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ACTIVITY-1
Performing and observing the following reactions and classifying them into:
A. Combination reaction
B. Decomposition reaction
C. Displacement reaction
D. Double displacement reaction
(i) Action of water on quicklime
(ii) Action of heat on ferrous sulphate crystals
(iii) Iron nails kept in copper sulphate solution
(iv) Reaction between sodium sulphate and barium chloride solutions.
Procedure:
Observations:
Inferences:
Quick lime reacts vigorously with water to produce slaked lime releasing a large amount
of heat. So the reaction is highly exothermic.
Slaked lime is only slightly soluble in water, so it forms a suspension of slaked lime in
water.
The clear solution obtained after the suspension settles is called lime water.
Exhaled air contains CO2 which turns lime water milky.
Calcium oxide and water react to form only a single product, calcium hydroxide. So the
reaction is a combination reaction.
Procedure;
Take about 2g of ferrous sulphate crystals in a dry boiling tube and note the colour of the
crystals.
Hold the boiling tube with a test tube holder and heat the boiling tube over the flame of a
burner.
Smell the gas being emitted.
Observe the colour of the crystals after heating.
Observations:
Inference:
Ferrous sulphate crystals contain water molecules (FeSO 4. 7H2O). On heating, ferrous
sulphate crystals lose water and anhydrous ferrous sulphate (FeSO 4) is formed. So their
colour changes from light green to white.
On further heating, anhydrous ferrous sulphate decomposes to form ferric oxide (Fe 2O3),
sulphur dioxide (SO2) and sulphur trioxide (SO3). So, the gas emitted smells like burning
sulphur.
In this reaction, the single reactant FeSO 4 decomposes to form three different products.
So, the reaction is a decomposition reaction.
Precautions:
1. Do not point the mouth of the boiling tube at your neighbours or yourself.
2. Waft gases emitted from ferrous sulphate on heating gently towards your nose holding
the test tube at a distance. The gases SO 2 and SO3 are very harmful, so do not take a
deep breath when smelling the odour of the gases.
3. Always use a test tube holder while heating the test tube.
Clean two iron nails of sufficient size by rubbing them with sand paper so that their colour
appears greyish.
Take sufficient quantity of copper sulphate solution in two different test tubes.
Clamp the test tubes to different stands.
Tie one nail using a thread and hang in one test tube. Tie the other end of the thread to
the stand.
Keep the other nail in a Petri dish for comparison after the experiment.
Keep the two test tubes undisturbed for about 15 minutes.
Remove the iron nail immersed in the copper sulphate solution and put it in the Petridish.
Observations:
There is a brown coating on the iron nail dipped in the copper sulphate solution. Whereas
the iron nail placed in the Petri dish shows the grayish colour of iron.
The colour of the solution of copper sulphate in which the iron nail was dipped changes
to light greenish, whereas the colour of copper sulphate solution in the other test tube
does not change.
Inference:
The brown coating on the iron nail shows that copper is deposited on the iron nail by
displacing iron.
The greenish colour of the solution in the test tube shows that Fe 2+ ions are present in the
solution.
This shows that iron is more reactive than copper, as Fe 2+ ions have displaced Cu2+ ions
from copper sulphate solution.
This is a single displacement reaction in which copper has been displaced from iron from
copper sulphate solution.
Precautions:
1. Clean the iron nails by rubbing with sand paper to remove rust, dust or greasy surface.
2. Keep the control experiment to compare the colour of iron nails and copper sulphate
solution.
3. Avoid touching copper sulphate solution or nail dipped in copper sulphate solution as
copper sulphate is poisonous.
Procedure:
Inference:
When sodium sulphate chemically reacts with barium chloride in the form of their
aqueous solutions, white precipitate of barium sulphate appears. This confirms the
presence of sulphate (SO42-) ions.
It is a double displacement reaction in which sulphate ions are displaced by chloride ions
and chloride ions are displaced by sulphate ions.
Precautions:
ACTIVITY-2
Objective
To study the properties of acids and bases (HCl and NaOH) by their reaction with:
Procedure:
The evolution of hydrogen gas can be seen by conducting the following experiments.
Precautions:
1. Take small quantities of zinc, HCl and NaOH for their reaction, otherwise large amount of
hydrogen produced may cause explosion.
2. To hydrogen burning take a fine jet.
3. Add HCl to Na2CO3, only when apparatus is made carefully airtight.
4. NaOH and HCl are injurious, handle these chemicals carefully.