NEET_CHEMISTRY Achiever(E) Minor Test-7 (21-02-2021)

No. of Q = 23 Proof : Final

Composed by : Aadil Proof by : DB Sir
Syllbus Solutions (upto lecture 9) (8), Thermodynamics (5)
Chemical Equilibrium (10) Checked by : DB Sir

Q.46 For the synthesis of ammonia by the reaction

N2 + 3H2  2NH3 in the Haber's process, the
attainment of equilibrium is correctly Q.47
predicted by the curve :
concentration 
The figure shows the change in concentration
of species A and B as a function of time.The
equilibrium constant Kc for the reaction A(g) 
2B(g) is :

(1*)
Molar

0.4 M


0.3 M

Conc.
(1*) Kc > 1
(2) K < 1
(3) K = 1
(4) data insufficient
concentration 

(2)
Sol. A(g)  2B(g)
Molar

t=0 0.3 0
t = teq 0.3 – x 2x
0.3 – 0.2 2x = 0.4


(3)
concentration

KC =
Molar

KC =
KC = 1.6


4)
concentration

Q.48 At 527º C, the reaction given below has K c = 4

Molar

(
Sol. N2(g) + 3H2(g)  2NH3(g) What is the KP for the reaction ?
At : Equilibrium - N2(g) + 3H2(g)  2NH3(g)

(1) 16 × (800 R)2 (2)

(3*) (4) None of these

KC = 4
Sol.

For N2 + 3H2 2NH3 KC =

1
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NEET_CHEMISTRY Achiever(E) Minor Test-7 (21-02-2021)

KP = KC (RT)ng [ ]
KC =
KP =
Q.52 In the reaction X(g) + Y(g) 2Z (g),
2 mole of X, 1 mole of Y and 1 mole of Z are
KP = placed in a 10 litre vessel and allowed to
reach equilibrium. If final concentration of Z is
Q.49 The equilibrium constant for the reaction N2 0.2 M, then Kc for the given reaction is :
(g) + O2 (g)  2NO (g) is 4 × 10 at 200 K. In
–4

presence of a catalyst, equilibrium is attained (1) 1.60 (2)

ten times faster. Therefore, the equilibrium
constant in presence of the catalyst at 200 K
is : (3*) (4) None of these
(1) 40 × 10–4
(2*) 4 × 10–4 Sol. x + y 2z
(3) 4 × 10 –3 2 1 1
(4) difficult to compute without more data
Sol. Value of KC does not depend on catalyst = 0.2

Q.50 For the reaction 2NO2(g) + O2(g) N2O5(g), if 0.15 0.05 0.2
the equilibrium constant is Kp , then the
equilibrium constant for the reaction
2N2O5(g)  4NO2(g) + O2 (g) would be : KC =

Q.53 For the dissociation reaction

(1) (2) N2O4 (g) 2NO2(g), the degree of
dissociation () in terms of KP and total
equilibrium pressure P is %
(3*) (4)

Sol. 2NO2(g) +  Kp (1) (2*)

Reverse

(3) (4) None of these

N2O5(g) 2NO2(g) + 
Sol. N2O4 (g) 2NO2(g)
t=0 1 0
Multiply with 2
t = eq 1– 2
total mole = 1 + 
2N2O5(g) 4NO2(g) + O2(g) 
Q.51 Given [CS2] = 0.120 M, [H2] = 0.10,
[H2S] = 0.20 and [CH4] = 8.40 × 10–5 M for the P.P.
following reaction at 900ºC, at equilibrium
calculate the equilibrium constant (Kc) :
CS2(g) + 4H2 (g)  CH4 (g) + 2H2S(g)
(1) 0.0120 (2) 0.0980
(3*) 0.280 (4) 0.120 Kp =

Sol. KC = KP =
42p + Kp2 = Kp

KC =
2 =

2
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NEET_CHEMISTRY Achiever(E) Minor Test-7 (21-02-2021)
(3*) 68.4 (4) 136.8
Sol.  1 =  2 , C 1 = C2

Q.54 A reversible chemical reaction having two , 5x = 342

reactants in equilibrium. If the concentrations
of the reactants are doubled, then the
equilibrium constant will : x=
(1) also be doubled x = 68.4
(2) be halved
(3) become one-fourth
(4*) remain the same
Q.58 If liquids A and B form an ideal solution :
Q.55 One mole of a compound AB reacts with one
(1) The free energy of mixing is zero
mole of a compound CD according to the
equation, (2) The free energy as well as the entropy of
AB + CD  AD + CB mixing are each zero
When equilibrium had been established it was (3*) The enthalpy of mixing is zero
(4) The entropy of mixing is zero
found that 3/4 mole each of reactant AB and
CD had been converted to AD and CB. There
Q.59 A solution of 17.00 g of a polymer in 200.0 mL
is no change in volume. The equilibrium
of toluene had an osmotic pressure of
constant for the reaction is :
0.036 atm at 27ºC. What is the apparent
formula weight of the polymer ?
(1) (2) (1) 40,000 (2*) 58,000
(3) 80,000 (4) 94,000
(3) (4*) 9
Sol. AB + CD AD + CB Sol.
t=0 1 1 0 0
t = eq 1–x 1–x x x

Q.60 Equal volumes of 0.1M urea and 0.1M glucose

solution are mixed. The mixture will have
(1) lower osmotic pressure
KC = (2) higher osmotic pressure
Q.56 Moles of Na2SO4 to be dissolved in 12 mole (3*) same osmotic pressure
water to lower its vapour pressure by 10 mm (4) None of these
Hg at a temperature at which vapour Sol. i.c
pressure of pure water is 50 mm is :  i = 1 & c = 0.1 for both solution
(1) 1.5 mole (2) 2 mole thus  will remain unchanged .
(3*) 1 mole (4) 3 mole
Q.61 18 g of glucose (C6H12O6) is added to 178.2 g
of water. The vapour pressure of water for
Sol.
this aqueous solution at 100ºC is
(1) 7.60 torr (2) 76.00 torr
(3*) 752.40 torr (4) 759.00 torr

= ,n=1
Sol. = XGlucose
Q.57 A 5% (w/V) solution of cane sugar (molecular
weight = 342) is isotonic with 1% (w/V)
solution of a non-electrolyte substance X. The = 0.01
molecular weight of X is :
(1) 34.2 (2) 171.2

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NEET_CHEMISTRY Achiever(E) Minor Test-7 (21-02-2021)
PS = 752.4 0
(P = 760 torr) (3*)The surroundings are always in
equilibrium with the system
Q.62 At 20ºC, the vapour pressure of benzene is (4) The system changes into the surroundings
75 torr and that of toluene is 22 torr. The spontaneously
partial vapour pressure of benzene at 20ºC
for a solution containing 78 g of benzene and Q.67 A gas absorbs 200 J of heat and expands
46 g of toluene in torr is against the external pressure of 1.5 atm from
(1*) 50 (2) 25 (3) 37.5 (4) 53.5 a volume of 0.5 litre to 1.0 litre, calculate the
change in internal energy :
Sol. (1*) 125 J (2) 225 J
(3) 115 J (4) 155 J

Sol. W = – Pext (V)

PB = 0.667 × 75 = 50 torr = – 1.5 (1 – 0.5)
= – 0.75
Q.63 In a mixture A and B, components show = – 0.75 × 100
negative deviation as = – 75 J
(1) Tb < 0 E = q + W
(2*) Vmix < 0 E = 200 – 75
(3) A – B interaction is weaker than A–A and = 125 J
B–B interaction
(4) None of the above reason is correct Q.68 At constant volume 1150 kcal heat is
Sol. For negative deviation released when following reaction is carried
out at 27ºC.
Tb > 0, V < 0, (A – B) > (A – A) & (B – B)
C7H16() +11O2(g) 7CO2(g) + 8H2O ()
The heat change at constant pressure is :
(1*) –1152.4 Kcal (2) –1116.2 Kcal
Q.64 Identify the state function among the following (3) –1167.4 Kcal (4) –1150.17 Kcal
:
(1) q (2) q – w Sol. C7H16() +11O2(g) 7CO2(g) + 8H2O ()
H = E + ngRT
(3) (4*) q + w
H = –1150 +
= –1152.4 kcal
Q.65 For an isothermal reversible expansion of one
mole of an ideal gas from 1 dm 3 to 4 dm3 at
27ºC, the value of q is :
(1) 57 cal (2*) 831.9 cal
(3) 13 cal (4) 0

Sol. Isothermal reversible

W = – 2.303 nRT log

W = – 2.303 × 1 × 2 × 300 log 4
W = – 831.9 cal
E = q + W
q+W=0
q = – W = + 831.9 cal

Q.66 In thermodynamics, a process is called

reversible when :
(1) Surroundings and system change into
each other
(2) There is no boundary between system
and surroundings

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