150 ml
HNO3 volumetric 35 mL volumetric
flask flask

Calculate the molar concentration of the last solution?

Calculate the dilution factor of the process?

13) A solution of Potassium chromate (K2CrO4, FW: 194) was prepared by

dissolving 5.745 g of primary substance in 250 mL volumetric flask. The
solution was diluted as follows:

K2CrO4 35.5 mL 50 mL
solution 25.0 mL
250 mL 2
50 mL

12.0 mL
\
25 mL

Calculate the molar conc. of each solution?

Calculate the dilution factor?

Calculate the ppm conc. of K+ in the last solution (AM of K: 39)?

14) A solution of BaCl2 (FW: 208) was prepared by dissolving 1.986 g of primary
standard in 50 mL volumetric flask. 16.4 mL were transferred into 50 mL
volumetric flask and diluted with water. 18.0 mL of the resulting solution were
diluted in 100 mL volumetric flask. From end solution 30 mL were diluted in
50 mL volumetric flask.

Calculate molarity and % w/v of the last solution?

Calculate ppm conc. of Cl¯ in last solution? (AM of Cl: 35.5)
Calculate the volume of AgNO3 0.01 M required to titrate 10.0 mL of the end
solution?
BaCl2 + AgNO3 AgCl + Ba+2 + NO3¯ (Balance the equation)
15) A 200 mL solution of Na2CO3 (25.00 % w/v, FW: 105.99) was diluted by
transferring 20.50 mL of the solution into 50 mL volumetric flask. From the
resulting solution 30.20 mL were diluted in 100 mL volumetric flask. 15.88
mL of the last solution were diluted in 100 mL volumetric flask. 25 mL of the
last solution were titrated using 0.2 M HCl.
What is the volume (mL) required in titration?
CO3¯ 2 + H+ CO2 + H2O (Balance the equation)
Calculate [Na+] in each solution of the dilution process?

16) A solution of Ce(SO4)2 (5.50% w/v, FW: 332) was diluted within a dilution
factor of 2:17. Calculate [Ce+4] and ppm of Ce+4 in diluted solution? (AM of
Ce: 58)?

17) What is the molar conc. of K+ in a solution that is 63.3 ppm of K3Fe(CN)6
(FW: 329.3)?