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Geotech Geol Eng (2009) 27:43–51

DOI 10.1007/s10706-008-9210-7

ORIGINAL PAPER

Permeability of Municipal Solid Waste in Bioreactor


Landfill with Degradation
M. S. Hossain Æ K. K. Penmethsa Æ L. Hoyos

Received: 28 May 2007 / Accepted: 20 April 2008 / Published online: 15 May 2008
Ó Springer Science+Business Media B.V. 2008

Abstract Bioreactor landfills are operated for rapid A series of constant head permeability tests were
stabilization of waste, increased landfill gas genera- performed on the samples generated in laboratory
tion for cost-effective energy recovery, gain in scale bioreactor landfills to determine variation of
landfill space, enhanced leachate treatment, and permeability of MSW with degradation. The test
reduced post closure maintenance period. The fun- results indicated that the permeability of MSW in
damental process of waste stabilization in bioreactor bioreactor landfills decreases with decomposition.
landfill is recirculation of generated leachate back Based on the test results, the permeability of MSW at
into the landfills. This creates a favorable environ- the first phase of degradation was estimated as
ment for rapid microbial decomposition of the 0.0088 cm/s at density 700 kg/m3. However, with
biodegradable solid waste. In order to better estimate degradation, permeability decreased to 0.0013 cm/s
the generated leachate and design of leachate recir- at the same density, for MSW at Phase IV.
culation system, clear understanding of the
permeability of the Municipal Solid Waste (MSW) Keywords Bioreactor landfill  Permeability 
with degradation and the factors influencing the Decomposition  Solid waste  Density
permeability is necessary. The objective of the paper
is to determine the changes in hydraulic properties of
MSW in bioreactor landfill with time and decompo-
sition. Four small-scale bioreactor landfills were built 1 Introduction
in laboratory and samples were prepared to represent
each phase of decomposition. Then, the changes in A conventional landfill is designed to minimize
hydraulic properties of MSW in bioreactor landfill moisture intrusion into the landfill. The waste
with time and decomposition were determined. remains almost dry making the waste decomposition
a long-term process. Therefore, due to this long-term
waste decomposition process, settlement and gas
production continues for a long time, which requires
M. S. Hossain (&)  K. K. Penmethsa  L. Hoyos a long-term post closure-monitoring period. To
Department of Civil and Environmental Engineering,
University of Texas at Arlington, Arlington, TX 76019,
overcome these difficulties a new technology was
USA developed to accelerate the rate of waste decompo-
e-mail: hossain@uta.edu sition and stabilization known as bioreactor landfill.
The fundamental process of waste stabilization in
L. Hoyos
e-mail: hoyos@uta.edu
bioreactor landfill is recirculation of generated

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leachate into the landfills. Leachate recirculation the permeability in MSW are density, particle size,
plays an important role in successful operation of the porosity, material type, degree of saturation, stage of
bioreactor landfill. In favorable environmental con- decomposition, and depth within the landfill. Density
ditions, biological stabilization of the waste in a of the refuse is dependent on the refuse composition,
bioreactor landfill is expected to be much faster the amount and degree of compaction, surface cover,
compared to the conventional landfill. There are over burden pressure and moisture content of the
many advantages of leachate recirculation including refuse during compaction. During the regular land
(1) settlement before placement of the final cover filling period, the refuse is compacted in thin lifts
which decreases the risk of damage to the final cover; leading to horizontal stratification within the landfill.
(2) increased effective refuse density and landfill This might result in greater horizontal permeability of
capacity; (3) reduced leachate treatment costs; (4) the waste than the vertical permeability. In addition
increased rates of gas production; and (5) accelerated to the particle size, the application of daily and
refuse decomposition shortening the regulated post intermediate soil covers leads to anisotropy and
closure monitoring period and reducing the overall heterogeneity within a landfill (Powrie and Beaven
cost of the landfill (Barlaz et al. 1990; Reinhart and 1999; Hyder and Khire 2004). Hence, along with the
Townsend 1998; Reinhart et al. 2002). physical properties of the solid waste, various other
Permeability of Municipal Solid Waste (MSW) in factors like refuse placement and amount of com-
a bioreactor landfill is an important parameter to paction, properties of cover soil, depth of landfill
determine the recirculation rate and overall perfor- contribute to the behavior of MSW in a landfill.
mance of landfill. In order to better estimate the Moisture usually tends to flow through the large
generated leachate and design of leachate recircula- pores, leading to flow channeling. Oweis and Khera
tion system, clear understanding of the permeability (1990) found that channeling results in the downward
of the MSW and the factors influencing the perme- movement of leachate through interconnected pores
ability is necessary. at rates faster than the uniform flow under gravity.
The objective of the current study is to prepare This variation in flow results in non-uniform leachate
MSW samples at different stages of degradation and recirculation resulting in non-uniform biodegradation
to determine the permeability of MSW as a function leading to differential settlements (Hyder and Khire
of degree of decomposition. Also, the influence of 2004).
density and voids ratio on the permeability of MSW In a landfill, as depth increases, effective stress on
is investigated and presented in this paper. MSW at the solid waste increases. Increase in the effective
different stages of degradation is generated in four stress increases the waste density (Powrie and Beaven
laboratory scale bioreactors with leachate recircula- 1999). Blieker et al. (1993), from his study on Brock
tion under controlled conditions. The stages of west landfill, indicated difficulties in drilling with the
decomposition were determined based on the gas increase in depth due to the probable increase in
composition, gas production rate pH and volatile density which supports the assumption of increase in
organic content (VOC). Constant head permeability density with depth. Based on the field infiltration
tests were performed on the remolded samples from tests, Ettala (1987) indicated a variability of coeffi-
the reactors to determine the variation of permeability cient of permeability in between and within the
with degradation. Also, tests were repeated at three landfill indicating the heterogeneity of MSW in
densities for samples at each phase of decomposition landfills. Chen et al. (1995) studied the variation in
to determine the influence of overburden pressure or permeability with density of the samples and hydrau-
self weight on permeability. lic gradient and indicated a decrease in permeability
with time. Constant head tests were conducted on test
columns at densities 160 kg/m3, 320 kg/m3, and
2 Background 480 kg/m3. The permeability reduced from
9.6 9 10-2 cm/s to 4.7 9 10-5 cm/s when com-
Permeability is a property of material which permits pacted to densities 160–480 kg/m3, respectively and
the passage of any fluid through its interconnecting no significant influence were observed due to the
pore spaces. The physical properties that influence variation in hydraulic gradient. Powrie et al. (2005)

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Geotech Geol Eng (2009) 27:43–51 45

indicated decrease in permeability with increase in converted to CH4 and CO2; the pH increases; and
effective stress, density and decrease in porosity. cellulose and hemicellulose decomposition begin. In
Korman et al. (1987) indicated higher values of the decelerated methane production phase, the meth-
permeability of MSW for old refuse compared to ane production rate decreases, carboxylic acids are
fresh wastes, which might be attributed to the depleted and there is an increase in the rate of
heterogeneity and reconstitution of the sample in cellulose plus hemicellulose hydrolysis. While acid
the laboratory. However, there is a limited availabil- utilization limits methane production in Phases 2 and
ity of literature on variation of permeability with 3, cellulose and hemicellulose hydrolysis limits
degradation. With degradation the particle size of the methane production in Phase 4. In a laboratory scale
degradable constituent in MSW was expected to simulation, 70–75% of the initial cellulose and
decrease which might significantly influence the hemicellulose were converted to CH4 and CO2
permeability of MSW. In this paper an attempt is (Barlaz et al. 1989). In bioreactor landfills, the
made to determine the permeability of MSW with increased moisture enhances progression of the refuse
stage of decomposition and determine the influence to Phases 3 and 4 relative to a control landfill. Gas
of percentage finer fraction (less than US sieve #200) production from landfills is typically modeled using
and density on the permeability of MSW. the US EPA Landgem model (1998) as follows:
G ¼ WL0 kekt ð2Þ
3 Refuse Biodegradation where, G = annual methane generation for a specific
year (t) (m3CH4/year); W = mass of waste buried
A complex series of chemical and biological reac- annually (ton/year); L0 = methane potential (m3CH4/
tions is initiated with the burial of refuse in a landfill. t of waste): t = time after initial waste placement
Refuse decomposition has been described in an (year); and k = first order decay rate constant
aerobic phase, an anaerobic acid phase, an acceler- (1/year).
ated methane production phase, and a decelerated
methane production phase (Barlaz et al. 1989). The 3.1 Experimental Design
conversion of cellulose to methane (CH4) and carbon
dioxide (CO2) is described by Eq. 1. Refuse samples representing various stages of
decomposition were generated in laboratory scale
ðC6 H10 O5 Þn þ n H2 O ! 3n CH4 þ 3n CO2 ð1Þ
reactors that were operated under the conditions to
In the aerobic phase (Phase 1), the oxygen simulate the decomposition in bioreactor landfills.
entrained in the refuse at burial is consumed and The stages of decomposition were determined based
there is no mechanism for its replenishment based on on the gas production rate and composition, pH, and
conventional landfill practice. CO2 will be the major by volatile solids composition. Reactors were
gaseous product and there will be little to no cellulose destructively sampled to obtain samples at the
and hemicellulose biodegradation. In the anaerobic anaerobic acid phase, accelerated methane phase,
acid phase (Phase 2), carboxylic acids (acetic, early and decelerated methane phase, respectively.
propionic, butyric) accumulate and the pH decreases. Initially, particle size distribution was completed to
These acids accumulate because of an imbalance determine the changes in particle size and possibly
between the various groups of bacteria required to increase of finer particles with decomposition of
convert refuse to methane. Phase 2 is characterized MSW. Then, constant head permeability tests were
by acidic leachate, little gas production, and little to performed on the remolded samples collected from
no cellulose and hemicellulose decomposition the reactors to determine the changes in permeability
because environmental conditions are not suitable with degradation. The tests were repeated at three
for the bacteria required for refuse decomposition. In densities to determine the influence of overburden
the accelerated methane production phase (Phase 3), stress on permeability. Based on the literature review
suitable environmental conditions develop and the the unit weight of MSW ranged between 20 pcf
methane production rate increases to some maximum (302 kg/m3) and 80 pcf (1281 kg/m3) depending on
value; the accumulated carboxylic acids are the compaction effort. Therefore for the current

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study, tests were performed at 40 pcf (640.73 kg/m3), weight. The percent weight loss from ignition yielded
50 pcf (800.92 kg/m3) and 60 pcf (961.10 kg/m3). the total amount of volatile matter.

3.2 Preparation of MSW Samples at Different


Stages of Decomposition 4 Geotechnical Testing Procedures

Municipal solid waste (MSW) samples were col- 4.1 Grain Size Distribution
lected from a transfer station in Burlington, Texas.
The standard collection procedure was followed for Considering the wide range of particle size and the
obtaining a representative well-mixed sample. Ini- nature of the waste, wet sieve analysis was con-
tially, physical characterization of the waste, ducted. The degraded MSW particles adhere to each
including visual inspection of refuse composition other when dried and conventional dry analysis may
was completed. Based on the physical characteristics, not give accurate results. For fraction passing US
the average paper, plastic and food waste was sieve No. 200 hydrometer analysis was conducted.
determined as 56, 13 and 16%, respectively. The wet sieve analysis on MSW samples at different
Four 16-l reactors filled with MSW to prepare stages of decomposition was conducted in accordance
samples at different stages of decomposition. Suffi- with standard test method of particle size analysis of
cient quantity of moisture was added to adjust the soils (ASTM D422-63).
moisture content to 55% (wet weight basis), and to
generate a leachate of 1.5 l. Reactors were operated 4.2 Permeability
under conditions designated to simulate a bioreactor
including: (a) the addition of sufficient moisture to The coefficient of permeability of the MSW samples
induce leachate production; (b) leachate recircula- was measured at different phases of decomposition
tion; and (c) the addition of an inoculum of and densities. Tests were also conducted to determine
anerobically digested sewage sludge. The leachate the influence of percentage finer fraction (particle
was neutralized with potassium hydroxide and sulfu- size less than US sieve # 200) and density on the
ric acid for acidic and alkaline conditions as permeability of MSW. The MSW particles are much
necessary and recycled 4 days a week. The neutral- thinner and flatter than the soil particles and the flow
ization of generated leachate was done to accelerate in waste might be through inter particle and intra
the decomposition process. All reactors were main- particle voids, hence the general principles applicable
tained at a room temperature of 22–29°C. for soils may not be applicable to MSW. However,
The reactors were dismantled and destructively due to the lack of standard test procedure for
sampled at each phase of decomposition. The stage of determination of permeability of MSW, the standard
decomposition was determined based on the gas test procedure for determination of permeability of
production rate and composition, pH, and by presence the granular soils (ASTM D 2434-68) is adopted for
of volatile solids. Gas was collected in five-layer gas the current work. The test setup consists of an acrylic
bags. The volume of gas was measured by pumping it cylinder with inside diameter of 15.24 cm (6 inches)
out through a standard pump (which pumps at a rate and a height of 24 cm. The remolded sample from the
of 0.5 l/min). Methane gas concentration was mea- reactors was utilized for testing. Particles greater than
sured using a gas chromatograph equipped with a 3 inches (half the diameter of test cylinders) were
thermal conductivity detector. The volatile solids shredded to reduce the boundary affects. Shredding
were determined in accordance with Standard Meth- may affect the permeability of MSW. However, this
ods APHA Method 2440-E. Samples were dried at is a common practice to shred bigger particles to
105°C to a constant weight and held in a desiccator. smaller pieces to accommodate them in smaller
Approximately 100 g of dried sample were then equipments during testing. The required densities
placed in ceramic dish and inserted into a muffle were obtained by changing the packing of sample by
furnace at 550°C for 20 min. Samples were removed maintaining the constant height of the sample. The
and allowed to cool in a desiccator to a constant weight of the sample was predetermined by

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Geotech Geol Eng (2009) 27:43–51 47

multiplying the volume of the sample with the 5.2 Geotechnical Testing Results
required density.
5.2.1 Visual Inspection and Particle Size Analysis

5 Test Results Based on visual inspection there was no observable


disintegration of paper and plastic, in Phase I and
5.1 Refuse Decomposition Results Phase II of degradation. Numbers on the paper were
clearly visible even after the second phase of
Methane production rates and the pH of the generated disintegration. Chunks of paper and textile were
leachate are presented in Figs. 1 and 2, respectively. observed in phase III implying a partial disintegration
The anaerobic digester sludge and leachate neutral- of paper and textile. However, paper was completely
ization with recirculation enhanced the refuse disintegrated and was in the form of paste at the end
decomposition. Each of these reactors was destruc- of phase IV. Figure 3 shows the disintegrated paper
tively sampled on days 25, 106, 225, and 253. Based in each phase of decomposition. Wet sieve analysis
on the methane production rate in Fig. 1, and pH data on the fraction retained on US sieve No. 200
in Fig. 2, at day 25 sample (Reactor 1-1) was in indicated particle disintegration as the stage of
anaerobic acid phase. At day 106 (Reactor 1-3) when decomposition progresses. Figure 4 presents the
the rate of methane production was at peak and pH particle size distribution curves for municipal solid
was about neutral, the sample was in accelerated waste at different stages of decomposition.
methane production phase. And at day 225 (Reactor Particle size distribution curves indicated an
1-4) and 253 (Reactor 1-2), as presented in Figs. 1 increase in percent of fraction passing US sieve No.
and 2, samples were in decelerated methane produc- 200 with degradation. The MSW particles were
tion phases. relatively larger during the initial stages of degrada-
The composition of solids removed from each of tion and with degradation, the matrix structure of
the reactor is presented in Table 1. Leachate recircu- paper, textile and other degradable constituents were
lation had a significant effect on the degradation of broken down into smaller particles. This resulted in
the waste. The accelerated degradation is also an overall increase in percentage of finer fraction
indicated by the significant decrease in degradable passing US sieve 200. The percentage of finer
constituents. The percent change (utilized) in volatile particles (US sieve No. 200) for Phase I is only
solids increased from 0.91% in Phase I to 39.24 % in 10% when compared to 39% in Phase IV. The
final phase. At the same time the cumulative methane increase in finer fraction with degradation is about 2–
production increased as the waste gets degraded and 3 times, which is expected to change the hydraulic
VOC is converted into gases. behavior of MSW in a landfill.

Fig. 1 Rate of gas


0.7
production from reactors at
each phase of Reactor 1-1 Reactor 1-2
0.6
decomposition Phase II
Methane Yield, L/lb/day

Reactor 1-3 Reactor 1-4


0.5

0.4

0.3 Phase III


Phase I
0.2

0.1 Phase IV

0.0
0 50 100 150 200 250
Days

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Fig. 2 pH of generated 9.5


leachate from the bioreactor
cells 9

8.5 Phase IV
Phase III
8

7.5

pH
7
Phase II
6.5 Reactor 1-1 Reactor 1-2

6 Reactor 1-3 Reactor 1-4

5.5
Phase
5
0 50 100 150 200 250
Time, days

5.2.2 Permeability with Degradation


Table 1 Methane production and sample composition in
sampled
Permeability tests were conducted on MSW samples at
Phase Time of Cumulative methane % Change in
reactor production (l) volatile solids
each phase of degradation at three different densities.
operation Permeability of municipal solid waste was in the
order of 10-2 cm/s after the first phase of disintegration
I 25 23.49 0.91 and decreased to the order of 10-4 cm/s at the final
II 106 195.03 1.40 phase of degradation. Figure 5 presents the change in
III 225 487.73 12.88 permeability of MSW at each phase of degradation at
IV 253 515.41 39.24 different densities (700 kg/m3, 800 kg/m3, 900 kg/m3).
Based on grain size distribution results, there is an
Fig. 3 Disintegration of
paper with degradation

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Geotech Geol Eng (2009) 27:43–51 49

1000 3.2

900 2.8

Density (kg/m3)

Void Ratio
800 2.4

700 2

600 1.6
0 0.002 0.004 0.006 0.008 0.0010 0.0012
Permeability (cm/s)
Density - Phase I Density - Phase II Density - Phase III
Density - Phase IV Void Ratio - Phase I Void Ratio - Phase II
Void Ratio - Phase III Void Ratio - Phase IV

Fig 4 Particle size distribution of MSW with degradation Fig. 6 Permeability with density and void ratio

increase in percentage finer contents with degradation, of sample the voids ratio decreases, thus, decreasing
and accordingly pore size, geometry and continuity of the permeability. Permeability decreased with
the pore space are expected to change. Figure 5 also decrease in voids ratio of MSW. The possible reason
presents the variation in permeability with percentage might be due to the decrease in size of the flow
of particles passing US sieve # 200. Increase in density channels with the decrease in voids ratio, resulted in
resulted in decrease in permeability. Chen (1995) from an overall reduction of permeability.
his study on the temporal variation of permeability of
MSW, indicated a decrease in permeability with time.
5.2.4 Permeability with Density
5.2.3 Permeability with Voids Ratio
The permeability of MSW with density is presented
Moisture transport in MSW are expected to be in Fig. 6. The test results showed that the permeabil-
through the inter particle and intra particle voids ity decreased with increasing density at each phase of
depending on their size and continuity. The changes decomposition. In order to study the variation in
in permeability of the MSW at Phases I, II, III and IV permeability of MSW at each phase of degradation at
of degradation with the calculated void ratio is a given density, test results were interpolated at
presented in Fig. 6. With the increase in the density 700 kg/m3, 800 kg/m3, and 900 kg/m3. It was
observed that the coefficient of permeability
1.00E-02 decreases with the increase in density at all stages
Phase I
9.00E-03 of degradation. Blieker et al. (1993) reported diffi-
Coefficient of permeability (cm/s)

8.00E-03 culties in drilling with depth, which implies an


Phase II
7.00E-03 increase in density of MSW with depth. Oweis and
700
6.00E-03 800
Khera (1990); Blieker et al. (1993); and Powrie et al.
5.00E-03 900 (2005) indicated a decrease in permeability with
4.00E-03 increase in density. The experimental results from
3.00E-03 Phase III current study conform to the existing research.
2.00E-03 Phase IV
Figure 7 gives the comparison of results obtained
1.00E-03
in the current research with permeability obtained by
0.00E+00
other researchers (Powrie et al. 2005; Gabr 1995;
0 10 15 20 25 30 35 40 45 50 Jang et al. 2002; Landva and Clark 1986). The
Percentage finer
permeability results when plotted against their corre-
Fig. 5 Permeability with the percentage of particles passing sponding densities gave an agreeable relation with
US Sieve No. 200 the test results of these researchers.

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50 Geotech Geol Eng (2009) 27:43–51

1.0E+00 No. 200 occupying the pore spaces thus decreas-


ing the size of the flow path.
1.0E+01
3. Density of the sample is observed to have
significant affect on the permeability of MSW.
1.0E+02
Permeability decreased with the increase in
Permeability (cm/s)

1.0E+03
density. The possible reason for the decrease
might be due to the reduction in pore size and
1.0E+04 change in geometry and continuity of pores
resulting in decrease in area of flow.
1.0E+05 4. There is a decrease in voids ratio with increase in
density, thus, resulting in decrease in permeability.
1.0E+06
500 700 900 1100 1300
Therefore, the variation in permeability with time and
Density(kg/m3)
Current Study Gabr (1995) Jang et al. (2002)
landfill depth should be considered during design of
Powrie et al. (2005) Landva and Clark (1986) landfill rather than considering an average value for
the entire landfill height and operation period.
Fig. 7 Comparison of permeability values obtained in the
current study with others

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6 Summary and Conclusions
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