Name: Shivam Maheshchandra

Student id:300210268
Assignment-1
CHG8132

For Component A
Applicability for Langmuir isotherm
Part -A
For Component, A Data as Shown in Below table

P (kPa) NA (mmole/g) = V P/nA (kPa.g/mmole)

0 0 -
10 0.14 71.42857
20 0.24 83.33333
35 0.34 102.9412
44 0.39 112.8205
55 0.43 127.907
61 0.46 132.6087
70 0.49 142.8571
85 0.52 163.4615
100 0.54 185.1852
 P/Na (kPa.g/mmole) Vs. P (kPa)
200
180
f(x) = 1.24290139557827 x + 58.43894034174
160
140
P/nA(kPa.g/mmole)

120
100
80
60
40
20
0
0 20 40 60 80 100 120
P (kPa)

BP
Langmuir isotherm general equation: θ=
1+ BP
V
Where θ = Vm

v BP
Thus =
vm 1+ BP
p 1 p
After rearranging this equation = +
v vm× B vm
1 1
Where is eqaual to intercept and is equal to slope
vm× B vm
After Plot Graph Between P/Na (kPa.g/mmole) Vs. P (kPa) we get Intercept value and slope.
Intercept=58.439

Slope=1.2429

In this graph nA is equal to V

1
From graph slope is equal to 1.2429 which is value of
Vm
Vm=0.8046 mmole/g
1
= 58.439 after put value of Vm in this equation we get Value of B
vm× B
 1
=58.439
0.8046 × B
1
B=
0.8046 ×58.439
B = 0.0212
v 0.14
θ= = =0.1740 ( For p 10 kPa )
vm 0.8046
v 0.54
θ= = =0.6711 ( For p 100 kPa )
vm 0.8046

The graph gives a liner line which means that this model is perfect for
Langmuir isotherm.
Also θ Value is in range of 0 To 1 is also the reason.

Part B
Graph of n Vs. P

Na Vs P
0.6

0.5

0.4
nA (mmole/g)

0.3

0.2

0.1

0
0 20 40 60 80 100 120
P (kPa)

p 1 p
Langmuir isotherm general equation = +
v vm× B vm
1 1
We have value of intercept vm× B and Slope vm so for if we put value of P at
different point for example P = 2 kPa
 p 1 p
= +
v vm× B vm
2
=58.439+2 ×1.2429
v

We get value of V = 0.03282 mmol/g

Likewise, for different 100 values
P (kPa) V (mmol/g) P (kPa) V (mmol/g) P (kPa) V (mmol/g) P (kPa) V (mmol/g)
0 0 26 0.286487 51 0.418627 76 0.497059
1 0.016755 27 0.293487 52 0.422524 77 0.499538
2 0.032827 28 0.3003 53 0.426344 78 0.501978
3 0.048257 29 0.306933 54 0.430088 79 0.504379
4 0.063081 30 0.313394 55 0.433759 80 0.506743
5 0.077335 31 0.31969 56 0.437359 81 0.509069
6 0.091052 32 0.325826 57 0.440889 82 0.51136
7 0.104261 33 0.331809 58 0.444352 83 0.513615
8 0.11699 34 0.337645 59 0.44775 84 0.515836
9 0.129264 35 0.343338 60 0.451084 85 0.518023
10 0.141107 36 0.348893 61 0.454356 86 0.520177
11 0.152543 37 0.354317 62 0.457569 87 0.522299
12 0.163591 38 0.359613 63 0.460723 88 0.524389
13 0.17427 39 0.364786 64 0.46382 89 0.526449
14 0.1846 40 0.36984 65 0.466862 90 0.528479
15 0.194597 41 0.374779 66 0.46985 91 0.53048
16 0.204276 42 0.379607 67 0.472786 92 0.532451
17 0.213653 43 0.384328 68 0.47567 93 0.534395
18 0.222741 44 0.388945 69 0.478505 94 0.536311
19 0.231555 45 0.393462 70 0.481292 95 0.538199
20 0.240105 46 0.397881 71 0.484031 96 0.540062
21 0.248403 47 0.402207 72 0.486724 97 0.541899
22 0.256462 48 0.406441 73 0.489372 98 0.54371
23 0.26429 49 0.410588 74 0.491977 99 0.545496
24 0.271897 50 0.414649 75 0.494539 100 0.547259
25 0.279294
Comparing Original Plot with Different 100 Pressure values

0.6 Na (mmol/g) Vs. P(kPa)

0.5

0.4
nA (mmol/g)

0.3 Langmuir at 100 points

Original Plot

0.2

0.1

0
0 20 40 60 80 100 120
P (kPa)

This graph clearly indicates that original data matches with different 100
pressure values for Langmuir isotherm.
So, Langmuir model is applicable for this set of data.
Applicability for BET isotherm

For Component, A Data as Shown in Below table

P (kPa) NA (mmole/g) = V P/V(P0-P) P/P0

0 0 - 0
10 0.14 0.510204 0.066667
20 0.24 0.641026 0.133333
35 0.34 0.895141 0.233333
44 0.39 1.064344 0.293333
55 0.43 1.346389 0.366667
61 0.46 1.489985 0.406667
70 0.49 1.785714 0.466667
85 0.52 2.514793 0.566667
100 0.54 3.703704 0.666667

𝑃/( 𝑉 ×( 𝑃𝑜 −𝑃) ) Vs. P/P0

4

3.5

3
f(x) = 4.89215010913239 x − 0.189286670990438
2.5
𝑃/( 𝑉×(𝑃𝑜−𝑃) )

1.5

0.5

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
P/P0

P 1 ( C−1 ) × P
BET isotherm general equation: = + (eq….01)
V × ( Po−P ) Vm ×C Vm ×C × Po
1 ( C−1 )
Where is equal to intercept and is equal to Slope
Vm ×C Vm ×C
In this graph nA is equal to V
 P P
After Plot Graph Between Vs. we get Intercept value and slope.
V × ( Po−P ) Po
Intercept= (-0.1893)

Slope=4.8922

( C−1 )
From graph slope is equal to 4.8922 which is value of (eq…02)
Vm ×C
1
Intercept is equal to (-0.1893) which is value of
Vm ×C
Form this we get value of Vm ×C
1
= (−0.1893 ) (eq…03)
Vm ×C

So, value of Vm ×C=(−5.2826 )

( C−1 )
Put value of Vm x C in equation 02 we get value of C
Vm ×C

( C−1 )
=4.8922
Vm ×C

( C−1 )
=4.8922
(−5.2826 )

( C−1 )=(−25.8435 )
So, C = (-24.8435) after putting this value in eq 03 we get value of Vm
1
= (−0.1893 )
Vm ×C

1
=(−0.1893 )
Vm × (−25.8435 )
Vm = 0.2044 mmol/g
 This Graph clearly shows that no linear line. Although it gets negative intercept value
P
So that for surface area determination range of P/P0 is 0.05 ≤ ≤ 0.3 for that range.
P0

𝑃/(𝑉 ×( 𝑃𝑜 −𝑃) ) Vs. P/P0

1.2

1 f(x) = 2.45747091474827 x + 0.331238162535101

0.8
𝑃/( 𝑉×(𝑃𝑜−𝑃) )

0.6

0.4

0.2

0
0.05 0.1 0.15 0.2 0.25 0.3 0.35
P./P0

P P
After Plot Graph Between Vs. we get Intercept value and slope.
V × ( Po−P ) Po
Intercept = 0.3312

Slope =2.4575

( C−1 )
From graph slope is equal to 4.8922 which is value of (eq…02)
Vm ×C
1
Intercept is equal to (0.3312) which is value of
Vm ×C
Form this we get value of Vm ×C
1
= ( 0.3312 ) (eq…04)
Vm ×C

So, value of Vm ×C=( 3.0193 )

( C−1 )
Put value of Vm x C in equation 02 we get value of C
Vm ×C
 ( C−1 )
=2.4575
Vm ×C

( C−1 )
=2.4575
( 3.0193 )

( C−1 )=( 7.4199 )

So, C = (8.4199) after putting this value in eq 04 we get value of Vm
1
= ( 0.3312 )
Vm ×C

1
=( 0.3312 )
Vm × ( 8.4199 )
Vm = 0.3586 mmol/g

Part B
Graph of n Vs. P

Na Vs P
0.6

0.5

0.4

0.3

0.2

0.1

0
0 20 40 60 80 100 120

P 1 ( C−1 ) × P
BET isotherm general equation: = +
V × ( Po−P ) Vm ×C Vm ×C × Po

We have value of intercept and slope so find value of V using these values
 P 1 ( C−1 ) × P
= +
V × ( Po−P ) Vm ×C Vm ×C × Po
P P
=0.3 312+2.4575
V × ( Po−P ) Po

For 4 Kpa
4 4
=0.3 312+2.4575
V × ( 150−4 ) 150

V = 0.069 mmol/g

Likewise, for Different 100 Pressure values data shown in below table

P V P V P V P V
0 0 13 0.174372 25.5 0.273466 38 0.355732
0.5 0.009854 13.5 0.179047 26 0.276924 38.5 0.358946
1 0.019309 14 0.183638 26.5 0.280359 39 0.362162
1.5 0.028392 14.5 0.188149 27 0.283772 39.2 0.363449
2 0.037128 15 0.192584 27.5 0.287166 39.4 0.364736
2.5 0.045543 15.5 0.196947 28 0.290541 39.6 0.366023
3 0.053656 16 0.201241 28.5 0.293899 39.8 0.367312
3.5 0.061488 16.5 0.20547 29 0.29724 40 0.3686
4 0.069057 17 0.209638 29.5 0.300566 40.2 0.369889
4.5 0.076379 17.5 0.213746 30 0.303877 40.4 0.371179
5 0.08347 18 0.217798 30.5 0.307176 40.6 0.37247
5.5 0.090343 18.5 0.221798 31 0.310463 40.8 0.373761
6 0.097012 19 0.225746 31.5 0.313738 41 0.375053
6.5 0.103489 19.5 0.229647 32 0.317004 41.2 0.376346
7 0.109784 20 0.233501 32.5 0.320261 41.4 0.377639
7.5 0.115909 20.5 0.237312 33 0.323509 41.6 0.378934
8 0.121873 21 0.241082 33.5 0.32675 41.8 0.380229
8.5 0.127685 21.5 0.244813 34 0.329985 42 0.381525
9 0.133354 22 0.248506 34.5 0.333214 42.2 0.382823
9.5 0.138886 22.5 0.252164 35 0.336438 42.4 0.384121
10 0.14429 23 0.255788 35.5 0.339659 42.6 0.385421
10.5 0.149573 23.5 0.259381 36 0.342877 42.8 0.386721
11 0.15474 24 0.262943 36.5 0.346092 43 0.388023
11.5 0.159798 24.5 0.266477 37 0.349306 43.2 0.389326
12 0.164753 25 0.269984 37.5 0.352519 43.4 0.390631
12.5 0.169609            
Comparing Original Plot with Different 100 Pressure values

na Vs P
0.45

0.4

0.35

0.3
BET at 100 points in P/P0 Limit
0.25
nA (mmol/g)

Range
Original
0.2

0.15

0.1

0.05

0
0 20 40 60 80 100 120
P (kPa)

This graph clearly indicates that original data Does not matches with
different 100 pressure values for BET isotherm.
So BET model is not applicable for this set of data
Applicability for Freundlich isotherm

For Component, A Data as Shown in Below table

P (kPa) nA (mmol/g) ln P ln V
0 0    
10 0.14 2.302585 -1.96611
20 0.24 2.995732 -1.42712
35 0.34 3.555348 -1.07881
44 0.39 3.78419 -0.94161
55 0.43 4.007333 -0.84397
61 0.46 4.110874 -0.77653
70 0.49 4.248495 -0.71335
85 0.52 4.442651 -0.65393
100 0.54 4.60517 -0.61619

ln V Vs. ln P
0
2 2.5 3 3.5 4 4.5 5

-0.5
f(x) = 0.590977947468718 x − 3.23797929944075

-1
ln V

-1.5

-2

-2.5
ln P

Freundlich isotherm general equation

V =K × P 1/a
Rearrange this equation
 1
lnV ¿ lnk+ lnP
a
1
Where ln k is intercept and is slope
a
After plot graph between ln V Vs. ln P we get value of intercept and slope
Intercept = (-3.238)
Slope = 0.591

1
From equation we get value of =0.591
a
So, value of a=1.692
From equation we get value of lnk=(−3.238)
So, value of k=0.0392

This graph clearly indicates that with linear plot.

Freundlich model is applicable for this set of data

Part B
Graph of n Vs. P
 Na Vs P
0.6

0.5

0.4

0.3
nA

0.2

0.1

0
0 20 40 60 80 100 120
P (kPa)

Freundlich isotherm general equation

V =K × P 1/a
Rearrange this equation
1
lnV ¿ lnk+ lnP
a
1
lnV ¿ lnk+ lnP
a

We have value of intercept and slope so find value of V using these values
For 6 kpa

1
lnV ¿ lnk+ lnP
a
lnV ¿ ¿ ¿)
V=0.1131 mmol/g

Likewise, for 100 different pressure value are shown in below table.

P v P v P v P v
0.26915 0.40080 0.50735
0 0 26 6 51 1 76 9
0.03924 0.27522 0.40542 0.51129
1 2 27 7 52 7 77 4
0.28120 0.41001 0.51520
2 0.05911 28 6 53 7 78 8
 0.07511 0.28709 0.41457 0.51910
3 6 29 9 54 1 79 1
0.08903 0.29290 0.41909 0.52297
4 7 30 9 55 1 80 5
0.10158 0.29864 0.42357 0.52682
5 9 31 1 56 8 81 8
0.11314 0.30429 0.42803 0.53066
6 7 32 7 57 2 82 3
0.12393 0.30988 0.43245 0.53447
7 9 33 2 58 4 83 8
0.13411 0.31539 0.43684 0.53827
8 6 34 8 59 6 84 4
0.14378 0.32084 0.44120 0.54205
9 4 35 8 60 6 85 2
0.15302 0.32623 0.44553 0.54581
10 2 36 4 61 8 86 2
0.16188 0.54955
11 9 37 0.33156 62 0.44984 87 4
0.17043 0.33682 0.45411 0.55327
12 2 38 7 63 4 88 8
0.17868 0.34203 0.55698
13 8 39 7 64 0.45836 89 6
0.18668 0.34719 0.46257 0.56067
14 8 40 4 65 9 90 6
0.19445 0.35229 0.46677 0.56434
15 7 41 8 66 2 91 9
0.20201 0.35735 0.47093 0.56800
16 8 42 1 67 9 92 6
0.20938 0.36235 0.47508 0.57164
17 7 43 5 68 1 93 7
0.21658 0.36731 0.47919 0.57527
18 1 44 2 69 7 94 2
0.22361 0.37222 0.57888
19 3 45 3 70 0.48329 95 1
0.23049 0.37708 0.48735 0.58247
20 6 46 9 71 8 96 4
0.23723 0.38191 0.49140 0.58605
21 9 47 3 72 3 97 3
0.24385 0.38669 0.49542 0.58961
22 2 48 5 73 5 98 6
0.25034 0.39143 0.49942 0.59316
23 3 49 6 74 5 99 4
0.39613 0.50340 0.59669
24 0.25672 50 7 75 3 100 8
0.26298
25 9            
Comparing Original Plot with Different 100 Pressure values

nA Vs. P
0.7

0.6

0.5
nA (mmol/g)

0.4

0.3

0.2

0.1

0
0 20 40 60 80 100 120
P(kPa)

Original Freundlich at 100 points

This graph clearly indicates that original data matches with different 100
pressure values for Freundlich isotherm.
So Freundlich model is applicable for this set of data
For Component B

Applicability for Langmuir isotherm

For Component, B Data as Shown in Below table

P (kPa) nB (mmole/g) = V P/nB (kPa.g/mmole)

0 0  
4 0.05 80
10 0.09 111.1111
25 0.15 166.6667
44 0.21 209.5238
55 0.23 239.1304
61 0.24 254.1667
70 0.26 269.2308
85 0.28 303.5714
100 0.3 333.3333

P/Na (kPa.g/mmole) Vs. P (kPa)

350
f(x) = 2.57284729917915 x + 88.7401717843403
300

250

200
P/nb

150

100

50

0
0 20 40 60 80 100 120
P (kPa)

BP
Langmuir isotherm general equation: θ=
1+ BP
 V
Where θ = Vm

v BP
Thus =
vm 1+ BP
p 1 p
After rearranging this equation = +
v vm× B vm
1 1
Where is eqaual to intercept and is equal to slope
vm× B vm
After Plot Graph Between P/Na (kPa.g/mmole) Vs. P (kPa) we get Intercept value and slope.
Intercept=58.439

Slope=1.2429

In this graph nA is equal to V

1
From graph slope is equal to 2.5728 which is value of
Vm
Vm=0.3887 mmole/g
1
= 58.439 after put value of Vm in this equation we get Value of B
vm× B
1
=88.74
0.3887 × B
1
B=
0.3887 ×88.74
B = 0.029
v 0.05
θ= = =0.1286 ( For p10 kPa )
vm 0.3887
v 0.3
θ= = =0.7718 ( For p 100 kPa )
vm 0.3887

The graph gives a liner line which means that this model is perfect for
Langmuir isotherm.
Also θ Value is in range of 0 To 1 is also the reason.
Part B
Graph of n Vs. P

nB Vs P
0.35

0.3

0.25
nB (mmol/g)

0.2

0.15

0.1

0.05

0
0 20 40 60 80 100 120
P (kPa)

p 1 p
Langmuir isotherm general equation = +
v vm× B vm
1 1
We have value of intercept vm× B and Slope vm so for if we put vaue of P at
different point for example P = 2 kPa
p 1 p
= +
v vm× B vm
2
=88.74+ 2× 2.5728
v

We get value of V = 0.021303 mmol/g

Likewise, for different 100 values
V
(mmol/g Langmui Langmui Langmui
P (kPa) ) P rV P rV P rV
0.23186 0.26734
0 0 26 0.16706 51 8 76 9
0.01095 0.17066 0.23368 0.26843
1 1 27 4 52 1 77 7
0.02130 0.17415 0.23545 0.26950
2 3 28 3 53 3 78 6
0.03110 0.17753 0.23718 0.27055
3 1 29 2 54 4 79 6
0.04039 0.18080 0.23887 0.27158
4 1 30 6 55 7 80 8
0.04921 0.24053 0.27260
5 1 31 0.18398 56 2 81 2
0.05759 0.18705 0.24215 0.27359
6 4 32 8 57 2 82 8
0.06557 0.19004 0.24373 0.27457
7 4 33 6 58 6 83 8
0.07317 0.19294 0.24528 0.27554
8 8 34 6 59 6 84 1
0.08043 0.19576 0.24680 0.27648
9 2 35 3 60 4 85 8
0.08736 0.19849 0.27741
10 1 36 9 61 0.24829 86 9
0.09398 0.24974 0.27833
11 4 37 0.20116 62 5 87 4
0.10032 0.20374 0.27923
12 3 38 6 63 0.25117 88 5
0.10639 0.20626 0.25256 0.28012
13 5 39 3 64 6 89 2
0.11221 0.20871 0.25393 0.28099
14 6 40 2 65 4 90 4
0.11780 0.21109 0.25527 0.28185
15 2 41 6 66 5 91 2
0.12316 0.21341 0.25658 0.28269
16 7 42 7 67 9 92 6
0.12832 0.21567 0.25787 0.28352
17 4 43 9 68 8 93 8
 0.13328 0.21788 0.25914 0.28434
18 4 44 3 69 2 94 6
0.13805 0.22003 0.26038 0.28515
19 8 45 2 70 2 95 2
0.14265 0.22212 0.26159 0.28594
20 7 46 7 71 8 96 5
0.14709 0.22417 0.26279 0.28672
21 1 47 1 72 1 97 6
0.15136 0.22616 0.26396 0.28749
22 8 48 5 73 3 98 6
0.15549 0.22811 0.26511 0.28825
23 5 49 2 74 2 99 4
0.15948 0.23001 0.26624 0.28900
24 2 50 2 75 1 100 1
0.16333
25 5

Comparing Original Plot with Different 100 Pressure values

 Nb (mmol/g) Vs. P(kPa)
0.35

0.3

0.25

0.2
nA (mmol/g)

0.15

0.1

0.05

0
0 20 40 60 80 100 120
P (kPa)
Langmuir at 100 points Original Data

This graph clearly indicates that original data matches with different 100
pressure values for Langmuir isotherm.
So, Langmuir model is applicable for this set of data

Applicability for BET isotherm

For Component, B Data as Shown in Below table

P (kPa) nB (mmole/g) = V P/V(P0-P) P/P0

0 0    
4 0.05 0.481928 0.023529
10 0.09 0.694444 0.058824
25 0.15 1.149425 0.147059
44 0.21 1.662887 0.258824
55 0.23 2.079395 0.323529
61 0.24 2.331804 0.358824
70 0.26 2.692308 0.411765
85 0.28 3.571429 0.5
100 0.3 4.761905 0.588235

𝑃/( 𝑉 ×( 𝑃𝑜 −𝑃) ) Vs. 𝑃/𝑃𝑜

5
4.5
4 f(x) = 6.99359662960156 x + 0.0831675922737163
3.5
3
𝑃/( 𝑉×(𝑃𝑜−𝑃) )

2.5
2
1.5
1
0.5
0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7
𝑃/𝑃𝑜

P 1 ( C−1 ) × P
BET isotherm general equation: = + (eq….01)
V × ( Po−P ) Vm ×C Vm ×C × Po

1 ( C−1 )
Where is equal to intercept and is equal to Slope
Vm ×C Vm ×C

P P
After Plot Graph Between Vs. we get Intercept value and slope.
V × ( Po−P ) Po
Intercept= (0.0832)

Slope=6.9936
 ( C−1 )
From graph slope is equal to 6.9936 which is value of (eq…02)
Vm ×C
1
Intercept is equal to (0.0832) which is value of
Vm ×C
Form this we get value of Vm ×C
1
= ( 0.0832 ) (eq…03)
Vm ×C

So, value of Vm ×C=( 12.0192 )

( C−1 )
Put value of Vm x C in equation 02 we get value of C
Vm ×C

( C−1 )
=6.9936
Vm ×C

( C−1 )
=6.9936
( 12.0192 )

( C−1 )=( 84.0574 )

So, C = (85.0574) after putting this value in eq 03 we get value of Vm
1
= ( 0.0832 )
Vm ×C

1
= ( 0.0832 )
Vm × ( 85.0574 )
Vm = 0.1413

This Graph clearly shows that no linear line. Although it gets negative intercept value
P
So that for surface area determination range of P/P0 is 0.05 ≤ ≤ 0.3 for that range.
P0
 Chart Title
1.8

1.6 f(x) = 4.98731159941644 x + 0.388425818554946

1.4

1.2

0.8

0.6

0.4

0.2

0
0 0.05 0.1 0.15 0.2 0.25 0.3

P P
After Plot Graph Between Vs. we get Intercept value and slope.
V × ( Po−P ) Po
Intercept = 0.3884

Slope =4.9873

( C−1 )
From graph slope is equal to 4.9873 which is value of (eq…02)
Vm ×C
1
Intercept is equal to (0.3884) which is value of
Vm ×C
Form this we get value of Vm ×C
1
= ( 0.3884 ) (eq…03)
Vm ×C

So, value of Vm ×C=( 2.5747 )

( C−1 )
Put value of Vm x C in equation 02 we get value of C
Vm ×C

( C−1 )
=4.9873
Vm ×C
 ( C−1 )
=4.9873
( 2.5474 )

( C−1 )=( 12.7046 )

So, C = (13.7046) after putting this value in eq 03 we get value of Vm
1
= ( 0.3884 )
Vm ×C

1
=( 0.3884 )
Vm × ( 13.7046 )
Vm = 0.1879 mmol/g

Part B
Graph of n Vs. P

nB Vs P
0.35

0.3

0.25
nB (mmol/g)

0.2

0.15

0.1

0.05

0
0 20 40 60 80 100 120
P (kPa)

P 1 ( C−1 ) × P
BET isotherm general equation: = +
V × ( Po−P ) Vm ×C Vm ×C × Po

We have value of intercept and slope so find value of V using these values
P 1 ( C−1 ) × P
= +
V × ( Po−P ) Vm ×C Vm ×C × Po
P P
=0.3884+ 4.9873
V × ( Po−P ) Po

For 4 Kpa
 4 4
=0.3884 +4.9873
V × ( 170−4 ) 170

V = 0.04765 mmol/g
Like wise for 100 different P are shown in below table
P V P V P V P V
0.10756 0.15527
0 0 13 6 25.5 6 38 0.19151
0.00731 0.10996 0.15684 0.19288
0.5 8 13.5 5 26 6 38.5 5
0.01416 0.11230 0.15840 0.19425
1 5 14 3 26.5 1 39 8
0.02058 0.11458 0.15994 0.19480
1.5 7 14.5 5 27 2 39.2 7
0.02662 0.11681 0.16146 0.19535
2 8 15 3 27.5 9 39.4 6
0.03232 0.16298 0.19590
2.5 4 15.5 0.11899 28 3 39.6 5
0.03770 0.16448 0.19645
3 7 16 0.12112 28.5 5 39.8 3
0.04280 0.12320 0.16597 0.19700
3.5 6 16.5 5 29 6 40 1
0.04764 0.12524 0.16745 0.19754
4 5 17 8 29.5 7 40.2 9
0.05224 0.16892 0.19809
4.5 7 17.5 0.12725 30 7 40.4 7
0.05663 0.12921 0.17038 0.19864
5 2 18 5 30.5 8 40.6 4
0.06081 0.13114 0.17183 0.19919
5.5 7 18.5 3 31 9 40.8 2
0.06481 0.13303 0.17328
6 9 19 8 31.5 3 41 0.19974
0.06865 0.17471 0.20028
6.5 1 19.5 0.1349 32 9 41.2 7
0.07232 0.13673 0.17614 0.20083
7 7 20 2 32.5 7 41.4 4
0.07585 0.13853 0.17756 0.20138
7.5 8 20.5 5 33 9 41.6 2
0.07925 0.14031 0.17898 0.20192
8 4 21 1 33.5 4 41.8 9
0.08252 0.14206 0.18039 0.20247
8.5 5 21.5 1 34 3 42 7
0.14378 0.18179 0.20302
9 0.08568 22 6 34.5 7 42.2 4
0.08872 0.14548 0.18319 0.20357
9.5 7 22.5 9 35 7 42.4 2
0.09167 0.14716 0.18459 0.20411
10 3 23 9 35.5 1 42.6 9
 0.09452 0.14882 0.18598 0.20466
10.5 5 23.5 8 36 2 42.8 7
0.09728 0.15046 0.18736 0.20521
11 8 24 7 36.5 8 43 5
0.09996 0.15208 0.18875 0.20576
11.5 9 24.5 7 37 2 43.2 3
0.10257 0.19013 0.20631
12 3 25 0.15369 37.5 2 43.4 1
0.10510
12.5 4            

Comparing Original Plot with Different 100 Pressure values

 nB Vs P
0.35

0.3

0.25
BET at 100 points in P/P0 Limit
0.2 Range
Axis Title

Linear (BET at 100 points in P/P0

0.15 Limit Range)
Original
0.1

0.05

0
0 20 40 60 80 100 120
Axis Title

This graph clearly indicates that original data matches with different 100
pressure values for BET isotherm.
So BET model is applicable for this set of data.

Applicability for Freundlich isotherm

For Component, B Data as Shown in Below table

P nB ln P ln V
0 0    
4 0.05 1.386294 -2.99573
10 0.09 2.302585 -2.40795
25 0.15 3.218876 -1.89712
 44 0.21 3.78419 -1.56065
55 0.23 4.007333 -1.46968
61 0.24 4.110874 -1.42712
70 0.26 4.248495 -1.34707
85 0.28 4.442651 -1.27297
100 0.3 4.60517 -1.20397

ln V
0
1 1.5 2 2.5 3 3.5 4 4.5 5
-0.5

-1
f(x) = 0.55775531989963 x − 3.72108930668036
-1.5
Axis Title

-2

-2.5

-3

-3.5
Axis Title

Freundlich isotherm general equation

V =K × P 1/a
Rearrange this equation
1
lnV ¿ lnk+ lnP
a
1
Where ln k is intercept and is slope
a
After plot graph between ln V Vs. ln P we get value of intercept and slope
Intercept = (-3.7211)
Slope = 0.5578

1
From equation we get value of =0.5578
a
So, value of a=1.7928
From equation we get value of lnk=(−3.7211)
So, value of k = 0.024

This graph clearly indicates with liner plot that Freundlich isotherm.
So Freundlich model is applicable for this set of data
Part B
Graph of n Vs. P

nB Vs P
0.35

0.3

0.25

0.2
nB (mmol/g)

0.15

0.1

0.05

0
0 20 40 60 80 100 120
P (kPa)

Freundlich isotherm general equation

V =K × P 1/a
Rearrange this equation
1
lnV ¿ lnk+ lnP
a
1
lnV ¿ lnk+ lnP
a

We have value of intercept and slope so find value of V using these values
For 6 kpa

1
lnV ¿ lnk+ lnP
a
lnV ¿ ¿ ¿)
V=0.1131 mmol/g

Likewise, for 100 different pressure value are shown in below table.
P v P v P v P v
0.14901 0.21698 0.27105
0 0 26 1 51 5 76 9
1 0.02420 27 0.15218 52 0.21934 77 0.27304
 7 1 8 3
0.03563 0.22169 0.27501
2 4 28 0.1553 53 1 78 6
0.04467 0.22401 0.27697
3 7 29 0.15837 54 4 79 7
0.05245 0.16139 0.22631 0.27892
4 4 30 3 55 9 80 7
0.05940 0.16437 0.22860 0.28086
5 6 31 2 56 5 81 6
0.06576 0.16730 0.23087 0.28279
6 6 32 9 57 3 82 5
0.07167 0.17020 0.23312 0.28471
7 1 33 6 58 4 83 4
0.07721 0.17306 0.23535 0.28662
8 3 34 4 59 8 84 2
0.08245 0.17588 0.23757 0.28852
9 6 35 5 60 4 85 1
0.08744 0.23977 0.29040
10 7 36 0.17867 61 5 86 9
0.09222 0.18142 0.29228
11 2 37 2 62 0.24196 87 8
0.09680 0.18414 0.24412 0.29415
12 9 38 1 63 9 88 7
0.10122 0.18682 0.24628 0.29601
13 9 39 8 64 3 89 7
0.10550 0.18948 0.24842 0.29786
14 1 40 5 65 2 90 8
0.19211 0.25054 0.29970
15 0.10964 41 3 66 7 91 9
0.11365 0.19471 0.25265 0.30154
16 9 42 3 67 7 92 2
0.11756 0.19728 0.25475 0.30336
17 9 43 6 68 4 93 6
0.12137 0.19983 0.25683 0.30518
18 7 44 2 69 7 94 1
0.12509 0.20235 0.25890 0.30698
19 4 45 3 70 6 95 8
0.12872 0.20484 0.26096 0.30878
20 5 46 9 71 3 96 6
0.13227 0.20732 0.26300 0.31057
21 6 47 1 72 7 97 6
0.13575 0.26503 0.31235
22 3 48 0.20977 73 8 98 8
0.13916 0.21219 0.26705 0.31413
23 1 49 6 74 7 99 2
0.14250 0.21460 0.26906 0.31589
24 5 50 1 75 4 100 8
0.14578
25 7            
Comparing Original Plot with Different 100 Pressure values

nB Vs. P
0.35

0.3

0.25

0.2

0.15

0.1

0.05

0
0 20 40 60 80 100 120

Original Freundlich at 100 points

This graph clearly indicates that original data matches with different 100
pressure values for Freundlich isotherm.
So Freundlich model is applicable for this set of data