electrode immersed

A
hydrogen
is in
of
a
som
Ef pn=o ( nd ) .

By
how

much will the red .

potential change
if an
equivalent amount
of Naoh is added

to this som so
that solution becomes
neutral .

( Pne I atm) ← 295K .

 HT +
E →
If nz
°

Ep ,
-E -

005,1 log , Pn
( ND

0059,1-1
t
E re I = O
g,
-

"
-

F-
0.0¥ log
+ lo O
=
=
-
4137
Refined )
-

o
,
-
change
in ⑧ o.in#v
=
I calculate Echl for

Ptln link::c;.nl/FondHiatm' ,
Hi
2=904 .

At 298k the Kc of
Cf rxn
"

Zn
"

tuning @nCNnDuJ is 109

If E&n( nnz) , ]+Yzn+unnz=
- t -
037 find E%hn+z
¥

Cathode
Af Andy -

in -
N' te ut +
e-
etna
T ,
'
It
ton ? ,d=n
' →

Kon ← K O O
O
l O
eog
I -09 eog
0.75
- -

O -75 0.75
l -
 Anode cathode

7¥
/
Miao
.
""
0*55

F- cell =
O -

005,92 log
,
.NL
Chik
F-cell =

0.057 log .cn#I

,

F- = O -
378
cell
-
 Secondary Reference
* calomel Electrode -

-
⑧ EMf=o24#g
Anode Pt ot

cathode
clingy
Pt,
-
 Hamdardat egm EMF
@
=
'

Dh = Dh + Rt en Q

F- cell =
Eine -

tf en Q

sTTsaI-RtlnQ#
At E cell & Dh O
-

egm
-
- o -

-
 riced Rfp bn key
-
⑦ =

: en logo keg
O E
2302,1L
-
=

E : eef ao*nI
+
log key
o
,
kege-nnetgnln.IT
NEF At agg K value of Kc -
-

109g for the oxn

"

@ ( Nhs)y)
"
Zn t 4 NAZI

Ee
}E(mcnnDD%n-unn,=ti
2
find value Eta , .mu ?
 "

-8¥
① Tnt Nnz f @ ( Nady
-

)
+4DIG
"

founds thin:3
m
-1¥ -

② ,
"
±

Target oho,
M 2E
③ M -
+
.

eg① & ② will geteq 3

reversing
we
on

; AE
to
Dh }= -
Dh -

,
 2fE°mgzfz ( 2303Mt og ok
)
-
-

- =
,

coning f 2fE ; )
-

F- = 0.77 v

zymase
-
§ Consider the cell at afc

/
Ages ng)Bres) .

/ BIL g)
-

ltdkgslagdl Ay
Tf Ksp of Ag
Br and
AGI are

5×10-13 and ,
-

o
' °

respectively
For what ratio
of BI Coq ) and
Conan
Sf
the would be
d- Long ) emf zero .
n

Y Tf
cell is taken to be couch cell

E- feel =
0

Andy Ag
→
Ag ! x
E

cathode Agfa tee →

Ay
Tiga
 O

eu= 0.07C
-
'
log ..

µµg
Ece
so Cafta -
Nfl .

i÷Mi÷in%¥ *÷
'
.
 -
BI ) Too
(
÷oo
=
=

2nd method Eoc ell to

#
Eceee =
Eft lag cling
-

EBI lag Bol Ag

 Ieee
F- =

EE ayyng t
"

° log ,
Ksp (Agu) )
f ringing ↳ e.arr
-
o '

F- feel = + o

059,1 log
'

, .
Ksplay 4) -

00,592 log oks

, playBI

IEE-ioosfl.am#s::YnI..,Pe..
 Anodes Ay + BE →
ay
Bote

agate Ag El
cathode
-
+

-
Brags d- Caq)
←
petty

Eyed riced o°' logo

-

O
so

F- Ieee
= to
-05,9L log !
,
( )
BI

Nof
+
o.org#g.oksPfTtpYngI ,
=
to
" p
l o go

A- Ict )
=
krpfAg#
Ksp ( Agb)
-

(B = too
at
 Thermodynamicfuncti.ms#ellRxn
① DIE -
NFE ?
cell
& Ahs -

nFEcey

② G=n TS
-

H=EtPD
G'= ⇐ + PV) - Ts (
Tds Sde
dG=dE+PdV+vdP - -
 From F- LOT
→

dw
DE -
-
dy t

Pdv
= dq -

dq=dEtPd#
From
¥
SLOT

fdq=
ds -
-
 d9 =
@
-
EM + Vdp
--# -
Sd T

$
§

$dG=VdP
* x
&

cell is
taking place at const p
(if;ne!Y
Tf
xn
const
- '

of
B
d G = Vd P -
Sd T
-
At const p
Vdp = o

dG= - Sdt

⇐
-

¥1 .

Ds =
-

fdCDd)p
DG nf f-
cell
= -

(
DS
⇐ FF
⇐ -
- n

DS=tnFfddfEceu②
 temperature co
efficient if
daff
-

the cell .

③ Dh = DH -
TAS

DG TDS
DH = +

|DM=-nfEceµtnFTdEg##
HI solve Race 11 All Questions