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MATERIAL SAFETY DATA SHEET

Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
1. PRODUCT AND COMPANY

TRADE NAME SOOTREMOVER


APPLICATION Other cleaning products

PRODUCT-NO 650 571240 (25 kg)

Producer/Importer UNITOR CHEMICALS, Kjemi-Service AS


Address P.O.Box 49
Zipcode & City 3163 Borgheim
Country Norway
Telephone + 47 33 35 15 00
Fax + 47 33 35 15 05
Issued by Leen de Visser (+31 6 538 63736)
Emergency number Int. +44 1865 407333

Int. +1 703 5273887


USA (800) 424-9300
Greece Int. +30 1 7793777

2. COMPOSITION OF PRODUCT
No Ingredients name CAS-NO Conc.(weight%) Classification
1 Copper chloride 7447-39-4 5 - 10 Xn,22
2 Copper hydroxide chloride 12069-68-1 5 - 10 T,25-36/38
3 Components which do not contribute to the classification of the 60 - 90
product.

Legend T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising,
F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment, Mut=Genetoxic,
Sens=Sensitizing, Carc=Carcinogen, Repr=Causes birth defects

3. HAZARD IDENTIFICATION

Harmful
Powder.Green.Partly soluble
Harmful if swallowed.
Irritating to eyes and respiratory system.

4. FIRST AID
GENERAL
Seek medical attention if any signs of unconsciousness or discomfort develop.Show this safety data sheet to the
physician present.
INHALATION
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MATERIAL SAFETY DATA SHEET
Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
Low inhalation risk.General first aid; provide fresh air, keep the patient warm and at rest.Get medical advice if discomfort
develops.
SKIN CONTACT
Wash skin thoroughly with soap and water for several minutes.Get medical attention if irritation persists after
washing.Remove contaminated clothing immediately.
EYE CONTACT
Flush with large amounts of water for at least 10 minutes.Keep eye wide open while flushing.Get medical advice.
INGESTION
Never give anything to drink and never try to induce vomiting if the patient is not fully conscious.Give plenty of water or
milk to drink.Get medical advice immediately.

5. FIRE FIGHTING MEASURES


PROPER FIREFIGHTING EQUIPMENT
Use extinguishing media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARDS
Non-flammable.
OTHER INFORMATION
Prevent release of fire control water to surface water or ground water.

6. ACCIDENTAL RELEASE MEASURES


SAFETY MEASURES TO PROTECT PERSONS
Use personal protective equipment as specified in section 8.
SAFETY MEASURES TO PROTECT THE ENVIRONMENT
No special environmental precautions required
PROPER METHODS FOR DAMAGE LIMITATION AND CLEANUP
Sweep up and empty into suitable containers for disposal.Flush with large amounts of water to clean the area.

7. HANDLING AND STORAGE


HANDLING ADVICE
Use personal protective equipment as specified in section 8.Avoid contact with skin and eyes.Eyewash facilities should
be available at the workplace.
STORAGE
S-3/9/49 Keep only in the original container in a cool, well ventilated place.

8. EXPOSURE CONTROL AND PERSONAL PROTECTION

Ingredients name CAS-no TLV value TLV Year


Copper chloride 7447-39-4 0.0
Copper hydroxide chloride 12069-68-1 0.0

EXPOSURE CONTROL
No information on exposure limits for the ingredient
RESP. PROTECTION
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MATERIAL SAFETY DATA SHEET
Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
Normally not necessary in ordinary use.
Wear particulate respirator if there is dust formation.
EYE PROTECTION
Wear dust-proof goggles if dust formation is possible.
HAND PROTECTION
Use protective gloves of impervious material, e.g. rubber/plastic.
SKIN PROTECTION
Protective clothing should be worn if there is a possibility of direct contact or splashes.

9. PHYSICAL AND CHEMICAL PROPERTIES


Form Hygroscopic powder.
Colour Green.
Odour Odourless.
Solubility Partly soluble
Melting point/range N/E Density 1.2 @ 20 ºC
Expl. limit LEL-UEL., %-%: N/A Solubility in water ~10 %
Vapor pressure N/E Saturation conc. N/A
Decomposition temp. N/A Rel. density sat. air (air=1) N/A
pH Solution 6 (1%) Boiling point/range N/E
Flash point N/A pH concentrate: N/A
Molecular weight N/A Viscosity N/A
Auto Ignition temp. N/A Smelling limits lo-hi N/A
Rel. vapor density (air=1) N/A Rel. evap. velocity N/A
Air reactive - Water reactive -

OTHER INFORMATION
N/A = Not applicable.
N/E = Not established.

10. STABILITY AND REACTIVITY


STABILITY
Stable under normal conditions.
MATERIALS TO AVOID
Aluminium.
Zinc
Copper.
Tin
HAZARDOUS DECOMPOSITION PRODUCTS
No decomposition if stored and used as directed.
OTHER INFORMATION
Avoid intense heating.

11. TOXICOLOGICAL INFORMATION


OTHER TOX. INFORMATION
Normal use of the product is expected to be of low health hazard.
GENERAL
Repeated or prolonged exposure may cause irritation to eyes and skin.
INHALATION
Dust may irritate respiratory tract and lungs.
SKIN CONTACT

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MATERIAL SAFETY DATA SHEET
Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
Irritating to skin.
EYE CONTACT
Dust particles in the eyes cause irritation and smarting.
INGESTION
Ingestion of small amounts will normally not cause any complications.
CANCER
Carcinogenic properties are not known.

12. ECOLOGICAL INFORMATION


MOBILITY
Dissolves in water .
BREAKDOWN
Not relevant.
ACCUMULATION
Does not bioaccumulate.
ECOTOXITY
No ecological effects are expected in normal use.Copper ions are toxic to fish, bacteria, algae and protozoans at
concentrations below 1 mg/litre. Fish (C.auratus): Toxic at 0.01 mg/litre. Mussels: Lethal at 0.55 mg/litre / 12 hours.
Oysters: Toxic at 0.1 mg/litre.Sodium chloride will dissolve into components which are natural in seawater if discharged.

13. DISPOSAL

S-35 This material and its container must be disposed of in a safe way.S-35 In accordance with local and national
regulations.

14. TRANSPORT INFORMATION

GENERAL
Goods classified for transport : YES
UN-no: : 3288
PROPER SHIPPING NAME : Toxic solid, inorganic, n.o.s. (Copper chloride, copper hydroxide
carbonate)
Flash point : N/A
Packing group : III

Label information:

ADR
Class : 6.1
Item. : 65c
Haz. id. no. : 60
ERI-Card : 6-03
TREM-Card : 61G64bc
Labeltype : 6.1

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MATERIAL SAFETY DATA SHEET
Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
Labelcolour : White./Black.

IMDG-CODE
Class : 6.1
Subsidiary risk : -
Marine pollutant : no
EMS : 6.1-04
MFAG : 150
Page Number : 6270-6
Labeltype : 6.1
Labelcolour : White./Black.

IATA-DGR
Class : 6.1
Subsidiary risk : -
Labeltype : 6.1
Labelcolour : White./Black.
Aircraft Cat. : Passenger & Cargo aircraft

US DOT
Class : 6.1
Marine pollutant : NO
RQ : N/E
Labeltype : 6.1
Labelcolour : White./Black.

15. REGULATORY INFORMATION

Classification

Harmful

COMPOSITION
Copper chloride (5 - 10), Copper hydroxide chloride (5 - 10)

R-PHRASES
R-22 Harmful if swallowed.
S-PHRASES
S-36/39 Wear suitable protective clothing and eye/face protection.
REFERENCES
The product is labelled in accordance with EU directive 88/379.
OTHER INFORMATION
Classified according to European directive on classification of dangerous preparations 90/492/EEC.

16. OTHER INFORMATION

ISSUED: 15/Oct/1999

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MATERIAL SAFETY DATA SHEET
Last changed: 15/Oct/1999 Internal no.: :Rev. LdV-3 Replaces date: 12/Dec/1998

SOOTREMOVER
VENDOR NOTES
The safety data sheet fulfills requirements specified in Directive 93/112/EEC.The safety data sheet has been prepared
on the basis of information given by our suppliers and our present knowledge.Information given is intented to present
guidelines for safe handling, use, processing, storage, transport, disposal and discharge; it is not intended to be a
guarantee or quality specification.The intent of this safety data sheet is to give a description of the product with regard to
safe storage, handling and use.Information given applies only to the product itself, and not in combination with other
products or in any processed form, unless this is specified in the text.We believe that all information in this safety data
sheet (which replaces all previous versions) was correct at the date of issue.It is the responsibility of the recipient of
this safety data sheet to ensure that information given here is read and understood by all who use, handle, dispose of or
in any way come in contact with the product.

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