REPORT OF ANALYSIS

Client : PT. HM SAMPOERNA TBK PLANT SUKOREJO

Jl. Raya Surabaya-Malang, Km.51.4 , Pandaan, Jerukuwik
Ngadimulyo, Kec.Sukorejo, Kab.Pasuruan , Jawa Timur 67161
Type Of Sample : Emission Air
Tested for : Pergub Jawa Timur no.10 tahun 2009 , Lampiran I.X
Date Of Sampling : MAY 27,2021 15.00 wib
Sample Identification : Unit DRY ICE EXPANDED TOBACCO (DIET)
: Fuel LNG
: Engine Capacity (kVa) -
: Inside Diameter (m) 1.48
: Height (m) 15 m
: Upstream 11.8 m
: Downstream 2.96
: Number Of Traverse Point 8
: Coordinate S 07o 41' 57.3995"
E 112o 41' 35.0639"

Test Result
Threshold
NO. Parameter Unit Measurement Methods
Limit Value
Concentration
1 Ammonia (NH3) mg/Nm³ <0.01 400 PO/ENV-EMS/03
2 Chlorine gas (Cl2) mg/Nm³ <0.01 10 SNI 19-7117.10-2005
3 Hidrogen Chloride ( HCl ) mg/Nm³ <0.01 5 SNI 19-7117.8 - 2005
4 Hidrogen Flouride ( HF ) mg/Nm³ <0.01 10 SNI 19-7117.9 - 2005
5 Nitrogen Oxide (NO₂) mg/Nm³ 1.1 1000 PO/ENV-EMS/03
6 Opasitas % <20 35 SNI 19-7117.11-2005
7 Total Particulate mg/Nm³ 17.3 350 SNI 7117.17:2009
8 SO₂ (Sulfur Dioxide) mg/Nm³ <0.26 800 PO/ENV-EMS/02
9 Hidrogen Sulfide (H2S) mg/Nm³ <0.01 35 SNI 7117.14:2009
Metal
1 Mercury(Hg) mg/Nm³ <0.008 5 SNI 7117.20:2009
2 Arsenic ( As ) mg/Nm³ <0.001 8 SNI 7117.20:2009
3 Antimoni (Sb) mg/Nm³ <0.05 8 SNI 7117.20:2009
4 Cadmium ( Cd ) mg/Nm³ <0.02 8 SNI 7117.20:2009
5 Zinc (Zn) mg/Nm³ <0.03 50 SNI 7117.20:2009
6 Lead ( Pb ) mg/Nm³ <0.008 12 SNI 7117.20:2009
Secunder data
1 CO₂ (Carbon Dioxide) % 10.1 - SNI 19-7117.10-2005
2 O₂ (Oxygen) % 13.8 - SNI 19-7117.10-2005
3 Isokinetic % 104.3 90 - 110 Calculated
4 Linear Velocity m/s 6.9 - SNI 7117.14:2009
5 Flow Rate (ACT) m³/s 11.8 - SNI 7117.14:2009
6 Flow Rate (STD) m³/s 4.9 - SNI 7117.14:2009
 PT SUCOFINDO
CALCULATION METALS ON EMISSION SOURCE STATIONARY
SUCOFINDO

Company : PT. HM SAMPOERNA TBK PLANT SUKOREJO

Location DRY ICE EXPANDED TOBACCO (DIET)
Lab No. :
Methode : SNI 7117.20-2009
Date Analysis : JUNI 2021

Blank Mahaka Lime Plant R1

Parameters KMnO4 / Impinger 1 & Impinger 2&3 Impinger 4 & Impinger 5 & 6 Total (mg)
HNO3 / H2O2 HNO3 0,1 N HCl 8N Rinse HNO3 (KMnO4/H2SO
H2SO4 0,1N
(HNO3/H2O2) Rinse HCl 8N
4)
Arsen (As) 0.0000 0.0000 0.0000 0.0020
Laboratorium
result (mg/L)

Cadmium (Cd) 0.0000 0.0005 0.0006 0.0009

Chromium (Cr) 0.0000 0.0020 0.0000 0.0107
Merkuri (Hg) 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0100
Lead (Pb) 0.0000 0.0000 0.0000 0.0025
Thalium (Tl) 0.0000 0.0000 0.0000 0.0000
Antimony (Sb) 0.0000 0.0248 0.0000 0.0461
Cobalt (Co) 0.0000 0.0049 0.0000 0.0000
Copper (Cu) 0.0000 0.0079 0.0000 0.0517
Nikel (Ni) 0.0000 0.0041 0.0000 0.0237
Selenium (Se) 0.0000 0.0000 0.0000 0.0000
Mangan (Mn) 0.0000 0.0000 0.0000 0.0252
Vanadium (V) 0.0000 0.0052 0.0000 0.0016
Volume (mL) 100 100 100 100 100 100 100 100
Arsenic (As) 0.0000 0.0000 0.0000 0.0002 0.0002
Weight (mg)

Cadmium (Cd) 0.0000 0.0001 0.0001 0.0001 0.0002

Chromium (Cr) 0.0000 0.0002 0.0000 0.0011 0.0013
Merkuri (Hg) 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0010 0.0010
Lead (Pb) 0.0000 0.0000 0.0000 0.0002 0.0002
Thalium (Tl) 0.0000 0.0000 0.0000 0.0000 0.0000
Antimony (Sb) 0.0000 0.0025 0.0000 0.0046 0.0071
Cobalt (Co) 0.0000 0.0005 0.0000 0.0000 0.0005
Copper (Cu) 0.0000 0.0008 0.0000 0.0052 0.0060
Nikel (Ni) 0.0000 0.0004 0.0000 0.0000 0.0004
Selenium (Se) 0.0000 0.0000 0.0000 0.0000 0.0000
Mangan (Mn) 0.0000 0.0000 0.0000 0.0000 0.0000
Vanadium (V) 0.0000 0.0005 0.0000 0.0002 0.0007
Arsenic (As) 0.000189 Arsenic (As) 0.000290 <0.001
Result Corrected by 10% O2 (mg/Nm³)
Concentration

Cadmium (Cd) 0.000184 Cadmium (Cd) 0.000282 <0.02

(mg/Nm³)

Chromium (Cr) 0.001199 Chromium (Cr) 0.001839 <0.008

Merkuri (Hg) 0.000944 Merkuri (Hg) 0.001448 <0.008
Lead (Pb) 0.000231 Lead (Pb) 0.000355 <0.03
Thalium (Tl) 0.000000 Thalium (Tl) 0.000000 <0.2
Antimony (Sb) 0.006690 Antimony (Sb) 0.010259 <0.05
Cobalt (Co) 0.000463 Cobalt (Co) 0.000710 <0.008
Copper (Cu) 0.005628 Copper (Cu) 0.008630 <0.008
Nikel (Ni) 0.000387 Nikel (Ni) 0.000594 <0.008
Selenium (Se) 0.000000 Selenium (Se) 0.000000 <0.004
Mangan (Mn) 0.000000 Mangan (Mn) 0.000000 <0.007
Vanadium (V) 0.000642 Vanadium (V) 0.000985 <0.007
Vmstd (l) : 1059
O2 (%) : 13.79 Analyst : Harry W U Supervisor :Sri Nugroho
Signature : Signature :
 P
KONSENTRASI HCl
2
KURVA I = ( X = Y -0.0067 / 2.5200 )…….R = 0.9986
X= Y- 0.0067 / 2.52
Sample DIET Sample DIET input data
Abs. Spl 0 Abs. Spl 0
Abs. Blanko 0.000 Abs. Blanko 0.000
Conc. Spl 0.003 Conc. Spl 0.003
Conc. Blanko 0.003 Conc. Blanko 0.003
Diluted 250 5 50 Diluted 250 5 50
Vs 0.028509 m3 Vs 0.042 m3
( A-B ) x FP x (36.5/35.5) ( A-B ) x FP x (36.5/35.5)
Calculated C = Calculated C =
Vs Vs
0.000 0.000
Result < 0.01 mg/Nm3 Result < 0.01 mg/Nm3

KONSENTRASI HF
2
KURVA I = ( X = Y - 0.0035 / 0.6667 )…….R = 0.9984
X= Y+ 0.0035 / 0.6667
Sample DIET Sample DIET
Abs. Spl 0 Abs. Spl 0
Abs. Blanko 0.000 Abs. Blanko 0.000
Conc. Spl 0.000 Conc. Spl 0.000
Conc. Blanko 0.000 Conc. Blanko 0.000
Diluted 250 20 12.5 Diluted 250 20 12.5
Vs 0.020 m3 Vs 0.011 m3
( A-B ) x FP x (20/19) ( A-B ) x FP x (20/19)
Calculated C = Calculated C =
Vs Vs
0.000 0.000
Result < 0.01 mg/Nm3 Result < 0.01 mg/Nm3
 METRIC UNITS

PT SUCOFINDO
Determination of Linier Velocity, Molecullar Mass of Dry Gas and Total Particulate
Client PT. HM SAMPOERNA PLANT SUKOREJO Technician SJD/WY/MMA
Unit DRY ICE EXPANDED TOBACCO (DIET) Start Time 3:30 Standard Temperature
Date of sampling MAY 27,2021 15.00 wib End Time 4:30 25 °C 298 K
Metode SNI 7117.14-2009 (Linier Velocity) Lab No 0
SNI 7117.15-2009 (Molecullar Mass of Dry Gas)
SNI 7117.17-2009(Total Particulate)
STACK DATA EQUIPMENT ESTIMATES FILTERS 298
(%)O₂
% Moisture est: 10 % H2O est METER BOX: Est. Tm: 33.0 °C Main Filter (g) Recovery (g) 760 mm Hg
CORRECTION
Barometric: 758.0 mm Hg Y: 0.9965 Est. Ts: 344.6 °C W1 0.3443 1.4019 REFERENCE
Static Press: 2.0 mm H2O DH@: 47.30 mm H2O Est. dP: 1.4 mm H2O Wo 0.3274 1.4010
Stack Press: 758.1 mm Hg PITOT: Est. Dn: 13.19 mm W1-Wo 0.0169 0.0009 13
%CO2: 10.11 % Cp: 0.84 LEAK CHECKS K FACTOR
%O2: 13.79 % NOZZLE: DGM initial ______ ______ ______ liters
17.04
%N2/CO: 76.10 % Dn: 11.10 mm DGM final ______ ______ ______ liters
Md: 30.17 g/g-mole Diameter Stack 1.48 m Leak Rate ______ ______ ______ lpm Particulate Mass (mg)
Ms: 28.95 g/g-mole Traverse Point 8 Vacuum ______ ______ ______ in. Hg 17.8

Sample Time Pitot Gas Temperatures (°C) Orifice Press. Pump Gas Temps
Sample

Imp Vs
Point

(minutes) Dry Gas Meter Reading (liters) DP DGM DH (mm H20) Vac. (°C) % ISO
(°C) (m/s)
Begin End (mm H2O) Inlet Outlet Stack Ideal Actual (in Hg) Probe Filter sqrt(dP)
A1 0 7.50 118203.00 1.20 33.0 33.0 349 20.2 20.0 3 120 120 19.0 97.5 5.42 1.095
2 7.50 15.00 118305.00 1.40 33.0 33.0 350 23.5 24.0 3 120 120 19.0 102.8 5.86 1.183
3 15.00 22.50 118421.00 1.60 33.0 33.0 351 26.8 28.0 3 120 120 19.0 101.2 6.26 1.265
4 22.50 30.00 118543.00 1.60 33.0 33.0 352 26.8 28.0 3 120 120 19.0 99.6 6.27 1.265
5 30.00 37.50 118663.00 2.60 33.0 33.0 351 43.5 44.0 4 120 120 19.0 101.0 7.99 1.612
6 37.50 45.00 118818.00 2.40 33.0 33.0 344 40.6 42.0 4 120 120 16.0 101.2 7.63 1.549
7 45.00 52.50 118968.00 2.20 33.0 33.0 346 37.1 38.0 4 120 120 16.0 102.3 7.32 1.483
8 52.50 60.00 119113.00 2.40 33.0 33.0 346 40.5 42.0 4 120 121 16.0 100.7 7.64 1.549
9 60.00 119262.00 - - -
10 0.00 - - -
11 0 - - -
12 0 - - -
13 0 - - -
14 0 - - -
15 0 - - -
16 0 - - -
17 0 - - -
18 0 - - -
19 0 - - -
20 0 - - -
21 0 - - -
22 0 - - -
23 0 - - -
24 0 - - -
Final DGM:

Run Time Vm DP (H2O) Tm Ts DH (H2O) Vs

RESULTS

Max. Vac %ISO

60.00 min 1.059 m3 1.93 mm 33.0 °C 348.6 °C 4 33.25 mm 104.3 6.9 m/s
##### #####
Vmstd Stack Area Qsd Qa Concentration Concentration Corr O₂ Emission Rate
3 mg/Nm³
1.0283 Nm 1.719 m² 4.9 m³/s 11.8 m³/s 17.3 mg/Nm³ 19.2 0.303 kg/hr
Test Personnel : Sujud Joko U Supervisor Sri Nugroho

Signature : Signature :

METRIC UNITS
 PT SUCOFINDO
Determination of Water Content

Client : PT. HM SAMPOERNA PLANT SUKOREJO

Unit : DRY ICE EXPANDED TOBACCO (DIET)
Date of sampling : MAY 27,2021 15.00 wib
Technician : SJD/WY/MMA
Lab No : 0
Metode : SNI 7117.16-2009

Impinger No Wo (g) W1 (g) (W1-Wo)

1 613.00 713.00 100.00 g
2 711.00 717.00 6.00 g
3 711.00 716.00 5.00 g
4 601.00 603.00 2.00
5 719.00 721.00 2.00
6 702.00 704.00 2.00
Volume of condensed water vapor 117.00 g
Silica Gel 739.00 742.00
Volume of condensed water vapor in silica gel 3.00 g

Component
Volume of gas sampled through dry gas meter (Vm) 1.059 m³
Dry gas meter (DGM) calibration factor (Y) 0.9965
DGM temperature in Celsius (tm) 33.0 °C
DGM temperature in Kelvin (Tm) 306.0 K
Temperature Standard (Tstd) 298.0 K
DGM orifice pressure differential (dH) 33.25 mmH2O
Barometric pressure actual (Pbar) 758.0 mmHg
Barometric pressure standard (Pstd) 760 mmHg
Gas Ideal a Constant (R) 0.06236 mmHg.m³/g-mol.K
Weight Molecular of Water M 18 g/mol

Component
Volume of dry gas sampled convert to STD Condition Vm(std) 1.0283 Nm³
Volume of condensed water vapor convert to STD Condition Vwc(std) 0.16 Nm³
Volume of condensed water vapor in silica gel convert to STD Condition Vwsg(std) 0.00408 Nm³
Mole Fraction of water vapor condensed Bws 0.137 (v/v)
Water Content %H2O 13.7 %(v/v)
 PT SUCOFINDO
Specification of Stack

Client : PT. HM SAMPOERNA PLANT SUKOREJO

Unit : DRY ICE EXPANDED TOBACCO (DIET)
Date of sampling : MAY 27,2021 15.00 wib
Technician : SJD/WY/MMA
Type of stack : CIRCULAR
Fuel : LNG
Number of sampling hole : 1
Engine Capacity : -
Diameter of stack (m) : 1.48
Height of stack (m) : 15 m
Upstream (B) : 11.8 m
Downstream (A) : 2.96
Number of traverse point : 8
o
Coordinate S 07 41' 57.3995"
o
E 112 41' 35.0639"