SOLUTIONS PAPER-2(PCB) CODE-BA (UPSEE 2017)

PHYSICS
Sol.1. (C) ray will be still totally internally reflected at interface.
1
 n2 
As n2 decreases , i C
 sin   also decreases, so condition i  iC is still satisfied and there
 n1 
will be still total internal reflection at interface. If angle of incidence is increased then ray will be
still totally internally reflected at interface because i  iC .
Sol.2. (B) 2eV
KEmax  h max    3  1  2eV
Sol.3. (C) 100 cm
A B C D

F F

30 20 30 10
10

AD=30+10+20+30+10=100cm
Sol.4. (B) conduction
As atoms in the spoon vibrates about their equilibrium positions and transfer energy from one end
to other end. This process is conduction.
Sol.5. (B) along +y axis dq dE
P
dq

Consider any two symmetric dipole elements, net contribution due to these elements at point P is
along +y axis . Similarly by principle of superposition we can say that net electric field at P is
directed along +y axis.
Sol.6. (D) 8 kR 2
KEi  PEi  KE f  PE f
1 2 1 2
 0 k  OA  R   KE f  k OB  R 
2 2
1 2 1 2
 k 5 R  R   KE f  k  R  R 
2 2
2
 KE f  8kR
Sol.7. (B) 9 J
1 1 (3)(6) 2
U  Ceq V 2   3  9J
2 2 (3  6)
Sol.8. (A) experiences a force directed along the radial direction only.
Circular motion is a special case in gravitational field. There may be straight line,elliptical paths,
but force will be always directed toward the centre of the sphere.
Sol.9. (C) speed is maximum at t=4s.
t 3 t  0, 2, 4 t 1
x  A x0 x  A
v 0 vmax v 0
mg
Sol.10. (A)
k
kx kx F.B.D. of lower rod
kx kx
T2  2mg
kx  kx  2mg
mg
x
k
T2  2mg
T1  mg T1  mg

Sol.11. (C) 9
We consider two possible cases:
Case  I Case  II

nC
5
nB nB
4 4
nA
5 nA
nC
nC  nA  4  5  9
nA  nC  1
Sol.12. (A) 0.6 m / s
By momentum conservation
(10  103 )1000  (10  103 )  400  10v
 v  0.6m / s
Sol.13. (B) AP  AQ
Q
P
N
O
A Q P

For complimentary angles range ON is same for P and Q as points O and N are on same
horizontal plane. From figure AP  AQ
Sol.14. (D) 60 Hz
Second overtone n=3  f3  3f0  60Hz
Sol.15. (B) 4m / s 2
2 d2x 2
x  slope (t )  2t  2  4
dt
Sol.16. (C) 1s
In one time constant 63% change occurs in the value of current .The 63% of maximum current is
1.26 A .It is obvious from graph that current 1.26A corresponds to time which is slightly greater
than 0.9sec. Hence option having 1s is most appropriate.
Sol.17. (C) zero
a
b

At the position of smaller loop, Magnetic field due to larger loop is parallel to plane of smaller
loop. Due to larger loop, magnetic flux linked with smaller loop is zero. Hence mutual induction
is zero.
1  Mi2  0  Mi2  M  0
Sol.18. (D) 3 m / s
1 1
Impulse during t=2 to t=4 is  3  2  5    4  3  5   0
2 2
Impulse =change in momentum
mv f  mvi  0  v f  vi  3  speed  3
Sol.19. (D) 10
8

5 1

     
aQ  ˆi ,aP  5ˆi  8 ˆj  arel  aP  aQ  6ˆi  8 ˆj , arel  10
Sol.20. (A) pressure of 85cm of Hg
Pgas  Patm  P  76cm of Hg  9cm of Hg  85cm of Hg
Sol.21. (C) work done by gas is negative
PV
Volume does not remain constant throughout the process AB . As T  ,temperature
nRT
decreases initially as both P and V decreases .By area under curve ,net work done is negative.
P A

 
   
B
V
2 3
Sol.22. (A) 20 kgm s
dKE  
 Pall  F.v  ma.v  100 103   20ˆi  10 ˆj  .10ˆi  20
dt
Sol.23. (C) It remains stationary
Maximum possible friction force F frictionMax.   0.5 2 g  10 N
Maximum applied force Fapplied Max.  8 1  8 N
F F
applied Max. frictionMax. so the block will remain stationary
Sol.24. (A) 84kPa
 V  6 0.004
p  B    2100  10   84 kPa
 V  100

2
m2 R 2
Sol.25. (D) m1R 
3
2 2
 AC  2R  R2
I  I ABC  I AOC   mi R 2  m2  R 2  mi  m2  m1 R 2  m2
12 12 3
Sol.26. (A) dark
Path difference   13.5  13  12     n  12  
   
So there will be minima.
Sol.27. (A) It will be clockwise
As collision is elastic ,so after collision ball moves towards left with speed v .As walls and
ground are smooth ,there is no tangential torque on the ball. Only normal forces and mg force
pass through the centre of the ball ,so their torques about the centre are zero. Torques on the ball
about its centre is zero . By   I  ,angular acceleration is zero hence angular velocity does not
change.
Sol.28. (A) electron
mv
R v ,q and B are same so Rm
qB
Mass of electron is minimum for given options.
Sol.29. (C) 8 Nm
1
  iAB sin 90 o  2   2  2  2  8 Nm
2
2
Sol.30. (A) 84 m
Result should have only two significant numbers (same as 12m).
Sol.31. (C) 27 C 18V

i
6F
6

3F 6

18
i  1 .5 A and V2  R2i  6  1.5  9V ; q2   3  9  27C
66
x
Sol.32. (B)
0 t
Initially velocity is constant ,so slope of x-t graph is constant and finite .Finally velocity becomes
zero hence slope of x-t graph becomes zero.
Sol.33(C) 20m 3
mg   airVg  26 g  1.3Vg  V  20m 3
Sol.34. (D) 5
3

0V R

2

Since equivalent internal resistance of equivalent cell across the external resistor R is 2  3  5
,Hence power delivered to R will be maximum if R  5 
1
Sol.35. (A)
4
l l RA 1 VA R A I 1
RA  2
,RB  2
    
  2R    R RB 4 VB RB I 4
Sol.36. (A) Al
Sol.37. (A) 7 kgm2s1
L  2  2  2 sin 90o  3  3  3 sin 0o  1 1 1sin 90o  8  1  7
2V 2
Sol.38. (A)
3R
2 2
V V V 2 2V 2
P   
Req R  R 3R 3R
2 2
Sol.39. (C) A  0, B  1, C  0
A0 1 F 1
B 1

C 0 1

Sol.40. (D) remains same

I0 Intensity of unpolarised light
Intensity after passing through polaroid A is IA  
2 2
2
Intensity after passing through polaroid B is I B  I A cos 
Here  is the angle between pass axes of A and B .Here their pass(transmission) axes always
I0
remain parallel to each other i.e.   0 .  IB  IA   constant. Hence during the rotation,
2
intensity of transmitted light through polaroid B remains same.
Sol.41. (B) 4 days
8000  4000  2000  1000
4days 4days 4days
T1/2  4days
Sol.42. (B) 1035 A o
12420 12420 12420
    1035 A o
E E 2  E1 4  (16)
Sol.43. (D) 2V
In reverse bias ,it is equivalent to open circuit condition. From figure given below
VAB  2V 2V
A B

100

Sol.44. (B) greater than P but less than 16P

P  T4 ,P  T4 HereT  273  50 ,T  273  100  T  T  2T
4
P  273  100  P 4
  1   2
P  273  50  P
Sol.45. (D) It is not possible
It is not possible, because it will violate the second law of thermodynamics (Clausius statement)
.If we consider imaginary case in which temperature of sample becomes more than 600K then it
will radiated power is more than absorbed power. Hence it will correspond to decreasing
temperature situation. So it is not possible to heat the sample to 900K.
k p
Sol.46. (C)
r2
kpcos 900
r2

A r
kpcos p kpcos 0
r2 r2

k p cos  k p
VA   2
r2 r

Sol.47. (C)
b  a  
2 2

R
   
  B1 .A1  B2 .A 2  Bb 2 cos 0o  Ba 2 cos 180o  B  b 2  a 2    b 2  a 2  t
d
dt  b  a  
2 2

i  
R R R
 F
Sol.48. (C)
MR
F sin 30O

O
F cos 30O 30
120O
C

MR 2 F
  I  F sin 300 R  
2 MR
Sol.49. (C) acceleration may be zero at t=2
Let us consider an example in which particle is projected vertically upward from ground at t=0
and it reaches highest point at t=2.
Then at that instant(t=2) velocity v=0 but acceleration=−g. Here displacement is non zero for the
duration t=0 to t=2. For t>2 the ball again acquires velocity. In this example options(A),(B) and
(D) are incorrect.
Let us consider another example in which a particle is moving on horizontal plane and it comes to
rest permanently at t=1 ,then this is the one of the special case in which acceleration of particle is
zero at t=2.
Sol.50. (C)  4ˆi  2ˆj m / s
v  1 v 0
e   separation    y  vy  2
 vapproach  y 2 40

vx remains same,Hence v final  4iˆ  2jˆ

 CHEMISTRY
Sol.51. (A) [Co(CO)4 ] and Ni(CO)4
[Co(CO)4 ] has total electrons =3+2×4+1=12,
Ni(CO)4 has total electrons =4+2×4=12 ;Thus isoelectronic
Sol.52(B) (i), (ii) & (iv)
XeF6 has distortion and become Pentagonal bipyramid with one lone pair.
F
O Cl
F
F O O
Xe Cl Cl
I
F F Sb
O  O Cl
F Cl
XeF6 O 
IO 56
Cl 5  6  7   1  48
Orthoperiiodate  5   Octahedral
Octahedral
7  6  6   5  48 electrons
Octahedral

SnCl62   4  6(7)  2  48
6 set of electrons  octahedral
Sol.53. (B) H2S < NH3 < H2O < HF
Sol.54. (D) BF3
BF3 can form π bond also in addition to σ bond. As F is more electronegative and octate in B
is not complete.
Sol.55. (D) H2O
H2O will act as Brönsted acid as provided H+ ion.
Sol.56. (B) 0.354 gm
pOH  pK b  log
 NH 4Cl   pOH   log K  log  NH 4Cl   pOH  log  NH 4Cl 
b
 NH 3   NH 3   NH 3  Kb
 14  9.45  log
 NH 4Cl   log 3  0.47
 NH 3  Kb
 log1014  (log109  log3)  log
 NH 4Cl   log
1014
 log
 NH4Cl   1014   NH 4Cl 
 NH3  Kb 109  3  NH3  Kb 109  3  NH 3  Kb
1014 1014
 9  3 b  4 
NH K  NH Cl  9
 0.011.85 105   NH 4Cl   0.35
10  3 10  3
2 Kp
Sol.57. (D)
1 2 K p
2 HI ( g )  H 2 ( g )  I 2 ( g )
At eq.2(1  x ) x x
Total moles at equilibrium =2-2x+x+x=2 ,here x= degree of dissociation
  x  x  2
   P x2 x 2 Kp
2 2
K p     2  2
 2 Kp  x
4 1  x  P 2 4 1  x  1 x 1 2 K p
4
Sol.58. (C) 171
6g 60
A 6% solution of sucrose C22H22O11 conc.=  0.06ml 1  molel 1
100 ml 342
30
For unknown solution conc.= 3 g per 100cc  30 gl 1  mole l 1
m
60 30 30  342
For isotropic solution  m  171
342 m 60
Sol.59. (D) 491 kJ
CH 3COOH  2O2  2CO2  2 H 2O
869  2   395   2   285    f H ( CH 3COOH )
Simplification gives
2  434.5  2   395   2   285    S H (CH 3COOH )
1
or  434.5   395    285    f H  491   f H
2
Sol.60. (B) Sulphur
Sol.61. (A) Cathode is Lead dioxide (PbO2) and anode is Lead (Pb)
Sol.62. (D) ( ∆Ssystem+ ∆S surrounding ) > 0
Sol.63. (A) PVm=RT
At low pressure & high pressure V is very high ,thus a2 and b are negligible, finally reduced
Vm
eq. PVm=RT
Sol.64. (D)
t 3/4

 A 0
If t1/2 vs. A0 is constant ,it is radioactive decay hence is not of zero order. Thus answer
will be
t 3/ 4

 A 0

Sol.65. (C) Hexane

Sol.66. (A) 5  1010 gm
Let W be the weight of Ra 238 in equilibrium as
Th232 t1/2Th 1 N0 / 232 1.4 1010
   ; N 0  AvagardoNo
Ra 238 t1/2 Ra W  N0 / 238 7
238
W 9
 5  1010 gm
232  2  10
 1
Sol.67. (B) n=4, l=0, m=0, s=+
2
For option (A) electron is in 3d
For option (B) electron is in 4s
For option (C) electron is in 4p
For option (D) electron is in 5s
1
According to Aufbau principle 4s<3d<4p<5s. Hence Answer will be n=4,l=0, m=0,s=+
2
Sol.68. (A) 4, 6

Sol.69. (C) COOH COOH

Terlhalic acid.
Sol.70. (B) cis-1, 3-dimethylcyclohexane



Two chiral centre of plane of symmetry so it is meso compound.
Sol.71. (C) 2 ethyl-3 methyl pentanal
OH
Sol.72. (A)
 CHCl3  aq. NaOH 

In Reimer-Tieman ,phenol reacts with CHCl3 & aq. KOH/NaOH to give Selicil Aldehyde.
Sol.73. (B) B < S < P < F
I.P. in period increases  left to right.
I.P. in group up to down  decreases.
Sol.74. (B)
20 Carbocation will be more stable than 10
Substituted carbocation will more stable than simple.
Sol.75. (A) Be3N2
Sol.76. (C) Cannizzaro reaction
Sol.77. (C) BN
Sol.78. (C) i > iv > ii > iii
Acidity ∝ 1
basicty
Sol.79. (C) (i),(ii)


Br
(i)

1,2 hydride shift

H 

Br
(ii)
Sol.80. (A) iii < i < iv < ii
Acidic strength ∝ electron withdrawing group strength.
1 1 1
R  H  I   
I H R
Sol.81. (A) Only –I effect
Due to SIR effect –NO2 group goes out of plane of the paper (-I).
Sol.82. (C) AgNO3
Sol.83. (A) 6-ethyl-2-methyl-5-propyldecane
CH3
(4)
H CH2 CH2 CH  CH3 
(3) (2) (1)

CH3 CH2 CH2CH2 C(6 ) (5)

C CH2CH2 CH3
(10 ) (9 ) (8) (7)

CH2 CH3 H
Sol.84. (B) D-fructose
CHO CHO CH2 OH
OH 
OH O
OH OH

OH 

 OH 
 

base base OH
OH OH OH
OH OH OH
CH2OH CH2 OH CH2OH
D Manose D Glucose D Fructose
O
Sol.85. (B) Benzoquionone

 NH  Cr O
H SO  4 2

2 4
2 7

Benzoquinone
O
Conjugated diketones
Sol.86. (C) 19 , 
H
H H
H C H
H
H H H
19 and  H
Sol.87. (B) (i) and (iii)
As a plane of symmetry exist in compound(ii),there is no chirality in it. Hence (i) &(iii) will be
optically active.
Sol.88. (A) BCl3 and AlCl3 are both Lewis acids and BCl3 is stronger than AlCl3
BCl3 and AlCl3 both are Lewis acids but BCl3 is more electron deficient than AlCl3 so BCl3 s
stronger Lewis acid than AlCl3 due to high electron negativity.(E.N. B-2.0,Al 1.5)
Sol.89. (C) I, II, IV
O

Compound C CH3 cannot be obtained by Friedel Craft acylation, In ,NO2

NO2

NO2
 Group has -M or –R effect so it cannot be used in Friedel Craft acylation ,this is deactivating &
metadirecting group in ESR.
O
O
C Cl
 H3 C C Cl AlCl
3
NO2
NO2
Sol.90. (A) 4-butyl-1-ethyl-2-methylcycloheptane
Naming according to closest set of locant rule
1
6 7
5 2
4 3

Sol.91. (D) 5-chloro-2-methylcyclohexanol

CH3
3 2 1 OH

4 6
5
Cl

Sol.92. (A) -hydroxyaldehyde

R
R
H or OH   R CH 2 CH 2 C condensation 
CHO
R CH 2  CHO 

Dilute OH
 H 2O
 R CH 2 CH C CHO
H
Aldoladdition
 ,  unsaturated aldehyde
In aldol addition it is β hydroxyl aldehyde(aldol both alcohol and aldehyde group) But in aldol
condensation the product is α,β unsaturated aldehyde
O 2N
Sol.93. (D)

OH
O 2N
NO2
O 2N
NO 2 OH
OH OH
Highest dipole moment
Sol.94. (A) 4
Grignard reagent will react on CO bond there are four C-O bond .These will be addition of
Grignard reagent at four positions.
HO COOEt
2mol total  4mol
O
1mol
1mol
Sol.95. (A) KO2
KO2  K   O2  17 e in valance cellso unpaired electron present &show paramagmetism
SiO2  Si4  2O2  Diamagnetic
2s2 2 p6 2s 2 2 p6
TiO2  Ti4  2O2  Diamagnetic
3d 0 2s 2 2 p6
BaO2  Ba2  2O2  Diamagnetic
XeConfiguration NeConfiguration
Sol.96. (C) CH 3
Nucleophilicity order

CH 3  NH 2  OH   F
Sol.97. (D) For lead +2, for tin +4
PbO 2 + Pb    2PbO,   ΔG 0 < 0
i.e. ΔG0 is negative so reaction is fisiable i.e. for Pb,+2 Oxidation state is more stable.
SnO 2 + Sn     2SnO,   ΔG 0 > 0
i.e. ΔG0 is positive so reaction is nonfisiable i.e. for Sn,+4 Oxidation state is more stable.
Correct answer is (D) For lead +2, for tin +4
For lead +2, for tin +4 Oxidation State are more characteristics.
Sol.98. (A) 1-Phenyl-2-butane
(i) Ph  CH 2  CH  CH  CH 3 Geometrical isomerism.
CH 2  CH  CH  CH3
(ii) Ph No Geometrical isomerism

CH 2  C  CH 2  CH3
(iii) Ph
No Geometrical isomerism

Ph
(iv) C  CH  CH3 No Geometrical isomerism
Ph
Sol.99. (C) associate
At CMC they associate.

Sol.100. (B) CH3 O CHO

CH3 O CHO will be most reactive.

Hence most appropriate option is CH3 O CHO

 BIOLOGY
Sol.101: (C) Colloidal suspensions
Sol.102: (A) Thermaregulation
Sol.103: (C)Oriental cockroach
Sol.104: (B) Monera ,Protista ,Fungi, Plantae and Animalia
Sol.105: (C) Orchid
Sol.106: (D)Drupe
Sol.107: (C) Endodermis
Sol.108: (B) Nucleoside
Sol.109: (B) Lamellae
Sol.110: (D) Extra chromosomal DNA segment
Sol.111: (B) Foot
Sol.112: (C) Cycas rachis
Sol.113: (C) Haploid Sparophyte
Sol.114: (A) Total stem parasite
Sol.115: (B) Guttation
Sol.116: (A) RNA molecule
Sol.117: (C) Red
Sol.118: (C) Physical Process
Sol.119: (B) Gibberellin
Sol.120: (C) Removal of anthers
Sol.121: (C) Opening of flower
Sol.122: (B) Gamete
Sol.123: (A) Mutation
Sol.124: (B) Zygoti intra fallopian transfer
Sol.125: (B) Nutrition
Sol.126: (A) Cretaceous
Sol.127: (A) Colon
Sol.128: (D) Carpora allata
Sol.129: (D) Liver
Sol.130: (D) Spleen
Sol.131: (B) Glycoprotein
Sol.132: (A) All vertebrates
Sol.133: (B) Seed coat colour
Sol.134: (D) Cuticle
Sol.135: (B) Helper T lymphocytes
Sol.136: (D) all of the options
Sol.137: (C) Placenta and fully developed foetus
Sol.138: (B) Leishmania donovani
Sol.139: (B) Fats
Sol.140: (D) no eyes
Sol.141: (C) Bombyx
Sol.142: (C) G1, S , G2 and M
Sol.143: (C) Excretion
Sol.144: (D) Cryopresevation
Sol.145: (A) Epidermis of root
Sol.146: (B) Typoid fever
Sol.147: (B) Ventral Nerve cord
Sol.148: (D) Fungi
Sol.149: (D) Sporophyll
Sol.150: (C) Bentham and Hooker