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Renewable and Sustainable Energy Reviews 144 (2021) 111049

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Renewable and Sustainable Energy Reviews


journal homepage: http://www.elsevier.com/locate/rser

The electric vehicle energy management: An overview of the energy system


and related modeling and simulation
Amier Ibrahim a, b, Fangming Jiang a, *
a
Laboratory of Advanced Energy Systems, Guangdong Key Laboratory of New and Renewable Energy Research and Development, CAS Key Laboratory of Renewable
Energy, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences (CAS), Guangzhou, 510640, Guangdong, PR China
b
University of Chinese Academy of Sciences, Beijing, 100049, PR China

A R T I C L E I N F O A B S T R A C T

Keywords: Transition into the electrified transportation sector is being investigated among the feasible technological res­
Electric vehicle olutions to tackle the mounting climate change issues. Such a transition also comes with the prospect of smart
Energy storage system vehicles and shared transportation schemes. An electric vehicle relies solely on stored electric energy to propel
Lithium-ion batteries
the vehicle and maintain comfortable driving conditions. This dependence signifies the need for good energy
Battery thermal management system
Electric vehicle air conditioning
management predicated on optimization of the design and operation of the vehicle’s energy system, namely
Modeling and simulation energy storage and consumption systems. Through the analysis of the relevant literature this paper aims to
Equivalent circuit model provide a comprehensive discussion that covers the energy management of the whole electric vehicle in terms of
the main storage/consumption systems. It describes the various energy storage systems utilized in electric ve­
hicles with more elaborate details on Li-ion batteries. It then, focuses on the detailed analysis of the prevalent
intercalation batteries but also offers a limited discussion on new-generation batteries and their development
path. Furthermore, it discusses electric vehicle energy consumption and points out the major energy consump­
tion systems within a typical electric vehicle. It first unpacks the cabin cooling system in terms of its types and
energy consumption. Then it proceeds to unpacks the battery thermal management system and classifies it ac­
cording to working fluid, thermal cycle and power consumption. It discusses as well the widely adopted cooling
systems in terms of advantages, disadvantages and describes related studies. Finally, it puts together the relevant
state-of-the-art numerical models with special attention focused on equivalent circuit models and discusses
associated simulation resources and software packages. It also presents an illustrative case-study to elaborate on
the thermal modeling and simulation of Li-ion batteries using the equivalent circuit model.

1. Introduction transportation scheme based largely on private motorized vehicles ac­


counts for more than half of the world’s liquid fossil fuel consumption
Transportation is arguably among the most important human ac­ and nearly a quarter of the world’s energy-related (CO2) emissions [2].
tivities of present-day Societies. It is also one of the main pillars of these Transportation emissions are primarily comprised of CO2, CH4 and NO2
Societies’ economies and operates as one of its foundation, support, and but globally, CO2 accounts for 95% of transportation (GHG) emissions
service provider. Growth in transportation and its subsequent energy [1]. Between 2010 and 2015, transportation emissions grew annually by
demand is driven to a great extent by economic development, popula­ 2.5% and the sector has experienced the quickest growth in the past
tion increase as well as hypermobility within the transportation system. century [3]. In 2009, road transportation was responsible for 23% of
These factors combined rendered transportation as the fastest-growing global CO2 emissions of which automobiles and light trucks generated
energy demand and greenhouse gas (GHG) producer. Transportation well over 60% of emissions in high-income countries [1,4]. Road
consumption of petroleum fuels incurs many socio-environmental transport also books about 80% of air pollution in developing cities
challenges that can be noticed at the local scale in terms of air pollu­ (WHO 2009) [5]. In the year 2000, it accounted for 22.5% and 21.2% of
tion from vehicle exhausts, also at the global scale as (GHG) emissions, total global NOx and particulate matter (PM) emissions, respectively [6].
mostly in the form of carbon dioxide (CO2) [1]. The current The transportation sector is largely oil-dependent and is the least

* Corresponding author.
E-mail address: fm_jiang2000@yahoo.com (F. Jiang).

https://doi.org/10.1016/j.rser.2021.111049
Received 28 August 2019; Received in revised form 2 May 2020; Accepted 23 March 2021
Available online 3 April 2021
1364-0321/© 2021 Elsevier Ltd. All rights reserved.
A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

diversified among all energy end-use sectors, it consumed 65% of global applications if not addressed properly. Such adverse effects might occur
oil final energy demand with 92% consisting of oil products suggesting when operating these cells outside their temperature and voltage limits.
key challenges for deep decarburization [3,7]. In later sections this paper will discuss in more detail such effects as well
In its fourth assessment report (AR4), Intergovernmental Panel on as highlight some of the measures being deployed to prevent/counteract
Climate Change (IPCC) recognized human’s influence on climate to have any unwanted effects that may arise.
a net heating effect that has manifested itself in many aspects of climate This review was motivated by the pressing need for action to balance
such as ocean warming, continental average temperatures, temperatures the part of the global warming problem that is associated with the
extremes, and wind patterns. One of the significant drivers of climate transportation sector’s GHG emissions. Such a need has already driven a
change was found to be the rise in anthropogenic GHG concentrations to substantial increase in research related to electric vehicles. It is envi­
levels beyond that of the pre-industrial era that could be determined sioned that this paper would fill an existing gap for new or experienced
from ice-core concentrations spanning thousands of years [8,9]. A recent scientists opting to join this endeavor and choosing to research Li-ion
analysis confidently suggested that such anthropogenic influences could batteries within the context of their utilization in macro-scale applica­
incur temperature changes due to enhanced natural greenhouse effects tions as in energy storage systems (ESS) for electric vehicles. It is ex­
[10]. Some of the projected health risks due to climate-change-related pected that this paper would offer a comprehensive understanding of the
extreme weather conditions (i.e. Intense heatwaves) include degrada­ electric vehicle energy system and highlight the major aspects of energy
tion in air quality, which in 2018, accounted for around 2.9 million storage and energy consumption systems. Also, it is expected that it
premature death globally [11]. Other risks include temperature-related would provide a practical comparison between the various alternatives
morbidity and mortality, undernutrition, reduced labor productivity and available to each of both energy systems to optimize energy manage­
occupational health concerns [12]. To balance these adverse effects, ment to yield an improved EV driving range. To do this, the paper is
IPCC called for action in the form of a human intervention known as structured into six sections. The next section (Section 2) introduces the
“mitigation of climate change” to reduce the sources or enhance the electric vehicle and its general architecture with a short timeline of their
sinks of GHGs [13]. One approach of mitigation is a dramatic reduction history of evolution. After that, the energy storage options utilized in a
of energy demand presented by (Grubler et al., 2018 [14]) describing a typical electric vehicle are reviewed with a more targeted discussion on
low energy demand scenario. Another approach is the electrification of the widely implemented Li-ion batteries. The Li-ion battery is then
transportation and manufacturing sectors to a point that renders introduced in terms of its structure, working principle and the adverse
non-electric fuel use insignificant [3]. In its article 2, United Nations effects associated with high temperatures for the different Li-ion
Framework Convention on Climate Change (UNFCC) adopted mitiga­ chemistries. Then, the energy consumption is discussed in terms of the
tion, together with adaptation to climate change to stabilize atmo­ major consumers within a typical EV. A discussion in Section 5 is pre­
spheric GHG concentrations at low levels within a timeframe adequate sented to introduce and elaborate on the modeling and simulation
for ecosystems to adapt [13,15]. The Paris agreement on climate change approach utilized a means of researching Li-ion batteries with a more
represented a consensus of the parties attending the united nations detailed analysis allocated to the equivalent circuit model (ECM) used in
climate change conference in 2015 and became international law in such macro-scale applications. Also, a short case-study is prepared and
2016 [16]. discussed before presenting the paper’s concluding remarks in Section 6.
Countries such as UK, France, Germany, Netherlands and other
countries have adopted the Paris agreement goals and pursued devel­ 2. Electric vehicle
oping strategies predicated on electrification of the transportation sector
by revealing a schedule to stop producing internal combustion engine Electric vehicles were developed in the early days of the industrial
vehicles (ICEVs) by 2040 [17]. Electric vehicles show comparable and revolution. The intention for them was to serve as a means of private
sometimes lower life cost per km to that of ICEVs, and can still undergo commute during the first years of the automotive industry in addition to
more improvements by the development of more durable EVs [18]. steam cars (Locomobile). However both electric vehicles and steam cars
Some of the challenges that confront efforts to facilitate complete lost the consumer market to the rapidly progressing ICE vehicles. In
adoption of EVs are the range and price of electric vehicles [19]. These 1996, Cowan and Hultén discussed the possibility of escaping a lock-in
factors are interrelated since a big battery pack enables for a longer situation in the case of electric vehicles. Their paper highlighted four
range but would increase the vehicle’s price and design complexity of phases to be a history of technological lock-in with ICEVs becoming
battery cooling systems required to manage the temperature of the more entrenched, namely, (1) the formative years of the automobile
battery pack. Travel electrification indicated by the percentage of industry (1885–1905), (2) establishment of gasoline car as a dominant
vehicle-miles-traveled (VMT) powered by electricity instead of fossil option (1905–1920), (3) consolidation of its leading position
fuel greatly influences the environmental effects of the adoption of such (1920–1973), (4) questioning the gasoline car (1973–1998) and a fifth
means of commute [20]. It is mainly affected by the range of the battery which could represent an escape or (partial escape) from technological
pack [21]; smaller battery would increase range anxiety and limit travel lock-in by the legislated introduction of large manufacturing of EVs after
distance [22,23], while larger battery would increase the cost [24] 1998. According to their research some of the factors that could assist in
which makes balancing incurred design tradeoffs a major challenge to overcoming the lock-in include technological as well as production and
future adoption of all-electric vehicles (AEV). These challenges can be marketing solutions. However, the conclusion was that an escape from
balanced by good energy management established on the optimization the lock-in was highly unlikely to happen due to inferior EVs at that time
of the design and operation of the electric vehicle energy system. and an inability to compete with ICEVs under conditions established by
The energy storage system is the most important component of the users at the time [25]. Electric vehicles are generally characterized by
electric vehicle and has been so since its early pioneering days. This their use of an electric traction motor for propulsion of the vehicle [26].
system can have various designs depending on the selected technology These motors are powered from an efficient energy storage device such
(battery packs, ultracapacitors, etc.). Out of these technologies, the as contemporary Li-ion batteries or ultra-capacitors [27]. Currently, EV
battery cell is by far the most widely utilized energy storage technology models include electric spacecraft or aircraft, rail or road vehicles, ships
in EV applications. Today, several battery chemistries are available or submarines [28]. A main feature of EVs is the utilization of some
commercially but the most prevalent chemistries are variations of the Li- additional electrical components such as electric machines, power
ion chemistry [19]. This market advantage rests largely on the relative electronics and embedded powertrain controllers more than typical
superiority of Li-ion chemistries when it comes to energy density, ICEVs. The significant advances in such components have contributed to
thermal tolerance and some other characteristics. Nevertheless, Li-ion the enhancement of electric vehicle drivetrain designs [29,30].
cells suffer from a variety of adverse effects that would limit their Currently, drivetrain design of road electric vehicles would either follow

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

a comparable approach to that of a conventional ICEV with a main mounting pressure of rising atmospheric GHG concentrations [25].
electric motor replacing the ICE and then connected via transmission to Electric vehicles are now considered the most promising alternative to
the EV wheels, or adopt a different design approach that is unique to EVs ICEVs with null tailpipe emissions contributing to fight localized
based on having electric motors integrated directly into the rims of all pollution. Contemporary progress in battery technology has signifi­
the wheels [31]. Currently, road EVs include hybrid electric vehicles cantly boosted the EV driving range. Today, it is common for a com­
(HEV), pure electric vehicles (PEVs) also known as (plug-in electric mercial EV such as (BMW i3, Nissan Leaf, and Tesla Model S) to have a
vehicles (PEVs), battery electric vehicles (BEV), battery plug-in electric range of 200–300 miles along with other enhanced features such as
vehicles (BPEVs) or all-electric vehicles (AEVs)) and fuel cell electric acceleration, speed, size and number of seats [51]. In 2017, Andwari
vehicles (FCEVs) also known as hydrogen fuel cell vehicles (HFCVs) et al. [52] reviewed the readiness level of BEV. Their paper discussed the
[32]. This spectrum of electric vehicle’s drive train is bounded on its various aspects related to electric vehicles in terms of technology
opposite extremes by none-plug-in hybrid vehicles (i.e. series hybrid readiness and expected progress as well as techno-economic issues and
electric vehicles (SHEVs)) and battery plug-in electric vehicles (BPEVs) policy role. The conclusion was that BEVs are no longer a niche market
with plug-in hybrid electric vehicles (PHEVs) somewhere in between due to recent technological advances. Fig. 1 shows a summary of in­
[33]. A SHEV is composed of an ICE that is exclusively used to power an centives and the total EV tally in various countries worldwide.
electric motor while a BPEV relies only on energy stored by charging a For the year 2025, Diamler has set a goal for its EVs to reach 15–25%
battery pack from an external power source [34]. None plug-in hybrid share of sales while BMW aims for a 15–20% share of sales for the same
electric vehicles can be classified into mild hybrid vehicles designed of year. Honda on the other hand targets reaching 67% share of sales by
battery packs with small energy and power capabilities mostly of Ni-MH 2030. Fig. 2 outlines the projected number of EV sales of various car
cells. Such vehicles have demonstrated 10%–15% fuel saving. Another manufacturers. In EPA automotive trends report of 2018, these manu­
classification is full hybrid vehicles with high enough energy and power facturers were found to have made significant improvements on fuel
capabilities that allow an all-electric drive mode for a small range. Full efficiency and CO2 emissions through the adoption of various advanced
hybrid vehicles show fuel saving of 30%–40% [35,36]. In comparison, a technologies related to ICEVs to lower vehicle emissions in addition to a
PHEV uses a battery pack that can be charged from an external power trend of adopting PHEVs, EVs, and FCVs across all manufactures [51]. In
source to provide propulsion for short distances until power is depleted 2019, Sioshansi et al. [19] analyzed various projections of the rate of
then an on-board ICE is engaged to recharge the battery pack [33]. All transition from conventional ICEVs to EVs among other questions
PHEV types utilize Li-ion battery cells and could be considered as full related to the proximity of peak oil demand. Their resolution focused on
hybrid vehicles [36]. A widely researched subject when it comes to the critical question “will automobile companies invest more in accel­
HEVs is the ride-comfort studied in terms of noise vibration and erating EV development or rather invest in advancing liquid fuel-saving
harshness of the vehicle [35]. Table 1 shows the general characteristics technology?“. From cited studies, their paper identified several attri­
of various types of electric vehicles. butes of EVs that could speed up the transition from ICEVs. For instance,
A dramatic change in outlook towards EVs began in the 1990s. This transition to EVs could benefit extensively from accessing similar
was manifested by the development of government agencies and aca­ economies of scale to that of ICEVs. The advent of transport as a shared
demic institutions to intense R&D programs connected to electric ve­
hicles as well as the initiation of aggressive commercialization programs
for electric vehicles by major automotive manufactures [30]. The most
important battery characteristics include ampere-hour capacity, specific
power, energy density, discharge rate, cost and safety of the technology.
Such characteristics have a significant influence on the performance,
safety and efficiency of the electric vehicle [39]. Battery is also the key
challenge to the commercialization of EVs due to its high cost. The
FreedomCAR initiative developed several requirements and tests for
energy storage systems (ESS) for automotive applications. The aim is to
facilitate maximal performance through state monitoring, protection,
management and balancing of the battery pack [40–50]. USABC set
several mid-term and long-term performance targets for battery cells
used in electric vehicle applications. These goals aim to improve battery
performance characteristics such as specific energy, energy density and
life cycle from mid-term to long-term which would impact vehicle
characteristics such as driving range, weight, size and acceleration [39].
Recent technological advances in battery technology have led to the Fig. 1. Total number of EV and the adopted incentive policy for various
current recovery of EVs which has been further reinforced by the countries [19].

Table 1
General characteristics and requirements of various types of electric vehicles.
Type of Battery pack Actual used capacity Power Typical Chemistry and energy Weight of the Operating Reference
electric vehicle capacity (kWh) (maximum %) required (kW) voltage (v) density (Wh/kg) battery pack (kg) range (C)
̊

HEVs <3 – – – (Ni-MH) 40–50 60 – [37]


Mild hybrid 1–2 40 – – (Ni-MH) – - 30 to 52 [37,38]
Full hybrid 0.3 – 10–30 48–200 (Ni-MH) – – [36]
1–2.5 – 60 300–600 (Ni-MH) – – [36]
Plug-in-hybrid 5.6–18 – – – (Li-ion) 90–100 60–200 – [37]
5–12 75 – – (Li-ion) – - 30 to 52 [37,38]
4–10 – 60 300–600 (Li-ion) – – [36]
Full EV 35–54 – – – (Li-ion) 90–100 450 – [37]
22–80 80 – – (Li-ion) – - 40 to 50 [37,38]
15+ – 60 300–600 (Li-ion) – – [36]

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Despite this, FES can still feature in the transportation sector due to
favorable attributes such as long lifetime (more than 15 years), broad
temperature range, low maintenance needs, quick power response and
short recharge time [56]. In 2014, Audi Sport utilized the pioneering
work of Williams Hybrid Power (WHP) to include a flywheel storage
system in their Audi R18. This development was part of a trend of using
hybrid propulsion systems in top tier motorsports that started since the
year 2000 to improve fuel efficiency reducing the required number of pit
stops [57].
Ultra-capacitors (also known as super-capacitors) has the main
feature of producing a substantial amount of energy at low voltage due
to their high capacitance. Their advantages include long lifetime (the
longest among all ESS options), higher power density, fast charging and
discharging response but are burdened with low energy density [58,59].
The main types of UC deployed in the EV industry include electric
Fig. 2. Projected number of EV sales of various car manufacturers [19]. double-layer capacitors (EDLC)—carbon/carbon, pseudocapacitors and
hybrid capacitors. Recently, Li-ion UC has been developed showing
service (TaaS) can also further accelerate the transition to EVs. The higher energy density and wider voltage range [60]. The use of UC in
conclusion was that EVs are likely to experience price drop due to some commercial vehicles such as Mazda 6 has demonstrated a capacity
cheaper battery costs at the same time ICEVs would undergo a price to reduce fuel consumption by up to 10%. On the other hand, battery
increase as fuel efficiency standards are tightened. Furthermore, EVs are technology (especially Li-ion technology) can offer significantly higher
projected to gain additional consumer attention as cost per km travel energy density promoting it for a premier status within contemporary
declines by adoption of TaaS and similar schemes. energy storage technologies for EV applications [61]. Fig. 3 shows the
characteristics of battery technology while Fig. 4 shows characteristics
3. Energy storage of UC. In 2017, Bloomberg new energy finance report (BNEF) showed
that the total installed manufacturing capacity of Li-ion battery was 103
This section introduces some of the energy storage systems (ESS) GWh. According to this report, battery technology is the predominant
used in EV applications with particular attention on the battery tech­ choice of the EV industry in the present day. It is the most utilized energy
nology in terms of the battery cell and the battery pack. storage system in commercial electric vehicle manufacturers. In its sales
Today, storage systems of electrical energy can be realized from outlook BNEF predicted that annual demand for Li-ion batteries for EVs
designs such as flywheel, ultra-capacitor (UC) and various battery would be 408 GWh by 2025 and 1293 GWh by 2030. The report stated
technologies [7,45]. Some of these designs have been adopted for EV that this demand is generally driven by utilization of batteries in com­
applications. Flywheel energy storage (FES) technology can deliver en­ mercial EVs [62].
ergy output either in kinetic form (rotational energy) or in electrical
form. According to Chris Brockbank (business manager from Torotrak), 3.1. The battery cell
FES energy conversion efficiency from braking energy to FES can reach
up to 70% which is twice the efficiency of transforming energy from A battery cell is an electrochemical device that chemically stores
braking to electric energy and then to FES [53]. Multiple research electrical energy for later use. A battery cell has many characteristics
agencies have developed ultra-high-speed flywheel systems for EVs. In that influence its applicability to electric vehicles. The two central
comparison to UCs, flywheel systems offer higher energy density and characteristics are nominal average charge capacity measured in
power density. The main disadvantages are safety issues and gyroscopic ampere-hours (Ah) and nominal discharge voltage in volts (V). Knowing
force which might render FES not well suited for transportation [54,55]. these values, energy in watt-hours (Wh) stored in the battery can be
calculated as the product of nominal average charge capacity (Ah) and

Fig. 3. Characteristics of the rechargeable battery [61].

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Fig. 4. Characteristics of the ultra-capacitor [61].

nominal voltage (V). Other derivable quantities include the battery state overcharge, and high production cost [72,73]. Current commercialized
of charge (SOC) in the percentage of the fully charged state of the bat­ Li-ion cells of different cathode materials are based on intercalation
tery. The minimum and maximum voltage limits of the tested battery chemistry and considered to be the most promising choice among the
cell determine the corresponding SOC limits. Operating a battery cell various lithium-based battery cells which rendered them the most
frequently-enough out of its voltage limits is showed to have a detri­ studied in detail in recent reports [63,74,75]. Battery cells based on
mental effect on the cell operating life. The C-rate of a battery cell de­ (LixCoO2) (LCO) were the first developed commercial cells in early 1990
termines the discharge current value to completely deplete the cell and offer good power and energy densities but are limited by safety
charge capacity in 1 h starting from a fully charged SOC. This renders concerns and high cost. Other cells developed after LCO include Lix(Ni,
the C-rate to be proportional to the charge capacity of the battery cell i.e. Mn, Co)O2 cells (NMC) that are safer and less expensive and LixMn2O4
1C means the cell is depleted in 1 h and the corresponding discharge (LMO) which are burdened by poor thermal stability. Other lithium-ion
current will be equal to the cell’s capacity in amperes; while 2C means cells such as NCA cells (Lix(Ni, Co, Al)O2) have the highest energy
the cell is depleted in half an hour and the corresponding discharge density while LFP cells (LixFePO4) has the advantage of improved safety
current will be equal to double that of the 1C rate. The maximum current properties due to enhanced thermal and chemical stability but has low
that a cell can withstand depends on its chemistry and the corresponding energy density and short calendar life [76–78]. Fig. 5 summarizes per­
heat generated [63]. Today, available battery technology that is suitable formance level of some commercialized Li-ion chemistries.
for vehicle application include lead-acid, Li-ion, Ni-MH, Ni–Zn, and New generation lithium batteries stem from a variety of innovative
Na–S [64]. The lead-acid chemistry is already deployed in ICEVs and has R&D efforts that aim to satisfy the electric vehicle requirement of the
reached a mature stage of development and incurs low cost for its largest energy storage capacity with the smallest associated weight
application. These advantages present lead-acid batteries as a candidate through development endeavors investigating new high capacity cath­
for HEVs applications. However, it has disadvantages such as having a ode and anode as well as new electrolyte with high oxidation potential.
heavyweight and a negative environmental footprint as well as short Some of the development paths that are adopted to improve energy
lifecycle and low specific energy (20–40 Wh/kg) and low power density density are shown in Fig. 6. For instance, Li-ion batteries can deploy
which would mandate a huge mass to provide requirements for EV ap­ more than one type of Li-insertion cathode or utilize novel separators
plications [61,65–68]. Nickel-based battery cells include that are fabricated to allow for better wetting by the electrolyte solution
nickel-cadmium, nickel-iron, nickel-zinc and nickel-metal-hydride. The [79,80]. Furthermore, these efforts also include the use of ionic liquids
nickel-cadmium (Ni–Cd) cell shows high specific energy (40–60 Wh/kg)
and high power density (80–350 W/kg) but is limited to low discharge
rate and is less favored for automobile applications due to its memory
effect, high cost and high toxicity. Nickel-zinc cells are more relatively
environmentally friendly with high specific energy and high peak power
but troubled by short life cycle. Nickel-metal-hydride (Ni-MH) cells have
been utilized in HEV applications in vehicles such as Toyota Prius. These
cells are environmentally friendly with a long life cycle (600–2000 cy­
cles) and high energy density (50–80 Wh/kg) but have disadvantages
such as higher self-discharge rate, longer charging time and generating a
large amount of heat during charging, which all complicate the charging
process resulting in a need for intricate charging algorithms and
expensive chargers [61,69].
Battery cells utilizing lithium chemistry are widely adopted in EV
applications due to characteristics such as high efficiency, long lifecycle,
low toxicity, lightweight, high specific energy, high energy density
(90–200 Wh/kg) and high power density(500–2000 W/kg) [61,70,71].
Their main disadvantages include safety issues due to low tolerability to Fig. 5. Performance level of various commercial Li-ion chemistries [36].

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Fig. 6. Status and prospect of automotive batteries [93].

(IL) solvents to develop new electrolyte solutions which would widen


the electrochemical window and offer enhanced safety features as well
as the development of solid-state Li-ion batteries utilizing different
electrolytes i.e. Gel and polymeric [81–87]. However, it remains to be a
difficult task to find a replacement for the currently used alkyl carbonate
solvents. It is worth noting that it has been proven to be not useful to use
ILs as co-solvents to alkyl carbonate solvents. Despite this, ILs remains
full of potential and can open new horizons when further improvements
are achieved (i.e. in their physical properties) [88]. New generation
batteries also include those based on conversion chemistry such as (Li–S
and Li-air) which would significantly improve energy density beyond
the current intercalation chemistry of Li-ion cells. For instance, con­
version anodes such as (Li) have 10 times greater specific capacities to Fig. 7. Shapes of commercial Li-ion cell (a) Prismatic cell [102] (b) Cylindrical
Cell [36].
that of graphite while conversion cathodes such as sulfur (S) and oxygen
(O2) demonstrate a six-time superiority in specific capacities [89]. Li–S
cells and Li–O2 cells are estimated to have a theoretical specific energy lithium-containing salt (LiPF6) dissolved in an organic liquid mixture
of approximately 1168 Wh/kg and 1752–2691 Wh/kg respectively [90]. such as ethylene carbonate (EC), propylene carbonate (PC), diethyl
However, such cells are challenged by short lifespan and severe safety carbonate (DEC) or ethyl methyl carbonate (EMC) [99]. The separator
concerns greatly hinder their practical application [91,92]. functions as a safety fuse that melts down in case of high temperature in
addition to electrically insulating negative and positive electrodes
3.1.1. Configuration of the intercalation Li-ion cell allowing only for Li-ions to pass through [100,101]. The current col­
Commercial Li-ion cells in EV applications accounted for nearly all of lector is a sheet metal attached to the surface area of electrodes. Its
the storage capacity in the market with cylindrical shape Li-ion cells function is to collect generated current from both electrodes and is
booking almost half of the total number of cells. Fig. 7 shows cylindrical usually made of copper for the negative electrode and aluminum for the
as well as prismatic shapes of Li-ion cells. The prismatic shape has a positive electrode. The container case (usually aluminum or steel) is
higher space utilization efficiency while the cylindrical shape is easier to meant to provide structural integrity to the cell and improve
manufacture. Ciez and Whitacre [94] compared cylindrical and pris­ thermo-physical properties [97].
matic cells costs using a process-based cost model. Their conclusion
showed that the cell chemistry plays a key role in determining the per 3.1.2. Working principle of the intercalation Li-ion cell
kWh cost of the batteries. The cylindrical cell format was too small for During charge, electrical energy provided from an external source
low specific energy batteries such as LMO which limited the thickness of causes an oxidation reaction at the anode electrode releasing positive
the electrodes inviting the need for additional cells to meet energy re­ lithium ions and an equal amount of electrons at the surface of the
quirements for EV application. On the other hand, prismatic LMO cells electrode. Electrons are collected by the Aluminum current collector
offered an opportunity for large cell formats with thicker electrodes and then directed to flow through the charging equipment to the cathode
reduced cost per kWh. NMC and NCA cylindrical cells are less expensive electrode. Simultaneously, a reduction reaction at the cathode electrode
per kWh to manufacture than LMO cells. The main components of a takes place when positive lithium ions (Cations) that diffuse through the
typical Li-ion cell are positive and negative electrodes (intercalation electrolyte react with charging electrons. Reduction products are
electrodes), non-aqueous electrolyte, separator layer, two current col­ eventually intercalated into the electrode materials. This intercalation
lectors and a container case. Electrodes have a key role in establishing process is limited by the single-electron reaction [103]. During
energy density and capacity of the cell. The widespread intercalation discharge, the process is reversed by directing electrons to flow from the
electrodes were first developed in 1978 [95,96]. Such electrodes are copper current collector through the external load. The separator only
developed from materials structured to allow for easy insertion and allows for lithium ions flow, forcing electrons through the external cir­
discharge of lithium ions. Positive electrode material can be of layered cuit. This charge/discharge process is continuously repeated for the life
structure (LCO) commonly used for portable electronics, NMC, NCA and cycle of the battery cell. This process along with associated reaction at
LiNiO2 (LNO); spinal structure (LMO) and olivine structure (LFP) and each electrode is depicted in Fig. 8 for LCO cells.
LiMnPO4 (LMP) [97]. Negative electrode material is usually of carbo­
naceous origin such as graphite (most popular), coke, and mesocarbon
microbeads (MCMB) [98]. The electrolyte is a non-aqueous solution of a

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Fig. 8. Working principle of intercalation Li-ion cell [104].

3.2. The battery pack and adverse effects of un-regulated high (high or low) reveal the need for an effective battery thermal manage­
temperature ment system (BTMS). For a Li-ion battery pack, temperature beyond
acceptable range and temperature non-uniformity both are detrimental
Electric vehicles use a battery pack (also known as a battery) of tens to the battery pack performance and could result in a safety problem.
of thousands of battery cells to provide necessary energy and power Fig. 9 shows the working range of Li-ion cells. The ambient environment
requirements. These packs need to satisfy several requirements to be is an essential feature in temperature regulation dynamics, however,
used in electric vehicles. Common requirements set by most original dreadful ambient conditions (extreme hot or cold temperatures) are
equipment manufacturers (OEMs) include about 10 service years and impractical to avoid which presents a key challenge to battery pack
safety against fire [105]. A battery pack is made of several electrically temperature regulation and thermal management [113–119]. Here the
interconnected battery modules, a battery module is comprised of paper briefly discusses deteriorations due to unregulated high temper­
multiple groups of individual Li-ion cells. For the module or the battery atures such as performance degradation, thermal runaway and tem­
pack, connecting in parallel increases the energy capacity by increasing perature mal-distribution.
the charge/discharge (Ah) capacity, while connecting in series results in
an increased power capacity by increasing charge/discharge current. An
example of this could be the battery pack of Tesla Model S which is put
together by arranging 7104 cylindrical 18650 NCA-based Li-ion cells
(18 is the diameter in mm; 65 is the height in mm; 0 is the code for
cylindrical cell) in 16 modules [106]. Each module has 6 groups of 74
individual cells connected in parallel and then all 6 groups are con­
nected in series to form the battery module [107]. The ‘‘mSnP’’ deno­
tation can be used to indicate the series-parallel combination within a
battery module, where (m) is the number of cells connected in series and
(n) is the number of cells connected in parallel. Today, battery packs
show an apparent variability in energy capacity and subsequently
driving range for various commercial EV models such as BMW Mini e,
Ford Focus EV, Mitsubishi IMIEV and Tesla model S. For instance, the
Tesla Model S battery pack has a total energy capacity of 85 kWh while
BMW Mini e, Ford Focus EV, Mitsubishi IMIEV have energy capacities of
35, 23 and 16 kWh respectively [61]. Currently, battery packs for
commercial EVs are designed mostly from lithium cells with negative
electrodes that are carbon-based, but using LTO (Li4Ti5O12) as a nega­
tive electrode is a promising option that is demonstrating significance
due to its capability to enhance cells durability and fast charging per­
formance; while positive electrodes used include LMO, LFP, NCM, and
NCA. Within the battery pack, each Li-ion cell experiences temperature
rise during the discharge process but it does not well tolerate neither
temperatures beyond its operation range nor the non-uniform distribu­
tion of temperature [108]. The temperature range (safety range) differs
according to the chemistry used from - 40 to 60 ̊C [109]. However to get
optimum output, the battery temperature needs to be regulated within a
desired operating range specific for EV application between 15 and 35 ̊ C
[109–111]. When frequent temperature miss-regulation occurs for an
extended period, it causes some adverse effects that are shown to be
harmful to the cell performance, lifecycle and could even result in safety
problem, which would affect the overall efficiency and performance of
the cell and subsequently the battery pack and the electric vehicle [112].
For a battery pack, the adverse effects of unregulated temperature Fig. 9. Working range of the Li-ion cell [127].

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Performance degradation, cyclic based (due to charge/discharge locations within the cell. Some research showed that the positive elec­
cycles) or calendar life based (due to storage without use), refers to a trode of LiCoO2 generates four times more heat than the rest of the cell
drop in capacity and power qualities of Li-ion battery (also known as [139]. This would cause local deteriorations impairing the overall per­
capacity fade and power loss) [120]. Power loss is generally more severe formance of the cell and may result in a failure to the battery. Electrode
at sub-zero temperatures which would call for larger battery packs to be modification can enhance intra-cell temperature uniformity, as well as
deployed to perform the intended application i.e. engine cold-cranking using an intra-cell cooling method such as using the electrolyte as the
for hybrid EVs [118]. Capacity fade can be attributed to the loss of coolant [140,141].
active material inside the battery cell through transformation into an
inactive phase (lithium loss) [40]. Capacity fade can be due to the 4. Energy consumption
overcharge of Li-ion cells while power loss can be a result of increased
internal impedance [116,121,122]. The current number of combina­ Energy consumption of a mid-size vehicle is about 165 Wh/km for
tions of electrode materials and electrolyte solvent/salts is over­ urban driving and 137 Wh/km for highway driving according to the U.S.
whelming which makes it difficult to put together a coherent and urban dynamometer driving schedule (UDDS) and the highway fuel
comprehensive picture of all mechanisms associated with capacity fade. economy driving schedule (HWFEDS). Hence, the vehicle’s driving
However, operating temperature as well as storage temperature appears range would depend significantly on the amount of onboard energy set
to have a clear influence on performance degradation for nearly all forth by the type of energy source and its energy density and bounded by
electrode materials and electrolyte chemistries [40]. Ramadass et al. design considerations such as overall weight [39]. Evaluating the energy
[111] and Shim et al. [113] showed a reduction in capacity by (22.5% consumption of EVs has a significant role in assessing and quantifying
and 26.46%) and (4% and 65%) respectively for different types of bat­ their environmental benefits. Such efforts include measurements of
teries under various temperature and cycle number conditions. Other comparative energy consumption for prototype, pre-production and
studies investigating capacity fade include Ehrlich who reported 9% production passenger vehicles on a like-for-like basis that were con­
capacity fade for (C/LiMnO4 and C/LiCoO2) cells after 500 cycles at 1C ducted during the Brighton to London future car challenge (BLFCC)
rate [123] and Liu et al. (2010) who reported 7.5%, 20.1%, and 22.1% organized by Britain’s royal automobile club (RAC) in 2010 and again in
capacity loss after 2628 cycle, 757 cycle and 1376 respectively for 2011. Drivers were free to decide which combination of eco-driving
(C/LiFePO4) under various temperatures and voltages [124]. Research techniques to use to navigate the 57 mile urban/extra-urban route in a
on calendar life degradation e.g. Wu et al. reported a 20 mAh drop in predefined time window using as little energy as possible. In 2010, a
capacity due to storage at 60 ̊C for 60 days, while Jiang and Zhang listed comparative study conducted during this challenge by presenting the
the requirements of storage of Li-ion batteries to lessen degradation energy consumption of different types of vehicles (AEV, HEV, ICEV and
possibility when storing them without use [125,126]. HFCV). Results showed that AEV ranked as the least energy consumer
Thermal runaway is the chain effect that ensues when a high- (average 0.62 MJ/km) followed by HEV (average 1.14 MJ/km) then
temperature state induces a series of exothermic reactions that are HFCV (1.2 MJ/km) and lastly ICEV (average 1.68 MJ/km). The paper
enhanced and increased via yet more elevated temperature until an also estimated CO2 emissions for the same types of vehicles. Results
irreversible incident happens [40,128]. It could be caused by lithium showed that HEV ranked as the lowest emitter of CO2 (70 g CO2/km)
plating (the deposition of Li on the graphite anode in dendritic struc­ followed by the most efficient diesel vehicles (80 g CO2/km) then the
tures) due to the high overcharge of Li-ion cells or charging at sub-zero majority of diesel vehicles (surpassed 110 g CO2/km) while AEVs
temperatures [129]. To avoid such consequences, a variety of abuse tests emitted (70–110 g CO2/km) assuming united kingdom grid average
have been designed to measure the thermal stability and abuse tolerance emissions factor of 542 g CO2/kWh [142]. The stated consumption of
of a Li-ion cell, e.g. oven exposure [130], short-circuit [131], overcharge electric vehicles in this study is found to be within the range of energy
[132], nail penetration [133] and crush tests [134]. A typical path for consumption for commercial EVs published by some manufacturers as
thermal runaway starts at about 90 ̊C by the exothermic decomposition summarized in Fig. 10 [143]. In 2011, Lorf et al. [144] presented an
of the SEI (solid electrolyte interface) layer of the negative electrode; analysis of the factors influencing the energy consumption of various
then an even highly exothermic reaction between the exposed negative types of vehicle technologies participating in the RAC future car chal­
electrode and the electrolyte occurs at about 100 ̊C; next, the polymer lenge. The race (a 91.94 km route from Brighton to London in England)
separator melts down at the temperature around 130 ◦ c leading to po­ is won by crossing the end line in a predetermined time frame (a min­
tential short-circuit between the electrode. If temperature continues to imum of 2 h and 45 min and a maximum of 3 h and 30 min, including a
rise to more than 200 ̊C, a chain reaction may occur as the positive 15–30 min stop-over) using as little energy as possible. All legal pas­
electrode (lithium metal oxide material) decomposes giving out free senger cars and light commercial vehicles (ICEVs, HEVs, PHEV, AEVs,
oxygen which may react to the solvent in the electrolyte or the positive etc.) produced after January 1st, 2001 were eligible for this competition.
electrode materials. All these aforementioned reactions generate
gaseous products which in combination with high-temperature increase
internal pressure resulting in swelling of the battery cell or could even
lead to explosions [40]. The potential hazards of thermal runaway could
be lessened by deploying a variety of safety mechanisms including
thermal fuses, self-resetting devices, shutdown of separators, additives
of electrolyte, thermal retardant electrolytes and electrodes, and also the
development of an efficient battery thermal management system [135,
136]. Temperature mal-distribution in a battery pack is a result of the
unequal dissipation of heat caused by the decrease of heat transfer co­
efficient value from a maximum at external boundary cells to a mini­
mum at the inner cells of the battery pack. This could lead to vast
variations between cells in performance indicators that strongly depend
on temperature such as the capacity of individual cells. A well designed
BTMS could be utilized to regulate inter-cell temperature deviation and
keep the temperature deviation below a recommended value of 5 ̊C
[137,138]. Another concern is temperature imbalance within a cell
which is caused by a difference in heat generation rate between different Fig. 10. Energy consumption of various EV models [143].

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ICEVs had to satisfy a maximum requirement of emissions of 110 g [148] discussed and reviewed these factors and their influence on
CO2/km (new European driving cycle) [145]. Results showed that ve­ electric vehicle energy consumption during the use phase and classified
hicle’s energy consumption and ensued emissions are greatly influenced them into six groups as shown in Fig. 11. Sub-factors influencing vehicle
by its power train technology, traction ratio (percentage of time used to technology, natural environment and driver-related factors are sum­
accelerate the vehicle relative to total driving time) and regenerative marized in Table 2 along with their impacts. In the same study, the
braking magnitude, and less influenced by the average speed in the authors used real-world data and adopted an empirical approach using a
range 25–70 km/h. Sweeting et al. [143] studied typical liquid fuel Nissan Leaf 2011 to study the impacts of many factors on EV energy
ICEVs and EVs energy consumption. Results showed that EVs can offer consumption. Consequently, several EV energy consumption factors
up to 75% reduction in “tank to wheel” energy consumption and would were highlighted to be statistically more significant. In their results,
offer only about 58% in case of having poor energy management char­ climate and topography showed a significant impact on energy con­
acteristics in terms of vehicle design optimization, driving style and sumption compared to other factors. Results also showed a statistical
auxiliary loads. The energy management referred to in Ref. [143] was insignificance of interaction of topography and climate but high statis­
used to denote the condition of auxiliary power draws (such as heating) tical significance of combined effect of traffic and topography (high
and driving style. However, the energy management of EVs can also traffic means numerous acceleration events which on a slope route
refer to strategies predicated on the use of sophisticated algorithms would demand more energy) as well as traffic and climate, and infra­
based on power electronics and power processors to optimize the overall structure and climate due to longer duration of deployment of HVAC
performance of the electric vehicle. A comprehensive review within system per kilometer when driving through an urban area (it takes more
such context was published in 2013 by Tie and Tan [63]. In their paper, time to drive 1 km in an urban area). Also, the paper derived a numerical
energy management was divided into a low-level component control binary model using data collected from a test vehicle to simulate real
concerned with (i) the different types of arrangements to the various world usage. This simplified model was based on the processed data but
power electronic components and (ii) strategies on controlling energy excluding interactions between factors. The model suggested that HVAC
and power flow. And a high-level supervisory control focused on (i) has the most significant impact on energy consumption dramatically
rule-based control including both (a) deterministic i.e. on-off strategies affecting driving range especially in a hilly high traffic area. Further­
and (b) fuzzy-rule based more sophisticated controllers such as the two more, topography is another factor that was found to greatly impact
fuzzy logic controllers driver’s intention predictor DIP and power bal­
ance controller PBC, and (ii) optimization (analytical or numerical) by
(a) global optimization based on future and past power demands and (b) Table 2
real-time optimization methods (RTO). Impacts of various sub-factors influencing technology, environment and driver
factors [148,152,153].
Another study by Liu et al. [119] utilized deep learning and genetic
algorithm to design an integrated management system for real-time Factor Sub-factors Influenced by Impacts
applications to control the multi-mode powertrain of plug-in hybrid Technology Battery pack Cell chemistry, Battery pack’s total
electric vehicles. This work introduced a hierarchical framework to and vehicle capacity, mass and mass, capacity and
generate the necessary control actions. The presented model has been energy density, energy density
number of cells and
successfully validated and shown a high ability to improve the fuel SOH
economy. BTMS Working mode Cooling/heating
More research was done on electric vehicles to evaluate a variety of (heating or cooling) load
parameters, their correlations, and influences associated with energy HVAC Local climate and HVAC load
driver’s behavior
consumption. Neubauer et al. [146] used NREL’s battery lifetime anal­
Natural Topography –
ysis and simulation tool for vehicles (BLAST-V) to investigate the environment Climate and – HVAC load and
sensitivity of EV utility to driver aggression and climate, cabin heating factors weather driving behavior
and cooling, cabin pre-conditioning, BTMS cooling and heating over conditions
vehicle lifetime. In another study there was an excess of 16 factors that Driver factors Driving style Experience, age, and Acceleration profile
gender
were identified to influence energy consumption [147]. In 2016, Li et al.

Fig. 11. Factors influencing EV energy consumption during the use phase [145].

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

energy consumption. Lohse-Busch et al. [149] studied impacts of and HP technology and classified them into VCC systems and non-VCC
ambient temperature on energy consumption for various vehicles (HEV, systems. Among VCC systems this paper discussed R134a systems, CO2
PHEV and BEV) by comparing energy consumption at various temper­ systems, other working fluid systems, and AC/HP systems as well as
atures to a reference value at 72 ̊F. Their results at 20 ̊F, showed the challenges associated with them. Among non-VCC systems this paper
highest increase in energy consumption (2%–100%) was ensued in cold discussed magnetocaloric effect systems, and thermoelectric effect sys­
climate (due to high powertrain losses) to get powertrain temperature tems. A comparison between the three heat pump technologies shows a
up to operating levels. At 95 ̊F, the increase in energy consumption (2%– variety of advantages and disadvantages related to size, performance
70%) was ensued due to engaging HVAC system to maintain cabin and other criterion as summarized in Table 3. Another review by Zhang
temperature at 72 ̊F. It was presented that these reported losses et al. [32] classified HP/AC systems based on vapor compression
depended on the HVAC system type, powertrain architecture, power­ refrigeration (VCR) used in conventional vehicles into dedicated heater
train capabilities and drive patterns. It was also highlighted that con­ systems (DH) and fuel heater (FH) systems while reversible cycle sys­
trolling for powertrain efficiency would maximize impacts of HVAC tems were classified into HP systems and improved HP systems with
energy loss. In their effort to describe a simplified analytical function for demisting. Non-VCC systems include thermal energy storage systems
estimating energy consumption for electric vehicles, Yuan et al. [150] (TES), thermoelectric (TE) and magnetic effect (ME) systems, waste heat
highlighted major losses and subsequent efficiencies of the charged driven systems (WHD). Integrated thermal management (ITM) systems
energy as well as the regenerative braking energy flow path for an combining AC and BTMS include air cooling, evaporative cooling, and
electric vehicle. Zhang et al. [151] recognized the air conditioning secondary loop cooling. Their paper compared advantages and disad­
system as the largest energy consumer among auxiliary systems of an vantages of different solutions as summarized in Table 4. The drawn
electric vehicle. Their paper studied its total annual energy consumption conclusion was that despite disadvantages of VCR-DH systems (high
and influencing factors across capital cities of 30 provinces in China. The electricity consumption or impracticality issues for fuel-operated
conclusion made was that energy consumption was influenced by the heaters), these systems are widely adopted owing to their limited vari­
geographical location of the city (which would determine its climate) as ations compared to existing systems in conventional ICEVs. Comparably,
well as the intensity of vehicle use within the city. The paper also VCC-HP systems are more energy efficient as well as able to flexibly
showed that heat pump systems are more efficient than simple systems adapt to different EVs making them a more preferred option. Further­
with PTC (Positive Thermal Coefficient) heaters and were most efficient more, the ITM systems are the future of vehicle conditioning and battery
in mid-latitude locations. cooling, but are still in need to overcome challenges such as complex
These studies highlighted various factors impacting the energy structure, and higher requirement on control of the system.
consumption of the electric vehicle. However, factors such as powertrain In an electric vehicle, energy and power demands for heating as well
efficiency, BTMS, HVAC and driving style were found to be widely as the HVAC system are provided exclusively electrically from the bat­
common across most studies. This paper shall review two factors namely tery pack. This could negatively impact the driving range of the vehicle
HVAC and BTMS, as discussed in the next two sub-sections. depending on outside weather conditions. In real-world scenarios
heating load (due to lack of waste heat) and HVAC transient loads are
4.1. Cabin thermal management important contributors to overall energy consumption [164]. Samadani
et al. [165] showed that HVAC energy consumption of a mid-size Sedan
The automotive air conditioning system provides necessary heating, decreased its driving range by 40%, 49% and 53% for an ambient
ventilation, and air conditioning to ensure a comfortable environment in temperature of 8 ̊C, - 2 ̊C and - 12 ̊C. The national renewable energy
the driving cabin and enough visibility (defogging and deicing) for laboratory (NREL) showed that the energy needed for cabin cooling
purposes of driving safety [154–158]. It is designed to mainly regulate loads can reduce PEV range by up to 35%–50% [166]. Fig. 12 shows the
the cabin’s air temperature and humidity to satisfy passenger’s thermal effect of heating on range reduction extracted from a study by Meyer
comfort [159–161]. Cabin thermal management aims primarily to et al. [28]. It is observable that heating always leads to range reduction
minimize energy use without compromising passenger comfort. The due to large energy needs while the severity of impact depends on the
electric vehicle air conditioning system often utilizes a scroll compressor type of heating technology being used. Various technology solutions
in place the reciprocating compressor used in the traditional air condi­ have been explored to reduce energy consumption to increase the
tioning system of ICEVs. This would offer the advantages of lower en­ driving range. Tesla, recommends using seat heaters instead of cabin
ergy consumption and lightweight. In both cases, the automotive air heating to reduce energy consumption for its Model S users [167].
conditioning system typically uses a huge amount of the vehicle’s on­ Thermal energy storage (TES) technology offers another relatively
board energy. Orofino et al. [162] showed that operating the HVAC inexpensive solution to extend the driving range of EVs [32]. Fig. 13
system increased the fuel consumption of a group of ICE vehicles with shows the effects of thermal storage on HVAC energy consumption.
different sizes by 23% up to 41%. Similarly, Torregrosa-Jaime et al. Bellocchi et al. [160] showed that air conditioning can consume up to
noted that the absence of waste heat in an electric vehicle led to cabin 32% of vehicle’s onboard energy which can decrease range to 72 km
heating posing a significant challenge which would negatively impact from a base value of 94 km. However, the introduction of a heat pump
vehicle energy management and subsequently its driving range. Heat reduces energy consumption by 17–52% in heating mode depending on
pump systems have proved to be a significant improvement for EVs due geographical context and decreases driving range loss to about 6%.
to their capability to improve the coefficient of performance (COP)
reducing HVAC energy consumption. HVAC systems that are based on
Table 3
the vapor compression cycle are dominant in the mobile air conditioning
Advantages and disadvantages of various heat pump technologies [43].
domain due to advantages such as convenient replacement, low cost and
easy maintenance. It is also the preferred option for adoption in EVs for HP Technology Advantages Disadvantages

their capability to fulfill the manufacturer’s aspiration for a direct MAGNETOCALORIC Compactness, quiet MCM material, poor COP at
transition from conventional vehicles. In addition to the widely-used EFFECT extreme conditions, complex
design
common vapor compression systems, current technology includes
VAPOR High capacity density, Poor COP under large
other options that can be classified as non-VCC systems such as mag­ COMPRESSION compactness temperature difference,
netocaloric and thermoelectric systems [163]. Qi [158] reviewed ad­ alternative refrigerant issues
vances in air conditioning and heat pump systems for vehicle THERMOELECTRIC Compactness, quiet, no Lower COP, less capacity
applications. The paper by Qi [158] discussed the design and perfor­ EFFECT moving parts or density
working fluid
mance characteristics of the current options of Air Conditioning (AC)

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Table 4
Advantages and disadvantages of various AC systems [32].
AC Systems Advantages Disadvantages

VCR-DH VCR-EH systems Simplicity, reliability, quiet Low heating COP, associated with alternative refrigerant and
SYSTEMS serious driving range issues
VCR-FH systems Simplicity, reliability, and little influence on the driving range Tailpipe emissions
VCC-HP Compactness, compatible with current AC technology, high Poor COP at extreme conditions, range loss at cold temperatures
SYSTEMS capacity density
NON-VCC TES systems High performance and energy-efficient Low energy density
SYSTEMS
TE or ME AC systems Compactness, quiet, easy mode switch Low COP and capacity density, driving range loss
WHE systems Energy efficient Insufficient waste heat for BEV
Solar assisted AC Energy efficiency, ability to recharge the vehicle battery, Intermittent nature of the sun
systems reduction in cooling load
Air cycle HP systems Free working fluid, simplicity and cheapness, environmentally Low heating effect, poor energy efficiency, noisy
friendly
ITM SYSTEMS Air cooling Simplicity, space-saving, low cost Dust deposit, high air mass flow, bad heat transfer performance
Evaporative cooling Compactness, good heat transfer performance Battery descaling, heating the battery is a challenge in winter
Secondary loop Energy efficient Complex system, battery descaling
cooling

day environmental conditions, geographic location, and trip start time.


Their paper also studied trends of increased range due to cabin
pre-conditioning and quantified its predicted increase depending on
geographic location. The presented results showed a strong influence of
local ambient environment conditions on HVAC energy consumption, as
well as a pronounced difference in EV range subject to trip start time and
ambient conditions (95 km–128 km). Cabin pre-conditioning effects are
found to be relatively minor for trips starting in the early portion of the
day due to low contrast between thermal comfort and ambient condi­
tions. On the other hand, trips starting later in the day experience high
thermal “soak” increasing the transient power required to establish
thermal comfort conditions. Meyer et al. [28] investigated various so­
lutions developed and approved by Hanon systems, Hyundai America
technical center, Inc. (HATCI) and the national renewable energy lab­
oratory (NREL) for Kia soul BEV range extension. The research vehicle (a
Kia soul, BEV) is usually equipped with either a PTC heater or an R134a
Fig. 12. Effects of heating on EV driving range [28]. HP using ambient air and waste heat of vehicle components for its heat
source with PTC heater combination [175]. Results demonstrated the
effect of thermal storage (TS) incorporation to be 5%–22% range
extension at ambient temperatures ranging from 5 ̊ C to – 18 ̊ C
respectively.
In 2019, Marshall et al. [154] reviewed vehicle thermal management
focusing on the cabin, electronics (batteries and insulated-gate bipolar
transistors), and exterior components of vehicles. The paper indicated
that the main challenges to the cabin thermal management are related to
the HVAC system with improvement efforts generally focused on two
key areas, namely, minimizing HVAC load by reducing heat absorption
through various technologies (i.e. Surface glazing and tinting and also
photovoltachromic devices) and improving the efficiency of the cooling
system by technologies such as zoned cooling. Furthermore, the paper
also highlighted the difference in handling HVAC improvements for EVs.
For instance, power demands for EVs can be reduced by the imple­
mentation of heat pumps and thermal batteries.
Fig. 13. Effects of thermal storage on HVAC energy consumption [28].

Other methods that are investigated to reduce the energy consumption 4.2. Battery thermal management
of the HVAC system include zonal heating/cooling [168,169],
solar-reflective glazing [170,171] and cabin thermal isolation [172]. Thermal control of the battery pack is one of the main requirements
Cabin pre-conditioning has also been studied as another viable solution of the battery management system (BMS) to prevent undesirable con­
to increase the range of EVs, but its benefits showed a strong dependence sequences. Regardless of the size and various types of EVs for road
on time of the day [173,174]. Generally, it aims to regulate and maintain transport, all of them require a BMS [176]. Broadly, a BMS is any system
the cabin environment during charge time reducing transient power (mechanical, electronic or any possible device or technology) that
requirements. In US, Kambly and Bradley [174] utilized a system-level manages the battery (a single cell, a module or a battery pack)
approach of HVAC energy consumption in EVs and its correlation to rechargeable or non-rechargeable [177,178]. A BMS is typically
transient environmental parameters to develop a model to study and comprised of sensors, multiple algorithm controllers, actuators, signal
simulate effects of various factors impacting driving range such as day to wires and computation algorithms to decide the optimum charge/di­
scharge current characteristics from estimations of SOC and SOH of the

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

battery [39]. Some of its objectives include protection against damage, disadvantages of passive and active systems. Then, the PCM-based
ensuring proper operating range and prolonging battery life cycle. These BTMSs for rectangular and cylindrical batteries were extensively
goals are realized by monitoring the battery, estimating its state, reviewed embracing relevant literature on topics such as synthesis, types
balancing it, reporting data, etc. [179] Thermal control is achieved by and properties of PCMs, and the performance of PCM-based BTMSs. For
the battery thermal management system (BTMS). The BTMS is based on active systems the same paper [182] reviewed the technology of ther­
a variety of conventional and emerging thermal management system moelectric cooler (TEC) and the relevant literature. It also briefly dis­
(TMS) strategies [180]. It performs cooling/heating to keep the tem­ cussed the limitations and challenges of PCM-BTMS and TEC-BTMS. It
perature within the operating range and below a maximum value concluded that the rectangular based PCM-BTMS system slightly out­
pre-specified as a safety limit for different battery chemistry [109–111]. performed their cylindrical based counterpart. Also, a research gap
The BTMS’s desired features include ease of installation, ease of oper­ could be established regarding PCM systems by considering existing
ation and maintenance, lightness of weight and freedom from emissions limitations and challenges such as supercooling, availability, and flam­
of harmful gases [181]. Ambient environment plays an essential role in mability. Their review of TEC based BTMS highlighted a lack of litera­
temperature regulation dynamics, however, dreadful ambient condi­ ture in this area of research since 2003. Smith et al. [183] proposed a
tions (extreme hot or cold temperatures) are impractical to avoid which BTMS system for high power battery of 8 prismatic cells based on heat
presents a key challenge to battery pack temperature regulation and pipe technology. The system was designed of heat extraction module for
thermal management [113–119]. Some of the ways to provide the cell level thermal control, heat dissipation module of liquid cooled cold
necessary thermal management under cold conditions include the wide plates for system level thermal control, and heat transfer module to
utilization of external heating methods in addition to various novel and transfer heat between them. The system was tested for a heat load of up
advanced technologies. For instance, in 2017 Wang et al. [118] reported to 400 W/module and demonstrated satisfactory performance.
a novel Li-ion structure called the “all-climate-battery” (ACB) that can Another classification based on thermal cycle options organizes
-without external heating-heat itself up from sub-freezing temperatures. BTMS systems into VCC systems, non-VCC systems and a hybrid mix of
Results of their study showed the ability of heating this battery to zero both systems. Kim et al. [184] reviewed BTMS systems for EVs in terms
degree Celsius in 20 s and 30 s from – 20 ̊C and – 30 ̊C respectively while of their maximum temperature and maximum temperature difference as
only consuming about 3.8% and 5.5% of the cell capacity respectively. well as discussing an effective design that would complement the dis­
In a subsequent study, the same research group went on to demonstrate advantages of each system. The paper categorized BTMS systems as
the fast charging capability at sub-freezing temperatures that can be shown in Fig. 15 into VCC based systems such as cabin air cooling,
reaped through the use of the same ACB structure for over 500 cycles second-loop liquid cooling, and direct refrigerant two-phase cooling,
without Li plating [129]. For the high-temperature thermal manage­ and non-VCC based systems such as phase change material cooling, heat
ment, Fig. 14 shows some of the various classification methods for TMS pipe cooling, and thermoelectric element cooling. It also showed that
deployed in BTMS designs. Today, a well-known classification based on BTMS systems based on VCC are widely adopted in EVs due to their
power consumption classifies BTMSs into active systems that utilize advantage of utilizing prevailing mobile AC systems. Furthermore, It
additional sources such as liquid flow and forced air to enhance heat discussed the advantages and disadvantages of VCC systems and various
transfer, and passive systems such as heat pipe and phase change ma­ studies related to their performance enhancement.
terials (PCMs). Siddique et al. [182] reviewed some of the promising In 2018, Cen et al. [185] experimentally studied the cooling of a
passive and active BTMSs, and discussed the general advantages and battery pack of BAK 18650 cylindrical Li-ion cells by direct utilization of

Fig. 14. Various classification methods for TMSs deployed in BTMS designs.

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Fig. 15. Various battery cooling systems [184].

AC refrigerant in a fin and tube heat exchanger configuration without cooling when it comes to the huge heat extraction capabilities required
considering applicability to heating or defrost. In their results, the pro­ for high-performance electric vehicles. Studies related to mini channel
posed system showed acceptable thermal control by keeping the pack cold plate cooling include investigating the geometry of the cooling
temperature below 35 ̊ C under high ambient temperature as high as 40 ̊ channel such as those carried out by Jarrett and Kim (2011) [201] and
C. Furthermore, temperature non-uniformity was within 1.5 ̊ C under Jarrett and Kim (2014) [202]. And investigating the number of channels
road drive test conditions and remained below 4 ̊ C under constant and flow direction was researched by Jin et al. (2014) [203], Huo et al.
discharge rate of 1.5 C. Also, configuration of the refrigeration circuit (2015) [204], Zhao et al. (2015) [205], Qian et al. (2016) [206] and Lan
was shown to have a significant impact on temperature non-uniformity et al. (2016) [207]. Commercial vehicles utilize a variety of battery
which inferred potential improvement through further optimization. cooling concepts, e.g. Tesla Model S uses an indirect liquid cooling
Krüger et al. [186] used thermal battery and heat exchanger simulation system, Nissan leaf uses an air cooling system and BMW i3 uses a
models to evaluate the effects of additional cooling demand imposed by refrigeration cooling system. Current BTMS categories are summarized
battery cooling on the refrigeration cycle of a hybrid electric vehicle. in Table 5 in terms of the pros and cons associated with each category.
Their results showed that the energy consumption of the refrigeration Arora et al., 2018 [180] reviewed existing and emerging TMSs with the
cycle was increased by up to 11% depending on weather conditions and goal of identifying prospective candidates for implementation in
drive cycle. Also, in hot weather conditions battery cooling negatively modular architecture of electric vehicles battery pack. Their paper
affects thermal comfort of the passenger as it increases evaporator outlet concluded that a hybrid system of at least two different TMSs would
temperature by 1 K. Classifying BTMS systems according to the working offer a robust modular option for thermally managing the battery pack.
fluid (air, liquid, PCMs, and hybrid systems) would give a broader view It also inferred that the PCM-TMS is a promising candidate to be an
and contrast the performance of each cooling medium regardless of the integral part of the TMS hybrid design considering factors such as
adopted thermal cycle. Air systems offer advantages such as simplicity integration, cost, technical risk, and energy efficiency. Thermoelectric
and low maintenance costs but is limited by disadvantages such as noisy based TMS is another promising candidate due to acceptable COP and
operation and low heat capacity of air [187,188]. It can be subdivided superior state of development.
according to the source of air into three categories: (i) utilizing outside
air, (ii) utilizing outside air plus preconditioned cabin air, and (iii) uti­ 5. Modeling and simulation
lizing cooled air from evaporator [189]. Studies on air cooling investi­
gate the enhancement of various major design variables, namely Behavior and performance of a number of components of previously
geometry of airflow channel investigated by Park (2013) [190], Xu and discussed EV energy systems have been numerically modeled and
He (2013) [191], Sun and Dixon (2014) [192]; cell layout investigated simulated using several open-source/commercial numerical simulation
by Xie et al. (2017) [193], Hong et al. (2018) [194], Fan et al. (2013) software packages. Despite a slight discrepancy with experimental re­
[195], Wang et al. (2014) [196] and Yang et al. (2015) [197]; and sults, the simulation approach is widely adopted in the process of EV
airflow path investigated by Mahamud and Park (2011) [198], Yu et al. development and manufacturing because it offers many advantages such
(2014) [199] and Lu et al. (2016) [200]. Secondary loop liquid cooling as presenting a more comprehensive result (it could estimate the result
(an indirect liquid cooling method) is widely utilized in commercialized of all points unlike that of experimental testing), flexibility (ability to
electric vehicles. It can overcome the drawbacks associated with air investigate multiple variations of a specific design or lab test scheme),

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Table 5
Pros/cons of various BTMS systems [185].
Air-based Indirect liquid Dielectric liquids Refrigeration circuit TEC PCM

General aspects
Ease of use ++ – + + ++ ++
Flexibility of package integration + ++ – + + ++
a
Space needed – – + + o
Weight + – – o + o
Thermal management efficiency
Max. Cooling power – + o ++ – –
Integration of heating + + – +/− ++ +
Conditioning uniformity – + + ++ + ++
Interference with other components o – + – ++ ++
Economic considerations
Initial costs ++ o – – o +
Maintenance efforts + – – – + ++
Lifetime + o o – ++ ++
Eligibility for special use cases
Battery swapping ++ – + – ++ ++
Fast charging – ++ – ++ – +
Extreme climate – + – ++ – +

++ clearly superior + superior o neutral - inferior – clearly inferior.


a
Only as a secondary system assisting the main thermal management.

internal insight (ability to estimate e.g. core temperature of the battery


Table 6
cell), and time/cost saving (reduced number of physical models manu­
Comparison between model types [209].
factured for testing). Next and within this context, this paper will discuss
numerical modeling and simulation of battery cell and battery pack Model Accuracy Complexity Physical Suited
interpretability application
(simulating electric and thermal behavior as well as TMS performance),
and total EV simulation (related to total energy consumption and range Physical Very High (>50 High Battery system
high parameters) design
estimation).
+++ – ++
Empirical Medium Low (2–3 Low Predictions of
5.1. Modeling parameters) lifetime and
– – – efficiency
Abstract Medium Medium to low Limited to Real-time
The battery cell can be modeled to investigate its behavior and (2 up to 30 acceptable monitoring and
response during charge/discharge process as well as estimating values parameters) diagnosis
descriptive of the battery cell/pack present operating states such as state – + +
of charge (SOC) and instantaneous available power in addition to other
quantities. The estimation procedure of such quantities must be able to
low level (micro-scale) structural details and associated electrochemical
adapt to the change in cell/pack characteristics that are incurred during
phenomena of the battery cell (thermodynamics, active species kinetics
operation. Battery models can be categorized into various groups ac­
and transport phenomena) which enables them to offer significant
cording to criteria such as the perspective of modeling, depth of
analytical insight as well as producing the highest predictive accuracy
modeling, modeling approach and time scale of the modeling process.
among all model types [40,210]. The main disadvantage of these models
The different perspective of modeling gives rise to electrochemical
is the huge number of parameters involved (sometimes more than 50
models, thermal models, electrical models, mechanical models, molec­
parameters such as diffusion coefficients and other material related
ular models and a combination of interdisciplinary models e.g. electro-
characteristics), and the sizable configuration effort required to estab­
thermal models. The different level (depth) of modeling gives rise to
lish the physical model [209,211]. For Li-ion batteries, the
system-level models, pack level models, stack and module-level models,
physics-based approaches available to generate battery models include
full cell models, half-cell models and material level models. The various
molecular-scale partial differential equations (PDEs), micro-scale (par­
modeling techniques give rise to physical-based models, empirical
ticle-scale) PDEs, continuum cell-scale PDEs (obtained by volume
models, analytical or mathematical models and hybrid models. Models
averaging of particle scale PDEs) and cell scale ordinary differential
that vary according to their time scale include short term models that are
equations (ODEs) obtained via model order reduction. Current electro­
useful for the dynamic behavior of the cell and partial charge and
chemical models include a number of models established from the P2D
discharge. Also, medium-term models that can be used for full-cycle
(pseudo-two-dimensional) model firstly presented by Newman’s group
modeling and finally long term models applied to multiple cycles and
based on electrochemical kinetics and the theories of the porous elec­
complete lifetime analysis [208]. Saidani et al. reviewed battery models
trode and concentrated solution as well as general conservation laws of
available in literature by grouping them into physical models, empirical
charge, mass, and energy [42,212]. In 2013, Fang et al. [213] developed
models and abstract models [209]. These three types offer a wide range
and validated an electrochemical-thermal model for LiFePO4/graphite
of accuracy (how close is the model’s result to the correct value),
battery describing several charge/discharge related heat phenomenon
complexity (according to the number of variables involved in the model,
such as entropic heat, joule heat, ionic migration heat. Li et al. (2018)
which would affect simulation time/resources and real-time applica­
[214] developed and investigated an electrochemical-thermal coupled
bility), and physical interpretability (analytical insight provided by the
model for LiFePO4/graphene hybrid cathode lithium-ion batteries.
model). These models are usually coupled to an appropriate thermal
However, recent advances in contemporary computing power made it
model (selected expressions for heat generation, energy balance and
realistic for researchers such as Song et al. [215] and Xu et al. [216] to
thermal boundary conditions) to investigate the thermal and heat
develop and investigate higher-order (3D) electrochemical based
transfer behavior of battery cell or battery pack. A comparison between
models.
all three types of models is summarized in Table 6.
Empirical models (also known as black boxes) are based on empirical
Physical models (also known as white boxes) are concerned with the

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

parameters that often have no physical meaning and offer no valuable an unscented Kalman filter (UKF) algorithm and used it to estimate the
insight into the system [210,217]. The mathematical approach used to battery SOC. Their model accounts for impacts on the battery internal
develop the function transferring inputs into outputs is what facilitates resistance due to different/C-rates and SOCs, as well as impacts on the
the quick response in predictions of such models as well as their ease of battery capacity due to different temperatures and C-rates. Their work
configuration. Generally, these models have limited accuracy especially compared model results to experimental data and showed that their
for oversimplified cases but could experience further enhancement if proposed model can simultaneously ease computational cost and
combined with physical-based models [217]. However, more sophisti­ improve SOC estimation. Fig. 17 depicts (a) terminal voltage and (b)
cated empirical models such as those based on stochastic models have maximum error and it shows that their presented model can adequately
shown improved performance and ability to deliver better battery simulate the battery’s terminal voltage with a maximum error less than
parameter results. For instance, stochastic models in the microstructure 3%. Fig. 18 shows the model simulation of SOC and subsequent pre­
domain can be fitted to real tomographic image data and used to diction error.
generate virtual 3D microstructures which would help to overcome is­ Baccouche et al. [230] reviewed various model-based SOC estima­
sues of high-cost imaging and low sensibility [218–221]. Hein et al. tion approaches for NMC batteries at 25 ◦ C that utilize various OCV and
[222] used 3D virtual images generated by the stochastic model and 3D ECM models. The reviewed ECM battery models included several 1st
real images of anode microstructure to investigate differences between order models and a single 2nd order ECM model. The OCV models
various electrochemical quantities. These differences were found to be covered a variety of models that include linear, exponential, and poly­
negligible at low currents while a more pronounced effect for small nomial while SOC estimation algorithms included among others the
differences was identified at large currents. Also, their qualitative and extended Kalman filter (EKF) and PI observer. This paper also proposed
quantitative analysis indicated comparable behavior of real and virtual a model for OCV estimation that was integrated with the 1st order ECM
structures under simulation. Westhoff et al. [223] presented a para­ model and EKF for SOC estimation. It compared the performance of the
metric stochastic 3D microstructure model to simulate the morphology suggested model to other reviewed models as depicted in Fig. 19 and
of battery cell anodes. In Refs. [223–226], the researchers used models concluded that this OCV model presents the best compromise and it has
from contemporary publications to propose a significantly simplified reduced computation and memory cost by utilizing simplified functions
framework for modeling 3D microstructure of battery electrodes while and only five coefficients for computations. It showed a reliable fit with
providing a decent fit to tomographic image data for several kinds of experimental data (RMSE is about 0.01V) and the best SOC estimation
electrodes [223–226]. Fig. 16 shows the 3D visualizations of (a) cutout precision (error is less than 3%). All of which prompted its applicability
from tomographic image data and (b) model realization for the power in BMS of electric vehicles for online SOC estimation. The paper sug­
cell anode. Comparison of characteristics of tomographic image data gested as well its model to be validated at temperatures other than 25 ◦ C
and corresponding model realizations showed small differences in vol­ to further prove its reliability.
ume fraction, specific surface area, mean sphericity, specific integral of
mean curvature and specific Euler characteristic.
Abstract models (also known as grey boxes) are somewhere between
white and black box models. Abstract models provide an equivalent/
alternative but dissimilar representation of the physical phenomena
[210]. Among the various possible forms of abstract models, equivalent
circuit models (ECM) that replaces complex electrochemical processes
by simple electrical circuit representations remain the more popular
choice due to conservation of the correlation with battery dynamics and
other advantages such as simplicity, practicality and adequate accuracy
[227]. Furthermore, abstract models also have a reduced configuration
cost, but still require a calibration scheme to compute model’s circuit
parameter values from experimental data (e.g. lookup-tables that are
used to calculate the OCV as a function of SOC for most ECM model
types). ECM has been used to describe and investigate various processes
that take place during a battery cell operation (charge/discharge elec­
trical response, thermal behavior, etc.) as well as estimating a number of
important quantities such as (SOC, SOH, etc.). Dubarry et al. [228]
established the positive impact of the accurate estimation of parameters
of the cell ECM model on the modeling of the battery pack performance.
Lu et al. [127] discussed many algorithms utilized for estimation of SOC,
SOH and other parameters. Among integrated algorithms for SOC esti­
mation which utilizes two or more classic SOC estimation algorithms,
namely simple correction, weighted fusion in addition to Kalman
filtering (or extended Kalman filtering, EKF). All of which can be com­
bined with several ECM-models that may or may not include hysteresis
voltages. Tian et al. [229] presented a modified ECM model enhanced by

Fig. 16. Tomographic image and model realization of cell anode [224]. Fig. 17. Terminal voltage [229].

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

[233]. Vehicle modeling can be accomplished by either developing a


vehicle analytical model to simulate electrical parameters based on ki­
nematic and dynamic requirements (backward modeling) utilizing
instantaneous acceleration, speed, road grade, friction, and rolling
resistance coefficients or following a statistical approach based on
measurements of the EV consumption either from real-world data or test
cycles [234–239]. The common backward models include the prevalent
VSP model that calculates the mass-specific power required at the
vehicle wheels, in addition to the Virginia Tech Comprehensive
Power-based EV Energy consumption Model (VT-CPEM model) which
calculates a non-mass-specific vehicle power with minor differences
between them in terms of adopted parameters by each model such as
acceleration, wind velocity [240]. Fiori et al. [241] developed a model
to estimate the instantaneous energy consumption as well as instanta­
neous regenerative braking energy of EVs using second-by-second
vehicle speed, acceleration and roadway grade data as input variables.
Their results demonstrated an accurate estimation of energy consump­
tion producing an average error of 5.9% relative to experimental data.
This model can be used in many applications such as smartphone
eco-driving and transportation simulation to quantify fleet energy con­
sumption. Wu et al. [232] proposed an analytical model for power
consumption estimation in real-time and its relationship to vehicle
speed, acceleration and roadway grade (angle of inclination). The pro­
posed model was validated using data collected from a test vehicle
Fig. 18. SOC estimation [229].
through a system designed to collect in-use data such as SOC, current,
voltage, pack power, velocity, acceleration, and vehicle position (lati­
On the other hand, modeling the whole electric vehicle can be used tude, longitude, and elevation). Results showed that this model can
to estimate overall energy consumption as well as instantaneous energy successfully estimate EV instantaneous power consumption and trip
consumption (power consumption) under various driving conditions energy consumption. Zhang et al. [233] developed an extended version
and identify influencing factors. Overall energy consumption can be of a VSP based mesoscopic model to calculate EV energy consumption
estimated using statistical data distributions (often detached from under real-world driving conditions while taking into account regener­
vehicle dynamics and drivetrain behavior), but instantaneous energy ative braking and analyzing energy consumption characteristics and
consumption would better be estimated using analytical models (linked mechanical dynamics from physical and statistical standpoints. Zhang
to drivetrain performance) to minimize computation time as well as et al. [242] developed a physics based model for the purpose of
allowing for a more confident identification of drivetrain parameters analyzing a mid-size electric vehicle energy consumption and then dis­
and their influences on energy consumption [231,232]. A simple way to cussed and evaluated influences on energy consumption and energy
evaluate the vehicle’s energy consumption and its relevant character­ intensity imposed by factors such as ambient temperature and average
istics is through the use of macroscopic models such as EMFAC, mobile driving speed. Yuan et al. [150] derived a simple linear binary function
and its future replacement moves that are based on a few input pa­ from a physical-based statistical model for estimating energy con­
rameters. More sophisticated options include the higher predictive sumption for EVs by using relationship between driving cycle and
precision microscopic models such as CMEM and VT-MICRO models vehicle parameters. Their results showed that the model perfectly rep­
which demand a huge number of input parameters, or the use of resented the energy consumption of electric vehicles under different
mesoscopic models that require a moderate number of input parameters driving conditions.
but offer moderate predictive precision such as VT-MESO and measure

Fig. 19. Comparison of various estimation models [230].

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Nowadays, the ECM models are widely adopted in research related to for every state of charge, and ignoring it would muddle SOC modeling
electric vehicles, e.g. battery research and EV energy consumption. and cause significant prediction errors. Mathematically, overall hyster­
These models play a key role in the multi-level simplification of the esis can be represented as a sum of two terms for instantaneous and
modeling and simulation of associated processes and operation dy­ dynamic hysteresis. The ESC model developed by Plett [244] is a
namics as well as the estimation of a number of the various key pa­ comprehensive representation of the battery cell comparable to the 1st
rameters for the purpose of design enhancement or real-time monitoring order RC model and includes the effects of hysteresis in addition to
and control. This multi-level simplification can be achieved due to the Ohmic resistance and diffusion voltages plus some extra functions for
various fidelity levels characterizing the ECM model types. The low pass filters of current. These filters would further improve modeling
following of this sub-section will further unpack the ECM model. accuracy. However, overall hysteresis with no additional filters can be
Generally, for the Li-ion battery cell the various ECM model types added to typical RC model types of various fidelities such as 1st order
can be used to represent static performance without hysteresis being [252–254], 2nd order [250], 3rd order [255] to minimize prediction
considered and dynamic performance considering hysteresis. In 2012, errors, especially when modeling LFP cells that are significantly affected
Hu et al. [243] reviewed a selected 12 types of reported state-of-the-art by hysteresis. In a series of three papers, Plett used an extended Kalman
ECM models for two types of Li-ion batteries, LFP and NMC. The filtering (EKF) and presented a method to estimate various present
simplest ECM model that can be used to describe the dynamics of a battery parameters including SOC and capacity fade for a lithium-ion
battery cell under time-variant input current is the internal resistance polymer battery pack. This method was also expected to be useful for
“R-int” model. This model is composed of a constant voltage source and other Li-ion chemistries. The topics discussed within these papers
an internal resistance (Ohmic resistance) connected in series to simulate include the required mathematical background, cell modeling and sys­
the polarization of the cell discharge voltage. In this model, the modeled tem identification requirements, and the final solution, together with
voltage is the difference between the open-circuit voltage as a function published results. The first paper discussed the necessary mathematical
of the state of charge and the voltage drop across the internal resistance background and presented the basic method in a way to help generate
[244]. The R-int model does not consider the voltage diffusion process some intuitive feel to the necessary computational steps and also illus­
that takes place after each discharge step. This limits its applicability to trative examples showing types of results obtained by EKF [256]. The
only simple electronics. A more suitable model for the large-scale bat­ second paper [244] evolved a suitable model from cell cycling tests
tery pack applications would be the 1st order RC model, also known as under various temperatures. During this process, two types of cell tests
the Thevenin model. The RC model configuration connects a single were performed. The first type comprised a sequence of constant-current
resistor-capacitor sub-branch in series to the voltage source and the discharge pulses and rests followed by a sequence of constant-current
internal resistance [228,245,246]. The model’s fidelity can be enhanced charge pulses and rests, starting from a fully charged cell as shown in
by increasing the number of RC sub-branches giving rise to variations Fig. 23. The second test was a sequence of 16 urban dynamometer
such as 2nd order [247–249] and 3rd order [250] RC models. Fig. 20 driving schedule (UDDS) cycles, separated by 40A discharge pulses and
shows the R-int model, RC model and the enhanced-self-correcting 5 min rests, and spread over the 90–10% SOC range as shown in Fig. 24.
(ESC) model. The evolved ESC model included terms that describe the dynamic con­
Johnson et al. [251] summarized the battery modeling capabilities of tributions due to open-circuit voltage, Ohmic loss, polarization time
ADVISOR. Their work compared/validated the R-int model and 1st constants, electro-chemical hysteresis, and the effects of temperature.
order RC model for the SAFT 6 Ah Li-ion battery over fifteen 100 s Also, a comparison was conducted between combined model, simple
US06-derived power cycles. Voltage results for one cycle as shown in model, two hysteresis models and two ESC models with different filters.
Fig. 21 indicated the superior performance of the RC model to the R-int Voltage results of pulsed-current tests are shown in Fig. 26 while Fig. 25
model with a maximum error of 1% and 7% respectively. SOC com­ shows results from one cycle of the UDDS test. Pulsed-current results
parison/validation for 15 cycles in Fig. 22 shows little contrast between showed significant improvement in estimation performance by addition
various methods for the initial cycles (e.g. <200 s) but after that it is the of filter states but the paper stated that not much improvement was
RC model that shows a better fit to experimental SOC. noted by increasing the number of filters beyond 4. UDDS test results
Ideally, if the cell is left to rest long enough diffusion voltages would showed that the ESC model with 4 filter states has the best fit to true
decay to zero which means that model voltage would decay to a voltage curves compared to 2 filter states and other ECM model types.
particular OCV value. In a real battery cell, hysteresis would result in a The third paper discussed applications where results from EKF can be
stable range of values of open-circuit voltage -instead of a single value- used in typical BMS algorithms [257].
Another common ECM model is the PNGV model developed by the
PNGV team (standard model for “PNGV battery test manual” in 2001
and “freedom car battery test manual” in 2003) and also adopted in
PNGV systems analysis toolkit (PSAT 4.1) [255,258]. Also, there is the
Randles circuit that is inspired by electrochemical principles. The model
is composed of an internal resistance (Rint) to model the electrolyte
resistance, an RC branch resistance (Rct) to model the charge transfer
resistance, a double layer capacitor to model the charge building up in
the electrolyte at the electrode surface, and a frequency-dependent
Warburg element (Warburg impedance Zw) to model the diffusion of
lithium ions in electrodes. This Warburg element has many mathemat­
ical expressions but its effect can be approximated by multiple RC
branches connected in series. At intermediate frequencies, the Randles
circuit would collapse into the typical RC model by substituting the
double-layer capacitor by a typical capacitor, and the Warburg element
by an adequate number of RC branches. This simplification can be
initiated because of the insignificance of impact on the circuit perfor­
mance of the double-layer capacitor at such frequencies, and the
dominant effect of charge transfer dynamics on voltage diffusion [259].

Fig. 20. Various ECM types.

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Fig. 21. Voltage estimation of RC and R-int models [251].

investigate the behavior and performance of such systems. It is one of


the main targets of simulation to investigate heat generation and
transport within an individual battery cell as well as the battery pack
and its thermal management system, because of the huge significance of
thermal balance and temperature regulation for the Li-ion based energy
storage systems. In a battery cell, heat is generated through five mech­
anisms, namely, entropy change and “electrical” resistance in both
electrodes, and electrolyte resistance, which are all encapsulated within
the thermal model as reversible heat (also known as entropic heat) and
irreversible heat that includes active polarization heat and Ohmic heat
(also known as Joule heat) [46,260,261]. It is worth noting that except
for very low current (i.e. C/5 or lower), the cell current remains the main
influential operation variable for heat generation within a given battery
cell. Today, the thermal model can be coupled to different ECM model
types to simulate and perform various studies under several operating
and loading conditions comparable to that of the real electric vehicle.
Published drive cycles -whether as industry benchmark or for research
purposes-are used to stimulate the battery cell/pack to simulate the
transient performance (transient drive cycles that are characterized by
Fig. 22. SOC estimation of RC and R-int models [251]. many speed changes) or the non-transient performance (modal driving
cycles that involve prolonged spans of constant speed) [262]. Generally,
5.2. Simulation and simulation resources drive cycles are a sequence of points representing the relationship be­
tween vehicle speed and time. Drive cycles are established to assess the
Numerical models related to components of the electric vehicle en­ vehicle performance (i.e. efficiency and fuel consumption) and are
either generated based on practical tests or have some theoretical basis.
ergy system are employed in commercial or open-source simulation
software packages such as ANSYS-FLUENT, MATLAB, OCTAVE to Popular drive cycles include NEDC and ECE15 originated in Europe,
FTP, UDDS, and LA92 originated in the US, and 10–15 mode and JC08

Fig. 23. Pulsed-current test results [244].

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Fig. 24. UDDS test results [244].

originated in Japan [63]. Parameter identification through the least model, fundamental lead-acid model and the saber’s lead-acid electrical
square method is an important stage in the simulation of different bat­ RC model which is not based on MATLAB but can be linked to ADVISOR.
tery models. It is used to estimate values of the various parameters of the These models represented a variety of chemistries and approaches
selected simulation model by utilizing data from battery identification (electrical representation, neural networks, etc.). Total electric vehicle
experiments that are carried out in special testing platforms (e.g. ARBIN simulation can be used to evaluate energy flow and losses across the
BT2000) according to predefined testing procedures (e.g. USABC or various components of many vehicle types as well as corresponding
freedom-car battery test manual) [263]. emissions. For this type of simulation, several programs have been
Battery related simulations can be conducted using commercial developed such as ADVISOR (vehicle simulator for ICEV, HEV, EV, and
software packages such as ANSYS FLUENT or MATLAB or free software FCV developed in MATLAB environment by the NREL and some other
packages such as OCTAVE, DUALFOIL (developed by Purdue University) similar programs developed on various programing environments
or MODOLICA and DYMOLA engine. Modelica is a non-proprietary [269]. For instance, Butler et al. [270] discussed a simulation package
modeling language that offers greater flexibility in modeling battery (V-ELPH) for EV and HEV containing electric motor, ICE, batteries and
pack performance. It is a multi-domain-object-oriented language that support components; the package was developed at Texas A&M Uni­
includes integrated packages for thermal models of the battery pack and versity using the Simulink/MATLAB graphical simulation language.
components of the thermal management system in its TIL-suite (version Mierlo et al. [271] presented a vehicle simulation program (VSP) for EV,
3.4.1.) Library for thermo-fluid dynamic applications [264] and Dymola HEV, ICEV and FCV that aims to contrast different drivetrain technol­
(version 2015fd01) is the development environment that can be used to ogies based on corresponding losses, energy consumption and emissions
build, compile, run and simulate Modelica models to solve the model by studying drivetrain power flows. The VSP was developed on LabView
equations. Martín-Martín et al. [265] presented a system-level model to environment but authors indicated that it could be developed on
assess the thermal performance of a full electric minibus operated in two Simulink/MATLAB. Other research efforts related to energy consump­
modes: free cooling and active cooling. Dubarry et al. [227] used tion and range extension of electric vehicles included the use of
Modelica and Dymola to simulate their developed equivalent circuit ADVISOR and AMESIM (a commercial tool for automotive design that
model for a single cell up to battery pack simulation. Bellocchi et al. offers a system-level multi-physics approach) to simulate the dynamic
[160] used Modelica to set a dynamic model to analyze a reversible heat behavior of HVAC system and its energy consumption by Faruque et al.
pump HVAC system equipped with a regenerative heat exchanger to [272–274].
assess air conditioning loads and subsequent effects on driving range.
According to MATHWROKS, its main software MATLAB is increasingly 5.3. Case study: thermal modeling and simulation of Li-ion cells
adopted by EV manufacturers and battery researchers for tasks such as
battery characterization, SOC estimation, degradation and real-time A case study is prepared and presented here to portray a compre­
simulation. This is because of their continuous effort to relatively hensive view of the thermal modeling and simulation of the Li-ion cells
simplify the configuration and simulation process by developing the using the equivalent circuit model. Here the discussion examines a
SimScape-Simulink platform. In 2009, Plett of the University of Colo­ recently published paper [275] to demonstrate the coupling of ECM with
rado and Jackey of MATHWROKS company presented a semi-automated a thermal model to simulate the thermal performance of an individual
parameterization process to calculate parameter values for the ESC cell as well as a battery stack. This published paper presents a combined
model using Simulink parameter estimation tool. Simulation results of a electro-thermal state-space model that can be used to estimate the core
number of UDDS based cycles displayed satisfactory performance with as well as the surface temperature of a battery cell or a battery stack. The
around 1% error in voltage prediction [266]. Dagmar et al. [267] pre­ state-space model is a convenient way to estimate the dynamic response
sented a Simulink based model of two parts to simulate overall battery of its state parameters. Further information on the development of a
capacity and transient response for lib hybrid power system on utilizing state-space ECM model can be found in the equivalent circuit modeling
a completely automated approach. Daowd et al. [268] developed a new textbook authored by Plett [176]. In this book the author provides a
method for parameter estimation for three models, Thevenin model, detailed discussion, derivation and code samples (MATALB and
second-order ECM model and PNGV model, based on Simu­ OCTAVE) of the equivalent circuit model. The book is initiated by dis­
link/MATLAB parameter estimation tool. Their results indicated the cussing the BMS systems requirements, then it discusses - in separate
accuracy of the Simulink parameter estimation tool and its validity for chapters-simulation of a battery pack in addition to estimation of SOC
all three models’ parameter estimation. Johnson [251] summarized the (considering a state-space approach), SOH in and cell balancing. The
capabilities of the MATLAB based ADVISOR for battery modeling and published paper [275] examined here presented a coupled
simulation. Their paper presented 6 models available in ADVISOR, electro-thermal state-space model that has the terminal voltage, the core
namely, R-int model, RC model, PNGV model, lead-acid neural network temperature and the surface temperature as state parameters. For this

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Fig. 25. Result of one cycle of UDDS test [244].

case study, the discussion is set-up to take an evolutionary route from branch (U1) minus the voltage drop across the internal resistor (UR= R0 x
the electrical model (1st order R–C model) and the thermal model then I). Then differentiating this equation yields the general frame for the
combining them into the electro-thermal model for a single cylindrical output equation described earlier. The dynamic equation is the corner­
cell before eventually introducing the combined model for the battery stone on which the ECM model is built. It provides a significant
stack as well as a concluding summary. improvement on the most basic representation of the battery cell as an
ideal voltage source and describes the dynamic response of the terminal
5.3.1. The electrical model for the single cylindrical battery cell voltage in terms of the source voltage and a sum of various voltage drops
A lower resolution description of the ECM model utilized in the paper between the source and the terminal. This paper assumes constant
examined here can be expressed as follows. The model estimates the values for the resistor (R) and the current (I) within the dynamic
instantaneous terminal voltage (U̇t) as the difference between the equation. For that, the voltage drop across the internal resistor (R0)
instantaneous open-circuit voltage ( U̇oc ) and the instantaneous voltage plays no role in the output equation. The assumption of constant resis­
drop across the R–C branch ( U̇1 ). This can be referred to as the output tance and electrical current can be used to simplify the derivation and
equation. This equation can be reached after deriving the dynamic construction of the ECM model. It can limit the number of variables to be
equation of the terminal voltage (Ut) to be equal to the source voltage simulated which would reduce simulation cost. A higher-resolution
“open-circuit voltage” (Uoc) minus the voltage drop across the R–C description that would zoom into the details of the terms constituting

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

Fig. 26. Result for pulsed current test [244].

the previously described output equation can be expressed as follows. assumes for the radial direction a uniform heat generation rate and
For the open-circuit voltage the paper adopted a mathematical expres­ models the thermal dynamics along that direction by assuming (i) no
sion to estimate the open-circuit voltage (Uoc) value corresponding to heat flux at the center and (ii) the heat generation takes place at the core
the different SOC values. For the different SOC values, the paper used of the cylindrical cell. Then it develops a dual-state approximation of the
the Coulombic counting method. Then a new expression was developed thermal model in the radial direction in terms of (Tc and Ts) since the
to estimate the voltage drop across the R–C branch (U1) in terms of SOC. temperature distribution along the longitudinal direction is assumed to
All these terms were differentiated and substituted back into the output be more uniform due to the higher thermal conductivity in this direc­
equation to yield an expression for the instantaneous terminal voltage tion. This last assumption is widely used and can simplify the simulation
with various terms that contain a non-linear function of SOC. This non- process by reducing the model from 3D to 1D model without greatly
linear term would, later on, be incorporated into the state-space of the compromising the model’s prediction accuracy. The heat generation
combined electro-thermal model. equation normally accounts for the reversible (entropic heat) and irre­
versible (Joule heat) heat terms. It is worth noting that there is a widely
5.3.2. The thermal model for a single cylindrical battery cell accepted notion that entropic heat can be neglected without compro­
Heat is generated whenever a battery cell is being charged or dis­ mising the prediction accuracy at high current values. In such a case, the
charged. The thermal model used to describe this behavior is generally a heat generation equation would include only the Joule heat which is
selection of expressions for (i) the energy balance equation, (ii) the heat equal to the product of the square of the electrical current value and the
generation equation and (iii) the boundary conditions equation. The internal resistance value of the battery cell. Additional discussion on the
paper used a thermal model that balanced heat energy between three thermal model can be found in the review published by Liu et al. [97].
distinct temperatures for the core, surface and the ambient environment The paper examined here [275] approximated the heat generation as the
(Tc, Ts, Ta) with two thermal resistances, one between (Tc and Ts) and the product of squared electrical current (I) and the lumped resistance (Rd).
other between (Ts and Ta). For the boundary conditions the paper The lumped resistance was calculated as the sum of all resistances in the

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

1st order ECM model, namely the resistance from the R–C branch(R1) both an individual cell as well as a battery stack. Likewise, another
and the internal resistance (R0) for different ambient temperature parameterization process is used to estimate the parameters of the
values. thermal model from experimental data. The paper examined [275] used
a parameterized electro-thermal model to investigate the behavior of an
5.3.3. Combined electro-thermal model for the single cylindrical battery cell individual battery cell as well as a battery stack. The conclusion put
and the battery stack forward by the paper highlighted an independence of OCV from the
The combined model used in this paper [275] was established by effects of ambient temperatures at SOC between 0.3 and 0.95 at 5 ̊C and
coupling together the previously derived electrical and thermal models. 15 ̊C for the individual battery cell. It also showed the degree to which
The state vector of the model contains three parameters, namely ter­ the convection resistance and core heat capacity influenced variations of
minal voltage, core temperature and surface temperature. The input core and surface temperature of the cell in both transient and
vector contains values for electrical current, SOC, heat generation and steady-state. For the battery stack, the paper showed that the higher
the ambient temperature. For the single cell, the output equation is a conductive heat transfer that occurs in a battery stack promotes battery
scaled-state-vector while the state equation is the sum of (i) the state cells to exhibit slightly lower core and surface temperatures.
vector scaled by a matrix derived from thermal characteristics (resis­
tance and heat capacitance), (ii) the input vector scaled by a matrix 6. Concluding remarks
derived from electrical characteristics (R0, R1 & C values) and (iii) the
non-linear SOC expression obtained when deriving the electrical model. Nowadays, transportation plays a key role in contemporary societies
In this coupled model, the electrical model uses the load current (I) and and it is of great importance to investigate practical technology reso­
the electrical model parameters (R0, R1 & C) to compute the terminal lutions to manage some of the fundamental challenges facing this sector
voltage, the open-circuit-voltage and the state of charge. while the such as energy demand and global warming. Road Transport was
thermal model uses the heat generation (computed from the electrical responsible for around 80% of air pollution and almost a quarter of the
current and the lumped resistance Rd) and the ambient temperature to global GHG emissions with light trucks and automobiles bearing about
compute the core and surface temperatures. The surface temperature is 60% of this quota. Current technology offers a variety of means to go
then used to update the temperature-dependent parameters of the about overcoming transportation challenges through paths like
electrical model. For the battery stack, the paper assumes (i) similar heat enhanced designs for ICEVs to meet current strict environmental regu­
generation for each cell in series, (ii) constant core temperature for each lations or by the development of the battery electric vehicle. To balance
cell, (iii) small difference in surface temperature between any two anthropogenic effects on global warming and mitigate related risks to
neighboring cells. It then conducted an energy balance for the individual human life IPCC introduced a mitigation path that was predicted largely
battery cell due to conduction and convection under constant heat on electrification of the transportation sector. There is an increasing
generation and yielded a mathematical expression for the temperature trend of picking electric vehicles as a means of commute in a number of
gain factor (ΔK) in terms of the convective and conduction heat transfer countries due to strategic policies adopting the Paris agreement on
coefficients, the radius of the battery cell and some other parameters. climate change to stabilize global GHG emissions. The development of
This gain factor is then used to compute surface temperature for all cells the various electric vehicle types can be attributed to the technological
in the battery stack. When doing this calculation, the paper assumed that leap in energy storage systems especially rechargeable batteries. These
the surface temperature of cell #1 became the ambient temperature for batteries have various characteristics such as capacity and discharge rate
cell #2. which makes them suitable for different types of EVs. Long-range battery
electric vehicles have been shown to no longer be a niche market and
5.3.4. Parameterization various manufacturers have been announcing production plans to in­
After developing the ECM model in the manner described above or in crease their electric vehicle share of total sales. Battery electric vehicles
any other manner there is a parametrization process to estimate the have a life cost per km comparable and sometimes even lower to that of
model parameters. This process requires the collection of experimental ICEVs with room for improvements through the development of more
data. For instance, a battery cycling platform such as ARBIN-BT2000 is durable EVs, reduction in battery costs and adoption of large-scale
often used to collect electrical data necessary to estimate the electrical economies similar to that of ICEVs. This price gap is likely to undergo
model parameters of the selected ECM model. The Voltage data obtained further changes due to technological advances leading to cheaper bat­
from such cycling platforms can be used to estimate internal resistance teries and an accompanying increase in ICEVs price due to tightened fuel
R0 by applying Ohm’s law to the instantaneous voltage jump while R1 efficiency standards.
and C parameters can be estimated from the voltage transient during The energy system of an EV can be subdivided into two main cate­
relaxation. This paper [275] used the approach to determine R0, R1 and gories as an energy storage system and an energy consumption system.
C in a repeated manner until the terminal voltage reached cut-off voltage There are many technologies suitable for electric vehicle energy storage
under a controlled ambient temperature condition and also accounted systems but the rechargeable battery remains at the forefront of such
for hysteresis voltages by taking the average between charge and options. The current long-range battery-electric vehicle mostly utilizes
discharge voltages. For the thermal model, surface and ambient tem­ lithium-ion batteries in its energy storage system until other efficient
peratures as well as load current can be used to estimate the parameters battery options prove their practicality to be used in EVs. Current
of the thermal model. The ambient temperature control is normally commercialized lithium-ion batteries have many characteristics that are
achieved in a climatic chamber and surface temperature can be favorable for vehicle applications such as energy capacity, operating
measured using a thermocouple. voltage and specific energy but also come with designated challenges
related to heat generation and thermal management. Such cells also
5.3.5. Closing notes have a relatively expensive cost per kW*hr. However, this cost is ex­
The ECM model can be used to solely simulate the electrical per­ pected to experience further decrease when having access to large scale
formance of the battery cell. The simulation approach of the ECM model manufacturing (Giga-factories). New generation batteries aim to
relies on writing computer codes using experimental data from validated improve energy density through various paths such as the use of new
literature or laboratory tests to “ballpark” and optimize circuit- electrolytes, multiple lithium insertion cathodes or utilizing conversion
parameter values for a selected Li-ion chemistry so that the model chemistry rather than intercalation chemistry. New generation battery
behavior in terms of its current and voltage closely resembles that of the cells are estimated to have significantly higher specific energy which
true cell. The ECM model can also be coupled with a thermal model to could have a significant impact on electric vehicles once commercial­
attain the additional capability of simulating the thermal performance of ized. Battery packs for electric vehicles are mostly designed from lithium

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A. Ibrahim and F. Jiang Renewable and Sustainable Energy Reviews 144 (2021) 111049

cells with carbon-based negative electrodes. However, the emerging use valued information pertaining to a variety of R&D objectives. This
of LTO negative electrodes can offer better fast charging performance. contrast in the accuracy/interpretability gives rise to various uses and
These packs are not only required to be kept within a specific temper­ applications suitable for each type of these battery models. High-
ature range but also to avoid temperature mal-distribution greater than resolution battery models (i.e. physical models) can simulate low-level
5 ̊C. behavior and can aid in further developments of the design of the bat­
The battery-electric vehicle demonstrated the lowest energy con­ tery cell, while low-resolution battery models (i.e. abstract models) can
sumption per distance traveled when compared to other vehicle tech­ be used to estimate driving range and other vehicle design calculations
nologies while their CO2 emissions when calculated assuming a UK grid as well as real-time monitoring. Modeling of the electric vehicle can
average emission factor of 542 g CO2/kWh were found to be 70–110 g facilitate estimation of overall energy consumption which can be
CO2/km which was below the majority of diesel vehicles emissions computed using statistical data and instantaneous energy consumption
which surpassed 110 g CO2/km. EVs were found to be able to offer a which is better computed using analytical models simulating electrical
reduction of up to 75% in the tank to wheel energy consumption which parameters based on kinematic and dynamic requirements (backward
could drop to 58% in case of poor EV characteristics of design and modeling). Modeling can also help identify the most influential factors
auxiliary loads. As a general rule, energy consumed in activities other on energy consumption. Electric vehicle models range from macroscopic
than propelling the electric vehicle should be reduced as much as models offering a simple way to evaluate energy consumption using few
possible in order not to injure its driving range. The energy consumption input parameters to more sophisticated microscopic models providing
of any typical vehicle is being greatly influenced by its powertrain higher predictive precision with mesoscopic models somewhere in be­
technology, traction ratio and regenerative braking magnitude. The tween. The equivalent circuit model is widely utilized in battery and
energy consumption of a typical electric vehicle can be further studied electric vehicle simulations. It can provide multiple levels of accuracy in
according to the factors that may influence the on-board consumption of battery modeling and real-time monitoring and control. The enhanced
various systems. These factors include technical aspects of the electric self-correcting model can be used to simulate battery dynamic perfor­
vehicle, travel details as well as artificial and natural environments. The mance with hysteresis voltages taken into account. The Randles circuit
BTMS and HVAC systems were found to significantly influence the en­ can be used to simulate the electrochemical response of a battery cell.
ergy consumption of the electric vehicle by impacting the cooling/ Digital environments that can be used to program such simulation tools
heating loads for the battery pack and the driving cabin which in turn include a variety of commercial and open-source options such as
can be influenced by weather conditions and working mode. For any MATLAB and Modelica. It is through such options that electric vehicle
type of vehicle, cabin cooling serves some additional safety purposes like simulation tools such as ADVISOR and V-ELPH have been developed.
defogging and deicing besides providing a comfortable driving envi­ Simulation of the ECM model initially requires computing all model
ronment. The electric vehicle HVAC system that is based on the vapor parameter values. It is possible to perform such estimation by using
compression cycle (VCC) is quite comparable to that of other vehicle experimental data collected when exciting an individual battery cell
types with some additional features to provide the required heating due according to one of a number of pre-defined battery testing procedures.
to lack of waste heat. VCC systems utilizing R-134a for ICE vehicles can However, later simulation of an electric vehicle loading profile would
be adapted for electric vehicles with the required heating be provided require the use of drive cycles to provide an analogues performance to
through the use of a designated heater (PTC or fuel heater) or a that of an EV.
reversible heat pump configuration which can facilitate direct transition
into electric vehicles. Designated heater systems utilizing fuel heaters
are not preferable for electric vehicles and PTC heaters were found to Declaration of competing interest
result in serious losses in driving range. Heat pump systems can improve
driving range compared to PTC systems but were found to be challenged The authors declare that they have no known competing financial
by ice formation on heat exchanger at low temperatures resulting in interests or personal relationships that could have appeared to influence
range loss which can be balanced by the incorporation of some addi­ the work reported in this paper.
tional heat sources. Cabin pre-conditioning can reduce transient power
requirements eventually increasing the driving range. Thermal regula­ Acknowledgments
tion of the battery pack is very critical for electric vehicles. It aims to
keep the battery pack within an optimal operating range and avoid Financial support received from the China National Key R&D Project
safety concerns that can lead to some irreversible consequences. Battery (2018YFB0905300, 2018YFB0905303), the Guangdong Science and
thermal management systems are designed from a variety of conven­ Technology Department (2017B010120003, 2015A030308019,
tional and emerging thermal management strategies which can be 2016A030313172), and the Guangzhou Scientific and Technological
classified according to thermal cycle, working fluid and power con­ Development Plan (201804020020) is gratefully acknowledged.
sumption. Passive systems such as heat pipes and phase change mate­
rials require less energy input but are less efficient. However, such References
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