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Aim: To carry out the following chemical reactions and classify them as physical or chemical changes:
(i) Iron nail and copper sulphate solution in water (ii) burning of magnesium ribbon in air (iii)Zinc with
dilute sulphuric acid (iv) Heating of copper sulphate (v) sodium sulphate solution and barium chloride
in the form of their solutions in water.
Materials Required : a rack of clean test tube, fire tongs, Bunsen burner, test tube holder, iron nail,
copper sulphate solution, 10cm long magnesium ribbon, a small piece of granulated zinc, dilute
sulphuric acid , sodium sulphate solution, barium chloride solution.
Procedure :
Observations :
copper sulphate solution is blue in colour. On placing the iron nail in it for 5 minutes or more,
the colour of the solution starts changing from blue to greenish blue and finally light green.
The iron nail gets coated with brownish red deposit of copper metal. Iron is more reactive than
copper and it displaces Cu from 𝐶𝑢𝑆𝑂4 solution, it shows displacement reaction.
Take a small piece of magnesium ribbon and clean it by rubbing with sandpaper then hold it with a pair
of tongs and burn on a Bunsen burner.
Observations : It burns with a dazzling white flame to forms white powdery mass of magnesium oxide.
Add MgO to a petri dish containing distilled water and test it with a litmus paper. Red litmus turns blue.
𝑀𝑔(𝑂𝐻)2 is basic in nature, it shows combination reaction.
∆
𝟐𝑴𝒈(𝒔) + 𝑶𝟐 (𝒈) → 𝟐𝑴𝒈 𝑶 (𝒔) + 𝑯𝒆𝒂𝒕
Take 5 mL of dil. 𝐻2 𝑆𝑂4 solution in a test tube and add a zinc granules in it and observe it.
Observations : Reaction takes place, tiny bubbles and a gas is released that is hydrogen gas. Test
hydrogen gas by bringing a burning matchstick near the mouth of the test tube. Hydrogen gas burns with
a pop sound. It is a chemical change and shows displacement reaction with heat evolving out.
Heat few copper sulphate crystals in a dry test tube on a Bunsen burner and observe it.
Observations : Water vapour comes out and condenses near the mouth of the test tube, Blue colour of
crystals fades and turns into white powder. 𝐶𝑢𝑆𝑂4.5𝐻2 𝑂 loses water of crystallisation. After that take
small portion of white powder obtained in above reaction. Add water to it. White solid powder will turn
blue. Copper sulphate is hydrated.
(V) Experiment with sodium sulphate solution and barium chloride solution
Take 5 mL solution of sodium sulphate and 5 mL barium chloride and mix it in a test tube. Then allow
it to stand for some time.
Observations : A white precipitate is formed on keeping the test tube on standing for some time, two
layers of barium sulphate (white ppt. ) and colourless sodium chloride is obtained. It is a chemical
change and shows double displacement reaction.