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INDEX
* Basic Reflections 01 - 13
Key 85 - 86
CHEMISTRY PART - I IX CLASS - CBSE
BASIC REFLECTIONS
Atomic number : The atomic number of any element is defined as the number of protons present in
the nucleus. It is denoted by Z.
Examples :
1) The number of protons in hydrogen nucleus is one. Therefore the atomic number is one.
2) The number of protons in Helium nucleus is two. Therefore the atomic number is two.
Mass number : Mass number of an element is the sum of the protons and neutrons in its nucleus. It
is denoted by ‘A’
A=Z+n
Representation of an element : An element ‘X’ with atomic number ‘Z’ and mass number ‘A’ can be
represented as X AZ .
Isotopes : The atoms of the same element which have the same atomic number but different mass
number are called isotopes.
Examples : 1) H11, H12 , H13 2) Cl1735 , Cl1737 3) U 92235 , U 92238
Isotopes differ in number of neutrons. They have same chemical properties but differ in physical and
radioactive properties.
Isobars : The atoms of different elements which have the same mass number but different atomic
numbers are called isobars.
Examples : 1) C614 & N 714 2) Ar1840 , Ca20
40
Isobars differ in number of electrons, protons and neutrons. They differ in chemical, physical and
radioactive properties
Isotones : Isotones are the atoms of different elements which have the same number of neutrons.
Examples : 1) Si1430 , P1531 , S1632 2) C 614 and O816 3) Na1123 and Mg1224
They differ in physical and chemical properties.
Isodiaphers : The atoms of different elements which have same A - 2Z number are called Isodiaphers.
Examples : 11 Na 23 , 9 F 19
Works of Rutherford and Neils Bohr confirmed that an atom consists of three sub-atomic particles,
i.e. electrons, protons and neutrons.
It has been established that the central core of an atom consists of protons and neutrons and is commonly
called nucleus. The electrons revolve around the nucleus.
Neils Bohr suggested that the electrons revolving around nucleus are confined to certain fixed orbits
called shells or energy levels.
4 N shell
3
2
M shell
1 L shell
M shell
+ Positively Charged Nucles
K
L
M
N
Ø Electronic configuration : The distribution of electrons into various shells or energy levels of an
atom is called electronic configuration.
Ø Bohr–Bury scheme of Electronic configuration :
a) The maximum number of electrons which can be present in any shell of an atom is given by the
formula 2n2, where n is the shell number as counted from nucleus. Thus, according to above
formula:
Maximum no.of electrons in K – shell = 2n2 = 2(1)2 = 2.
Maximum no.of electrons in L – shell = 2n2 = 2(2)2 = 8.
Maximum no.of electrons in M – shell = 2n2 = 2(3)2 = 18.
Maximum no.of electrons in N – shell = 2n2 = 2(4)2 = 32.
b) The outermost shell (ultimate shell) of an atom cannot have more than 8 electrons.
c) The penultimate shell of any atom cannot have more than 18 electrons.
d) It is not necessary for a given shell to complete itself, before another shell starts forming. As a
rule, the new shell is formed as soon as the outermost shell attains eight electrons.
e) An atom becomes stable (i.e., it stops reacting chemically with other elements), when its outer
most shell has eight electrons, or it has only one shell containing 2-electrons.
Knowing the mass number and atomic number of an element,we can easily represent its geometric
atomic structure. Let us take the structure of some elements
24
For example : Mg.
12
Ø Valency of Non-Metals :
Valency of non-metals = (8 - number of valence electrons)
Generally non-metals possess 4 or 5 or 6 or 7 valence electrons.
Thus their valencies are 8-4, 8-5, 8-6, 8-7 i.e., 4, 3, 2 and 1 respectively.
Example :
Element : C N O F
Atomic number : 6 7 8 9
Electronic configuration : 2,4 2,5 2,6 2,7
Valency : 8- 4 = 4 8-5=3 8-6=2 8-7=1
Example : CH 4 NH3 H 2O HF
VA ns2 np3 X
H He
Li Be B C N O F Ne
Na Mg Al Si P S Cl Ar
IONS
Ø Definition :- Charged species which are formed by losing (or) gaining electrons are known as “Ions”
Ions may contain a single atom or a group of atoms.
Ø TYPES OF IONS :
Ions are two types based on the nature of the charge carried by them.
a) Electropositive ion (or) Cation:
An ion having a positive charge on it is known as an electropositive ion or a cation.
Example: K+, Ag+, Pb+2 etc.
b) Electronegative ion (or) Anion:
The ion having a negative charge on it is known as an electronegative ion or an anion.
Example : Cl- , O-2 , SO4-2 etc.
Ø Classification of ions:
Ions can be classified as follows:
a) Simple ion : It is an ion which contains one or more atoms of the same element.
Example: Ag+ (silver ion), S-2 (Sulphide ion), O-2 (Oxide ion), O2-2 (Peroxide ion).
b) Compound ion : It is an ion which consists of two or more atoms of different elements to
form a single unit.
Example : 1) SO4-2 (Sulphate ion)
It behaves as a single unit and is composed of one atom of sulphur and
four atoms of oxygen.
2) Nitrate ion (NO3-),
3) Phosphate ion (PO4-3) etc.
Rubidium Rb+ +1
Copper Cu+ (Cuprous) +1
Silver Ag + +1
Gold Au+ [Aurous or Gold (1)] +1
Mercury Hg+ [Mercurous or Mercury (1)] +1
Ammonium NH 4+ +1
Divalent
Beryllium Be+2 +2
Magnesium Mg+2 +2
Calcium Ca+2 +2
Strontium Sr+2 +2
Barium Ba+2 +2
Radium Ra+2 +2
Copper Cu+2 [Cupric (or) Copper (II)] +2
Mercury Hg+2 [Mercuric (or) Mercury(II)] +2
Iron Fe+2 [Ferrous (or) Iron (II)] +2
Chromium Cr+2 [Chromous] +2
Cobalt Co+2 [Cobaltous (or) Cobalt (II)] +2
Nickel Ni+2 +2
Manganese Mn+2 [Manganous (or) Manganese (II)] +2
Cadmium Cd+2 +2
Zinc Zn+2 +2
Lead Pb+2 [Plumbous (or) Lead (II)] +2
Tin Sn+2 [Stannous (or) Tin (II)] +2
Trivalent
Iron Fe+3 [Ferric (or) Iron (III)] +3
Manganese Mn+3 [Manganic (or) Manganese (III)] +3
Aluminium Al+3 +3
Gold Au+3 [Auric (or) Gold (III)] +3
Antimony Sb+3 [Antimonous (or) Antimony (III)] +3
Arsenic As+3 [Arsenous (or) Arsenic (III)] +3
Chromium Cr+3 [Chromic] +3
Cobalt Co+3 [Cobaltic (or) Cobalt (III)] +3
Boron B+3 +3
Tetravalent
Platinum Pt+4 [Platinic (or) Platinum (IV)] +4
Lead Pb+4 [Plumbic (or) Lead (IV)] +4
Tin Sn+4 [Stannic (or) Tin (IV)] +4
Pentavalent
Arsenic As+5 [Arsinic (V)] +5
Antimony Sb+5 [Antimonic (or) Antimony (V)] +5
CHEMICAL FORMULA
Definition : "The chemical formula of a compound is a symbolic representation of its composition".
Importance : “A Chemical formula gives the exact number of atoms of the same or different elements
present in a chemical substance.”
To write chemical formulae, the symbols of elements and the combining capacities of elements are
required.
Note: Here, the combining capacity of an element indicates the number of bonds formed by that
element
Example: Hydrogen Chlorine
Its valency is 1 Its valency is 1
Its combining capacity is 1 Its combining capacity is 1
Number of bonds formed by it is 1 Number of bonds formed by it is 1.
H—Cl
The combining capacity of hydrogen and chlorine is one. So only one bond is formed between H
and Cl .
Symbol Mg Cl
Magnesium chloride (MgCl2)
Valency 2 1
S.No. Name of the salt Formula Cation Anion Formula Frmula
Present Present of Acid of Base
1. Sodium chloride _______ _______ _______ _______ _______
2. Calcium chloride _______ _______ _______ _______ _______
3. Magnesium chloride _______ _______ _______ _______ _______
4. Zinc chloride _______ _______ _______ _______ _______
5. Sodium sulphate _______ _______ _______ _______ _______
6. Potassium sulphate _______ _______ _______ _______ _______
7. Clacium sulphate _______ _______ _______ _______ _______
8. Magnesium sulphate _______ _______ _______ _______ _______
9. Aluminium sulphate _______ _______ _______ _______ _______
10. Zinc sulphate _______ _______ _______ _______ _______
11. Copper sulphate _______ _______ _______ _______ _______
12. Ammonium sulphate _______ _______ _______ _______ _______
13. Sodium nitrate _______ _______ _______ _______ _______
14. Potassium nitrate _______ _______ _______ _______ _______
15. Sodium carbonate _______ _______ _______ _______ _______
16. Zinc carbonate _______ _______ _______ _______ _______
17. Sodium acetate _______ _______ _______ _______ _______
18. Iron sulphate _______ _______ _______ _______ _______
19. Ammonium chloride _______ _______ _______ _______ _______
20. Potassium chloride _______ _______ _______ _______ _______
Compound Formula
1) Barium Nitrate
2) Ammonium Carbonate
3) Barium Peroxide
4) Sodium Silicate
5) Stannic Chloride
Complete the following table :
⎯⎯⎯⎯⎯
Acid radicals
Basic radicals ↓
→ Chloride Nitrate Sulphate Phosphate Carbonate
Sodium
Barium
Calcium
Magnesium
Lead
Postassium